Kassim - Three-Body Abrasion of Al-SiC Composites
Kassim - Three-Body Abrasion of Al-SiC Composites
Kassim - Three-Body Abrasion of Al-SiC Composites
163–173
a
´ de Tribologia e Materiais, Departamento de Ciencias
Laboratorio ˆ ´
Fısicas, ˆ
UniÕersidade Federal de Uberlandia, ˆ
Campus Santa Monica, 38400-902,
MG, Brazil
b
´
Escola Politecnica ˜ Paulo, AÕ. Prof. Mello Morais 2463, 05508-900, Sao
da UniÕersidade de Sao ˜ Paulo, SP, Brazil
Abstract
While many works have been focused on the two-body abrasive wear of aluminum matrix composites, there are relatively few results
on the three-body abrasion performance of these composites. In the present study, the three-body abrasion of aluminum matrix composites
reinforced with silicon carbide particles ŽSiC p . has been investigated. The metal matrix composites ŽMMCs. were fabricated by a powder
metallurgy route involving a final hot extrusion step, with Al 1100 matrix and a-SiC p reinforcement with mean sizes of 10, 27 and 43
mm, in the proportions of 5, 10 and 20 vol.%. Using a wet monolayer tester, three-body abrasive wear tests were conducted under a
constant load against silicon carbide and alumina abrasives with four different grits of 320, 400, 600 and 1000. The microstructural
characterizations were performed using light microscopy. The dominant wear mechanisms were identified using scanning electron
microscopy. The influence of type of the abrasive particles on wear rate and dominating wear mechanism is reported. Relationships
between size and volume fraction of the SiC p reinforcement and wear rate is discussed. It is shown that SiC p reinforcement increases the
abrasion resistance against all the abrasives used. This increase is generally higher against alumina than silicon carbide abrasives. q 1999
Published by Elsevier Science S.A. All rights reserved.
Keywords: Al–SiC composites; SiC p reinforcement; Three-body abrasion; Abrasive particles; Wear mechanisms
0043-1648r99r$ - see front matter q 1999 Published by Elsevier Science S.A. All rights reserved.
PII: S 0 0 4 3 - 1 6 4 8 Ž 9 9 . 0 0 0 0 9 - 5
164 K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173
Table 1 Table 2
Characteristics of the materials tested Bulk hardness of materials tested
Code Volume percent of SiC p Average size of SiC p Material Hardness ŽHV 10.
particles wvol.%x particles wmmx
Al 29.6"0.2
Al Al-5-10 36.2"0.8
Al-5-10 5 10 Al-10-10 39.4"0.5
Al-10-10 10 10 Al-20-10 43.5"0.4
Al-20-10 20 10 Al-5-27 33.3"0.4
Al-5-27 5 27 Al-10-27 36.8"0.4
Al-10-27 10 27 Al-20-27 45.0"0.3
Al-20-27 20 27 Al-5-43 34.0"0.3
Al-5-43 5 43 Al-10-43 37.2"0.3
Al-10-43 10 43 Al-20-43 44.8"0.9
Al-20-43 20 43
Also for the composites containing the same amount of MMCs, manufactured with squeeze casting technique, us-
SiC P reinforcement, the abrasion resistance increased by ing a test method developed by Struers, Denmark. They
increasing the size of SiC p . found that the aluminum reinforced with Al 2 O 3 fibres
Axen ´ et al. w29x studied the abrasion resistance of showed no influence of fibre content on the abrasion
alumina fibre reinforced aluminum using a pin-on-drum resistance.
abrasion machine. The composites were manufactured by a The nature and properties of the interface between the
hot liquid infiltration technique. They concluded that fibre reinforcing phase and the matrix, affected by the method
reinforcement significantly improved the abrasion resis- of fabricating the composite, can influence the tribological
tance in milder abrasive situations, i.e., small and soft properties of the composites. The aim of the present study
abrasives and low applied loads. However, in severe abra- is to investigate the three-body abrasion behavior of differ-
sive situations, the abrasion resistance of the composites ent aluminum matrix composites reinforced with SiC p with
was equal to or, in some cases, even lower than that the average sizes of 10, 27 and 43 mm, as well as in the
unreinforced materials. proportions of 5, 10 and 20 vol.%, fabricated by a powder
Using a dry sandrrubber wheel abrasion tester, Bhansali metallurgy technique involving a hot extrusion step.
