Data file Name :C:\Users\Admin\Documents\04110224\TOBACCO EXTACT.

D
Acquired date :06 Nov 2024 10:51
Method Name :D:\MassHunter\GCMS\1\methods\BTEX.M
Sample Name :TOBACCO EXTACT

Compound RT (min) Scan numbeArea (Ab*s Baseline HeAbsolute H Peak WidthStart Time End Time ( Start Heigh
1 3.928 147 26635 8033 15845 0.092 3.877 3.968 7812
2 4.666 276 62611 30632 36388 0.063 4.632 4.695 5756
3 4.787 297 545006 73701 83310 0.303 4.701 5.004 7468
4 6.114 529 35460 13609 19589 0.092 6.08 6.171 5980
5 8.065 870 46350 21197 26064 0.126 8.008 8.134 4867
6 9.776 1169 40890 21524 27309 0.063 9.742 9.805 5785
7 13.478 1816 177122 33329 39429 0.155 13.415 13.57 6100
8 15.103 2100 25199 7890 22621 0.086 15.046 15.132 14731

A b u n d a n ce

TIC: TOBACCO EXTACT.D\ data.ms

4 .7 8 7
80000

75000

70000

65000

60000

55000

50000

45000

40000 1 3 .4 7 8
4 .6 6 6
35000

30000
9 .7 7 6
8 .0 6 5
25000
1 5 .1 0 3
20000 6 .1 1 4

3 .9 2 8
15000

10000

5000

0
4 .0 0 6 .0 0 8 .0 0 1 0 .0 0 1 2 .0 0 1 4 .0 0 1 6 .0 0 1 8 .0 0 2 0 .0 0
T im e - - >
End HeightPeak Type
7812 rBV
5756 rBV
15032 rVB
5980 rVB
4867 rVB
5785 rBV
6100 rBV
14731 rBV
Data file Name :C:\Users\Admin\Documents\04110224\TOBACCO EXTACT.D
Acquired date :06 Nov 2024 10:51
Method Name :D:\MassHunter\GCMS\1\methods\BTEX.M
Sample Name :TOBACCO EXTACT
Library #1 :D:\MassHunter\Library\NIST14.L
Library #2 :
Library #3 :

