Cty - 2325 Jee Mains

FIITJEE – JEE (Main)
Physics, Chemistry & Mathematics

QP Code:
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
TWO YEAR CRP–2325
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question carries +4 marks which will be awarded for every
correct answer and -1 mark will be deducted for every incorrect answer.
(ii) Part-B (01-05) contains five (05) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+4 marks for correct answer and there will be no negative marking.
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Enrolment Number :___________________________________________________
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TWO YEAR CRP-2325_PHASE-1_A-LOT_Main-1
PHYSICS
Only one correct option
Each question has four choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
1. The maximum number of components in which a vector can be resolved is

(A) 2 (B) 3
(C) Infinite (D) 4
2. The angle made by 𝑣⃗ = 6𝚤̂ + 4√2𝚥̂ + 4√2𝑘 with positive direction of 𝑥-axis is
√
(A) cos (B) cos
√
(C) cos (D) cos 2√2
3. Two uniform rods A and B of masses 𝑚 and 2𝑚 respectively are placed end to end as shown, on
a smooth horizontal surface and horizontal forces 10𝐹 and 2𝐹 are applied. Find the difference
of the magnitudes of the forces acting at the mid-points of A and B.
(A) 2𝐹 (B) 4𝐹
(C) 5𝐹 (D) 6𝐹
4. If two vectors 𝑎⃗ and 𝑏⃗ satisfy the relation 𝑎⃗. 𝑏⃗ = 𝑎⃗ × 𝑏⃗ , then the value of 𝑎⃗ − 𝑏⃗ will be
(A) √𝑎 + 𝑏 (B) 𝑎 + 𝑏 + √2𝑎𝑏
(C) √𝑎 + 𝑏 + 2𝑎𝑏 (D) 𝑎 + 𝑏 − √2𝑎𝑏
5. The component vector of 𝑎⃗ = 2𝚤̂ + 3𝚥̂ − 𝑘 in the direction of 𝑏⃗ = 𝚤̂ + 2𝚥̂, is

(A) (𝚤̂ + 2𝚥̂) (B) (𝚤̂ + 2𝚥̂)
(C) 2𝚤̂ + 3𝚥̂ − 𝑘 (D) 2𝚤̂ + 3𝚥̂ − 𝑘

SPACE FOR ROUGH WORK
Limited, Second Floor, Saraswati Bhawan, Lotus Link Square, New Link Road, Opp. D.N. Nagar Metro Gate No. 4, Andheri (W), Mumbai 400 053 Maharashtra
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6. A particle is projected horizontally from the top of a cliff of height H with a speed 2𝑔𝐻. The
radius of curvature of the trajectory at the instant of projection will be
(A) (B) 𝐻
(C) 2𝐻 (D) ∞
7. A particle is moving in 𝑥𝑦-plane at 10 m/s along 𝑦-axis. Two seconds later, its velocity is 20 m/s
along a direction making an angle of 30° with positive 𝑥-axis. Its average acceleration in this time
interval is
(A) 5√3 𝑚𝑠 along positive 𝑥-axis (B) 5√3 𝑚𝑠 along positive 𝑦-axis
(C) √3 𝑚𝑠 along negative 𝑥-axis (D) √3 𝑚𝑠 along negative 𝑦-axis
8. Find the maximum safe speed with which a vehicle can be driven on a circular banked road of
radius 10 m and angle of banking 37°. The coefficient of static friction between the tyres and the
road is 0.5 (Take 𝑔 = 10 𝑚𝑠 )
(A) 10 𝑚𝑠 (B) 10√2 𝑚𝑠
(C) 5 𝑚𝑠 (D) 5√2 𝑚𝑠
9. A block of mass 1 kg slides down a circular track that is one quadrant of a circle of radius 1 m.
Its speed at the bottom is 2 𝑚𝑠 . The work done by the friction force is (Take 𝑔 = 10 𝑚𝑠 )
(A) −8𝐽 (B) 8𝐽

(C) 9𝐽 (D) −9𝐽
10. If 𝑎⃗ is along north direction and 𝑏⃗ is along vertically upward direction, then 𝑏⃗ × 𝑎⃗ is directed
along
(A) East (B) West
(C) South (D) Vertically
11. The velocity displacement graph describing the motion of a bicycle is shown in the figure.
The acceleration displacement graph is best described by
(A) (B)
(C) (D)
12. The force F to be applied on the triangular block of mass M so that the block of mass m placed
on it appears stationary with respect to the wedge, is
(A) 𝑚𝑔 tan 𝜃 (B) (𝑀 + 𝑚)𝑔 tan 𝜃

(C) (𝑀 + 𝑚)𝑔 cos 𝜃 (D) (𝑀 + 𝑚)𝑔 sin 𝜃
13. A projectile is fired with velocity 𝑢 at right angles to the slope, which is inclined at an angle 𝜃
with the horizontal. The expression for the range R is
(A) sin 𝜃 cot 𝜃 (B) tan 𝜃 sec 𝜃
(C) tan 𝜃 (D) sin 2𝜃
14. A boat which has a speed of 5 km/hr in still water, crosses a river of width 1 km along the
shortest path in 15 minutes. The speed of river water in km/hr is
(A) 1 (B) 2
(C) 3 (D) √41
15. The frictional force on the block of mass 2 kg is (Take 𝑔 = 10 𝑚𝑠 )
(A) 16N (B) 40N

(C) 14N (D) 10N
16. Find the acceleration of block of mass m. Assume pulleys are massless and frictionless.
(A) (B)
(C) (D) none of the above
17. If the kinetic energy of a moving body becomes 4 times its initial energy, then the percentage
change in its momentum will be
(A) 100% (B) 200%
(C) 300% (D) 400%
18. The coefficient of static friction between a wooden block of mass 0.5 kg and a vertical rough wall
is 0.2. The magnitude of horizontal force that should be applied on the block to keep it adhere to
the wall will be (Take 𝑔 = 10 𝑚𝑠 )
(A) 25𝑁 (B) 50𝑁
(C) 2.5𝑁 (D) 5𝑁
19. If in the vertical circular motion of an object connected to a string of length 1 metre, the object
is given a speed of 5 m/s at the lowest point, find the height at which the string will become slack.
(Take 𝑔 = 10 𝑚𝑠 )
(A) 𝑚 (B) 𝑚
(C) 𝑚 (D) 𝑚
20. A helicopter is flying horizontally with a speed 𝑣 at an altitude ℎ has to drop a food packet for a
man on the ground. What is the distance of helicopter from the man when the food packet is
dropped?
(A) (B) 2𝑔ℎ𝑣 + ℎ
(C) +ℎ (D) +ℎ
Numerical Based Questions

This section contains 5 questions. Each question enter the correct numeric value (in decimal notation,
truncated/rounded off to second decimal place.
21. When a body slides down from rest along a smooth inclined plane making an angle of 30° with
the horizontal, it takes time T. When the same body slides down from rest along a rough incline
plane making the same angle and through the same distance it takes a time 𝛼𝑇; Where, 𝛼 is a
constant greater than 1. The coeficiente of friction between the body and the rough plane is
. . Find the value of 𝑥.

