LAB

SAFETY DATA SHEET

According to GHS, 5th Revision

SECTION 1 - IDENTIFICATION

1.1 Product identifier

Product name: LAB

Product Identifier: 05100

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: According to the technical data sheet of the product.

1.3 Details of the supplier of the Safety Data Sheet

YPF S.A.
Macacha Güemes n° 515, (C1106BKK) Puerto Madero, Ciudad Autónoma de Buenos Aires, Argentina.
P: +54 11 5441 2000. F: +54 11 5441 5796.

1.4 Emergency telephone number

Emergency phone (24 hours): CIQUIME 0800 222 2933 (from Argentina)
+54 11 4552 8747 (other countries)

SECTION 2 – HAZARD IDENTIFICATION

2.1 Classification of the substance or mixture

Classification according to the Globally Harmonized System

Aspiration hazard (Category 1)
Short-term (acute) aquatic hazard (Category 1)
Long-term (chronic) aquatic hazard (Category 1)

2.2 Label elements

Pictogram:

Signal word: DANGER

Hazard statements:
H304 - May be fatal if swallowed and enters airways.
H400 - Very toxic to aquatic life.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P301 + P310 + P331 - IF SWALLOWED: Call a POISON CENTER or a doctor. Do NOT induce vomiting.
P273 - Avoid release to the environment.
P391 - Collect spillage.
P405 - Store locked up.
P501 - Dispose of contents and/or container in accordance with national and international regulations.
Revision: 15 Revision date: April, 2023
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2.3 Other hazards

The mixture contains one or several components of unknown acute toxicity by oral, dermal or inhalation route.

SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS

3.1 Substance
3.1 Substance

Benzene, C10-13-alkyl derivs. (CAS 67774-74-7):100 % - Asp. Tox. 1; Aquatic Acute 1; Aquatic Chronic 1

SECTION 4 – FIRST-AID MEASURES

4.1 Description of first aid measures

General advice: Avoid exposure to the product and take appropriate protective measures. Consult your
doctor with the safety data sheet.
Inhalation: Move victim to an area with clean air. Keep her at rest. If not breathing, apply artificial
respiration. Call the doctor.
Skin contact: Wash skin with plenty of soap and water for at least 15 minutes. DO NOT use kerosene,
naphtha or solvents to remove the product. In case of burns from hot product, cool with
water for at least 5 minutes. Don't use ice.
Eye contact: Immediately flush eyes with water for at least 15 minutes, keeping eyelids open. If you
have contact lenses, remove them after 5 minutes and continue rinsing eyes. Consult
the doctor.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. If the victim is unconscious, call
a doctor immediately, and turn her on her side to reduce the risk of aspiration. Do not
give the victim anything to drink or eat.

4.2 Most important symptoms and effects, both acute and delayed

Inhalation: May cause irritation if mist is inhaled.

Skin Contact: May cause irritation or dermatitis on prolonged or repeated exposure.
Eye Contact: May cause eye irritation.
Ingestion: May cause nausea, vomiting, and diarrhea.

4.3 Indication of any immediate medical attention and special treatment needed

Medical advice: Perform symptomatic treatment. For more information, consult a Poison Center.

SECTION 5 – FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Use dry chemical, foam, sand or carbon dioxide (CO₂). Use the product according to surrounding materials. DO
NOT USE water jets as it may spread fire. The use of water can cause frothing, or product spillage by violent
boiling of water added.
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5.2 Special hazards arising from the substance or mixture

The liquid may burn but will not ignite easily.

5.3 Advice for firefighters

5.3.1 Firefighting instructions

Spray containers and/or tanks with water to keep them cool.
Continue cooling with water after fire is out
Prevent water used for fire control from entering containers, tanks, waterways, drains, or springs.
Hot material can cause violent boiling when in contact with water, being able to project and cause serious burns.
5.3.2 Protective clothing
Use SCBA and structural protection clothing for firefighters.
5.3.3 Hazardous combustion products
In case of fire, it may release irritating and/or toxic fumes and gases, such as carbon monoxide, and other
substances derived from incomplete combustion.

SECTION 6 – ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel

Evacuate personnel to a ventilated area.
6.1.2 For emergency responders
Wear positive pressure self-contained breathing apparatus and fire-fighting protective clothing (includes fire-
fighting helmet, jacket, pants, boots, and gloves). Avoid contact with the product during operations.
For non-fire spills or post-fire cleanup phase, wear chemical protective clothing specifically recommended by the
manufacturer.
Eliminate all sources of ignition (no smoking, flares, sparks or open flames in danger area). Evacuate people to a
ventilated area. Ventilate immediately, especially in low areas where vapors may accumulate. Do not allow reuse
of spilled product.

