SplitPDFFile 544 To 570

Sri Chaitanya IIT Academy.,India.
 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS & ALL_BT JEE-MAIN Date: 30-01-2023
Time: 09.00Am to 12.00Pm GTM-20 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
30‐01‐23_Sr.Super60_NUCLEUS & ALL_BT_ Jee‐Main_GTM‐20_Test Syllabus
PHYSICS : TOTAL SYLLABUS
CHEMISTRY : TOTAL SYLLABUS
MATHEMATICS
यश TG~ @bohring_bot
: TOTAL SYLLABUS
SRI CHAITANYA IIT ACADEMY, INDIA 30‐01‐23_ Sr.Super60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐20_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. An aircraft is flying at a height of 3400 m above the ground. If the angle subtended at a
ground observation point by the aircraft positions 10 sec apart is 600 , the speed of the
aircraft can’t be
580 680 780 880
1) m/s 2) m/s 3) m/s 4) m/s
3 3 3 3
2. A particle of mass m is projected from the ground with an initial speed u0 at an angle  with
the horizontal. At the highest point of its trajectory, it makes a completely inelastic collision
with another identical particle, which was thrown vertically upward from the ground with
the same initial speed u0 from foot of the highest point of first particle. The angle that the
composite system makes with the horizontal immediately after the collision is
   
1) 2)  3)  4)
4 4 4 2
3. The rms speed of a gas molecule at 27 0 C and 1.0 atm pressure is 100 ms 1. The rms speed of
same molecule at 127 0 C and 2.0 atm pressure will be
100 1 200 1
1) 100ms 1 2) 200ms 1 3) ms 4) ms
3 3
4. Relative permeability and dielectric constant of a medium are 2 and 1.5 respectively. The
refractive index of the medium is
3 4
1) 2) 3 3) 4) 3
2 3
5. Given below are two statements: One is labeled as

Assertion (A) and the other is labeled as
Reason (R) .
Assertion (A) The OR gate function corresponds to switches in parallel.
Reason (R) : The AND gate function corresponds to switches in series.
In the light of the above statements. Choose the most appropriate answer from the options
given below:
Sec: Sr.Super60_NUCLEUS & ALL_BT Page 2
1) Both (A) and (R) are true and (R) is the correct explanation of(A).
2) Both (A) and (R) are true and (R) is NOT the correct explanation of(A).
3) (A) is true but (R) is false.
4) (A) is false but (R) is true.
6. Which of the following figures best represents the variation of particle momentum and
associated de Broglie wavelength?
P
P
O O
I    II  
1) 2)
P P
O

O 
 III   IV 
3) 4)
7. A resistance R is to be measured using a metre-bridge. Student choose the standard
resistance S to be 100 . He finds the null point at l1  2.9cm. He is told to attempt to improve
the accuracy. Which of the following is a useful way?
1) He should measure l1 more accurately
2) He should change S to 1000 and repeat the experiment.
3) He should change S to 3 and repeat the experiment.
4) No other alternative is possible to take more accurate measurement with a metre-bridge.
8. The figure shows a bent rod rotating about its end O in a plane perpendicular to the magnetic

field B. . The part OA of the rod is non-conducting while the part AB is conducting. Find the
induced emf between the ends A and B.
A
R
B B
O
B R 2 3
1) 2) B R 2 3) B R 2 4) 2B R 2
2 2
9. A plane mirror is moving with velocity 4i  5 j  8k . The point object in front of the mirror
moves with a velocity 3i  4 j  5k , here k is along the normal to the plane mirror and facing
towards the object. The velocity of the images with respect to ground
(The given velocities are w.r.t ground) is :
1) 3i  4 j  5k 2) 3i  4 j  11k 3) 3i  4 j  11k 4) 7i  4 j  11k
10. Given below are two statements: One is labeled as
Assertion (A) and the other is labeled as
Reason (R) :
Assertion (A) : The electric potential and the electric field intensity at the centre of a square
having four fixed point charges at their vertices as shown in figure are zero.
q q
q q
Reason (R) : If electric potential at a point is zero then magnitude of electric field at that
point must be zero.
In the light of the above statement, choose the most appropriate answer from the options
given below :
1) Both (A) and (R) are true and (R) is the correct explanation of(A).
2) Both (A) and (R) are true and (R) is NOT the correct explanation of(A).
3) (A) is true but (R) is false.
11. In the formula X  5YZ 2 , X and Z have dimensions of capacitance and magnetic field,
respectively. What are the dimensions of Y in SI units?
1)  M 3 L2T 8 A4  2)  M 1L2T 4 A2  3)  M 1L0T 4 A2  4)  M 2 L2T 6 A3 
12. Two liquid drops of radii R1 and R2 are combined to form a liquid drop of radius R. The value
of R in terms of R1 and R2 is
R1 R2
1) 2) R12  R22 3) R1R2 4) 3 R13  R23
2
13. The PE of a harmonic oscillator of mass 2 kg at its mean position is 5J. If its total energy of
9 J and its amplitude is 0.01m, find its period.
  
