Lesson 3 - Intermolecular Forces - Final

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Intermolecular Forces

S BI 4 U
Types of Forces
INTRAMOLECULAR FORCES:
• the attractive force between atoms within a molecule
• the attractive force between ions within an ionic crystal
• very strong forces
• include ionic and covalent bonds

INTERMOLECULAR FORCES:
• The attractive forces between molecules
• weaker than intramolecular forces
Intermolecular Forces (IMF)

Intermolcular Forces

Dipole-Dipole Forces Ion -Dipole Forces Hydrogen Bonds London Dispersion Forces

ONLY POLAR MOLECULES ALL MOLECULES


Dipole – Dipole Forces
Attractive forces between polar molecules that have a permanent dipole. Dipole – Dipole forces are the
strongest intermolecular force, but weaker than a covalent bond.

The positive dipole of one


molecule is attracted to
the negative dipole of
another.
Ion – Dipole Forces
An Ion-dipole bond is an attractive force between an ion (anion or cation) and a molecule with a
permanent dipole.

Ion-dipole forces are the


strongest IMF due to the strong
charge of an ion relative to a
dipole.
Hydrogen Bonds
A hydrogen bond is typical formed betweenthe lone pair of an electronegative atom and the
hydrogen that is bound to either an oxygen, nitrogen or fluoride atom.
London Dispersion Forces
Van der Waals forces occur between nonpolar molecules with temporary dipoles. Due to the
electrons that are constantly in motion, hot spots are created within the molecules.

The molecules must be close


together in order for these
forces to occur.
Relative Forces of IMFs

RELATIVE
TYPE OF FORCE EXHIBITED BY
STRENGTH
Ion-Ion very strong Ionic Compounds

Ion - Dipole strong An ion and a molecule with a permanent dipole

Hydrogen bond moderate Molecules with an O-H, N-H, or H-F bond

Dipole – Dipole weak Molecules with a permanent dipole

London Dispersion very weak All molecules


Water
 Water is required for all life on Earth.
 Cells are 70 – 95 % water.
 Extracellular fluid is also water-based
 Aqueous medium contains dissolved proteins, nutrients and
ions essential for functioning.

What’s so special about water?


 polar – due to bent shape
 water molecules will from hydrogen bonds between
one another
Properties of Water
1. Water Clings.
• Cohesion
• Adhesion

2. Water absorbs lots of heat


• High specific heat capacity and hear of vaporization.
• Moderates air/land temperature
• Allows animals to thermo-regulate via evaporative cooling.
Properties of Water
3. Solid water is less dense than liquid water.
 Highest density at 4ᴼC
 Ice floats on liquid water
 Prevents bodies of water from freezing solid
Properties of Water
4. Water is a versatile solvent.
 Charged ends have a high affinity for charged ions and polar covalent substances.
 Allows many solutes to be dissolved and transported within the body.
Solubility of Substances in Water
Water is a great solvent due to its polarity.

Water is great at dissolving both ionic (+,-) compounds and polar (partial
positively, partial negatively charged molecules) molecules.
Solubility of Substances in Water
Hydrophilic Properties:
Solubility of Substances in Water
Hydrophobic Properties:

E.g Non-polar compounds are insoluble in water.

Oil – non-polar compound of carbon and hydrogen.


Homework
• Complete the IMFs Worksheet

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