6.2 Environmental precautions

Contain spilled liquid with a dam. Prevent entry into waterways, sewers, basements or confined areas.
Hazard of significant physical contamination in case of spillage on coastlines, beaches, soil, etc. due to its
floatability and oily consistency.
Avoid the entry of the product into sewers and water sources.
Spills form a film on the water surface not allowing oxygen transfer.

6.3 Methods and material for containment and cleaning up

Contain and recover the liquid when possible. Collect the liquid product with sand, vermiculite, earth, or inert
absorbent material and then completely clean the affected area. Dispose of the waste properly. Dispose of the
water and collected waste in marked containers for disposal as waste.

6.4 Reference to other sections

See Section 8 - Exposure Controls and Personal Protection, and Section 13 – Disposal considerations.
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SECTION 7 – HANDLING AND STORAGE

7.1 Precautions for safe handling

Do not eat, drink or smoke when handling it. Avoid contact with eyes, skin and clothing. Wash hands after handling
this product.
Use equipment and clothing that prevents the accumulation of electrostatic charges. Control and prevent the
formation of explosive atmospheres.
The material can accumulate static charges and generate an electrical spark. Ground the container during filling
and maintain contact with it. Do not use electronic equipment in the vicinity of filling areas, unless it is duly certified
as safe.
Product Transfer: Avoid splashing when filling. Keep containers closed when not in use. Contamination from
product transfer may cause vapor ignition.

7.2 Conditions for safe storage, including any incompatibilities

Store the product in a clean, dry and well ventilated area. Protect from the sun.
The type of container used to store the material can affect the accumulation and dissipation of electrostatic
charges. Storage containers must be grounded and bonded. Stationary containers, transfer containers, and their
associated equipment must be grounded and bonded to prevent electrostatic charge buildup.
Other Information: Vapors in the storage container may be at the flammable limit and therefore flammable.
Packaging materials: Supplied by the manufacturer.
Incompatibilities: Keep away from Strong oxidizing agents, acids and bases.

7.3 Specific end use(s)

According to the technical data sheet of the product.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

TLV-TWA (ACGIH): N/D

TLV-STEL (ACGIH): N/D

PEL (OSHA): N/D

IDLH (NIOSH): N/D

8.2 Exposure controls

8.2.1 Appropriate engineering controls

Keep workplace ventilated. The normal routine ventilation is usually adequate. Local hoods should be used for
operations that produce or release large amounts of product. In low or confined areas should be provided me-
chanical ventilation. Provide showers and eyewash stations.
8.2.2. Individual protection measures, such as personal protective equipment
Eye and face protection: When necessary, wear safety glasses complying with EN 166.
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Skin protection: When necessary, wear impermeable protective PVC, nitrile or butyl gloves (com-
plying with standards EN 374), clothes and safety footwear resistant to chemicals.
Respiratory protection: When necessary, wear an organic gas or steam (A) respirator. Special attention to
oxygen levels in the air should be paid.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance: Clear liquid.

Colour: N/D
Odour: N/D
Odour threshold: N/D
pH: N/D
Melting point: -70°C (-94°F)
Boiling point: 240°C (464°F)
Evaporation rate: N/D
Flammability: The product is not flammable, but it is combustible.
Flash point: 140°C (284°F)
Explosive limits: N/D
Auto-ignition temperature: N/D
Decomposition temperature: N/D
Vapour pressure (20°C): 0.013 hPa
Vapour density (air=1): >1
Relative density (20°C): 0,86 g/cm³
Solubility (20°C): 0.041 mg/L
Partition coefficient (logKo/w): N/D
Henry constant (20°C): N/D
Explosive properties: Not explosive. According to column 2 of Annex VII of REACH, this study is
not required because in the molecule no chemical groups are associated
with explosive properties.
Oxidizing properties: According to column 2 of Annex VII of REACH, this study is not necessary
because the substances present in the product, due to their chemical
structures, are incapable of reacting exothermically with combustible
materials.

9.2 Other information

Other properties: None.

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SECTION 10 – STABILITY AND REACTIVITY

10.1. Reactivity

It is not expected that product reactions or decomposition may occur under normal storage conditions. It does not
contain organic peroxides. It is not corrosive to metals. It does not react with water.

10.2. Chemical stability

The product is chemically stable and it does not require stabilizers.

10.3. Possibility of hazardous reactions

No hazardous polymerization is expected.

10.4. Conditions to avoid

Avoid high temperatures.

