Assignment-11c 24-25

SUMMER HOMEWORK – CHEMISTRY – Std.
11 C (2024-25)
Q1. Define the following terms: (a) Molecular mass (b) Equivalent mass (c) Avogadro constant (d) Mole. (e) Law of
reciprocal proportion (f) Molality.
Q1. (a) Phosphorous and chlorine combine to form two compounds. The first and second compounds contain 22.54%
and 14.88% by mass of phosphorous, respectively. Show that these data are consistent with the law of multiple
proportion.
(b) 1g of a metal produces 1.67 g of its oxide when heated in air. Its carbonate contains 28.57% of the metal. What
will be the weight of the metal oxide obtained by heating 1 g of the metal carbonate?
Q3.(a) Define vapour density. Show that the molecular mass of a gas is twice its vapour density.
(b) The vapour density of a mixture of NO2 and N2O4 is 38.3 at 300 K. calculate the mole fraction
and number of moles of NO2 in 100 g of the mixture. (Atomic mass: N=14, O=16)
Q4. 1 volume of a gaseous organic compound containing C, H and O required 2.5 volume of oxygen for complete
combustion and produced 2 volumes of carbon dioxide and 2 volumes of steam. If the volumes were measured at
the same temperature and pressure, determine molecular formula of the compound.
Q5. A compound contains 72% metal and 32% nitrogen. If one molecule of the compound contains 3 atoms of the metal
combined with 2 atoms of nitrogen, determine atomic mass of the metal.
Q6. The enzyme ‘peroxidase’ contains 0.5% selenium (atomic mass = 78.4) by mass. If one molecule of the enzyme
constitutes only one atom of selenium, calculate molecular mass of the enzyme.
Q7. 20 mg of a volatile organic liquid produced 22.5 cm3 of vapours measured at 300 K and 755 mm-Hg pressure.
Calculate molecular mass of the liquid.
Q8. The mineral dolomite contains calcium carbonate and magnesium carbonate. When a 2.0 g sample of dolomite was
heated strongly until constant weight, the residue weighed 1.012 g: CaCO 3  CaO + CO2 ; MgCO3  MgO + CO2
Calculate the percent composition of the dolomite. (Atomic mass: Ca=40, Mg=24, C=12, O=16)
Q9. 1.575 g hydrated crystals of oxalic acid (H2C2O4.xH2O) are dissolved in water and the volume made up to 250 mL.
16.68 mL of this solution is completely neutralised by 25 mL of M/10 NaOH solution. Calculate the value of x in oxalic
acid crystals. The neutralisation equation: H2C2O4 + 2NaOH  Na2C2O4 + 2H2O.
Q10. A sample of sulphuric acid (density = 1.28 g/cm3) is 68% by mass. Calculate the volume of this sample which should
be mixed with water to prepare 500 cm3 of semi normal solution.
Q11. A ball of stainless steel contains 85.6% iron by weight and has a density of 7.75 g cm -3. If radius of the bulb is
0.254 cm, calculate the number of iron atoms in the ball. (Atomic mass of Fe = 56)
Q12. 0.366 g of a base required 15 mL of N/5 HCl solution for neutralisation. If molecular mass of the base is 122
calculate acidity of the base.
Q13. What is the weight of 1 gram equivalent of the oxidising and reducing reagent in the following reaction :
5Zn + V2O5  5ZnO + 2V (Atomic mass: V=50.94, Zn = 63.38, O = 16)
Q14.In an experiment, 0.501 g of silver was dissolved in nitric acid and an excess of dil.HCl was added to the solution
when AgCl precipitated quantitatively. The dry precipitate weighed 0.6655 g. If equivalent weight of chlorine is 35.5,
calculate that of silver.
Q15. A welding fuel gas contains carbon and hydrogen only. Burning a small sample of it in oxygen gives 3.38 g carbon
dioxide, 0.690 g of water and no other products. A volume of 10.0 L measured at STP of this welding gas is found to
weigh 11.6 g. Calculate (i) empirical formula (ii) molar mass of the gas and (iii) molecular formula.
Q16. 1.28 g of a mixture containing K2CO3 and Na2CO3 are present in 100 mL aqueous solution. 20 mL of this solution is
completely neutralised by 40 mL of 0.1 N HCl. Calculate the mass of K 2CO3 and Na2CO3 in the mixture.
Q17. (a)‘Reduction and oxidation are complementary reactions’- explain the statement with an illustrative example.
(b) Determine the oxidation state of the underlined atom in the following compounds:
1. NaH2PO2 2. XeO2F2 3. Na3[Ag(S2O3)2] 4. Fe4[Fe(CN)6]3 5. H2S2O8 6. CH2O
Q18. Balance the following equations, clearly showing the steps, by the method indicated:
(a) N2O4 + BrO3 1–  NO3 1– + Br1– (by Ion Electron Method)
(b) (NH4)2Cr2O7  N2 + Cr2O3 + H2O (by Oxidation Number Method)
(c) Cr2O72- + H+ + SO2  Cr3+ + H2O + HSO41- (by Ion Electron Method)
(d) KNO2 + FeSO4 + H2SO4  K2SO4 + Fe2(SO4)3 + NO + H2O (by Oxidation Number Method)
(e) NaI + H2O2  NaIO3 +H2O (by Ion Electron Method)
(f) KMnO4 + MnSO4 + H2O  K2SO4 + MnO2 + H2SO4 (by Oxidation Number Method)
(g) Cr(OH)3 + IO3 1– + OH 1–  CrO42 – + I 1– + H2O (by Ion Electron Method
(i) Cu2S + Cu2O  Cu + SO2 (by Oxidation Number Method)
Q19. The strength of commercial hydrogen peroxide is specifically stated as ‘volume strength” which implies ‘the
volume of oxygen evolved at STP on dissociation of a unit volume of the sample hydrogen peroxide according to
the equation: 2H2O2  2H2O + O2 ’. Thus a ‘10V H2O2’ means 1 litre of it will liberate 10 litres of oxygen at STP.
Calculate the strength of this sample of hydrogen peroxide in normality.

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SUMMER HOMEWORK – CHEMISTRY – Std.

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