√
22. The position of a particle moving along a straight line is given as 𝑥 = 2𝑡 + 4𝑡 + 7 (𝑥 is in metre
and 𝑡 is in second) Average acceleration in the interval [1,4] is 5𝑛 (in 𝑚𝑠 ). Find the value of 𝑛.
23. Two blocks of masses 8 kg and 4 kg are connected by a string as shown. Intially, they are at rest
on the floor. A vertically upward force of 𝐹 = 100𝑁 is applied on the pulley. Find the difference
between the initial accelerations of 4 kg block and 8 kg block in 𝑚𝑠 . (Take 𝑔 = 10 𝑚𝑠 )
24. Two persons A and B running along a circular track start from same position in same direction.
A and B both run with constant speeds of 12 m/s and 8 m/s respectively. The radius of circular
track is 70 metre. The time after which both A and B meet, is T second. The actual distance
( )
covered by A is D metre. Then find the value of
25. A force 𝐹 = (15 + 0.50𝑥)𝑁 acts on a particle in 𝑥-direction. The work done by this force during
displacement from 𝑥 = 0 to 2 (𝑥 is in metre) is 4𝑛 (in joule). Find the value of 𝑛.
CHEMISTRY
26. Which quantum number define the orientation of orbitals in the space around the nucleus?
(A) Principal quantum number (B) Angular momentum quantum
(C) Magnetic quantum number (D) Spin quantum number
27. The set representing correct order of ionic radius is

(A) 𝑁𝑎 > 𝐿𝑖 > 𝑚𝑔 > 𝐵𝑒 (B) 𝐿𝑖 > 𝑁𝑎 > 𝑚𝑔 > 𝐵𝑒
(C) 𝑚𝑔 > 𝐵𝑒 > 𝐿𝑖 > 𝑁𝑎 (D) 𝐿𝑖 > 𝐵𝑒 > 𝑁𝑎 > 𝑚𝑔
28. The ion having a noble gas configuration is

(A) 𝑆𝑒 (B) 𝐹𝑒
(C) 𝐶𝑟 (D) 𝐶𝑢
29. The molecular orbital with highest energy in a nitrogen molecule is

(A) 𝜎 (B) 𝜋
(C) 𝜎∗ (D) 𝜋∗
30. Correct order of increasing 𝑥 − 0 − 𝑥 bond angle is (𝑥 = 𝐻, 𝐹, 𝐶𝑙)

(A) 𝐻 𝑂 > 𝐶𝑙 𝑂 > 𝐹 𝑂 (B) 𝐶𝑙 𝑂 > 𝐻 𝑂 > 𝐹 𝑂
(C) 𝐹 𝑂 > 𝐶𝑙 𝑂 > 𝐻 𝑂 (D) 𝐹 𝑂 > 𝐻 𝑂 > 𝐶𝑙 𝑂
31. The orbital which does not participate in 𝑠𝑝 𝑑 hybridisation.

(A) 𝑝 (B) 𝑑
(C) 𝑑 (D) 𝑝
32. Among the following back bonding is exhibited by

(A) 𝑁𝐹 (B) (𝐶𝐻 ) 𝑁
(C) 𝐶𝐻 𝑁𝐶𝑂 (D) 𝑆𝑖𝐻 𝑁𝐶𝑂
33. The electron identified by quantum number 𝑛 and 𝑙

(a) 𝑛 = 4, 𝑙 = 1 (b) 𝑛 = 4, 𝑙 = 0
(c) 𝑛 = 3, 𝑙 = 2 (d) 𝑛 = 3, 𝑙 = 1
Can be placed in order of increasing energy as
(A) 𝑐<𝑑<𝑏<𝑎 (B) 𝑑<𝑏<𝑐<𝑎
(C) 𝑏<𝑑<𝑎<𝑐 (D) 𝑎<𝑐<𝑏<𝑑
34. A 5.0 𝑐𝑚 solution of 𝐻 𝑂 liberates 0.508 𝑔𝑚 of 𝐼 from an acidified 𝐾𝐼 solution. The strength
of 𝐻 𝑂 solution in terms of volume strength at STP is
(A) 2.24 𝑉 (B) 1.12 𝑉
(C) 4.48 𝑉 (D) 8.96 𝑉
35. Equal weight of 𝑍𝑛 metal and iodine are mixed together and the iodine is completely converted
to 𝑍𝑛𝐼 . What fraction of weight of the original zinc remains unreacted. (At weight 𝑍𝑛 = 65)
(A) 0.500 (B) 0.744
(C) 0.488 (D) 0.256
36. 𝐵𝑒 reacts with excess of caustic soda to form

(A) 𝐵𝑒(𝑂𝐻) (B) 𝐵𝑒𝑂
(C) 𝑁𝑎 [𝐵𝑒(𝑂𝐻) ] (D) 𝐵𝑒(𝑂𝐻) . 𝐵𝑒𝐶𝑂
37. What product will be obtained when 𝑀𝑔𝐶𝑂 dissolved in hot dil. 𝐻 𝑆𝑂 ?
(A) 𝑀𝑔𝑆𝑂 , 𝐻 𝑂, 𝐶𝑂 (B) 𝑀𝑔𝑆, 𝐻 𝑂, 𝐶𝑂
(C) 𝑀𝑔𝑆𝑂 , 𝐻 𝐶𝑂 (D) 𝑀𝑔𝑆, 𝐻 𝐶𝑂
38. Chemical (A) is used for water softening to remove temporary hardness. A reacts with 𝑁𝑎 𝐶𝑂
to generate caustic soda. When 𝐶𝑂 is bubled through (A) it turns cloudy. What is chemical
formula of A.
(A) 𝐶𝑎𝐶𝑂 (B) 𝐶𝑎𝑂
(C) 𝐶𝑎(𝑂𝐻) (D) 𝐶𝑎(𝐻𝐶𝑂 )
39. The products obtained on heating 𝐿𝑖𝑁𝑂 will be

(A) 𝐿𝑖 𝑂 + 𝑁𝑂 + 𝑂 (B) 𝐿𝑖 𝑁 + 𝑂
(C) 𝐿𝑖 𝑂 + 𝑁𝑂 + 𝑂 (D) 𝐿𝑖𝑁𝑂 + 𝑂
40. Compressibility factor for 𝐻 behaving as real gas is

(A) 1 (B) 1−
(C) 1+ (D)
41. The Vander Waal gas constant 𝑎 is given by

(A) 𝑣 (B) 3𝑃 𝑣
(C) (D)
42. The root mean square speed of gas molecules at a temperature 27K and pressure 1.5 bar is
1 × 10 cm/sec. If both temperature and pressure are raised three times, calculate new rms
speed of gas molecule.
(A) 1.73 × 10 cm/sec. (B) 1.414 × 10 cm/sec.
(C) 1.73 × 10 cm/sec. (D) 1.414 × 10 cm/sec.
43. Arrange following compound in order of increasing dipole moment toluene (I), m-
dichlorobenzene (II), o-dichlorobenzene (III), p-dichlorobenzene (IV)
(A) I < IV < II < III (B) IV < I < II < III
(C) IV < I < III < II (D) IV < II < I < III
44. Which of the following is a wrong order with respect to property mentioned against each?
(A) 𝑂 > 𝑂 > 𝑂 (Paramagnetic moment)
(B) 𝑁𝑂 > 𝑁𝑂 > 𝑁𝑂 (Bond length)
(C) 𝐻 > 𝐻 > 𝐻𝑒 (Bond energy)
(D) 𝑁𝑂 > 𝑁𝑂 > 𝑁𝑂 (Bond angle)
45. The pair that has similar atomic radii is

