SAFETY DATA SHEET

Revision Date 15-Jan-2021 Version 9

1. IDENTIFICATION
Product identifier
Product Name COPPER ANTI-SEIZE LUBRICANT 8OZ

Other means of identification

Product Code 09128

Recommended use of the chemical and restrictions on use

Recommended Use Lubricant
Uses advised against No information available

Details of the supplier of the safety data sheet

Manufacturer Address May Also Be Distributed by:
ITW Permatex ITW Permatex Canada
6875 Parkland Blvd. 101-2360 Bristol Circle
Solon, Ohio 44139 USA Oakville, ON Canada L6H 6M5
Telephone: 1-87-Permatex Telephone: (800) 924-6994
(866) 732-9502
24-hour emergency phone number
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453

E-mail address: [email protected]

2. HAZARDS IDENTIFICATION
Classification

OSHA Regulatory Status

This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Carcinogenicity Category 1B

Label elements

Emergency Overview
Signal word
Danger

May cause cancer

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Appearance Copper Physical state Paste Liquid Odor Petroleum

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required

Precautionary Statements - Response

IF exposed or concerned: Get medical advice/attention

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN: Gently wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention

Precautionary Statements - Storage

Store in a well-ventilated place. Keep container tightly closed
Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information
Very toxic to aquatic life with long lasting effects.

Unknown acute toxicity 27.25 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS
The product contains no substances which at their given concentration, are considered to be hazardous to health.

Chemical Name CAS No Weight-%

DISTILLATES (PETROLEUM), 64742-54-7 30 - 60
HYDROTREATED HEAVY
PARAFFINIC
MAGNESIUM SILICATE 14807-96-6 10 - 30
LIMESTONE 1317-65-3 10 - 30
COPPER 7440-50-8 3-7
GRAPHITE 7782-42-5 1-5
AMORPHOUS SILICA 7631-86-9 1-5

4. FIRST AID MEASURES

Description of first aid measures

General advice Call 911 or emergency medical service. Remove and isolate contaminated clothing and
shoes.

Eye contact In case of contact with substance, immediately flush skin or eyes with running water for at
least 20 minutes.

Skin contact IF ON SKIN:. Wash with soap and water.

Inhalation Move victim to fresh air. If breathing is irregular or stopped, administer artificial respiration.

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Administer oxygen if breathing is difficult.

Ingestion IF SWALLOWED:. Do NOT induce vomiting.

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination.

Most important symptoms and effects, both acute and delayed

Symptoms See section 2 for more information.

Indication of any immediate medical attention and special treatment needed

Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Dry chemical, CO2, water spray or regular foam, Water spray, fog or regular foam, Move containers from fire area if you can do it
without risk, Dike fire-control water for later disposal

Unsuitable extinguishing media

Do not scatter spilled material with high pressure water streams

Specific hazards arising from the chemical

Some may burn but none ignite readily. Those substances designated with a "P" may polymerize explosively when heated or
involved in a fire. Some may be transported hot.

Explosion data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk.

Environmental precautions

Environmental precautions Prevent entry into waterways, sewers, basements or confined areas.

Methods and material for containment and cleaning up

Methods for containment Prevent dust cloud.

Methods for cleaning up Cover liquid spill with sand, earth or other non-combustible absorbent material. With clean
shovel place material into clean, dry container and cover loosely; move containers from spill
area. Take up with sand or other non-combustible absorbent material and place into
containers for later disposal. Cover powder spill with plastic sheet or tarp to minimize
spreading.

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE

Precautions for safe handling

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Advice on safe handling Avoid contact with skin and eyes.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep in a dry, cool and well-ventilated place.

Incompatible materials Strong oxidizing agents, Acids, Alkalis

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
MAGNESIUM SILICATE TWA: 2 mg/m3 particulate matter (vacated) TWA: 2 mg/m3 respirable IDLH: 1000 mg/m3
14807-96-6 containing no asbestos and <1% dust <1% Crystalline silica, TWA: 2 mg/m3 containing no
crystalline silica, respirable containing no Asbestos Asbestos and <1% Quartz
particulate matter TWA: 20 mppcf if 1% Quartz or respirable dust
more;use Quartz limit
LIMESTONE - TWA: 15 mg/m3 total dust TWA: 10 mg/m3 total dust
1317-65-3 TWA: 5 mg/m3 respirable fraction TWA: 5 mg/m3 respirable dust
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m3 respirable
fraction
COPPER TWA: 0.2 mg/m3 fume TWA: 0.1 mg/m3 fume IDLH: 100 mg/m3 dust, fume and
7440-50-8 TWA: 1 mg/m3 dust and mist mist
(vacated) TWA: 0.1 mg/m3 Cu dust, TWA: 1 mg/m3 dust and mist
fume, mist TWA: 0.1 mg/m3 fume
GRAPHITE TWA: 2 mg/m3 respirable TWA: 15 mg/m3 total dust IDLH: 1250 mg/m3
7782-42-5 particulate matter all forms except synthetic TWA: 2.5 mg/m3 natural respirable
graphite fibers TWA: 5 mg/m3 respirable fraction dust
synthetic
(vacated) TWA: 2.5 mg/m3
respirable dust natural
(vacated) TWA: 10 mg/m3 total
dust synthetic
(vacated) TWA: 5 mg/m3 respirable
fraction synthetic
TWA: 15 mppcf natural
AMORPHOUS SILICA - TWA: 50 µg/m3 excludes IDLH: 3000 mg/m3
7631-86-9 construction work, agricultural TWA: 6 mg/m3
operations, and exposures that
result from the processing of
sorptive clays
(vacated) TWA: 6 mg/m3 <1%
Crystalline silica
TWA: 20 mppcf
: (80)/(% SiO2) mg/m 3 TWA
NIOSH IDLH Immediately Dangerous to Life or Health

Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).