Compound RT (min) Scan numbeArea (Ab*s Baseline HeAbsolute H Peak WidthHit NumberHit Name Quality
1 3.928 147 26635 8033 15845 0.092 1 .alpha.-Tet 27
2 3H-indole, 25
3 2-Hydroxyc 16
4 Dodecahydr 14
5 2-(2-Furyl) 14
6 1H-1,2,4-Tri 14
7 3-(3-Amino 14
8 Silane, tri 12
9 7,8-Dihydro 12
10 Triamteren 10
11 Tris(tert-b 10
12 Oxalic acid 10
13 Arsenous aci 10
14 1,2-Bis(tri 10
15 2-[5-(3-Met 10
16 5H-dibenzo 10
17 acetic acid 9
18 7-(2-Hydro 9
19 1,2,5-Oxad 9
20 4-Phenyl-3, 9
2 4.666 276 62611 30632 36388 0.063 1 Undecane 81
2 Carbonic ac 78
3 Undecane 74
4 Undecane 74
5 Decane, 3, 64
6 Carbonic ac 64
7 Decyl octyl 64
8 1-Iodo-2-m 59
9 Carbonic ac 53
10 Decane, 2,3 53
11 Undecane 53
12 Tridecane, 50
13 Hexadecane 50
14 Undecane 49
15 1-Undecene 47
16 Octane, 2,4 47
17 Heptacosa 47
18 Nonane 43
19 Decane 43
20 Sulfurous a 38
3 4.787 297 545006 73701 83310 0.303 1 Benzoic aci 76
 2 Benzoic aci 76
3 Benzoic aci 68
4 Benzoic aci 59
5 Benzoic aci 52
6 Benzoic aci 52
7 Benzeneacet 47
8 Ethanone, 47
9 Benzoyl is 43
10 Acetopheno 43
11 Benzoyl chl 43
12 Benzenebut 43
13 Benzeneprop 43
14 Benzoylfor 43
15 Isopropyl p 43
16 1,2-Propan 43
17 Benzoic aci 43
18 1,2-Propan 43
19 N-Methoxy 43
20 1-Propanon 43
4 6.114 529 35460 13609 19589 0.092 1 Methyl 2-(t 47
2 Diglycolic 47
3 15,15'-Bi- 47
4 Tetraethyl 38
5 1,4,7,10,1 38
6 1-Butene, 3 28
7 2-Methoxye 28
8 Tricyclo[6. 28
9 2-Methyl-4- 28
10 Decaethyle 28
11 2-[2-[2-[2- 28
12 2-(2-(2-Eth 28
13 3,6,9,12,1 28
14 Methyl 2-(2 28
15 4-Methoxy- 28
16 3,3'-Trimet 28
17 Hexaethyle 28
18 Silane, (2- 28
19 Methyl 3-h 28
20 Lactic acid, 28
5 8.065 870 46350 21197 26064 0.126 1 9H-Purin-6 35
2 Benzonitril 35
3 Malonic aci 27
4 D-Arabinose 25
5 Benzo(b)th 25
6 Ethanone, 1 25
7 1H-isoindol 25
8 p-Phenylene 22
9 Propenone, 22
10 4-Hydroxy- 22
11 1,3-Dimeth 22
 12 Glyoxylami 22
13 N-Acetyl-L 22
14 1-(2,3-Dihy 22
15 Benzonitril 22
16 N-Acetyl-L 22
17 N-Acetyl-L 22
18 1H-1,2,3-Tr 22
19 3,5,6-Trimet 12
20 Benzamide, 12
6 9.776 1169 40890 21524 27309 0.063 1 Oxazolidin- 35
2 Benzofuraz 14
3 Trimethylsi 14
4 8-Methyl-1, 11
5 (E)-2-Fluor 10
6 Benzonitril 10
7 1H-Indole- 10
8 2,4-Dimeth 10
9 1-Phenyl-3- 10
10 Indol-2(3H) 10
11 Succinic ac 10
12 Propofol 10
13 4-Chloroqu 10
14 Benzonitril 10
15 1-(Methyla 10
16 8-Dimethyla 10
17 Hydratropam 10
18 phenol, 4-( 10
19 Silane, trie 10
20 Succinic ac 10
7 13.478 1816 177122 33329 39429 0.155 1 Pentadecano 97
2 Pentadecano 93
3 Hexadecano 91
4 Hexadecanoi 86
5 Hexadecano 86
6 Hexadecano 86
7 Hexadecano 80
8 Pentadecano 80
9 Methyl 9-m 78
10 Pentadecano 72
11 Hexadecano 72
12 Dodecanoic 72
13 Tridecanoic 64
14 Tridecanoic 64
15 Pentadecano 53
16 Decanoic ac 47
17 Methyl tet 35
18 Thiophene, 22
19 Tetradecano 22
20 Hexadecano 22
8 15.103 2100 25199 7890 22621 0.086 1 Dodecanoic 38
 2 Methyl tet 38
3 Tetradecano 38
4 Nonanoic ac 38
5 Undecanoic 38
6 Dodecanoic 38
7 Methyl 9-m 38
8 Methyl 11- 35
9 Methyl 9-m 35
10 Hexadecano 35
11 Pentadecano 35
12 Undecanoic 35
13 Methyl 6-m 35
14 Hexadecanoi 35
15 Cyclopenta 32
16 1,3-Dithian 14
17 Oxiraneunde 11
18 12-Tridecyn 10
19 10-Undecen 10
20 Arsenous aci 10