and Mehrabian w22x reported that the three-body abrasion
resistance of alloys Al 2014 and Al 2024 reinforced with
Al 2 O 3 particles were superior to those containing SiC p . 2. Experimental procedures
This was attributed to high fracture toughness of alumina
relative to silicon carbide. They also found that the com- 2.1. Materials
posite Al 2024–20 wt.% SiC p offered no significant im-
provement in the abrasion resistance due to a weak bond In this investigation the composites were all based on
between SiC p and the matrix, resulting from the presence the same matrix which was air atomized aluminum powder
of brittle Al 4 C 3 at the interface. Alahelisten et al. w27x Al 1100 Ž99.1 Al, 0.30 Si, 0.28 Fe; in wt.%. with an
studied the three-body abrasion performance of different average grain size of around 120 mm. The composites,
containing 5, 10 and 20 vol.% of a-SiC p with three canned and cold pressed in an Al alloy can with an
different mean sizes of 10, 27 and 43 mm, were made by uniaxial press at 100 MPa. Then the cans were pre-heated
powder metallurgy technique ŽTable 1.. The reported pro- for 3.5 h at 4208C and finally hot extruded in a vertical 15
portions and sizes of the SiC p were measured before the MN press with an extrusion ratio of 48:1. The final
fabrication of the composites studied, using a particle product consisted of 18 mm diameter cylindrical bars.
analyzer ŽMalvern 2600. and mass balance w30x. The com- For microscopic examination, MMCs specimens were
posites were fabricated by dry blending Al and SiC pow- cut with a low velocity diamond cutting wheel and then
ders using a Y-type mixer for 4 h. The mixed powder was ground for half a minute to obtain flat surfaces, using a
Fig. 2. Optical micrographs of the Al–SiC composites. Ža. Al-5-43, Žb. Al-10-43, Žc. Al-20-43, Žd. Al-5-27, Že. Al-10-27, Žf. Al-20-27, Žg. Al-5-10, Žh.
Al-10-10, Ži. Al-20-10.
166 K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173
Fig. 3 shows, as an example, the evolution of wear rate 3.2.1. Effect of abrasiÕe grit size
of the specimens Al-20-43 and Al-5-27 as a function of The effect of abrasive grit size on the abrasion resis-
abrasion time under different tribological conditions. It can tance of the SiC p-reinforced composites is shown in Figs.
be observed that the wear rate initially decreases with 4–6. Generally, the abrasion resistance decreases with
increasing the abrasion time until reaching the permanent abrasive grit size over the range studied. Significant im-
wear regime, in which the wear rate is nearly constant with provement in the wear resistance was found against abra-
the time. The time to reach this permanent wear regime sives with the smallest grit size 10 mm Ž1000 grit., while
was around 480 s. ŽFig. 3a. and 420 s. ŽFig. 3b.. These against abrasives with bigger grit sizes the effect is rela-
results confirm the necessity of achieving the permanent tively low, and with abrasives of 46 mm Ž320 grit. no
wear regime since without this procedure no comparative improvement was recorded. The reinforcement with SiC p
behavior can be found among the specimens studied. generally is more efficient in enhancing the wear resis-
Fig. 7. SEM micrographs of abraded surfaces of the specimen Al-5-10. Ža. SiC 320 Ž46 mm., Žb. SiC 1000 Ž10 mm., Žc. Al 2 O 3 320 Ž46 mm., Žd. Al 2 O 3
1000 Ž10 mm..
K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173 169
with metal and thus only support the applied load without
contributing to material removal. Mulhearn and Samuels
w32x studied samples of silicon carbide abrasives. They
found that the grains in the fine grit size appeared to
contain a large number of cracks which would make them
break easily and thus reduce their ability to remove mate-
rial. Larsen-Basse w33x also concluded that the conditioning
and deterioration of fine grit abrasives is more intense than
coarse grits for a given sliding distance. In agreement,
Johnson w34x found the pick up of abrasive particles by the
wearing surface is much greater for fine than for coarse
grits because the latter deteriorate less rapidly. Thus, it is
to be expected that the wear rate should be less for a
surface worn by a fine grit and when the effects of grit
Fig. 8. Wear resistance as a function of size of SiC p particles, volume deterioration and pick up are eliminated w33x, wear rate
fraction of SiC p s 20%. becomes independent of grit size.
