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    WORK SHEET 1 Chemical Kinetics

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    kishorasree

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    WORK SHEET 1 Chemical Kinetics

    Uploaded by

    kishorasree
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    WORK SHEET 1 chemical kinetics

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    10 views5 pages

    WORK SHEET 1 Chemical Kinetics

    Uploaded by

    kishorasree

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    WORK SHEET

    STD : 12 CHEMICAL KINETICS

    CASE BASED QUESTIONS

    1.The half-life of a reaction is the time required for the concentration of reactant to decrease
    by half, i.e.,[A]t = [A]/2 For first order reaction t1/2 = 0.693/k this means t1/2 is independent of
    initial concentration. Figure shows that typical variation of concentration of reactant
    exhibiting first order kinetics. It may be noted that though the major portion of the first order
    kinetics may be over in a finite time, but the reaction will never cease as the concentration of
    reactant will be zero only at infinite time.

    The following questions are multiple choice question. Choose the most appropriate
    answer:
    i)A first order reaction has a rate constant k=3.01 x 10-3 /s. How long it will take to
    decompose half of the reactant?
    (ii) The rate constant for a first order reaction is 7.0 x 10-4 s-1. If initial concentration of
    reactant is 0.080 M, what is the half-life of reaction?
    (iii) For the half-life period of a first order reaction, which one of the following
    statements is generally false?
    (iv) The rate of a first order reaction is 0.04 mol L-1 s-1 at 10 minutes and 0.03 mol L-1 s-
    1
    at 20 minutes after initiation. The half life of the reaction is

    OR

    The plot of t1/2 vs initial concentration [A]0 for a first order reaction is given by

    2.Read the given passage and answer the questions:


    Zero order reactions are relatively uncommon but they occur under special conditions. Some
    enzyme catalysed reactions and reactions which occurs on metal surfaces are a few examples
    of zero order reactions. The decompositions which occurs on metal surfaces are a few
    examples of zero order reactions. The decomposition of gaseous ammonia on a hot platinum
    surface is a zero order reaction at high pressure.
    2NH3(g) −−−−−→ N2(g) + 3H2(g) Rate=K[NH3]0=K

    In this reaction, Pt acts as a catalyst. At high pressure, the metal surface gets saturated with
    gas molecules. So a further change in reaction conditions is unable to alter the amount of
    ammonia on the surface of the catalyst making the rate of the reaction independent of its
    concentration.

    1. What are zero order reactions?


    2.If [R]0 And [R] are the concentrations of the reactant initially and after time t, give
    the equation relating k.

    3.Why is the decomposition of NH3 on Pt surface a zero order reaction?

    4.The rate of reaction is concerned with decrease in concentration of reactants or increase in


    the concentration of products per unit time. It can be expressed as instantaneous rate at a
    particular instant of time and average rate over a large interval of time. Mathematical
    representation of rate of reaction is given by rate law. Rate constant and order of a reaction
    can be determined from rate law or its integrated rate equation.
    a.What happens to rate of reaction for zero order reaction?
    b.What is the unit of k for zero order reaction?

    5.The rate of reaction is concerned with decrease in concentration of reactants or increase in the
    concentration of products per unit time. It can be expressed as instantaneous rate at a particular instant of
    time and average rate over a large interval of time. Mathematical representation of rate of reaction is given
    by rate law. Rate constant and order of a reaction can be determined from rate law or its integrated rate
    equation.

    i.For a reaction P + 2Q Products


    Rate = k[P]1/2 [Q]1. What is the order of the reaction?

    ii.Define pseudo first order reaction with an example.

    6.The rate of reaction is concerned with decrease in concentration of reactants or increase in


    the concentration of products per unit time. It can be expressed as instantaneous rate at a
    particular instant of time and average rate over a large interval of time. A number of factors
    such as temperature, concentration of reactants, catalyst affect the rate of reaction.
    Mathematical representation of rate of a reaction is given by rate law:
    Rate = k[A]x [B]y
    x and y indicate how sensitive the rate is to the change in concentration of A and B. Sum of x
    + y gives the overall order of a reaction.
    When a sequence of elementary reactions gives us the products, the reactions are called
    complex reactions. Molecularity and order of an elementary reaction are same. Zero order
    reactions are relatively uncommon but they occur under special conditions. All natural and
    artificial radioactive decay of unstable nuclei take place by first order kinetics.
    1.What is the effect of temperature on the rate constant of a reaction?
    2. How order and molecularity are different for complex reactions?