A b u n d a n ce

TIC: TOBACCO EXTACT.D\ data.ms

4 .7 8 7
80000

75000

70000

65000

60000

55000

50000

45000

40000 1 3 .4 7 8
4 .6 6 6
35000

30000
9 .7 7 6
8 .0 6 5
25000
1 5 .1 0 3
20000 6 .1 1 4

3 .9 2 8
15000

10000

5000

0
4 .0 0 6 .0 0 8 .0 0 1 0 .0 0 1 2 .0 0 1 4 .0 0 1 6 .0 0 1 8 .0 0 2 0 .0 0
T im e - - >
Mol WeightCAS NumbLibrary Entry Number Library
223.121 059516-48 D:\MassHun 86470
207.105 1000400-5 D:\MassHun 71658
224.084 000644-78 D:\MassHun 87703
207.162 108873-36 D:\MassHun 71593
253.074 1000225-0 D:\MassHun 114259
207.047 1000277-3 D:\MassHun 71829
223.1 030278-73 D:\MassHun 86744
236.16 014629-62 D:\MassHun 98396
408.126 1000287-2 D:\MassHun 241999
253.108 000396-01 D:\MassHun 113972
468.189 1000366-5 D:\MassHun 260810
253.111 1000309-4 D:\MassHun 114086
342.048 055429-29 D:\MassHun 199618
222.126 017151-09 D:\MassHun 85160
253.096 159053-07 D:\MassHun 114067
207.105 1000400-5 D:\MassHun 71669
253.07 1000396-6 D:\MassHun 113844
253.06 166766-15 D:\MassHun 114057
207.064 1000351-7 D:\MassHun 71817
207.105 006187-58 D:\MassHun 71666
156.188 001120-21 D:\MassHun 29358
298.251 1000382-9 D:\MassHun 157798
156.188 001120-21 D:\MassHun 29354
156.188 001120-21 D:\MassHun 29355
170.203 017312-55 D:\MassHun 40006
256.204 1000382-5 D:\MassHun 117251
270.292 1000406-3 D:\MassHun 130950
296.1 073105-67 D:\MassHun 154846
284.235 1000382-5 D:\MassHun 144147
184.219 062238-11 D:\MassHun 51454
156.188 001120-21 D:\MassHun 29356
198.235 013287-21 D:\MassHun 63630
352.163 000544-77 D:\MassHun 206779
156.188 001120-21 D:\MassHun 29357
168.188 074630-39 D:\MassHun 38299
156.188 062016-37 D:\MassHun 29378
380.438 000593-49 D:\MassHun 227469
128.157 000111-84 D:\MassHun 12937
142.172 000124-18 D:\MassHun 19650
236.145 1000309-1 D:\MassHun 97941
136.052 000093-58 D:\MassHun 16700
136.052 000093-58 D:\MassHun 16696
136.064 000613-94 D:\MassHun 16524
136.064 000613-94 D:\MassHun 16523
136.052 000093-58 D:\MassHun 16698
136.052 000093-58 D:\MassHun 16699
164.047 015206-55 D:\MassHun 35628
136.052 000582-24 D:\MassHun 16712
163.009 000532-55 D:\MassHun 34359
154.019 000532-27 D:\MassHun 28425
140.003 000098-88 D:\MassHun 18751
192.079 025333-24 D:\MassHun 57393
145.053 000614-16 D:\MassHun 22111
150.032 000611-73 D:\MassHun 25069
148.089 000611-70 D:\MassHun 23273
148.052 000579-07 D:\MassHun 23906
198.068 000093-99 D:\MassHun 63434
148.052 000579-07 D:\MassHun 23910
165.079 006919-61 D:\MassHun 36014
168.034 000936-59 D:\MassHun 39004
218.097 1000105-2 D:\MassHun 82022
291.111 1000381-9 D:\MassHun 150584
466.278 109773-67 D:\MassHun 260396
308.202 1000352-1 D:\MassHun 166682
510.304 114014-94 D:\MassHun 267564
448.304 1000221-5 D:\MassHun 256168
148.092 018173-74 D:\MassHun 23668
284.199 1000154-0 D:\MassHun 143997
220.031 033102-81 D:\MassHun 82786
530.312 1000352-0 D:\MassHun 269372
370.22 005117-19 D:\MassHun 220208
278.173 1000378-2 D:\MassHun 137787
294.204 001786-94 D:\MassHun 153209
206.097 1000366-8 D:\MassHun 71004
176.123 016654-44 D:\MassHun 44961
420.272 120343-86 D:\MassHun 247060
354.207 1000352-0 D:\MassHun 208238
186.144 020584-45 D:\MassHun 52650
330.259 1000144-2 D:\MassHun 188152
205.942 019836-22 D:\MassHun 70863
163.086 002009-52 D:\MassHun 34329
163.063 004107-65 D:\MassHun 34442
282.056 1000158-5 D:\MassHun 141335
284.112 003767-33 D:\MassHun 143257
163.046 006314-43 D:\MassHun 34506
398.049 1000309-8 D:\MassHun 237346
163.063 1000404-4 D:\MassHun 34488
283.205 032869-56 D:\MassHun 143044
281.051 299461-72 D:\MassHun 140826
163.063 004468-59 D:\MassHun 34476
248.25 052873-50 D:\MassHun 109948
163.063 032331-52 D:\MassHun 34422
222.1 001948-71 D:\MassHun 84890
355.063 1000300-1 D:\MassHun 209336
163.063 002024-83 D:\MassHun 34443
222.1 001948-71 D:\MassHun 84888
222.1 001948-71 D:\MassHun 84889
163.086 051719-86 D:\MassHun 34341
163.086 061139-80 D:\MassHun 34333
299.152 1000350-3 D:\MassHun 158751
280.015 122975-81 D:\MassHun 139329
163.075 006124-22 D:\MassHun 34366
370.127 1000297-9 D:\MassHun 220187
236.974 026228-41 D:\MassHun 99006
237.117 110915-65 D:\MassHun 99255
163.063 005653-62 D:\MassHun 34435
237.09 017310-26 D:\MassHun 99333
163.046 039842-01 D:\MassHun 34512
237.09 021683-60 D:\MassHun 99323
296.073 1000272-5 D:\MassHun 155073
434.208 1000381-6 D:\MassHun 251935
178.136 002078-54 D:\MassHun 46089
163.019 000611-35 D:\MassHun 34393
163.063 002024-83 D:\MassHun 34438
237.079 000082-38 D:\MassHun 99403
237.123 078146-62 D:\MassHun 98987
163.1 000826-54 D:\MassHun 34098
237.079 1000396-4 D:\MassHun 99411
192.118 000078-07 D:\MassHun 58125
420.192 1000381-6 D:\MassHun 247049
270.256 005129-60 D:\MassHun 130841
270.256 005129-60 D:\MassHun 130843
270.256 000112-39 D:\MassHun 130821
284.272 006929-04 D:\MassHun 144336
270.256 000112-39 D:\MassHun 130818
270.256 000112-39 D:\MassHun 130817
270.256 000112-39 D:\MassHun 130813
256.24 007132-64 D:\MassHun 117471
256.24 213617-69 D:\MassHun 117450
256.24 007132-64 D:\MassHun 117472
270.256 000112-39 D:\MassHun 130822
214.193 000111-82 D:\MassHun 78065
228.209 001731-88 D:\MassHun 91453
228.209 001731-88 D:\MassHun 91455
256.24 007132-64 D:\MassHun 117468
186.162 000110-42 D:\MassHun 52773
242.225 000124-10 D:\MassHun 104290
144.097 001613-49 D:\MassHun 21609
256.24 062691-05 D:\MassHun 117491
270.256 000112-39 D:\MassHun 130819
214.193 000111-82 D:\MassHun 78067
242.225 000124-10 D:\MassHun 104290
256.24 062691-05 D:\MassHun 117491
188.141 034957-73 D:\MassHun 54122
214.193 005129-56 D:\MassHun 78103
228.209 005129-65 D:\MassHun 91484
256.24 213617-69 D:\MassHun 117453
282.256 1000336-3 D:\MassHun 142105
256.24 213617-69 D:\MassHun 117450
270.256 000112-39 D:\MassHun 130818
256.24 007132-64 D:\MassHun 117468
214.193 005129-56 D:\MassHun 78102
158.131 002519-37 D:\MassHun 31277
284.272 006929-04 D:\MassHun 144336
268.24 025779-85 D:\MassHun 128702
241.023 024588-74 D:\MassHun 102818
312.266 038520-31 D:\MassHun 171287
224.178 056909-01 D:\MassHun 87607
198.162 000111-81 D:\MassHun 63282
342.048 055429-29 D:\MassHun 199618
Data File Name: C:\Users\Admin\Documents\04110224\TOBACCO EXTACT.D
Acquired Date: 06 Nov 2024 10:51
Method Name: D:\MassHunter\GCMS\1\methods\BTEX.M
Sample Name: TOBACCO EXTACT

