Cambridge International AS & A Level

CHEMISTRY9701/34
Paper 3 Advanced Practical Skills 2 May/June 2020

CONFIDENTIAL INSTRUCTIONS
*4908978104*

This document gives details of how to prepare for and administer the practical exam.

The information in this document and the identity of any materials supplied by Cambridge International
are confidential and must NOT reach candidates either directly or indirectly.

The supervisor must complete the report at the end of this document and return it with the scripts.

INSTRUCTIONS
●● If you have any queries regarding these confidential instructions, contact Cambridge International
stating the centre number, the syllabus and component number and the nature of the query.
email [email protected]
phone +44 1223 553554

This document has 8 pages. Blank pages are indicated.

IB20 06_9701_34_CI/4RP
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General information about practical exams

Centres must follow the guidance on science practical exams given in the Cambridge Handbook.

Safety

Supervisors must follow national and local regulations relating to safety and first aid.

Only those procedures described in the question paper should be attempted.

Supervisors must inform candidates that materials and apparatus used in the exam should be treated
with caution. Suitable eye protection should be used where necessary.

The following hazard codes are used in these confidential instructions, where relevant:

C corrosive MH moderate hazard

HH health hazard T acutely toxic
F flammable O oxidising
N hazardous to the aquatic environment

Hazard data sheets relating to substances used in this exam should be available from your chemical
supplier.

Before the exam

● The packets containing the question papers must not be opened before the exam.
● It is assumed that standard school laboratory facilities, as indicated in the Guide to Planning
Practical Science, will be available.
● Spare materials and apparatus for the tasks set must be available for candidates, if required.

During the exam

● It must be made clear to candidates at the start of the exam that they may request spare materials
and apparatus for the tasks set.
● Where specified, the supervisor must perform the experiments and record the results as instructed.
This must be done out of sight of the candidates, using the same materials and apparatus as the
candidates.
● Any assistance provided to candidates must be recorded in the supervisor’s report.
● If any materials or apparatus need to be replaced, for example, in the event of breakage or loss,
this must be recorded in the supervisor’s report.

After the exam

● The supervisor must complete a report for each practical session held and each laboratory used.
● Each packet of scripts returned to Cambridge International must contain the following items:

● the scripts of the candidates specified on the bar code label provided
● the supervisor’s results relevant to these candidates
● the supervisor’s reports relevant to these candidates
● seating plans for each practical session, referring to each candidate by candidate number
● the attendance register.

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Specific information for this practical exam

During the exam, the supervisor (NOT the invigilator) must do all the experiments and
record the results on a spare copy of the question paper, clearly labelled ‘supervisor’s
results’.

If chemicals are prepared in more than one batch, clearly labelled supervisor’s results
must be provided for each batch. The candidates using each batch must be listed on the
supervisor’s report.

Apparatus

The apparatus listed must be provided to each candidate.

1 × pipette filler
1 × 10 cm3 pipette
1 × 25 cm3 pipette
1 × 50 cm3 burette
2 × 150 cm3 or 250 cm3 conical flask
1 × burette stand and clamp
1 × 250 cm3 beaker
1 × funnel (for filling burette)
1 × white tile
1 × stopclock
2 × teat/dropping pipette
1 × spatula
1 × crucible with lid (approximate capacity 15 cm3)
1 × crucible tongs
1 × pipe-clay triangle
1 × tripod
1 × gauze
1 × Bunsen burner
1 × heat-proof mat
1 × test-tube holder
8 × test-tube*
1 × test-tube rack
wash bottle containing distilled water
pen for labelling glassware
paper towels
access to a balance weighing to at least 0.1 g
red and blue litmus papers
aluminium foil for testing nitrate/nitrite
wooden splints
the apparatus normally used in the centre for use with limewater in testing for carbon dioxide

*Candidates are expected to rinse and reuse test-tubes and boiling tubes where possible.
Additional tubes should be available.

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 Materials

The materials listed in the table must be provided to each candidate.

© UCLES 2020
Warning: small amounts of SO2 [C] [T], which can cause respiratory distress in some people, may be produced. The laboratory must be well
ventilated.

per
label identity notes
candidate
0.131 mol dm–3
FB 1 50 cm3 Dissolve 37.5 g of Na2CO3•10H2O [MH] in each dm3 of solution.
sodium carbonate
0.20 mol dm‒3 Dilute 100 cm3 of 2.0 mol dm–3 HCl, to 1 dm3. See current syllabus for
FB 2 120 cm3
hydrochloric acid preparation of 2.0 mol dm–3 HCl.
0.100 mol dm‒3
FB 3 120 cm3 Dissolve 4.00 g of NaOH [C] in each dm3 of solution.
sodium hydroxide
bromophenol blue [F][MH]
10 cm3 bromophenol blue indicator See preparation instructions in the current syllabus.
[HH]
4

FB 4 2.6 ± 0.1 g hydrated magnesium sulfate Provide 2.6 ± 0.1 g of MgSO4•7H2O in a stoppered container.