10.5. Incompatible materials

Keep away from Strong oxidizing agents, acids and bases.

10.6. Hazardous decomposition products

When heated, it may release toxic and irritating vapors. In case of fire, see section 5.

SECTION 11 – TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity:
There is no information about the toxicity of the product, but acute toxicity estimations are presented. ATE-LD50
oral (calc.): > 5000 mg/kg
ATE-LD50 der (calc.): > 5000 mg/kg
ATE-LC50 inh. (4 hs., calc): > 5 mg/l
Skin irr. (rabbit, estim.): not irritant
Eye irr. (rabbit, estim.): not irritant
Skin sens (Guinea pig, estim.): not sensitising
Resp. sens (Guinea pig, estim.): not sensitizing
Carcinogenicity, mutagenicity, reproductive toxicity and other effects:
Carcinogenicity: No information is available on any component of this product, present at levels greater than or
equal to 0.1%, that is classified as probable, possible or confirmed human carcinogen by IARC (International
Agency for Research on Cancer).
Mutagenicity: There are no components of this product, present at a concentration greater than or equal to 0.1%,
that classify as mutagens according to the GHS.
Tox. Repr .: There are no components of this product, present at a concentration greater than or equal to 0.1%,
that classify as hazardous for reproduction according to the GHS.
Teratogenicity: There are no components of this product, present at a concentration greater than or equal to
0.1%, that classify as a teratogen.
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STOT-SE: There are no components of this product, present at a concentration greater than or equal to 1%, that
they classify as toxic to target organs according to the GHS.
STOT-RE: There are no components of this product, present at a concentration greater than or equal to 1%,
that they classify as toxic to target organs according to the GHS.
Aspiration: The product is toxic by aspiration and its viscosity makes it possible to incorporate it by this route,
which is why it is classified as dangerous by aspiration.
Acute and delayed effects:
Routes of exposure: Inhalation, skin and eye contact.
Inhalation: May cause irritation if mist is inhaled.
Skin Contact: May cause irritation or dermatitis on prolonged or repeated exposure.
Eye Contact: May cause eye irritation.
Ingestion: May cause nausea, vomiting, and diarrhea.

SECTION 12 – ECOLOGICAL INFORMATION

12.1. Toxicity

There is no information about the ecotoxicity of the product, but acute toxicity estimations are presented. ATE-
EC50 (fish, calc., 96 h): < 1 mg/l
ATE-EC50 (inv., calc., 48 h): < 1 mg/l
ATE-EC50 (algas, calc., 72 h): < 1 mg/l
ATE-NOEC (fish, calc., 14 d): < 0,01 mg/l
ATE-NOEC (inv., calc., 14 d): 1 - 10 mg/l
PNEC (water): N/D
PNEC (sea): N/D
PNEC-STP: N/D

12.2. Persistence and degradability

BIODEGRADABILITY (): The product is not readily biodegradable.

12.3. Bioaccumulative potential

Log Ko/w: N/D

BIOCONCENTRATION FACTOR - BCF (OCDE 305): N/D

12.4. Mobility in soil

HENRY CONSTANT (20°C): N/D

LogKoc: N/D .

12.5. Results of PBT and vPvB assessment

This substance/mixture does not meet the PBT criteria of annex XIII of the REACH regulation.
This substance/mixture does not meet the vPvB criteria of annex XIII of the REACH regulation.

12.6. Other adverse effects

AOX and metal containing: Does not contain organic halogens nor metals.

SECTION 13 – DISPOSAL CONSIDERATIONS

Dispose of excess product and empty containers according to current legislation for the protection of the
environment and hazardous waste. Disposal procedure: incineration.
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SECTION 14 – TRANSPORT INFORMATION

14.1 Transport by land

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains Benzene derivatives)
UN/ID Number: 3082
Hazard class: 9
Packing group: III
Hazard identification number: 90
Excepted and limited quantity: 1000 / 5 L
Special provisions: 274; 331; 335; 375

14.2 Air transport (ICAO/IATA)

Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,

N.O.S. (contains Benzene derivatives)
UN/ID Number: 3082
Hazard class: 9
Packing group: III
PAX and Cargo Packing instructions: Y964; 30 kgG / 964; 450L
Cargo Packing instructions: 964; 450L
ERC: 9L
Special provisions: A97; A158

14.3 Sea transport (IMO)

IMDG Code
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains Benzene derivatives)
UN/ID N°: 3082
Hazard class: 9
Packing group: III
EMS: F-A, S-F
Stowage and manipulation: Categoría A