(A) 𝑇𝑖 and 𝐻 (B) 𝑀𝑜 and 𝑊
(C) 𝑆𝑐 and 𝑁𝑖 (D) 𝑀𝑛 and 𝑅𝑒

46. A moving particle is associated with wavelength 5 × 10 m if its momentum is reduced to half
of its value, compute the new wavelength. If answer is 10 then find 𝑥.
47. An electron is continuously accelerated in vacuum tube by applying potential difference. If its
de-Broglie wavelength is decreased by 1%. The percentage change in kinetic energy of electron
is
48. The radius (𝐴°) of the second Bohr orbit for hydrogen atom is
49. According to molecular orbitals theory, the number of electron present in antibonding molecular
orbitals of 𝑁 is
50. How many gram of magnesium can be completely dissolved in 400 ml of 0.1𝑀 𝐻𝐶𝑙 solution?
𝑀𝑔 + 2𝐻𝐶𝑙 ⟶ 𝑀𝑔𝐶𝑙 + 𝐻
MATHEMATICS
51. In a sport event of 100 sport persons, there are 27 Indian Men and 30 Indian Women out of
which 5 are Wrestler and 30 are either Indian Men or Wrestler. It is given that no foreign player
is wrestler, then
(A) No. of foreign players are 40 (B) No. of female wrestlers are 2
(C) No. of male wrestlers are 3 (D) No. of female or wrestlers are 32
52. If 𝑥 = 1 + log 𝑏𝑐 , 𝑦 = 1 + log 𝑎𝑏 , 𝑧 = 1 + log 𝑎𝑐 and = = ; where, 𝑥 + 𝑦 + 𝑧 =
3 (𝑥, 𝑦, 𝑧 > 0) then correct option is

(A) 𝑥𝑦𝑧 = 3 (B) 𝑥𝑦 + 𝑦𝑧 + 𝑧𝑥 = 5
(C) 𝑥+𝑦+𝑧 =2 (D) None of these
53. Domain of 𝑓(𝑥) = is subset of

( ) ( )
(A) [−1,4] (B) [0,5]

(C) [1,4] (D) [1,5]
54. Solution set of the inequality |𝑥 + 𝑥 + 7| − 6 − 7 + |𝑥 − 𝑥 + 3| − 5 ≤ 2|𝑥 − 2| is proper
subset of
(A) [−4,1] (B) [−3,2]
(C) [−2,3] (D) [−1,4]
55. Solution of inequality 3 + 2 − √3 ≤ 10 − 4√3 is

(A) 𝑥≤2 (B) 2≤𝑥<4
(C) 𝑥≥4 (D) 4 ≤ 𝑥 < 12
( )
56. Value of ∫ ( )
𝑑𝑥 + ∫ 𝑑𝑥 is
(A) tan 𝑒 − 1 (B) tan 𝑒 − 2

(C) tan 𝑒 + 1 (D) tan 𝑒 + 2
57. If in Δ𝐴𝐵𝐶, (sin 𝐴 + sin 𝐵 + sin 𝐶)(sin 𝐴 + sin 𝐵 − sin 𝑐) = 3 sin 𝐴 sin 𝐵, then angle 𝐶 is
(A) 30° (B) 45°
(C) 60° (D) 75°
( )
58. For < 𝜃 < , Solution of ∑ cosec 𝜃 + cosec 𝜃 + = 4√2 is
(A) (B)
(C) (D)
59. If 𝑃 divides 𝑃(0,0) and 𝑄(2187, 4374) in ratio 2: 1 and 𝑃 divides 𝑃 𝑄 in 2: 1 and so on then
coordinate of 𝑃 is
(A) (2184, 4368) (B) (2185, 4370)
(C) (2186, 4372) (D) (2188, 4370)
60. If a rod 𝐴𝐵 of length 2 moves in a plane in such a way that one end always lies on circle (𝑥 − 1) +
𝑦 = 4 and rod 𝐴𝐵 makes 60° with positive direction of 𝑥-axis (anti-clockwise) then locus of mid
point of rod 𝐴𝐵 is
(A) 𝑥 + 𝑦 − 3𝑥 − 3𝑦 − 1 = 0 (B) 𝑥 + 𝑦 − 3𝑥 − √3𝑦 − 1 = 0
(C) 𝑥 + 𝑦 − 3𝑥 + 3𝑦 − 1 = 0 (D) 𝑥 + 𝑦 − 3𝑥 − √3𝑦 + 1 = 0
61. If the lines 𝑥 sin 𝜃 − 𝑦 − cos 𝜃 = 0 , 𝑥 sin 𝜃 + 𝜆𝑦 + cos 𝜃 = 0, 𝑥 cos 𝜃 + 𝑦 + sin 𝜃 = 0, (𝜆, 𝜃𝜖𝑅) are
concurrent, then possible value of 𝜆 is
(A) √2 (B) √3
(C) 2 (D) √5
62. If the lines 2𝑥 + 𝑦 − 1 = 0, 𝜆𝑥 + 𝑦 − 3 = 0, 3𝑥 − 2𝑦 + 1 = 0 cannot form a triangle then product

of all possible values of 𝜆 is
(A) 16 (B) –16
(C) 48 (D) –48
63. In a Δ𝐴𝐵𝐶 if 𝐴(1,2) and 𝐷(5,6) is mid-point of 𝐵𝐶 and 𝑥 − 𝑦 + 3 = 0 is internal angle bisector of
∠𝐴𝐵𝐶. Then coordinate of vertex 𝐶 is
(A) (2,15) (B) (8,7)
(C) (−1,1) (D) (11,8)
64. Two sides of rhombus 𝐴𝐵𝐶𝐷 are parallel to line 𝑦 = 𝑥 + 2 and 𝑦 = 7𝑥 + 3. If diagonal of
rhombus intersect at point (1,2) and vertex A is on 𝑦-axis, then possible vertex of A is
(A) 0, (B) 0,
(C) 0, (D) 0,
65. Let 𝑃(7,0) be fixed point and 𝑄(sin(3𝜃 − 60°) , cos(3𝜃 − 60°)) is moving point. As 𝜃 changes
from 10° to 30°. Then area swept by 𝑃𝑄 is
(A) (B)
(C) (D)
66. Straight line 2𝑥 − 3𝑦 − 1 = 0 divides circular region 𝑥 + 𝑦 ≤ 6 into two parts. Then point
which does not lies in smaller part is
(A) 2, (B) ,−
(C) ,− (D) 1, −
67. Let 𝑂 be center of circle 𝑥 + 𝑦 − 4𝑥 − 6𝑦 + 3 = 0. If tangent at 𝑃(3,0), 𝑅(5,2) meets at 𝑄 then

center of circumcircle of Δ𝑃𝑄𝑅 is
(A) , (B) ,
(C) , (D) ,
68. If 𝛼, 𝛽 are roots of 𝑥 − 9𝑥 + 𝑝 = 0. If two orthogonal circles touching both axes are drawn from
𝑃(𝛼, 𝛽), then value the of 𝑝 is
(A) 13 (B) 13.5
(C) 14 (D) 14.5
69. Let log 10 , log 𝑥 is a point on circle whose ordinates of end of diameter are 𝛽 and −𝛽;
where, 𝑥 > 0 and 𝑥 ≠ 1 for 𝑖 = 1,2,3,4. Then, value of ∑ 𝑥 can be equal to
(A) 2 (B) 3
(C) 4 (D) 5
70. If a circle passes through point of intersection of coordinate axes with lines 𝜆𝑥 − 𝑦 + 1 = 0 and
𝑥 − 2𝑦 + 3 = 0. If 𝜆 and 𝜆 are two possible values of 𝜆, then perpendicular distance of 𝑃(1,1)
from line having intercept 𝜆 and 𝜆 on 𝑥 and 𝑦-axis respectively is
(A) (B)
√ √
(C) (D)
√ √

( )
71. (𝑥 − 1) = 𝑓(𝑥)(𝑥 − 2) + 𝑎𝑥 + 𝑏. If = 𝑝𝑞𝑟 ; where, (𝑝, 𝑞, 𝑟 are prime numbers) then the
value of is
72. lim 1 − cos − cos + cos . cos = then 𝑘 is equal to