Comp # Compound RT (min) Area Amount Units Qvalue

1 Toluene 3.299 270 3.58E-05 mg/L 19
2 Benzene 0 0 0 mg/L 0
3 Orto-Xyle 6.595 58 2.53E-05 mg/L 1
4 Para-Xylen 7.402 356 6.30E-05 mg/L 5
5 Benzene, (1 8.042 300 0.001834 mg/L 1
6 Benzene, (1 8.111 506 0 mg/L 46
7 Benzene, p 8.769 130 0.004521 mg/L 41

A b u n d a n ce

TIC: TOBACCO EXTACT.D\ data.ms

4 .7 8 7
80000

75000

70000

65000

60000

55000

50000

45000

40000 1 3 .4 7 8
4 .6 6 6
35000

30000
9 .7 7 6
8 .0 6 5
25000
1 5 .1 0 3
20000 6 .1 1 4

3 .9 2 8
15000

10000

5000

0
4 .0 0 6 .0 0 8 .0 0 1 0 .0 0 1 2 .0 0 1 4 .0 0 1 6 .0 0 1 8 .0 0 2 0 .0 0
T im e - - >
Method file Name : D:\MassHunter\GCMS\1\methods\BTEX.M
Calibration Table Description : BTEX
Last update to the quantitation database : Tue Nov 05 12:22:37 2024

# Peak Nam Exp RetTi Coef0 Coef1 Coef2 Corr Coeffi Curve fit type
1 Toluene 3.316 0 7551903 0 1 linear
2 Benzene 5.794 0 9018256 0 1 linear
3 Orto-Xyle 6.601 0 2288391 0 1 linear
4 Para-Xylen 7.402 0 5649147 0 1 linear
5 Benzene, (1 8.037 0 163549 0 1 linear
6 Benzene, (1 8.1 0 0 0 0 linear
7 Benzene, p 8.786 0 28753 0 1 linear

Toluene Conc Resp Amount RatResp Ratio

10 75519030

Benzene Conc Resp Amount RatResp Ratio

10 90182563

Orto-Xyle Conc Resp Amount RatResp Ratio

10 22883908

Para-XylenConc Resp Amount RatResp Ratio

10 56491470

Benzene, (1Conc Resp Amount RatResp Ratio

10 1635486

Benzene, (1Conc Resp Amount RatResp Ratio

Benzene, pConc Resp Amount RatResp Ratio

10 287529