1) s 2) s 3) s 4)  s
100 50 200
14. A capacitor C is fully charged with voltage V0 . After disconnecting the voltage source, it is
C
connected in parallel with another uncharged capacitor of capacitance . The energy loss in
2
the process after the charge is distributed between the two capacitors is
1 1 1 1
1) CV02 2) CV02 3) CV02 4) CV02
2 3 4 6
15. A proton beam is going from north to south and an electron beam is going from south to
north. Neglecting the earth’s magnetic field, the electron beam will be deflected
1) Towards the proton beam
2) Away from the proton beam
3) Upward
4) Downwards
16. The ratio of the weights of a body on the earth’s surface to that on the surface of a planet is
1
9:4. The mass of the planet is th of that of the earth, If R is the radius of the earth. What is
9
the radius of the planet? (Take the planets to have the same mass density)
R R R R
1) 2) 3) 4)
3 9 4 2
17. A conducting rod PQ is rotated in about an axis passing through O and perpendicular to the
plane of rotation of the rod with constant angular speed  .A magnetic field of induction B is
applied perpendicular to the plane of rotation. The one end of the rod is at a distance a and
other end is at a distance b from O. Find induced emf across the ends of the rod.
 B Q
P
o
a
b
B  b 2  a 2  B  b 2  a 2  B  b 2  a 2  B  b 2  a 2 
1) 2) 3) 4)
2
Sec: Sr.Super60_NUCLEUS & ALL_BT
2 3 4
Page 5
18. A photoelectric surface is illuminated successively by monochromatic light of wavelength 

and . If the maximum kinetic energy of the emitted photoelectrons in the second case is 3
2
times that in the first case, the work function of the surface of the material is (h= Planck’s
constant, c = speed of light)
hc 2hc hc hc
1) 2) 3) 4)
  3 2
19. Electrons with de-brogile wavelength  fall on the target in an
X-ray tube. The cut-off wavelength of the emitted X-rays is
2mc 2 2h 2m2c 2 2
1) 0  2) 0  3) 0  4) 0  
h mc h2
1
20. A Carnot engine operating between temperatures T1 and T2 has efficiency when T2 is
6
1
lowered by 62K, its efficiency increases to , Then T1 and T2 are respectively
3
1) 372 K and 310 K 2) 372 K and 330 K
3) 330 K and 268 K 4) 310 K and 248 K
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. The object in figure weighs 100 kg and hangs at rest. Then T1 / T2 is
T1 T2
37 0 530
100 kg
22. From a uniform circular disc of radius a, an isosceles right angled triangle with the
hypotenuse as the diameter of the disc is removed. The distance of the centre of mass of the
a
remaining portion from the centre of the circle is find the value of n .
n    1
23. An adiabatic cylinder has 8 gram of helium in it at 400 K and its piston of area 1 cm2 (which
has mass 1 kg) is movable. If a block of mass 62 kg is placed on the piston then the final
temperature of the gas will be  n 100  K find the value of n (Take atmospheric pressure to be
105 Nm 2 and g  10m / s 2 )
24. Electric potential is given by V  6 x  8 xy 2  8 y  6 yz  4 z 2 then electric force acting on 2C point

charge placed at origin will be
25. A radio isotope X with a half-life 1.4 109 years decays to Y which is stable. A sample of the
rock from a cave was found to contain X and Y in the ratio 1: 7 . The age of the rock is n  109
years. Find “n”.
7
26. If the ratio of the concentration of electrons to that of holes in a semiconductor is and the
5
7
ratio of currents is then, the ratio of their drift velocities respectively is
4
27. A travelling harmonic wave on a string is described by
y  x, t   7.5 sin  0.0050 x  12t   / 4 
where ‘x’ is in meter and ‘t’ is in sec, then speed of wave is (in m/s)
28. There is a potentiometer wire of length 1200 cm and 60 mA current is flowing in it. A
Battery of emf 5 V and internal resistance of 20  is balanced on potentiometer wire with
balancing length 1000 cm. The resistance of potentiometer wire is (in  )
29. Charges –q and +q located at A and B, respectively, constitute an electric dipole. Distance
AB = 2a, O is the midpoint of the dipole and OP is perpendicular to AB. A charge Q is
placed at P where OP = y and y >>2a. The charge Q experiences an electrostatic force F. If
Q is now moved along the equatorial line to P’ such that the OP '    , force on Q will be
y
3
close to   2a  is N  F find the value of N
y
3 
30. A resistance of 20  is connected to a source of an alternating voltage V  220 sin 100  t  .
The minimum time taken by the current to change from the peak value to rms value is
 n 10  sec
3

CHEMISTRY Max Marks: 100
correct.
31.
Na2 B4O7 .10 H 2O  
heat
 X  NaBO2  H 2O
X  Cr2O3 heat
 Y ( green coloured ) X and Y are :
1) Na3 BO3 and Cr  BO2 3 2) Na2 B4O7 and Cr  BO2 3

3) B2O3 and Cr  BO2  4) B2O3 and Cr  BO2 3
32. Assertion: The energy of electron in an atom increases with the increase in distance of the
electron from the nucleus
Reason: The de Broglie wavelength of an electron decreases with increase of its distance
from the nucleus
1) Both (A) and (R) are true and (R) is the correct explanation of (A)
2) Both (A) and (R) are true and (R) is not the correct explanation of (A)
3) (A) is true and (R) is false
33. The bond orders of NO  , O2 , CN  and CO32 are respectively
1) 3.0, 1.5, 3.0, 2.0 2) 2.5, 2.0, 2.5, 1.5
3) 3.0, 1.5, 3.0, 1.33 4) 1.33, 1.5, 2.5, 2.33
34. One mole of ideal gas taken in one litre vessel at 10 atm pressure at T K. It is isothermally
expanded to 10 litres. If it is free expansion then Stotal is  in J / K 
1) 19.14 2) Zero 3) 3.06 4) 16.08