´ and
For materials containing reinforcing particles, Axen
tance against Al 2 O 3 abrasives than SiC. This behavior can Zum Gahr w35x reported that the wear rate of steel sub-
be attributed to the hardness and geometry of the abrasive strates laser-clad with TiC particles was influenced by the
used, where the hardness of Al 2 O 3 is lower than that of size of the reinforcing particles, matrix hardness and the
SiC abrasive and SiC p reinforcing particles of the compos- abrasive grit size. The ratio of the average width of the
ites investigated, thereby increasing the wear resistance individual wear grooves to the mean free path between the
significantly. reinforcing particles was considered to be a determining
Numerous explanations have been suggested for the factor in wear behavior. Wang and Rack w25x proposed the
effect of abrasive grit size on the wear rate. Larsen-Basse term relative penetration depth Ž h r . which was defined as
w31x suggested that the efficiency of material removal the ratio of the abrasive particle penetration depth Ž h. to
depends on the elastic contact load, which varies with the the size of the reinforcing phase Ž d ., expressed as rein-
abrasive grit size. For a constant load, if the average forcement mean free path. At constant reinforcement vol-
abrasive grit size is increased, the density of abrasive ume fraction, this ratio was a critical variable, controlling
grains under the abraded surface is diminished, so that the the wear resistance of a composite reinforced with SiC p .
individual stress in each grain is increased. He concluded Below a relative penetration depth of unity, wear resis-
that the smaller-sized particles are only in elastic contact tance was found to increase dramatically with decreasing
Fig. 9. SEM micrographs of abraded surfaces of the composites worn by abrasive particles of 320 grit Ž46 mm.. Ža. Al-20-10, SiC and Žb. Al-5-43, Al 2 O 3 .
170 K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173
relative penetration depth. Above unity, the wear resis- ‘dimensions of the contact area’ proposed by Hutchings
tance was generally independent of the penetration depth. w21x can be used to explain wear results related to the size
Hutchings w21x introduced a concept of ‘dimensions of of abrading particles. At a constant volume fraction of
contact area’ to explain wear results related to the size of SiC p reinforcement with defined average size, wear resis-
abrasive particles. The dimensions of the abrasive particle tance of the composite decreased with increasing the size
relative to the size of the reinforcement determined whether of abrading particles due to an increase in the relative
the wearing composite acted as a heterogeneous or homo- penetration depth and contact area.
geneous solid to the particle contact. SEM micrographs of the abraded surfaces of the com-
In the present work, the concept of the ‘relative penetra- posites, worn by 46 mm Ž320 grit. and 10 mm Ž1000 grit.
tion depth’ proposed by Wang and Rack w25x and the abrasive particles, are shown in Fig. 7.
Fig. 10. SEM micrographs of abraded surfaces of the composites Ž20 vol.% of SiC p . worn by abrasive particles of 1000 grit Ž10 mm.. Ža. Al-20-10; SiC,
Žb. Al-20-43, SiC, Žc. Al-20-10; Al 2 O 3 , Žd. Al-20-43; Al 2 O 3 .
K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173 171
the abrasive used, where the hardness of Al 2 O 3 is lower 6. The improvement imparted by the SiC p reinforcement
than that of SiC. generally was higher against alumina than against sili-
con carbide for all grits tested.
3.2.3. Effect of Õolume fraction of SiC p
Figs. 4–6 show that the wear resistance against both
Acknowledgements
silicon carbide and alumina abrasives generally increases
with increasing the volume fraction of SiC p , when the size
The authors would like to thank the CNPq and
of the abrading particles was reduced from 46 mm to 10
FAPEMIG, Brazil for the financial support.
mm.
For example, Fig. 11 shows the wear resistance of the
composites, containing SiC p with an average size of 43 References
mm, as a function of volume fraction of the reinforcement.
When abrading with SiC or Al 2 O 3 abrasive particles of w1x M. Hunt, Mater. Eng. 108 Ž6. Ž1991. 27–30.