→
( )
73. Let 𝑓(𝑥) = ( )
, then the value of ∑ ° 𝑓(4 sin 2𝜃)
74. Value of ∏ sin(2𝑟 − 1) = then 𝑘 is equal to
75. Let 𝑃 be point on circle 𝑥 + 𝑦 = 4 with both coordinates being positive. Let tangent at 𝑃
intersect coordinate axes at 𝐴 and 𝐵. Let mid-point of 𝐴𝐵 is (ℎ, 𝑘). If the range of is [𝑎, 𝑏]
then 𝑎𝑏 is equal to

PHYSICS, CHEMISTRY & MATHEMATICS
ANSWER KEYS
Subject Q. Concept Ans Subject Q. Concept Ans Subject Q. Concept Code Ans
No. Code No. Code No.
PH 1 3193 C CH 26 2529 C MT 51 M120304 D
PH 2 3196 B CH 27 2537 A MT 52 M110201 D
PH 3 3249 D CH 28 2523 A MT 53 M110202, M120301 A
PH 4 3201 D CH 29 2552 C MT 54 M110202 B
PH 5 3200 A CH 30 2549 B MT 55 M111403 C
PH 6 3240 C CH 31 2547 B MT 56 M120801 C
PH 7 3223 A CH 32 2546 D MT 57 M111402 C
PH 8 3269 B CH 33 2529 B MT 58 M111401 D
PH 9 3282 A CH 34 2519 C MT 59 M110701 C
PH 10 3201 B CH 35 2504 B MT 60 M110801 B
PH 11 3218 A CH 36 2587 C MT 61 M110706, M111403 A
PH 12 3258 B CH 37 2587 A MT 62 M110704, M110706 D
PH 13 3230 B CH 38 2589 C MT 63 M110705 B
PH 14 3234 C CH 39 2583 A MT 64 M110707 A
PH 15 3266 C CH 40 2560 C MT 65 M110801 A
PH 16 3255 B CH 41 2561 D MT 66 M110705, M110802 C
PH 17 3273 A CH 42 2557 A MT 67 M110803, M110812 A
PH 18 3266 A CH 43 2550 B MT 68 M110801 B
PH 19 3281 B CH 44 2552 A MT 69 M110801 D
PH 20 3229 C CH 45 2537 B MT 70 M110801 B
PH 21 3266 3.00 CH 46 2527 7 MT 71 M120502 88.75
PH 22 3222 0.80 CH 47 2527 2 MT 72 M110601 0.25
PH 23 3256 2.50 CH 48 2525 MT 73 M111401 23

2.12
PH 24 3232 1.43 CH 49 2552 5 MT 74 M111401, M111405 64
PH 25 3272 7.75 CH 50 2504 0.48 MT 75 M110803, M111403 –6
SOLUTIONS
PHYSICS
1. C
A vector can be resolved in as many components as someone wishes.
2. B
|𝑣⃗| = 6 + 4√ 2 + 4√2 = 10
Therefore, required angle = cos = cos
3. D
Here A and B will be moving with same acceleration given by
𝑎= = …(i)
Taking left half of A as a system, for motion in horizontal direction, we have
10𝐹 − 𝐹 = 𝑎
⇒ 10𝐹 − 𝐹 = 2𝐹 …[Using equation (i)]

⇒ 𝐹 = 8𝐹
Now, taking the right half of B as a system,
𝐹 + 2𝐹 = 𝑚𝑎
⇒ 𝐹 + 2𝐹 = 4𝐹
⇒ 𝐹 = 2𝐹
∴ 𝐹 − 𝐹 = 8𝐹 − 2𝐹 = 6𝐹
4. D
𝑎⃗. 𝑏⃗
𝑎⃗ × 𝑏⃗ = 𝑎⃗ × 𝑏⃗
⇒ 𝑎𝑏 cos 𝜃 = 𝑎𝑏 sin 𝜃
⇒ 𝑎𝑏(sin 𝜃 − cos 𝜃) = 0
⇒ 𝑎 = 0 𝑜𝑟 𝑏 = 0 𝑜𝑟 sin 𝜃 − cos 𝜃 = 0
⇒ 𝑎 = 0 𝑜𝑟 𝑏 = 0 𝑜𝑟 tan 𝜃 = 1
⇒ 𝑎 = 0 𝑜𝑟 𝑏 = 0 𝑜𝑟 𝜃 = 45°
If 𝜃 = 45°, then 𝑎⃗ − 𝑏⃗ = √𝑎 + 𝑏 − 2𝑎𝑏 cos 45°
= 𝑎 + 𝑏 − √2𝑎𝑏
Or, 𝑎⃗ − 𝑏⃗ = 𝑎 + 𝑏 − √2𝑎𝑏
Which is also satisfied when either 𝑎 = 0 or 𝑏 = 0
5. A
⃗. ⃗
Component vector of 𝑎⃗ in the direction of 𝑏⃗ = 𝑏⃗
⃗
× ×
= 𝑏⃗
= 𝑏⃗ = (𝚤̂ + 2𝚥̂)
6. C
Since 𝑔⃗ ⊥ 𝑣⃗, therefore radial acceleration, 𝑎 = 𝑔
⇒ =𝑔 …(R = radius of curvature)
⇒ 𝑅= =
⇒ 𝑅 = 2𝐻
7. A
𝑣⃗ = 10𝚥̂ (in m/s)
and 𝑣⃗ = (20 cos 30°) 𝚤̂ + (20 sin 30°) 𝚥̂
⇒ 𝑣⃗ = 10√3𝚤̂ + 10𝚥̂ (in m/s)

∴ Change in velocity,
Δ𝑣⃗ = 𝑣 ⃗ − 𝑣 ⃗ = 10√3𝚤̂ (in m/s)

⃗
∴ Average acceleration, 𝑎 ⃗=
√ ̂
= = 5√3𝚤̂ (in m/s2)
8. B
𝑉 = 𝑔𝑅
° .
= 10 × 10 × . °
= 10 = 10
.
⇒𝑉 = 10√2 𝑚𝑠
9. A
Work done by frictional force = Change in mechanical energy
⇒ 𝑊 = Δ𝐾𝐸 + Δ𝑃𝐸 = 𝑚(𝑣 − 𝑣 ) − 𝑚𝑔𝑅
= 𝑚{𝑣 − 2𝑔𝑅} …(𝑣 = 0)
= × 1 × (2 − 2 × 10 × 1) = × (−16) 𝐽
⇒ 𝑊 = −8𝐽
10. B
By right hand thumb rule, 𝑏⃗ × 𝑎⃗ will be along west.
11. A
For first 200 m displacement, 𝑣 = 𝑥 + 10
Or 𝑣 = 𝑥 + 10
Differentiating both sides w.r.t., 𝑡
𝑎= 𝑣⇒𝑎= 𝑥 + 10
⇒𝑎= 𝑥+2
Which will be a straight line graph

At 𝑥 = 0, 𝑎 = 2 and at 𝑥 = 200, 𝑎 = 10
For 𝑥 = 200 𝑚 to 400 𝑚
𝑣 = 50 ⇒ 𝑎 = =0
Hence (A) is correct.