35. The correct order of stability of following carbanions is
..
H 3CO C H2
..
O2 N C H2
I   II 
..
C H2
..
H 3C C H2
 III   IV 
1) II >III>IV>I 2) III>IV>I>II 3) IV>I>II>III 4) I>II>III>IV
36. At high pressure the van der Waal’s equation for one mole of a real gas reduces to
3)  P  2 V  RT 4) PV  RT
a a
1) PV  RT  2) PV  RT  Pb
V  V 
37. The correct set from the following in which both pairs are in correct order of melting point
is:
1) LiF  LiCl ; MgO  NaCl 2) LiCl  LiF ; NaCl  MgO
3) LiF  LiCl ; NaCl  MgO 4) LiCl  LiF ; MgO  NaCl
38. CH 3CH 2CH 2Cl  CH 3 C HCH 3 Na
 Products
| Dry ether
Cl
Which of the following is not a product of above reaction?
1) 2)
3) 4)
39. Which one of the following has aromatic character?
1) Cyclopentadienyl cation 2) Cyclopentadienyl radical
3) Cyclopentadienyl anion 4) Cyclopentadiene
40.
Cl O  Na 
 NaOH
The above reaction requires which of the following reaction conditions?

1) 573K, cu,300 atm 2) 623K, cu, 300 atm
3) 573K, 300 atm 4) 623K, 300 atm
41. Select the incorrect statement.
1) In alkaline solution XeO3 forms xennate ions
2) Perxennate ions can be formed by disproportionation of xennates in alkaline conditions
3) In perxennates Xe is in +6 oxidation state
4) Perxennates can act as oxidizing agents
42. Which one of the following pairs of isomers and types of isomerism are correctly matched-
P. Co  NH 3 5  NO2   Cl2 and Co  NH 3 5  ONO   Cl2 .... linkage
Q. Cu  NH 3 4   PtCl4  and  Pt  NH 3 4  CuCl4 ...... co-ordination
R.  Pt  NH 3 4 Cl2  Br2 and  Pt  NH 3 4 Br2  Cl2 ..... ionization
Select the correct answer using the codes given below :

1) Q and R 2) P, Q and R 3) P and R 4) P and Q
43.
O
 A 
NH 2 
KOBr
  major product 
 
 
Br O
 B 
  major product 
LiAlH 4
NH 2 
H 3O   
 
Br
In the above reactions, product A and product B respectively are :

NH 2
,
NH 2
NH 2
,
NH 2
1) 2) Br Br
NH 2 NH 2
,
NH 2
,
NH 2
3) Br 4) Br
44. The flocculation values of these effective ions vary in the order for Gold sol as:
1) Sn 4  Al 3  Ba 2  Na  2) PO43  SO42  Cl 
3) Na   Al 3  Ba 2  Sn4 4) SO42  Na   PO43  Ba 2
45. Equimolar solutions of KCl and compound X in water show depression in freezing point in
the ratio of 4:1. Assuming KCl to be completely ionized, the compound X in the solutions
must:
1) Dissociate to the extent of 50% 2) Dissociate to the extent of 80%
3) Dimerise to the extent of 50% 4) Trimerise to the extent of 75%
46. Given below are two statements; one is labelledas Assertion (A) and the other is labelled as
Reason(R) .
Assertion (A) : Zone-refining is very usefull for producing ultra pure elements like metals
(Gi, In), metallioids (Si and Ge), nonmetal (Boran).
Reason (R) : Zone-refining process, impurities are more soluble in the rather molten metal
than in the solid metal. In the light of the above statements, choose the most appropriate
answer from the options given below:
1) Both (A) and (R) are correct but (R) is not the correct explanation of (A).
2) (A) is correct but (R) is not correct.
3) (A) is not correct but (R) is correct
4) Both (A) and (R) are correct and (R) is the correct explanation of (A).
47. Select the incorrect statement:
1) Novalac is linear polymer
2) Glyptal is a polymer of ethylene glycol and phthalic acid
3) Bakelite is a cross-linked phenol formaldehyde polymer
4) In manufacturing of tyre rubber, 10% of sulphur is used as a cross-linking agent
48. Among the following, the strongest reducing agent is
1) NH 3 2) PH3 3) AsH3 4) BiH 3
49. Given below are two statements:
Statement-I : Electron gain enthalpy becomes less negative as we go down the group.
Statement-II : Size of atom increases on going down the group. and the addition of electron
would be farther from the nucleus. In the light of the above statements, choose the
most appropriate answer from the options given below:
1) Statement I & II both are correct.
2) Statement I is correct but II are incorrect.
3) Statement I is incorrect but II is correct.
4) Both statement I & II are incorrect.
50. Given below are two statements:
Statement I: The E 0 value for Ce4 / Ce3 is  1.74 V .
Statement II: Ce is more stable in Ce4 state than Ce3 state.
In the light of the above statements, chose the most appropriate answer from the options
given below:
1) Both statement I and statement II are correct
2) Statement I is incorrect but statement II is correct
3) Both statement I and statement II are incorrect
4) Statement I is correct but statement II is incorrect
51. In the following reaction:
P4  xNaOH  yH 2O  PH 3  3NaH 2 PO2
Sum of x  y is
CH 3CH 2CH 2CH 2Cl 

Anhy . AlCl3
 Products
52.
How many monosubstituted product(s) is/are possible for the above reaction?
(Consider stereoisomers)
53. X g Y g  Z g
The equilibrium constant K p of above reaction is 3 atm at a certain temperature. If equal

moles of X,Y and Z are present at equilibrium in a one litre container, the equilibrium
pressure would be ( in atm)
54. Ge (Z=32)in its ground state electronic configuration has x completely filled orbitals with
ml  0 (Magnetic quantum number equals to 0) . The value of x is _______.
55. A3 B2 is a sparingly soluble salt of molar mass M  g mol 1  and solubility x g L1. The
5
solubility product satisfies K sp  a 

x 
 . The value of a is ___________(Integer answer)
M 
56. Consider the following first order competing reactions:

X 
k1
 A  B and Y 
k2
 C  D if 50% of the reaction of X was completed when 96% of the
reaction of Y was completed, the ratio of their rate constants  k2 / k1  is:
57. The relation between the molar conductance  M  and equivalent conductance  e  of the
solution of MgCl2 .KCl.6 H 2O is  M  e  x . Value of x is

58. The number of sp 2 hybridized carbons present in “aspartame” is __________.
59. The number of oxygen present in a nucleotide formed from a base, that is present only in
RNA is ___________.
60. A diene on reductive ozonolysis produces two moles of ethanal and one mole of propan -1,
3-dial. How many geometrical isomer(s) is/are possible for the diene?
MATHEMATICS Max Marks: 100
correct.
5n1  3n  22 n
61. lim
n 5n  2n  32 n3

1) 5 2) 3 3) 1 4) 0
62. Which of the following functions is non-differentiable at some point in its domain?
x2
1) f  x   2) f  x   log x 3) f  x   x3 log x 4) f  x    x  2 
3/5
x2  3
63. From the top of a tree, a man observes the angle of depression of a point on the ground
which is at a distance of 40 mts from the foot as 750 . The height of the tree is
1) 21 3 mts 2) 3 21 mts 3) 40  2  3  mts 4) 40 3 mts
64. Let S     2 , 2  : 2cos 2   3sin   0 . Then the sum of the elements of S is
13 5
1) 2 2)  3) 4)
6 3
65. The position vectors of the vertices of a triangle are 3i  4 j  5k , i  7k , 5i  5 j . The distance
between its circumcentre and orthocenter is
3
1) 306 2) 0 3) 306 4) 2 306
2
x2
The local maximum value of the function f  x     , x  0

2
66.
x
e
1
 4 4
 
2
1)  e  e 2) 1 3)   4) 2 e e
 e
Let f  x    x  1  1, x  1. Then the set  x : f  x   f 1  x  is equal to
2
67.
 3  i 3 3  i 3 
1) 0,1, 1 2) 0, 1, , 
 2 2 
3) 0,  1 4) Empty
68. Let L denote the line in the xy-plane with x and y intercepts as 3 and 1 respectively. Then
the image of the point  1, 4 in this line is
1)  ,  2)  ,  3)  ,  4)  , 
29 8 29 11 11 28 8 29
 5 5  5 5 5 5  5 5 
69. The system of linear equations  x  2 y  2 z  5, 2 x  3 y  5 z  8,
4 x   y  6 z  10 has
1) No solution when   8
2) A unique solution when   8
3) Infinitely many solutions when   2
4) No solution when   2
70. If the plane x  y  z  1 is rotated through an angle 900 about its line of intersection with the
plane x  2 y  3z  0 , then the new position of the plane is
1) x  8 y  7 z  2 2) x  8 y  7 z  2 3) x  5 y  4 z  1 4) x  5 y  4 z  1
If  a  ib     i then  b  ia  is equal to
5 5
71.
1)   i 2)   i 3)   i 4)   i
72. A chord of the circle x 2  y 2  4 x  6 y  0 passing through origin subtends an angle tan 1  7 / 4 
at the point where the circle meets positive y-axis, then equation of the chord is
1) 2 x  3 y  0 2) x  2 y  0 3) x  2 y  0 4) 2 x  3 y  0
x2 y 2
73. The number of normals to the ellipse   1 which are tangents to the circle x 2  y 2  9 is
25 16
1) 1 2) 2 3) 3 4) 0
1 1
ex x2 I
74. Let I1   dx and I 2   x3 dx then 1 
0
1 x 0 e 
2 x 3
 I2
3 e 1
1) 2) 3) 3e 4)
e 3 3e
75. The statement p   q  p  is equivalent to
1) p   p  q  2) p   p  q  3) p   p  q  4) p   p  q 
76. The number of real roots of the equation x3  3x  1  0 is

1) 0 2) 1 3) 2 4) 3
77. The area bounded by the curve f  x   x  sin x and its inverse between the ordinates
x  0 and x  2 is 2k , k  N then k = ___
1) 3 2) 4 3) 5 4) 6
78. The reminder, when 4  6 is divided by 25 is
87 87
1) 19 2) 21 3) 20 4) 22
x2 y2 x2 y2
79. Area of the quadrilateral formed by the foci of the hyperbola   1 and   1 is
a 2 b2 a 2 b2
1 2 2
1) 4  a 2  b 2  2) 2  a 2  b 2  3)  a 2  b2  4)
2
a  b 
80. Given the relation R   2,3 ,  3,4  on the set 2, 3, 4 . The minimum number of ordered pairs
to be included in R, so that R becomes reflexive and symmetric is

1) 4 2) 5 3) 7 4) 6
81. The median of 100 observations grouped in classes of equal width is 25. If the median class
interval is 20-30 and the number of observations, each less than 20 is 45 then the frequency
of median class is _______
n
2r  1 n
82. If S n   and S 20  then n  1  _______
r 1 r  2 r  r n 1
4 3 2
83. The number of seven digit integers with sum of the digits equal to 10 and formed by using
the digits 1,2 and 3 only is : _____
84. The total number of 3  3 matrices A having entries from the set 0,1,2,3 such that the sum of
all the diagonal entries of AAT is 9, is equal to _________