Appropriate engineering controls

Engineering Controls Showers

Eyewash stations
Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene™ or PVC gloves.

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Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Paste Liquid
Appearance Copper
Odor Petroleum
Odor threshold No information available

Property Values Remarks • Method

pH No information available
Melting point / freezing point No information available
Boiling point / boiling range No information available
Flash point 216 °C / 421 °F
Evaporation rate No information available Butyl acetate = 1
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper flammability limit: No information available
Lower flammability limit: No information available
Vapor pressure No information available
Vapor density No information available Air = 1
Relative density 1.21
Water solubility Insoluble in water
Solubility(ies) No information available
Partition coefficient No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity No information available
Dynamic viscosity No information available
Explosive properties No information available
Oxidizing properties No information available

Other Information
Softening point No information available
Molecular weight No information available
VOC content 0%
Density No information available
Bulk density No information available
SADT (self-accelerating No information available
decomposition temperature)

10. STABILITY AND REACTIVITY

Reactivity
No information available

Chemical stability
Stable under normal conditions

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid
Excessive heat.

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Incompatible materials
Strong oxidizing agents, Acids, Alkalis

Hazardous Decomposition Products

Carbon oxides
Metal oxides
Halogenated compounds

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Inhalation May cause irritation of respiratory tract.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May cause skin irritation and/or dermatitis.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

DISTILLATES (PETROLEUM), > 15 g/kg ( Rat ) > 5000 mg/kg ( Rabbit ) -
HYDROTREATED HEAVY
PARAFFINIC
64742-54-7
GRAPHITE - - > 2000 mg/m3 ( Rat ) 4 h
7782-42-5
AMORPHOUS SILICA = 7900 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) > 2.2 mg/L ( Rat ) 1 h
7631-86-9

Information on toxicological effects

Symptoms No information available.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Germ cell mutagenicity No information available.
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical Name ACGIH IARC NTP OSHA
DISTILLATES A2 Group 1 Known X
(PETROLEUM),
HYDROTREATED HEAVY
PARAFFINIC
64742-54-7
MAGNESIUM SILICATE - Group 3 - X
14807-96-6
AMORPHOUS SILICA - Group 3 - -
7631-86-9
ACGIH (American Conference of Governmental Industrial Hygienists)
A2 - Suspected Human Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Not classifiable as a human carcinogen
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Chronic toxicity May cause adverse liver effects.
Target Organ Effects Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory system, Skin.

The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral) 18281 mg/kg
ATEmix (dermal) 6332 mg/kg

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12. ECOLOGICAL INFORMATION

This product contains a chemical which is listed as a severe marine pollutant according to DOT.

Ecotoxicity

0 % of the mixture consists of component(s) of unknown hazards to the aquatic environment

Persistence and degradability

No information available.

Bioaccumulation
No information available.

Mobility
No information available.

Other adverse effects

No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number Not applicable

This product contains one or more substances that are listed with the State of California as a hazardous waste.

14. TRANSPORT INFORMATION

DOT
Proper shipping name Not regulated
Marine pollutant This product contains a chemical which is listed as a severe marine pollutant according to
DOT.

IATA
Proper shipping name Not regulated

IMDG
Proper shipping name Not regulated

15. REGULATORY INFORMATION

International Inventories
TSCA Complies
DSL/NDSL Complies
EINECS/ELINCS Complies
ENCS Does not comply
IECSC Complies
KECL Complies
PICCS Complies
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AICS Complies

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name SARA 313 - Threshold Values %

COPPER - 7440-50-8 1.0
SARA 311/312 Hazard Categories
Acute health hazard Yes
Chronic Health Hazard No
Fire hazard No
Sudden release of pressure hazard No
Reactive Hazard No

CWA (Clean Water Act)

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
COPPER - X X -
7440-50-8
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

COPPER 5000 lb - RQ 5000 lb final RQ
7440-50-8 RQ 2270 kg final RQ
US State Regulations

California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
AMORPHOUS SILICA *Carcinogen
7631-86-9
• *The asterisked chemical(s) listed are not subject to Proposition 65 because they are not airborne in the finished product
U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

MAGNESIUM SILICATE X X X
14807-96-6
LIMESTONE X X X
1317-65-3
COPPER X X X
7440-50-8
AMORPHOUS SILICA - X X
7631-86-9
GRAPHITE X X X
7782-42-5
U.S. EPA Label Information
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EPA Pesticide Registration Number Not applicable

WHMIS Hazard Class

D2A - Very toxic materials

16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION

NFPA Health hazards 1 Flammability 1 Instability 0 -
HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B

NFPA (National Fire Protection Association)

HMIS (Hazardous Material Information System)

Revision Date 15-Jan-2021

Disclaimer
Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled.
However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness
of the information. User is responsible for evaluating whether such information or this product is fit for a particular
purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this
product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc.
disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or
use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web
site.

End of Safety Data Sheet

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