12. B
𝐹 − 𝑁𝑠𝑖𝑛 𝜃 = 𝑀𝑎 …(i)
𝑚𝑔 sin 𝜃 = 𝑚𝑎 cos 𝜃
⇒ 𝑎 = 𝑔 tan 𝜃 …(ii)
𝑁 = 𝑚𝑔 cos 𝜃 + 𝑚𝑎 sin 𝜃 …(iii)
From (i) and (iii),
𝐹 = (𝑚𝑔 cos 𝜃 sin 𝜃 + 𝑚𝑎 sin 𝜃) + 𝑀𝑎 …(iv)
Using equation (ii) & (iv),
𝐹 = 𝑚𝑔 cos 𝜃 sin 𝜃 + 𝑚𝑔 + 𝑀𝑔 tan 𝜃
= 𝑚𝑔 (cos 𝜃 + sin 𝜃) + 𝑀𝑔 tan 𝜃
= 𝑚𝑔 tan 𝜃 + 𝑀𝑔 tan 𝜃 = (𝑀 + 𝑚)𝑔 tan 𝜃
13. B
Here, 𝛽 = 𝜃, 𝛼 = 90° − 𝜃
∴ 𝛼 + 𝛽 = 90°
( ). °. ( ° )
∴𝑅= = ×
⇒𝑅= = tan 𝜃 sec 𝜃
14. C
For shortest path, 𝑉 ⃗ is along the width of the river.
∵ 𝑉 .𝑇 = 𝑤
⇒𝑉 = = =
.
⇒ 𝑉 = 4 𝑘𝑚/ℎ𝑟
∴𝑉 = (𝑉 ) − (𝑉 ) = (5) − (4) = 3 (in km/hr)
15. C
Assuming that both the blocks move towards left with common acceleration 𝑎, we get
(20 − 10)𝑁 = (3 + 2)𝑘𝑔 × 𝑎

⇒ 𝑎 = 2 𝑚𝑠
In this case, net force on 2 kg block = 2 𝑘𝑔 × 2 𝑚𝑠 = 4𝑁
So, if 𝑓 be the frictional force on this block,
𝑓 − 10𝑁 = 4𝑁 ⇒ 𝑓 = 14𝑁
Also, 𝑓 = 𝜇 𝑁 = 𝜇 𝑚𝑔 = 0.8 × 20𝑁
⇒𝑓 = 16𝑁
Thus, 𝑓 < 𝑓
Hence, the assumption that both the blocks move together with a common acceleration, is correct.
Thus, 𝑓 = 14𝑁
16. B
For string constraint, acceleration of 𝑚 will be twice that of 2𝑚.

𝑇 = 𝑚(2𝑎) = 2𝑚𝑎 …(i)
2𝑚𝑔 − 2𝑇 = 2𝑚𝑎 …(ii)
From equation (i) and (ii)
2𝑚𝑔 − 4𝑚𝑎 = 2𝑚𝑎
⇒ 𝑔 − 2𝑎 = 𝑎 ⇒ 3𝑎 = 𝑔
⇒ 𝑎=
∴ Acceleration of 𝑚 = 2𝑎 =
17. A
𝑝 = √2𝑚𝑘 …(i)
∴ 𝑝 = √2𝑚𝑘 = 2𝑚(4𝑘)
⇒ 𝑝 = 2√2𝑚𝑘 = 2𝑝 …[From equation (i)]
Therefore, percentage change in momentum, is equal to
× 100% = × 100% = 100%
18. A
𝑚 = 0.5 kg, 𝜇 = 0.2
𝐹=𝑁 …(i)
𝑓 = 𝑚𝑔 …(ii)
∵ 𝑓 ≤ 𝜇𝑁
⇒ 𝑚𝑔 ≤ 𝜇𝐹
⇒ 𝐹≥
. ×
⇒ 𝐹≥ .
𝑁
⇒ 𝐹 ≥ 25𝑁
∴ A minimum force of 25N must be applied.
19. B
Velocity at lowest point, 𝑣 = 5 𝑚𝑠
Let 𝜃 be the angle made by the string with the vertical direction at
the time when the string slacks.
At this time, 𝑇 = 0
∴ Using 𝑚𝑔 cos 𝜃 + 𝑇 =
We get, 𝑚𝑔 cos 𝜃 + 0 =
⇒ 𝑣 = 𝑔𝑙 cos 𝜃 …(i)
For conservation of 𝑀𝐸, (𝑀𝐸) = (𝑀𝐸)
⇒ 𝑚𝑣 + 0 = 𝑚𝑣 + 𝑚𝑔𝑙(1 + cos 𝜃)
⇒ 𝑣 = 𝑣 − 2𝑔𝑙(1 + cos 𝜃) …(ii)

From equation (i) and (ii), 𝑔𝑙 cos 𝜃 = 𝑣 − 2𝑔𝑙(1 + cos 𝜃)
⇒ 2𝑔𝑙 + 3𝑔𝑙 cos 𝜃 = 𝑣 ⇒ 2 + 3 cos 𝜃 =
⇒ 2 + 3 cos 𝜃 = ×
= 2.5 ⇒ 3 cos 𝜃 = 0.5
⇒ cos 𝜃 =
∴ ℎ = 𝑙(1 + cos 𝜃) = 1 × 1 + = metre
20. C
Time taken by food packet to reach the man, 𝑡 =
∴ 𝑥 = 𝑣𝑡 = 𝑣
∴𝐷 =𝑥 +ℎ = +ℎ
⇒𝐷= +ℎ
21. 3.00
Let 𝑠 be the distance moved by the body on smooth inclined
plane, we have 𝑎 = 𝑔 sin 𝜃
∴ 𝑠 = 𝑎 𝑡 ⇒ 𝑠 = (𝑔 sin 𝜃)𝑡 …(i)
On rough inclined plane
𝑎 =
⇒𝑎 =
⇒𝑎 = = 𝑔 sin 𝜃 − 𝜇𝑔 cos 𝜃
⇒ 𝑎 = 𝑔(sin 𝜃 − 𝜇 cos 𝜃)
∴ 𝑠 = 𝑎 (𝛼𝑇)
⇒ 𝑠 = 𝑔(sin 𝜃 − 𝜇 cos 𝜃)𝛼 𝑇 …(ii)
From equation (i) and (ii), 𝛼 (sin 𝜃 − 𝜇 cos 𝜃) = sin 𝜃
⇒ sin 𝜃 − 𝜇 cos 𝜃 = ⇒ 𝜇 cos 𝜃 = sin 𝜃 1 −
⇒ 𝜇 = tan 𝜃 = tan 30° =

√
22. 0.80
𝑥 = 2𝑡 + 4𝑡 + 2
⇒𝑣= = 4𝑡 + 4 = 4(𝑡 + 1)
× ×
Therefore, average acceleration in the interval [1,4], is 𝑎 = = = 4 𝑚𝑠
Hence, 5𝑛 = 4 ⇒ 𝑛 = = 0.80
23. 2.50
Tension in the string, 𝑇 =
or, 𝑇 = 50𝑁
For 8 kg, T < Weight
Therefore, normal force will act on 8 kg to keep it at rest.
Therefore, its acceleration 𝑎 = 0
For 4 kg, T > Weight
Therefore, 4 kg will be lifted up and will move with acceleration,
𝑎 = = = 2.5 𝑚𝑠
Therefore, required difference, 𝑎 − 𝑎 = 2.5 𝑚𝑠
24. 1.43
Relative speed of A relative to B is (12 − 8)𝑚𝑠 = 4 𝑚𝑠
Relative distance to be covered by 𝐴 = 2𝜋𝑟
=2× × 70 𝑚 = 440 𝑚
∴𝑇= = 110 𝑠𝑒𝑐𝑜𝑛𝑑
∴ 𝐷 = 12 𝑚𝑠 × 110 𝑠 = 1320 𝑚𝑒𝑡𝑟𝑒