 
85. If y  y  x   0,  is the solution of the differential equation
2 
dy  
sec y  sin  x  y   sin  x  y   0, with y  0   0 . Then 5 y '   is equal to ______
dx 2
Let C be the curve defined by y  eabx . The curve C passes through the point P 1,1 and the
2
86.
slope of the tangent to C at P is (-2). Then the value of 2a – 3b is
87. Let Q be the foot of the perpendicular from the point P  7, 2,13 on the plane containing the
x 1 y 1 z  3 x 1 y  2 z  3
then  PQ  
2
lines   and  
6 7 8 3 5 7
f ' 4
88. Let f : R  R satisfy f  x  y   2x f  y   4 y f  x  x, y, R . If f  2  3 then 7 
f '  2
89. If 9 x2  2hxy  4 y 2  6 x  2 fy  3  0  h  0, f  0  represents two parallel lines, then h  f 
sin 2 x 2  cos 2 x cos 2 x

90. Let f  x   2  sin 2 x cos 2 x cos 2 x ; x   0,  . Then the maximum value of f  x  is
2
sin x 2
cos x 1  cos 2 x
equal to _____
SRI CHAITANYA IIT ACADEMY, INDIA 30‐01‐23_ Sr.S60_NUCLEUS & ALL_BT _ Jee‐Main_GTM‐20_KEY &SOL’S
Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS &ALL_BT JEE-MAIN Date: 30-01-2023
Time: 09.00Am to 12.00Pm GTM-20 Max. Marks: 300
KEY SHEET
PHYSICS
1 1 2 1 3 4 4 2 5 2
6 4 7 3 8 4 9 2 10 3
11 1 12 4 13 1 14 4 15 1
16 4 17 2 18 4 19 1 20 1
21 1 22 3 23 16 24 20 25 4
26 1 27 2400 28 100 29 27 30 3
CHEMISTRY
31 4 32 3 33 3 34 1 35 1
36 2 37 1 38 4 39 3 40 4
41 3 42 2 43 2 44 1 45 4
46 4 47 4 48 4 49 1 50 4
51 6 52 3 53 9 54 7 55 108
56 5 57 3 58 9 59 9 60 3
MATHEMATICS
61 4 62 4 63 3 64 1 65 3
66 1 67 3 68 3 69 4 70 2
71 2 72 3 73 4 74 3 75 2
76 4 77 1 78 3 79 2 80 2
81 10 82 21 83 77 84 766 85 2
86 5 87 96 88 124 89 8 90 6
SOLUTIONS
PHYSICS
1. For minimum speed, observer is symmetric between the 2 positions
A x B
300 300 h  3400 m
O tan 300 
 x / 2   2h tan 300 V 
680
m / s So, option (1) can’t be
min
h 3
2. From momentum conservation equation, we have
j
u02  2 gH

 u0 cos 
I
Pi  Pf
 m  u0 cos   i  m  
u02  2 gH j   2m  v ....... i 
u02 sin 2 
H ........ ii 
2g
 u cos  u cos 
From Equations (i) and (ii) v 0 i  0 j
2 2
Since both components of v are equal. Therefore, it is making 450 with horizontal.
3. V1 T
 1
V2 T2
4. Velocity of light in vacuum CV 
1
0 0
1
Velocity of light in the medium Cm 

CV  3
Refractive index of the medium is n    r r  2   3
Cm 0 0 2
5. Conceptual
6. 
h
 p  h Graph is rectangular hyperbola.
p
7. R
Since 
l1
R
Sl1

100  2.9cm   3
S 100  l1  100  l1  100  2.9  cm
The accuracy of measuring R can be improved if S and R are of the same order, i.e. S
should be changed to 3 .
8. Suppose straight length of the rod is l . The distance of the end B from O
OB 2  OA2   2 R   l 2   2 R 
2 2
The potential difference between A and B can be calculated as:

VA  VB  VO  VB   VO  VA  ...... i 
B  OB 
2
B 2 B Bl 2
 OA 
2
Here V0  VB   l  4 R 2  And V0  VB 
2 2 2 2
Substituting these values in equation (i), we get
B 2 3
VA  VB   l  4 R 2   l 2    4 R 2  2 B R 2 .
2   2
  
9. v M  4i  5 j  8k , v 0  3i  4 j  5k  Plane of the mirror is xy   v I  3i  4 j
    
  
and for kv  2v  v  2  8  5  11  v I  3i  4 j  11k
IZ MZ OZ
q
10. E E
q
E
q q
Kq Kq Kq Kq
E  0,V     0
x x x x
It is not necessary that if potential is zero then electric field is also zero.
11. X Q Q2  A2T 2 
X  5YZ 2  Y ......... 
i X  capacitance   
Z2 V W  ML2T 2 
 M 1L2T 4 A2 
Z   MT 2 A1  Y  
F
X   M 1L2T 4 A2  Z  B  2
IL  MT 2 A1 
Y   M 3 L2T 8 A4 
12. V  V1  V2
4 3 4 3 4 3
 R   R1   R2 3
R13  R23
3 2 3
13. 1 4 2
Maximum KE=TE- PEmin Or kA2  9  5  k   8 104 N / m
2 0.012
m 2 
Time period T  2  2  s
k 8 10 4
100
14. When two capacitors with capacitance C1 and C2 at potential V1 and V2 connected to
each other by wire, charge begin to flow from higher to lower potential till they
acquire common potential. Here, some loss of energy takes place which is given by
C1C2
V1  V3 
2
Heat loss, H 
2  C1  C2 
C
In the equation, put V2  0, V1  V0 C1  C , C2 
2
C
C 1
Loss of heat  2 V  0 2  C V 2 H  CV02
 C 0 6
0
6
2 C  
 2
15. Currents in same direction attract
16. Mass of object remains same
W earth  9 g earth 
Weight of object  acceleration due to gravity  
W planet  4 g planet 
2 2
9 GM  earth  R  planet  M  earth  R  planet 
    