320 grit Ž46 mm., the abrasion resistance of the composite w2x M. Noguchi, K. Fukizawa, Adv. Mater. Process. 143 Ž6. Ž1993.
was not significantly affected by volume fraction of SiC p . 20–26.
w3x H.N. Yoshimuro, M. Gonçalves, H. Goldenstein, The effect of SiC P
Also it is nearly the same as that of aluminum matrix. On
clusters and porosity on the mechanical properties of PM Al matrix
the other hand, when abrading with SiC or Al 2 O 3 abrasive composites, Key Eng. Mater. 127–131 Ž1997. 985–992.
particles of 1000 grit Ž10 mm., the abrasion resistance w4x H. Buhl, Advanced Aerospace Materials, Springer, Berlin, 1992.
significantly increased with increasing the volume fraction w5x J.W. Weeton, D.M. Peters, K.L. Thomas, Engineers Guide to Com-
of SiC p . posite Materials, American Society for Metals, 1987.
w6x M. Roy, B. Venkataraman, V. Bhanuprasad, Y. Mahajan, G. Sun-
The SEM micrograph of the worn surface when abraded
dararajan, The effect of particulate reinforcement on the sliding wear
by 10 mm Ž1000 grit. abrasives of Al 2 O 3 is presented in behaviour of aluminium matrix composites, Metallurgical Transac-
Fig. 12. Plastic deformation due to multi-indentations can tions 23 A Ž1992. 2833–2847.
be seen as a predominant wear mechanism. At the same w7x B.N. Pramila Bai, B.S. Ramasesh, M.K. Surappa, Dry sliding wear
size of SiC p Ž43 mm., the plastic deformation on the worn of A356-Al–SiC P composites, Wear 157 Ž1992. 295–304.
w8x A.T. Alpas, J. Zhang, Effect of SiC particulate reinforcement on the
surface was reduced by an increase in SiC p volume frac-
dry sliding wear of aluminium–silicon alloys, Wear 155 Ž1992.
tion from 5% ŽFig. 12. to 20% ŽFig. 10d.. It can also be 83–104.
seen that some SiC p reinforcement particles remain in w9x A.T. Alpas, J. Zhang, Wear rate transitions in cast aluminium–sili-
relief which leads to a protection of the matrix from the con alloys reinforced with SiC particles, Scripta Metallurgica et
abrading abrasive particles, thereby increasing the abrasion Materialia 26 Ž1992. 505–509.
w10x A.T. Alpas, J. Zhang, Effect of microstructure Žparticulate size and
resistance.
volume fraction. and counterface material on the sliding wear
resistance of particulate-reinforced aluminium matrix composites,
Metallurgical Transactions 25 A Ž1994. 969–983.
w11x S.F. Moustafa, Wear and wear mechanisms of Al–22%SirAl 2 O 3f
4. Conclusions composite, Wear 185 Ž1995. 189–195.
w12x A.T. Alpas, J. Zhang, Wear regimes and transitions in Al 2 O 3
From the investigation of the three-body abrasion wear particulate reinforced aluminium alloys, Mater. Sci. Eng. A 161
Ž1993. 273–284.
of different aluminum matrix composites, the following
w13x M.A. Martınez,
´ ´ J. Llorca, Wear of Al–Si alloys and
A. Martın,
conclusions can be made: Al–SirSiC composites at ambient and elevated temperatures, Scripta
1. The reinforcement of aluminum matrix with SiC p im- Metallurgica et Materialia 28 Ž1993. 207–212.
proved the abrasion resistance of all composites tested w14x A.P. Sannino, H.J. Rack, Dry sliding wear of discontinuously rein-
against all the abrasives used. forced aluminium composites: review and discussion, Wear 189
Ž1995. 1–19.
2. Plastic deformation due to multi-indentations was iden-
w15x X.Y. Li, K.N. Tandon, Formation of an amorphous phase of Al–Si
tified as the main wear mechanism operating on the during dry wear of a Al–SirSiC P composite, Scripta Metallurgica
worn surfaces of the composites studied. et Materialia 33 Ž1995. 485–490.