∴ = = = 1.43
25. 7.75
𝑊 = ∫ 𝐹𝑑𝑥 = ∫ (15 + 0.50𝑥) 𝑑𝑥
= 15𝑥 + = 15 × 2 +
⇒ 𝑊 = 31𝐽
∴ 4𝑛 = 31 ⇒ 𝑛 = = 7.75
CHEMISTRY
26. C
27. A
28. A
29. C
30. B
31. B
32. D
33. B
According to (𝑛 + 𝑙) rule, increasing order of energy will be 𝑑 < 𝑏 < 𝑐 < 𝑎
34. C
𝑚. 𝑒𝑞. 𝑜𝑓 𝐻 𝑂 = 𝑚. 𝑒𝑞. 𝑜𝑓 𝐼
. ×
𝑁×5= × 1000
𝑁 = 0.8𝑁
𝑉. 𝑆. = 5.6 × 𝑁 = 5.6 × .8 = 4.48𝑉
35. B
𝑍𝑛 + 𝐼 ⟶ 𝑍𝑛𝐼
Mass × × –
× ×
Mole
× × ×
− 0
× ×
𝑍𝑛 unreacted = × = 0.744
36. C
37. A
38. C
𝐶𝑎(𝐻𝐶𝑂 ) + 𝐶𝑎(𝑂𝐻) → 2𝐶𝑎𝐶𝑂 ↓ +𝐻 𝑂
𝐶𝑎(𝑂𝐻) + 𝑁𝑎 𝐶𝑂 ⟶ 𝐶𝑎𝐶𝑂 ↓ 𝑁𝑎𝑂𝐻
𝐶𝑎(𝑂𝐻) + 𝐶𝑂 ⟶ 𝐶𝑎𝐶𝑂 ↓ +𝐻 𝑂
39. A
4𝐿𝑖𝑁𝑂 ⟶ 2𝐿𝑖 𝑂 + 4𝑁𝑂 + 𝑂
40. C
𝑍 =1+ (For positive deviation)
41. D
𝑃 =
𝑣 = 3𝑏
𝑇 =
𝑇 = ×
×
= ×
×
𝑎=
42. A
𝑃𝑉 = 𝑚𝑛𝑢
𝑢 ∝ √𝑃𝑉
43. B
44. A
𝑁𝑂 > 𝑁𝑂 > 𝑁𝑂 (Bond length)
B.O. 2 2.5 3
𝐻 > 𝐻 > 𝐻𝑒 (Bond energy)
B.O. 1 0.5 0.5
𝑁𝑂 > 𝑁𝑂 > 𝑁𝑂 (Bond angle)
B.A. 180° 133° 115°
𝑂 < 𝑂 < 𝑂 (Paramagnetic moment)
Unpaired
𝑒 0 1 2
45. B
Due to lanthanoid contraction
46. 7
𝜆 = 5 × 10 m
𝜆= =
( )
=( )
( ) ×
𝜆 = ( )
= 2 × 5 × 10 = 10
47. 2
𝜆∝
√ . .
. . .
. .
= =
. .
. .
= (0.99) = 1.02𝐾. 𝐸.
. . . .
% change = . .
× 100 = 2%
48. 2.12 𝐴°
𝑅 = 0.529 𝐴°
= 0.529 × 2 = 2.12𝐴°
49. 5
Electronic configuration of 𝑁 is 𝜎1𝑠 𝜎 ∗ 1𝑠 𝜎2𝑠 𝜎 ∗ 2𝑠 𝜋2𝑝 ≈ 𝜋2𝑝 > 𝜎2𝑝 > 𝜋 ∗ 2𝑝
50. 𝟎. 𝟒𝟓 gm
× .
Moles of 𝐻𝐶𝑙 = = 0.04
Moles of 𝑚𝑔 to be dissolved = 0.02

Mass of 𝑚𝑔 = 0.02 × 24 = 0.48 𝑔𝑚
MATHEMATICS
51. D
30 = 27 + 5 − 𝑥
⇒𝑥=2
⇒ No. of female wrestler = 3
52. D
𝑥 = 1 + 𝑙𝑜𝑔 𝑏𝑐
𝑥 = log 𝑎 + log 𝑏𝑐
𝑥 = log (𝑎𝑏𝑐) ⇒ = log 𝑎
⇒ = log 𝑏 , = log 𝑐
⇒ + + = 1 ⇒ 𝑥𝑦 + 𝑦𝑧 + 𝑧𝑥 = 𝑥𝑦𝑧
= = =𝑘
⇒ ln 𝑥 + ln 𝑦 + ln 𝑧 = 0
⇒ ln 𝑥𝑦𝑧 = 0 ⇒ 𝑥𝑦𝑧 = 1 ⇒ 𝑥𝑦 + 𝑦𝑧 + 𝑧𝑥 = 1
⇒ (𝑥 + 𝑦 + 𝑧) = 𝑥 + 𝑦 + 𝑧 − 2(𝑥𝑦 + 𝑦𝑧 + 𝑧𝑥)
⇒3−2= 1
But this cannot be possible.
53. A
4 − (𝑥 − 1) (𝑥 − 2𝑥 − 2) > 0 ⇒ (𝑥 − 1) (𝑥 − 2𝑥 − 2) < 4
(𝑥 − 1) ((𝑥 − 1) − 3) < 4
Put (𝑥 − 1) = 𝑡
⇒ 𝑡(𝑡 − 3) < 4
⇒ 𝑡 − 3𝑡 − 4 < 0
⇒ (𝑡 − 4)(𝑡 + 1) < 0
⇒ −1 < (𝑥 − 1) < 4
⇒ (𝑥 − 1) > −1 and (𝑥 − 1) − 4 < 0
⇒ 𝑥 ∈ 𝑅 and (𝑥 + 1)(𝑥 − 3) < 0
⇒ 𝑥 ∈ (−1,3)
54. B
𝑥 +𝑥+7
− 6 − 7 + |𝑥 − 𝑥 + 3| − 5 ≤ 2|𝑥 − 2|
𝐷<0
𝑥 +𝑥+1
− 7 + |𝑥 − 𝑥 − 2| ≤ |2𝑥 − 4|
𝐷<0
|𝑥 + 𝑥 − 6| + |𝑥 − 𝑥 − 2| ≤ |(𝑥 + 𝑥 − 6) − (𝑥 − 𝑥 − 2)|
(𝑥 + 𝑥 − 6)(𝑥 − 𝑥 − 2) ≤ 0
(𝑥 + 3)(𝑥 − 2)(𝑥 − 2)(𝑥 + 1) ≤ 0
(𝑥 − 2) (𝑥 + 1)(𝑥 + 3) ≤ 0
⇒ 𝑥 ∈ (−3, −1) ∪ {2}
55. C
(3) = 𝑎, 2 − √3 = 𝑏
𝑎 + 𝑏 = 3 + 7 − 2√3 = 10 − 4√3
Now given, 𝑎 + 𝑏 ≤ √𝑎 + 𝑏
⇒ + ≤1
√ √
⇒ (sin 𝜃) + (cos 𝜃) ≤ 1
⇒ ≥2⇒𝑥≥4
56. C
( )
∫ sec (𝑥𝑒 ) 𝑑(𝑥𝑒 ) + × ∫ 𝑑𝑥 +
= [tan 𝑥 𝑒 ] + [𝑥 + ln(cos 𝑥 + sin 𝑥)]
= tan(𝑒) + 1
57. C
(sin 𝐴 + sin 𝐵 + sin 𝐶)(sin 𝐴 + sin 𝐵 − sin 𝐶) = 3 sin 𝐴 sin 𝐵
⇒ (sin 𝐴 + sin 𝐵) − sin 𝐶 = 3 sin 𝐴 sin 𝐵
⇒ sin 𝐴 + sin 𝐵 − sin 𝐶 = sin 𝐴 sin 𝐵
⇒ sin 𝐴 + sin(𝐵 + 𝐶) sin(𝐵 − 𝐶) = sin 𝐴 sin 𝐵
⇒ sin 𝐴 (sin(𝐵 + 𝐶) + sin(𝐵 − 𝐶)) = sin 𝐴 sin 𝐵
⇒ sin 𝐴 (2 sin 𝐵 cos 𝐶) = sin 𝐴 sin 𝐵
⇒ cos 𝐶 =
⇒ ∠𝐶 = 60°
58. D
( )
∑ cosec 𝜃 + cosec 𝜃 + = 4√ 2
( )
⇒∑ ( ) =4
( )
⇒∑ cot 𝜃 + − cot 𝜃 + =4
⇒ cot 𝜃 − cot 𝜃 + =4
⇒ cot 𝜃 + tan 𝜃 = 4
⇒ tan 𝜃 − 4 tan 𝜃 + 1 = 0
⇒ tan 𝜃 = 2 − √3 or tan 𝜃 = 2 + √3
⇒𝜃= or 𝜃 =
⇒𝜃= <𝜃<
59. C
𝑃 divides 𝑃𝑄 in 2: 1
: :
𝑃 divides 𝑃𝑄 in 3 − 1: 1
× ×
𝑃 = ,
𝑃 = (2186,4372)
60. B
Slope of rod 𝐴𝐵 is √3
A lies on circle (𝑥 − 1) + 𝑦 = 4
⇒ 𝐴(1 + 2 cos 𝜃 , 2 sin 𝜃)