4 GM  planet  R 2 earth  M  planet  R 2  earth 

2 2
R  planet  R  earth  R
 9 2
 R 2 planet   
R  earth  2 2
17. The induced emf across the element of length dx is
de  Bvx dx  B  x  dx.
O P Q
  
x
a dx
b
b
B  b 2  a 2 
The emf across the whole rod e  B  xdx 
a
2
18. k1 
hc
 k2  3k1 
2hc
 
3hc
 3
  
hc hc
So 2  so 
 2
19. h h h2 hc
  k  But, 0 
p 2mk 2m 2
k
2mc 2
From equation (i) and equation (ii) 0 
h
20.  1  T2 T2 
  1   1  
 6  T1 T1 
T2 5 6T
  T 1  2 ......... 1
T1 6 5
1  T2  62 
 1   .............. 2 
3  T1 
From eqn (1) and (2)
T2 310K and T1  372K
21. T1 cos37 0  T2 cos 530
4
 T2
3
T1 4T1  3T2 
T1 3

5 5 T2 4
22.
 a 2   0     a 2  a3
rcm 
   a 2    a 2 
23. 110 Mg 63 10
P1  P0  105 Pa  4
 2 105 Pa ; P2  P0   105  4
 64 105 Pa
10 A 10
5 5
T T
For adiabatic process 1 1  21
 400  3 
T23
2 2
P1 P2
 2 10  5 3
 64 10 5 3
2
T2  400  32  5  400  22  1600 K
24. Ex  
dV
   6  8 y2  Ey  
dV
  16 xy  8  6 z  Ez  
dV
   6 y  8z 
dx dy dy
At origin x  y  z  0 so Ex  6, E y  8 and Ez  0  E  E x2  E y2  10 N / C
Hence force F  QE  2  10  20 N
25.  t  t
N  No.e  1  8.e
 t l n2
e  8  t  3 l n 2  .t  3l n 2
t1/2
 t  3t1/2  3  1.4 109  4.2  109 Years
26. i
Using vd we get ;
ude ie nh 7 5 5
    
n udh ih ne 4 7 4
27. 
V
K
28. 5 V
Potential gradient   p
1000 1200
V p  6V
Vp 6
And R p    100
I 60 103
VP
L  1200 cm

1000cm
I  60 mA
G
5V 20 

29.  p
Electric field due to dipole on equatorial plane, E  k 3
r

 p
At point P, F p  k 3 Q ...............  i 
y

  p 
At point P , F p    k
'
Q  ...............  ii 
  y / 3 3

 
From

equation

(i) and (ii),

F p'  27 F p'  27 F
30. Both V and I are in the same phase. So, let us calculate the time taken by the voltage
to change from peak value to rms value. Now 220  220sin100 t1
 1 220
 or  100  t1   or  t1 
s again,  220 sin 100 t2
2 200 2
1 3 3
 or   sin 100 t2  or  100 t2   or  t2  s
2 4 400
1
Required time t2  t1  s  2.5 103 s
400
CHEMISTRY
31. 
Na2 B4O7   B2O3  NaBO2 3B2O3  Cr2O3  2Cr BO2   3
X Y
32. 
1
; V
1
K .E n
33. Apply MO theory. For CO32 : BO :1+
No.of π-bonds 1
 1   1.33
Total No σ bonds 3
34. S sys
V 10
 2.303 nR log 2  2.303  1 8.314  log  19.14 J / k
V1 1
Ssurr  0; Stotal  19.14 J / K
35. Carbonions are stabilized by e  with drawing groups
36. At high pressure ‘a’ is neglected due to repulsion between gas molecules.
 P V  b   RT or PV  RT  Pb
37. Lattice energy  Melting point
( L.E.) ( M.P.)
L.E . : LiF  LiCl
L.E. : MgO  NaCl
Lattice energy depends on the size of the ion. Smaller the size of anion or cation,
z z
higher the value of L.E. LE 
d
38. The products are due to coupling of different alkyl groups. CH 3CH 2CH 2Cl is RCl and
CH 3 C HCH 3 is R ' Cl , the products will be RR,R’R’ and RR’.
|
Cl
39. In cyclopentadienyl anion, each carbon is sp2 hybridized
H H
H
: H
40. Cl O  Na 
623 K 
 NaOH 
300 atm
Dow’s process
41. Xenates(+6), Perxenates(+8)
XeO3  NaOH  Na   HXeO4  2  HXeO4   2OH    XeO6   Xe  O2  2 H 2O
  4
42. Factual
43. KOBr - Hoffmann’s bromamide degradation with stepping down of series.
LiAlH 4 Reduces amides to 10 amines with same no. of carbon atoms
44. Flocculating value 
1
Flocculating power
According to Hardy-Schulze rule: Flocculating power : Sn 4  Al 3  Ba 2  Na  for
negatively charged sol
45. T f  KCl  T f  X  1
mKCl  mx   i X   For trimerisation of 75% extent
2
iKCl i x 