    SHORT ANSWER BASED QUESTION AND NUMERICALS

    7.A first order reaction is 40% complete in 80 minutes. Calculate the value of rate constant
    (k). In what time will the reaction be 90% completed?
    8.A first order reaction is 50% completed in 40 minutes at 300 K and in 20 minutes at 320 K.
    9.Calculate the activation energy of the reaction. (Given : log 2 = 0·3010, log 4 = 0·6021, R =
    8·314JK–1 mol–1)
    10.A first reaction has rate constant of 𝟎. 𝟎𝟎𝟓𝟏 𝒎𝒊𝒏 𝟏. If we begin with 0.10 M
    concentration of the reactant. What concentration of the reactant will be left after 3hours?
    11.The decomposition of NH3 on platinum surface is zero order reaction. If rate constant (k)
    is 4 x10–3 Ms–1 , how long will it take to reduce the initial concentration of NH3 from
    0.1 M to 0.064 M.
    12.The decomposition of on platinum surface is zero order reaction. What are the rates of
    production of and if ?

    ASSERTIION AND REASIN BASED QUESTION

    13.Assertion : Precipitation of silver chloride occurs instantaneously by mixing of aqueous


    solutions of silver nitrate and sodium chloride.
    Reason : Ionic reactions occur very fast.
    14.Assertion : The rate of reaction is the rate of change of concentration of a reactant or a
    product.
    Reason : Rate of reaction remians constant during the complete reaction.
    15.Assertion : Molecularity greater than three is not observed.
    Reason : The overall molecularity of complex reaction is equal to molecularity of the
    slowest step.
    16.Assertion : For a chemical reaction with rise in temperature by
    10∘ The rate constant is nearly doubled.
    Reason : At t + 10, the fraction of molecules having energy equal to or greater
    than activation energy gets doubled.

    17.Assertion : Rate of reaction increases with increase in temperature.


    Reason : Number of effective collisions increases with increase in temperature.

    18.Assertion: All collisions of reactant molecules do not lead to product


    Formation.
    Reason: Only those collisions in which molecules have correct orientation And
    sufficient kinetic energy lead to compound formation.

    19.Assertion: The enthalpy of reaction remains constant in the presence of a


    Catalyst
    Reason: A catalyst lowers down the activation energy but the Difference in
    energy of reactant and product remains same
    MATCH THE FOLLOWING QUESTION

    20.Column I Column II
    (a) Diamond (i) short interval of time
    (b) Instantaneous rate (ii) ordinarily rate of conversion is imperceptible
    c.Average rate (iii) long duration of time

    STATEMENT BASED QUESTION

    1.Increasing temperature will increase the rate of a reaction.


    2.If a solid is broken into small pieces it has a smaller surface area.
    3Catalysts have no effect on a chemical reaction because they are not used up.
    4.Increases in concentration make particles collide more frequently.
    5For particles to react, they must collide with enough energy.
    6.Adding a catalyst increases the activation energy for a reaction.
    7.Increasing concentration will increase the number of particles in the same
    volume.
    8.If pressure is decreased, there is less space between particles.
    9.The minimum energy that particles must collide with in order to react is called
    the activation energy.

    10 Catalysts must be shown in the chemical equation for a reaction.


    11.The hydrolysis of ester in alkaline medium is a
    12All radioactive decompoistion reactions are……first……..order reactions.
    13.Negative catalyst stop chemical reactions.
    14.A first order reaction has very high value of activation energy.
    The molecularity of a complex reaction is always greater than the order of the
    reaction.
    15. For a zero order reaction, the half-life period is independent of the initial
    concentration.
    16. 𝑥𝑔 of a radioactive substance will be decomposed to 7/8𝑥𝑔 in 40𝑠 if the half-
    life periof is 10 𝑠
    17.For a first order reaction, the half-life periof is 0.263 𝑘
    18.The difference between the energy maximum along a reaction path and the
    energy of the reactant is called activation energy.
    19. The slope of straight line in a plot of log.[𝐴] versus time for a first order raction
    is equal to -𝑘/2.303
    20.In a gaseous reaction, an increase in the pressure of the reactant gases increases
    the rate of reaction.

    .....................................................................................

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