⇒ 𝑁(1 + 2 cos 𝜃 + cos 60° , 2 sin 𝜃)
⇒ 𝑀(1 + 2 cos 𝜃 + cos 60° , 2 sin 𝜃 + sin 60°)
⇒𝑀 + 2 cos 𝜃 , √ + 2 sin 𝜃 ≡ (ℎ, 𝑘)
√
⇒ ℎ− + 𝑘− =4
⇒ 𝑥 + 𝑦 − 3𝑥 − √3𝑦 − 1 = 0
61. A
sin 𝜃 −1 − cos 𝜃
sin 𝜃 𝜆 cos 𝜃 = 0
cos 𝜃 1 sin 𝜃
⇒ sin 𝜃 (𝜆 sin 𝜃 − cos 𝜃) + (sin 𝜃 − cos 𝜃) − cos 𝜃 (sin 𝜃 − 𝜆 cos 𝜃)
⇒ 𝜆(sin 𝜃 + cos 𝜃) − 2 sin 𝜃 cos 𝜃 − cos 2𝜃 = 0
⇒ 𝜆 = sin 2𝜃 + cos 2𝜃
⇒ 𝜆 ∈ −√2, √2
62. D
𝐿 : 2𝑥 + 𝑦 − 1 = 0
𝐿 : 𝜆𝑥 + 𝑦 − 3 = 0
𝐿 : 3𝑥 − 2𝑦 + 1 = 0
Case 1: 𝐿 ||𝐿 ⇒ −2 = −𝜆 ⇒ 𝜆 = 2
Case 2: 𝐿 ||𝐿 ⇒ −𝜆 = ⇒ 𝜆 = −
Case 3: 𝐿 , 𝐿 and 𝐿 are concurrent.

2 1 −1
𝜆 1 −3 = 0 ⇒ 𝜆 = 16
3 −2 1
⇒ Product = 2 (16) = −48
63. B
Image of 𝐴(1,2) in 𝑥 − 𝑦 + 3 lies on 𝐵𝐶
( )
= =
𝐴(−1,4), 𝐷(5,6)
Equation of 𝐵𝐶 is 𝑦 − 6 = (𝑥 − 5)
𝐵𝐶: 𝑥 − 3𝑦 + 13 = 0
⇒ 𝐵(2,5) ⇒ 𝐶(8,7)
64. A
Diagonal 𝐴𝐶 is parallel to bisector of angle between these two lines
⇒ =±
√ √
⇒ 5(𝑥 − 𝑦 + 2) = ±(7𝑥 − 𝑦 + 3)
⇒ 2𝑥 + 4𝑦 − 7 = 0 and 12𝑥 − 6𝑦 + 13 = 0
⇒ Diagonal of rhombus are parallel to these line
⇒𝑚 = − or 2
⇒ = − or =2 …[𝐴(0, 𝛼)]
⇒ 𝛼 = or 𝛼 = 0
⇒ 𝐴 0, or 𝐴(0,0)
65. A
𝑄(sin(3𝜃 − 60°), cos(3𝜃 − 60°)) ≡ 𝑄(cos(150° − 3𝜃), sin(150° − 3𝜃))
⇒ 𝑄 (cos 120 °, sin 120°), 𝑄 (cos 60° , sin 60°)
Area = Area of sector 𝑂𝜃 𝜃
Area = (1) =
66. C
For point to lie in shaded region origin and point lie on
opposite side of line 𝑖. 𝑒. , 𝐿(𝑃) > 0 and 𝑆 < 0
𝐿: 2𝑥 − 3𝑦 − 1 = 0
𝑆: 𝑥 + 𝑦 − 6 = 0
(A) 2, : 2(2) − 3 −1>0
2 + −6<0
(B) ,− :2 −3 − −1>0
+ − −6 < 0
(C) ,− :2 −3 − −1>0
+ − −6 > 0
(D) 1, − : 2(1) − 3 − −1>0
(1) + − −6<0
67. A
𝑃𝑄: 𝑥(3) + 𝑦(0) − 2(𝑥 + 3) − 3(𝑦 + 0) + 3 = 0
𝑥 − 3𝑦 − 3 = 0
𝑄𝑅: 𝑥(5) + 𝑦(2) − 2(𝑥 + 5) − 3(𝑦 + 2) + 3 = 0
= 3𝑥 − 𝑦 − 13 = 0
⇒ 𝑄 ,
Quadrilateral 𝑂𝑃𝑄𝑅 is cyclic and 𝑂𝑄 is diameter of circumcircle.
⇒ Centre = , = ,
68. B
Circle touching both Axes is (𝑥 − 𝑟) + (𝑦 − 𝑟) = 𝑟
Passes through (𝛼, 𝛽)
𝑥 + 𝑦 − 2𝑟𝑥 − 2𝑟𝑦 + 𝑟 = 0
⇒ 2𝑟 𝑟 + 2𝑟 𝑟 = 𝑟 + 𝑟 ⇒ (𝑟 + 𝑟 ) = 6𝑟 𝑟
𝑟 − 2(𝛼 + 𝛽)𝑟 + 𝛼 + 𝛽 = 0
𝑟 + 𝑟 = 2(𝛼 + 𝛽), 𝑟 𝑟 = 𝛼 + 𝛽
⇒ 4(𝛼 + 𝛽) = 6(𝛼 + 𝛽 )
⇒ 𝛼 + 𝛽 − 4𝛼𝛽 = 0
⇒ (𝛼 + 𝛽) = 6𝛼𝛽
⇒ (9) = 6𝑝 ⇒ 𝑝 = 13.5
69. D
Centre (−𝑔, 0)
Equation of circle is 𝑥 + 𝑦 + 2𝑔𝑥 + 𝑐 = 0
⇒ + (log 𝑥 ) + 2𝑔 +𝑐 = 0
⇒ (log 𝑥 ) + 𝑐(log 𝑥 ) + 2𝑔(log 𝑥 )+1 =0