1  3 1
i  1    1  i 
6  4 2
46. Conceptual
47. 5% of sulphur is used for manufacturing of tyre rubber
48. Due to weak Bi – H bond.
49. Conceptual
50. Statement I is correct as +3 oxidation state of lanthanoids is more stable. Thus
E 0 4 3 is positive.
Ce /Ce
Statement II is incorrect as lanthanoids are more stable in +3 oxidation state.
51. P4  3NaOH  3H 2O  PH3  3NaH 2 PO2
X y6
52. The intially formed carbocation will undergo rearrangement. The 20 -carbocation will
form an optical isomer when attached with benzene.
53. p y  pz 3 3
Kp    3 Pequilibrium  px  p y  pz  3  3  3  9atm
px 3
54. 32 Ge 1s 2 2s 2 2 p 6 3s 2 3 p 6 4s 2 3d 10 4 p 2
ml  0, 1, 1 ml  1,0, 1  2, 1,0,1,2
ml  0  s  orbital and one p-orbital out of three in subshell, one d-orbital.
55. For any sparingly soluble salt
Ax By  x A y   y B x
In question its A3B2 K sp  108 S 5
So a = 108
56. 1 100
K 2  ln
1 100
........ i  K1  ln
K
........ ii  2 
ln 25
 4.65
t 4 t 50 K1 ln 2
57. M
 3   M  3  e n-factor of MgCl2 .KCl.H 2O  3.
e
58. O
||
O
||
O
||
OH  C*  CH 2  CH
|
 C*  NH  CH  C*  OCH 3
|
NH 2 NH 2
*
* *
* *
All marked carbon atoms of aspartame are sp
* 2
hybridized. Aspartame is methyl ester of dipeptide formed from aspartic acid and
phenylalanine.
59.
Nucleotide with uracile base present only in RNA.

60. The diene is CH 3CH  CH  CH 2  CH  CHCH 3
MATHEMATICS
61. n
5 3  4
n n
5.       
5.5  3  4 9 9 9 000
 lim   n   n   
n n n
lim n 0
n 5  2 n  27.9 n n
5 2 0  0  27
      27
9 9
2
62. 3
f  x    x  2 f 1  x    x  2 5 
3/5 3
Non – differentiable at x = 2
5 x  2
2/5
5
63. 750
750
400
tan 750 
h
40

h  40 tan 750 h  40 2  3 mts 
64. 1  5 7 11
2sin 2   3sin   2  0  sin   2  2sin   1  0 sin  
 , , , Sum  2
2 6 6 6 6
65. Clearly origin is equidistant to the vertices  circumcentre   0,0,0   S , centroid
 3 1 5 4  0  5 5  7 
 , ,    3,3, 4  Centroid divides HS in the ratio 2:1
 3 3 3 
Let H   ,  ,   OG 
2OS  1 OH    3,3, 4    0   ,  ,  
 
2 1  3 3 3
  9,   9,   12 HS  92  92  122  306
66. 2
x2
 x 1 x 1
2
f  x     , x  0 log e f  x   x 2  log 2  log x  f 1  x   0  log e      e 2  x 

 x 2 2 2 e
4
 e
 2  4
 
2
Local max.value     e e
 ee
 2 
 
 e
67. We know that if f  x   f 1  x  then f  x   x   x  1  1  x  x 2  x  0  x  x  1  0
2
 x  0, x  1
68. x y h  1 k  4 2  1  12  3
Line   1  x  3y  3  0  
3 1 1 3 1  9 
h  1 16 k  4 16 11 48 28
Image   , 
11 28
 ,  h ,k  4  k
1 5 3 5 5 5 5 5 5 
69.  2 2
For no solution 2 3 5  0   18  5   2 12  20   2  2 2  12   0
4  6
 2  6  16  0    8   2   0   2
70. x  y  z 1 (1) Required plane x  y  z  1    x  2 y  3z   0
1    x  1  2  y  1  3  z  1  0 (2) (1) and (2) are perpendicular
3
 (1) 1     11  2   11  3   0  2  3   
2
3
 Required plane is x  y  z  1  x  2 y  3z   0 2 x  2 y  2 z  2  3 x  6 y  9 z  0
2
 x  8 y  7 z  2 x  8 y  7 z  2
71.  a  ib     i Taking complex conjugate  a  ib     i
5 5

 i a  ib     i   i   b  ai     i  b  ai   
5 5 5 5
2
   i  
i
72.

 2,3
Equation of tangent at origin is

2
7 m
2  x  0   3  y  0   0  2 x  3 y  0 tan    3 7
4 2m 4
1
3
3m  2 7 1 1
   12 m  8  21  14 m  26m  13  m   y  x  x  2 y  0
3  2m 4 2 2
73. Equation of normal to the ellipse is
5x

4y
9
cos sin 
9
 r distance from centre  1
25sec   16cos ec 2
2
But radius of circle  3  No. of normals is 0.

74. 1
1
dt 1
1
e1 1
Put x 3  t  I 2    
3 0 e  2  t  3 0 e 1  t 
t
dt  I1
3e
I1
  3e
I2
75. Let the truth values of P and Q be T,F q  p is T  p   q  p  is T
p  q is T  P   p  q  is T
76. Let f  x   x3  3x  1 Then f 1  x   3 x 2  1 Let f 1  x   0  x  1 and f 1 f  1  0
2
77.
f  x  is symmetric about y  x Required area  2x  f  x   x dx
0
 2
 
 2   sin x dx     sin x  dx   2  2  2   2 K  3
3
0 
78.  5  1   5  1 1  5  1  5
87 87 87 87
487  687 2  87 C1.5 87 C3.53  .....87 C87 .587 
10.87  2  87 C3.53  ......87 C87 .587  =870+an expression divisible by 25
870 20
  34   Reminder is 20
25 25
79. Given hyperbola are conjugate and quadrilateral formed by their foci is a square.
y
 0,be2 
x
 ae1,0 0  ae2 ,0
 0, be2 
a 2 2 a  b 
2 2 2
2
x2 y 2 x2 y 2 b2 2
Now 2  2  1 and 2  2  1 e1  1  2 ; e2  1  2 ; e1 e2 
2
:
a b a b a b a 2b 2
a 2  b2
e1e2 
ab
 2ae1  2be2   2ab  a 2  b2   2 a 2  b 2
A
2 ab
 