Segregation: –
Marine pollutant: YES
Proper Shipping Name: UN3082; ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains
Benzene derivatives); Class 9; PG III; MARINE POLLUTANT
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SECTION 15 – REGULATORY INFORMATION

Not dangerous for the ozone layer.
Volatile organic compounds (VOC’s): N/D
NFPA: 2 1 0 - EPP: G

Regulation
Globally Harmonized System of Classification and Labelling of Chemicals, fifth revised edition, 2013 (GHS 2013 -
'ST / SG / AC 10/30 / Rev.5'). The fifth edition is taken into consideration because it is the one valid for Argentina
according to Resolution 801/2015 of the SRT. In any case, the information is contrasted with Revision 7 ('ST / SG
/ AC 10/30 / Rev.7') and clarification is made if required.
Agreement on Transport of Dangerous Products within the MERCOSUR, MERCOSUR\CMC\DEC N° 2/94.
European Agreement on the International Carriage of Dangerous Goods by Road (ADR 2021) and amendments.
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID 2021) and amendments.
International Maritime Dangerous Goods Code (IMDG 2020 - Amendment 40-20), International Maritime Organi-
zation (IMO).
Regulations of the International Air Transport Association (IATA 63 ed., 2022) on the transport of dangerous goods
by air.

SECTION 16 – OTHER INFORMATION

16.1 Abbreviations and acronyms

N/A: not applicable. Liquefied gas: liquefied gas

N/D: no data available. Oxid. Liquid: oxidizing liquid
CAS: Chemical Abstracts Service Flam. Liquid: flammable liquid
IARC: International Agency for Research on Cancer Pyr. Liq.: pyrophoric liquid
ACGIH: American Conference of Governmental In- Met. Corr.: corrosive for metals
dustrial Hygienists. Org. Perox.: organic peroxide
TLV: Threshold Limit Value Water React. Flam. Gas: substance reactive with wa-
TWA: Time Weighted Average ter, which emits flammable gases
STEL: Short Term Exposure Oxid. Solid: oxidizing solid
REL: Recommended Exposure Limit. Flam. Solid: flammable solid
PEL: Permissible Exposure Limit. Asp Tox.: aspiration toxicity
INSHT: National Institute for Safety and Health at Carc.: carcinogenicity
Work. Skin Corr. / Irrit.: Corrosion / skin irritation
ATE: Acute toxicity estimate. Eye Damage / Irrit .: Serious eye damage / eye irrita-
LD50: Lethal Dose. tion
LC50: Lethal Concentration. Lac.: toxic for reproduction - lactation
EC50: Average Effective Concentration. Muta.: mutagenicity
IC50: Inhibitory Concentration Medium. Repr.: toxic for reproduction
Skin Sens.: skin sensitizer
DENOMINATION OF GHS CLASSES Resp. Sens.: respiratory sensitizer
Aer.: aerosols STOT Rep. Exp.: Specific target organ toxicity - re-
Oxid. Gas: oxidizing gas peated exposure
Compressed gas: compressed gas STOT Single Exp.: Specific target organ toxicity - sin-
Dissolved gas: dissolved gas gle exposure
Flam. Gas: flammable gas Acute Tox.: Acute toxicity
Liquefied Refr. Gas: refrigerated liquefied gas
 LAB SAFETY DATA SHEET Page 10 of 10

Aquatic Acute: Hazardous to the aquatic environ- Aquatic Chronic: Dangerous for the aquatic environ-
ment - acute danger ment - chronic danger
Ozo.: Dangerous for the ozone layer.

16.2 Key literature references and sources for data

International Agency for Research on Cancer (IARC), carcinogen classification.

European Regulation 1272/2008, Classification, labeling and packing (CLP)

16.3 Classification and procedure used to derive the classification for mixtures

The classification was performed based on chemical analogues and product information compiled by CIQUIME.
SECTION 2: classification by analogy with other products, and based on product data in CIQUIME database.
SECTION 9: product data.
SECTION 11 and 12: calculation of acute toxicity estimation according to GHS, product data and bibliographic
data.
Change's control: v.1 - Adaptation to the GHS.

16.4 Disclaimer

This information only concerns the above-mentioned product and is not to be valid for other (s) product (s) or in
any process. This safety data sheet provides health and safety information. The information is to our best
knowledge, correct and complete. It is given in good faith but without warranty. The product should be used in
applications consistent with our product literature. Individuals handling this product should be in-formed of the
recommended safety precautions and should have access to this information. For any other use, exposure should
be evaluated so that they can implement appropriate handling practices and training programs to ensure safe
operations in the workplace.
It remains the user's own responsibility that this information is appropriate and complete for the special use of this
product.
CIC: 2304.578