⇒ log 𝑥 + log 𝑥 + log 𝑥 + log 𝑥 =0
⇒ log (𝑥 𝑥 𝑥 𝑥 ) = 0
⇒𝑥 𝑥 𝑥 𝑥 =1
⇒ ≥ (𝑥 𝑥 𝑥 𝑥 )
⇒ 𝑥 +𝑥 +𝑥 +𝑥 ≥ 4
But 𝑥 ≠ 1 ⇒ ∑ 𝑥 >4
70. B
𝐴 − , 0 𝐵(0,1) 𝐶(−3,0) 𝐷 0,
Equation of circle containing point 𝐵, 𝐶 and 𝐷 is 2𝑥 + 2𝑦 + 7𝑥 − 5𝑦 + 3 = 0
If 𝐴 − , 0 satisfies equation of circle then − + 3 = 0 ⇒ 3𝜆 − 7𝜆 + 2 = 0
⇒ (3𝜆 − 1)(𝜆 − 2) = 0
⇒ 𝜆 = ,2
Equation of line may be + = 1 or + =1
⇒ 6𝑥 + 𝑦 − 2 = 0 or 𝑥 + 6𝑦 − 2 = 0
⇒𝑑= =
√ √
71. 88.75
(𝑥 − 1) = 𝑓(𝑥)(𝑥 − 2) + 𝑎𝑥 + 𝑏
2025(𝑥 − 1) = 2𝑓(𝑥)(𝑥 − 2) + 𝑓 (𝑥)(𝑥 − 2) + 𝑎
(2025)(2024)(𝑥 − 1) = 2𝑓 (𝑥)(𝑥 − 2) + 2𝑓(𝑥) + 2𝑓 (𝑥)(𝑥 − 2) + 𝑓 (𝑥)(𝑥 − 2)
Put 𝑥 = 2
(2025)(2024) = 2𝑓(2)
⇒ 𝑓(2) = 1012 × 2025 = 2 3 5 . 11.23
⇒ 𝑝 = 11, 𝑞 = 23, 𝑟 = 3, 𝑠 = 4
⇒ = = 88.75
72. 0.25
lim 1 − cos 1 − cos

→
lim . lim .
→ →
= × × × … lim =
→
⇒ = ×
⇒ 𝑘 = 0.25
73. 23
( )
𝑓(𝑥) = ( ) ( )
⇒ 𝑓(𝑥) + 𝑓(4 − 𝑥) = 1
⇒ 𝑓(4 sin 2𝜃) + 𝑓(4 cos 2𝜃) = 1
°
∑ ° 𝑓(4 sin 2𝜃) = 𝑓(4 sin 0°) + 𝑓(4 sin 2°) + ⋯ … + 𝑓(4 sin 88°) + 𝑓(4 sin 90°)
[𝑓(4 sin 0°) + 𝑓(4 sin 90°)] + ⋯ + [𝑓(4 sin 44°) + 𝑓(4 sin 46°)]
= 1 + 1 + ⋯ + 1 = 23
74. 64
sin . sin . sin . sin . sin . sin . sin
= sin . sin . sin . 1. sin 𝜋 − . sin 𝜋 − . sin 𝜋 −
= sin . sin . sin
= cos − cos − cos −
= cos . cos . cos
= cos . cos . cos
= − cos . cos . cos
= cos . cos . cos
= = = ⇒ 64
75. –6
𝑃(2 cos 𝜃 , 2 sin 𝜃)
𝐴𝐵: 𝑇 = 𝑂
𝑥(2 cos 𝜃) + 𝑦(2 sin 𝜃) = 𝐴(2 sec 𝜃 , 0) 𝐵(0,2 cosec 𝜃)
ℎ= ,𝑘 =
sin 𝜃 = , cos 𝜃 =
Locus ⇒ + =1
= + +1
= [3 sin 𝜃 + 4 cos 𝜃 + 1]
Range of is [−2, 3]

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FIITJEE – JEE (Main)

Physics, Chemistry & Mathematics

Time Allotted: 3 Hours Maximum Marks: 300

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

1. The maximum number of components in which a vector can be resolved is

(A) √𝑎 + 𝑏 (B) 𝑎 + 𝑏 + √2𝑎𝑏

(C) √𝑎 + 𝑏 + 2𝑎𝑏 (D) 𝑎 + 𝑏 − √2𝑎𝑏

5. The component vector of 𝑎⃗ = 2𝚤̂ + 3𝚥̂ − 𝑘 in the direction of 𝑏⃗ = 𝚤̂ + 2𝚥̂, is

(C) 2𝚤̂ + 3𝚥̂ − 𝑘 (D) 2𝚤̂ + 3𝚥̂ − 𝑘

(A) −8𝐽 (B) 8𝐽

(A) 𝑚𝑔 tan 𝜃 (B) (𝑀 + 𝑚)𝑔 tan 𝜃

(A) sin 𝜃 cot 𝜃 (B) tan 𝜃 sec 𝜃

(C) tan 𝜃 (D) sin 2𝜃

15. The frictional force on the block of mass 2 kg is (Take 𝑔 = 10 𝑚𝑠 )

(A) 16N (B) 40N

(C) (D) none of the above

(A) (B) 2𝑔ℎ𝑣 + ℎ

SPACE FOR ROUGH WORK

Numerical Based Questions

. . Find the value of 𝑥.

27. The set representing correct order of ionic radius is

28. The ion having a noble gas configuration is

29. The molecular orbital with highest energy in a nitrogen molecule is

30. Correct order of increasing 𝑥 − 0 − 𝑥 bond angle is (𝑥 = 𝐻, 𝐹, 𝐶𝑙)

31. The orbital which does not participate in 𝑠𝑝 𝑑 hybridisation.

32. Among the following back bonding is exhibited by

33. The electron identified by quantum number 𝑛 and 𝑙

36. 𝐵𝑒 reacts with excess of caustic soda to form

39. The products obtained on heating 𝐿𝑖𝑁𝑂 will be

40. Compressibility factor for 𝐻 behaving as real gas is

41. The Vander Waal gas constant 𝑎 is given by

45. The pair that has similar atomic radii is

Numerical Based Questions

52. If 𝑥 = 1 + log 𝑏𝑐 , 𝑦 = 1 + log 𝑎𝑏 , 𝑧 = 1 + log 𝑎𝑐 and = = ; where, 𝑥 + 𝑦 + 𝑧 =

3 (𝑥, 𝑦, 𝑧 > 0) then correct option is

53. Domain of 𝑓(𝑥) = is subset of

(A) [−1,4] (B) [0,5]

54. Solution set of the inequality |𝑥 + 𝑥 + 7| − 6 − 7 + |𝑥 − 𝑥 + 3| − 5 ≤ 2|𝑥 − 2| is proper

55. Solution of inequality 3 + 2 − √3 ≤ 10 − 4√3 is

(A) tan 𝑒 − 1 (B) tan 𝑒 − 2

62. If the lines 2𝑥 + 𝑦 − 1 = 0, 𝜆𝑥 + 𝑦 − 3 = 0, 3𝑥 − 2𝑦 + 1 = 0 cannot form a triangle then product

67. Let 𝑂 be center of circle 𝑥 + 𝑦 − 4𝑥 − 6𝑦 + 3 = 0. If tangent at 𝑃(3,0), 𝑅(5,2) meets at 𝑄 then

Numerical Based Questions

72. lim 1 − cos − cos + cos . cos = then 𝑘 is equal to

74. Value of ∏ sin(2𝑟 − 1) = then 𝑘 is equal to

FIITJEE – JEE (Main)

PH 1 3193 C CH 26 2529 C MT 51 M120304 D

PH 2 3196 B CH 27 2537 A MT 52 M110201 D

PH 3 3249 D CH 28 2523 A MT 53 M110202, M120301 A

PH 4 3201 D CH 29 2552 C MT 54 M110202 B

PH 5 3200 A CH 30 2549 B MT 55 M111403 C

PH 6 3240 C CH 31 2547 B MT 56 M120801 C

PH 7 3223 A CH 32 2546 D MT 57 M111402 C

PH 8 3269 B CH 33 2529 B MT 58 M111401 D

PH 9 3282 A CH 34 2519 C MT 59 M110701 C

PH 10 3201 B CH 35 2504 B MT 60 M110801 B

PH 11 3218 A CH 36 2587 C MT 61 M110706, M111403 A