80. R   2,3 ,  3,3 ,  2,3 ,  3, 2  ,  3, 4  ,  4,3 ,  4, 4 
81. Given M  25, N  100, F  45, C  10, l  20
N
F
M l 2  c  f  10
f
82. n
2r  1 n 
1 1  1 440
Sn   2     2 
 1   n  1  21
r 1 r  r  1
2

r 1 r
2
 r  1  441 441

83. The required numbers contain
7!
1,1,1,1,1,2,3   42
5!
7!
1,1,1,1,2,2,2,   35
4!3!
Total no of ways  77
84. a b g  a 2  b 2  c 2 ad  be  cf ag  bh  ci 
c a d
 
A   d e f   A   b

h  AAT   da  eb  fc d 2  e2  f 2 dg  eh  fi 
T
e
 g h f i   ga  hb  ic gd  he  if g 2  h 2  i 2 
i   c
 
Given, a  b  c  d  e  f  g  h  i  9 a, b, c, d , e, f , g , h, i  0,1, 2,3
2 2 2 2 2 2 2 2 2
(i) One of them is 3, remaining are 0s 9 ways (ii) 2 of them are 2s, one of them is 1
and remaining 0s 9C2 .7C1  252 ays
iii) One of them is 2’s five of them are 1’s and remaining 0’s 9C .8C  504 ways 1 5
(iv) All are 1s1 waysTotal  9  252  504  1  767 ways

85. y
dy
 sin  x  y   sin  x  y   2sin x cos y sec2 ydy  2sin xdx
dx
  
tan y  2cos x  2  y  0   0  x   tan y  2  sec 2 y  y1  2sin x  5 y1    2
2 2
86. 2
y  eabx passes through (1, 1)  1  e ab
(1) Given slope  2  2bx  .e abx   2 2b.e a b  2 2b  2  b  1
2
 ab  0
  1,1
2a  3b  2 1  3  1  5
Sec: Sr.Super60_NUCLEUS & ALL_BTयश TG~ @bohring_bot Page 10

87. x 1 y 1 z  3
Eqn.of the plane containing the given lines is 6 7 8 0
3 5 7
7  2  2   13
24
 4 6  PQ   96
2
 x  2 y  z  0 PQ  
1  2 1
2
6
2 2
88. f  x  y   2 f  y   4 f  x  put
x y
y  2 f  x  2   2 x. 3  16 f  x 
f '  x  2   3.2 x log 2  16 f '  x 
put x  2 f  2  y   4 f  y   4 y f  2  f 1  2  y   4 f 1  y   3.4 y log 4
f 1  4   4 f 1  2   48log 22 f 1  4   4 f 1  2   96log 2      (2) From (1) and (2)
f 1  4  7 124 log 2 
f 1  2   7 log 2 f 1  4   124 log 2 2   124
f 1  2 7 log 2
89. h 2  ab h 2   9  4  h  6 af 2  bg 2  9  f 2   4  9  f 2  4 f  2
h f  62 8
90. Applying R1  R1  R2 , R2  R2  R3
2 2 0
f  x  2 0 1  4  2 cos 2x Max.value =4+2
sin x cos x 1  cos 2 x
2 2
6

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

5. Given below are two statements: One is labeled as

24. Electric potential is given by V  6 x  8 xy 2  8 y  6 yz  4 z 2 then electric force acting on 2C point

30. A resistance of 20  is connected to a source of an alternating voltage V  220 sin 100  t  .

Sec: Sr.Super60_NUCLEUS & ALL_BT Page 7

1) Na3 BO3 and Cr  BO2 3 2) Na2 B4O7 and Cr  BO2 3

1) 19.14 2) Zero 3) 3.06 4) 16.08

1) II >III>IV>I 2) III>IV>I>II 3) IV>I>II>III 4) I>II>III>IV

Which of the following is not a product of above reaction?

The above reaction requires which of the following reaction conditions?

Q. Cu  NH 3 4   PtCl4  and  Pt  NH 3 4  CuCl4 ...... co-ordination

R.  Pt  NH 3 4 Cl2  Br2 and  Pt  NH 3 4 Br2  Cl2 ..... ionization

Select the correct answer using the codes given below :

In the above reactions, product A and product B respectively are :

CH 3CH 2CH 2CH 2Cl 

The equilibrium constant K p of above reaction is 3 atm at a certain temperature. If equal

solubility product satisfies K sp  a 

56. Consider the following first order competing reactions:

reaction of Y was completed, the ratio of their rate constants  k2 / k1  is:

solution of MgCl2 .KCl.6 H 2O is  M  e  x . Value of x is

The local maximum value of the function f  x     , x  0

76. The number of real roots of the equation x3  3x  1  0 is

x  0 and x  2 is 2k , k  N then k = ___

to be included in R, so that R becomes reflexive and symmetric is

all the diagonal entries of AAT is 9, is equal to _________

89. If 9 x2  2hxy  4 y 2  6 x  2 fy  3  0  h  0, f  0  represents two parallel lines, then h  f 

sin 2 x 2  cos 2 x cos 2 x

Sri Chaitanya IIT Academy.,India.

300 300 h  3400 m

The potential difference between A and B can be calculated as:

Sec: Sr.Super60_NUCLEUS & ALL_BT Page 3

Sec: Sr.Super60_NUCLEUS & ALL_BT Page 6

Nucleotide with uracile base present only in RNA.

Equation of tangent at origin is

But radius of circle  3  No. of normals is 0.

(iv) All are 1s1 waysTotal  9  252  504  1  767 ways

Sec: Sr.Super60_NUCLEUS & ALL_BTयश TG~ @bohring_bot Page 10

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