3. The highest abrasion resistance of the composites was w16x Z.Y. Ma, Y.N. Liang, Y.Z. Zhang, Y.X. Lu, J. Bi, Sliding wear
found against 1000 grit Ž10 mm. for both abrasives behaviour of SiC particle reinforced 2024 aluminium alloy compos-
tested, while against abrasives with 320 grit Ž46 mm. no ites, Mater. Sci. Technol. 12 Ž1996. 751–756.
w17x S.C. Tjong, H.Z. Wang, S.Q. Wu, Wear behaviour of aluminium-
significant improvement in abrasion resistance was based metal matrix composites reinforced with a preform of alumi-
measured. nosilicate fibre, Metallurgical Transactions 27 A Ž1996. 2385–2389.
4. The abrasion resistance of the composites increased w18x A.J. Leonard, C. Perrin, W.M. Rainforth, Microstructural changes
with increasing the volume fraction of SiC p within the induced by dry sliding wear of a A357rSiC metal matrix composite,
range studied. Mater. Sci. Technol. 13 Ž1997. 41–48.
w19x G. Straffelini, F. Bonollo, A. Molinari, A. Tiziani, Influence of
5. At constant volume fraction of SiC P reinforcement, the matrix hardness on the dry sliding behaviour of 20 vol.% Al 2 O 3 -par-
abrasion resistance increased with an increase in the ticulate-reinforced 6061 Al metal matrix composite, Wear 211 Ž1997.
reinforcement size within the range studied. 192–197.
K.S. Al-Rubaie et al.r Wear 225–229 (1999) 163–173 173
w20x A.B. Gurcan, T.N. Baker, Wear behaviour of AA6061 aluminium w28x N. Axen,
´ S. Jacobson, Transitions in the abrasive wear resistance of
alloy and its composites, Wear 188 Ž1995. 185–191. fibre- and particle-reinforced aluminium, Wear 178 Ž1994. 1–7.
w21x I.M. Hutchings, Tribological properties of metal matrix composites, w29x N. Axen,
´ A. Alahelisten, S. Jacobson, Abrasive wear of alumina
Mater. Sci. Technol. 10 Ž1994. 513–517. fibre-reinforced aluminium, Wear 173 Ž1994. 95–104.
w22x K.J. Bhansali, R. Mehrabian, Abrasive wear of aluminium-matrix w30x H.N. Yoshimura, Produçao ˜ e caracterizaçao
˜ de compositos
´ de matriz
composites, Journal of Metals ŽSept. 1982. 30–34. ´
de Al reforçada com partıculas ˜ de pos,
de SiC obtidos por extrusao ´
w23x C. Garcıa-Cordovilla,
´ J. Narciso, E. Louis, Abrasive wear resistance ´
MSc Thesis, Escola Politecnica da Universidade de Sao˜ Paulo,
of aluminium alloyrceramic particulate composites, Wear 192 Ž1996. Brazil, 1994
170–177. w31x J. Larsen-Basse, Influence of size on groove formation during
w24x A.G. Wang, I.M. Hutchings, Wear of alumina fiber aluminium metal sliding abrasion, Wear 11 Ž1968. 213–222.
matrix composites by two-body abrasion, Mater. Sci. Technol. 5 w32x T.O. Mulhearn, L.E. Samuels, The abrasion of metals: a model of
Ž1989. 71–76. the process, Wear 5 Ž1962. 478–498.
w25x A. Wang, H.J. Rack, Abrasive wear of silicon carbide particulate- w33x J. Larsen-Basse, Some effects of specimen size on abrasive wear,
and whisker reinforced 7091 aluminium matrix composites, Wear Wear 19 Ž1972. 27–35.
146 Ž1991. 337–348. w34x R.W. Johnson, A Study of the pickup of abrasive particles during
w26x H.-L. Lee, W.-H. Lu, S. Chan, Abrasive wear of powder metallurgy abrasion of annealed aluminium on silicon carbide abrasive, Wear
Al alloy 6061–SiC particle composites, Wear 159 Ž1992. 223–231. 16 Ž1970. 351–358.
w27x A. Alahelisten, F. Bergman, M. Olsson, S. Hogmark, On the wear of w35x N. Axen,
´ K.-H. Zum Gahr, Verschleiß von TaC- und TiC-Laserdis-
aluminium and magnesium metal matrix composites, Wear 165 persionsschichten durch weiche und harte Abrasivstoffe, Mat.-wiss.
Ž1993. 221–226. u. Werkstofftech. 23 Ž1992. 360–367.