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FB 5 [F][N] 1g zinc powder Provide 1 g of Zn powder [F][N] in a stoppered container.

FB 6 [C][N] 10 cm3 0.2 mol dm‒3 zinc sulfate Dissolve 57.5 g of ZnSO4•7H2O [C][MH][N] in each dm3 of solution.

Dilute 200 cm3 of CH3COCH3 [F][MH] in 1 dm3 of solution. Provide

FB 7 [F][MH][HH] 5 cm3 20% aqueous propanone
5 cm3 in a stoppered container.
Add 800 cm3 of 1.0 mol dm–3 H2SO4 [MH] to 8.0 g of NH4VO3 [T].
aqueous 0.07 mol dm–3 Carefully add 160 cm3 of concentrated H2SO4 [C] and stir to dissolve
ammonium vanadate(V) 10 cm3 ammonium vanadate(V) in the solid. Make the solution up to 1 dm3 with distilled water. Suppliers
[C] 3.7 mol dm–3 sulfuric acid may provide NH4VO3 as ammonium vanadate(V), ammonium
metavanadate or ammonium polytrioxovanadate.
 per
label identity notes
candidate

© UCLES 2020
dilute hydrochloric acid 10 cm3 2.0 mol dm–3 HCl

dilute nitric acid [C] 10 cm3 2.0 mol dm–3 HNO3

dilute sulfuric acid [MH] 10 cm3 1.0 mol dm–3 H2SO4

aqueous ammonia [C][MH][N] 10 cm3 2.0 mol dm–3 NH3 See preparation instructions in the current syllabus.

aqueous sodium hydroxide [C] 10 cm3 2.0 mol dm–3 NaOH If necessary, each of these reagents can be provided as a
communal supply for groups of up to 6 candidates.
aqueous barium chloride 0.1 mol dm–3 BaCl 2
3
or 10 cm or Invigilators must be alert to the risk of contamination and the
aqueous barium nitrate 0.1 mol dm–3 Ba(NO3)2 opportunity for malpractice when using a communal supply.
saturated aqueous
limewater [MH] 10 cm3
5

calcium hydroxide, Ca(OH)2

aqueous silver nitrate 10 cm3 0.05 mol dm–3 AgNO3

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aqueous acidified 0.01 mol dm–3 KMnO4 in
10 cm3
potassium manganate(VII) [MH] 0.5 mol dm–3 H2SO4

● An excess of at least 10% of each material must be prepared to cover accidental loss.

● All solutions must be thoroughly mixed.

● If you are unable to source any of these chemicals, you must contact Cambridge International as far as possible in advance of the exam for
advice.

● Materials must be labelled only as specified in the ‘label’ column. The identities of chemicals labelled with letter codes, e.g. FB 1, may
be different from their descriptions in the question paper. Candidates must use the descriptions given in the question paper.

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BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of the University of
Cambridge Local Examinations Syndicate (UCLES), which itself is a department of the University of Cambridge.

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Supervisor’s report

Syllabus and component number /

Centre number

Centre name ��������������������������������������������������������������������������������������������������������������������������������������������

Time of the practical session �������������������������������������������������������������������������������������������������������������������

Laboratory name/number ������������������������������������������������������������������������������������������������������������������������

Give details of any difficulties experienced by the centre or by candidates (include the relevant
candidate names and candidate numbers).

You must include:

●  ny difficulties experienced by the centre in the preparation of materials

a
● any difficulties experienced by candidates, e.g. due to faulty materials or apparatus
● any specific assistance given to candidates.

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If chemicals have been prepared in more than one batch, list the candidates using each batch.

Declaration

1 Each packet that I am returning to Cambridge International contains the following items:

the scripts of the candidates specified on the bar code label provided
the supervisor’s results relevant to these candidates
the supervisor’s reports relevant to these candidates
seating plans for each practical session, referring to each candidate by candidate number
the attendance register.

2 Where the practical exam has taken place in more than one practical session, I have clearly
labelled the supervisor’s results, supervisor’s reports and seating plans with the time and laboratory
name/number for each practical session.

3 I have included details of difficulties relating to each practical session experienced by the centre or
by candidates.

4 I have reported any other adverse circumstances affecting candidates, e.g. illness, bereavement or
temporary injury, directly to Cambridge International on a special consideration form.

Signed ....................................................................................................... (supervisor)

Name (in block capitals) ............................................................................

© UCLES 2020 9701/34/CI/M/J/20