Kinetics Part I

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Kinetlc&

ROte of reactiun can be quantitivety expre)ed as the ‘ in wnt- ot,Pw uct pe unt
time Y in COvc f a veactant per unit ne.
SL unit uf ti me
Ain Cpnut A jn C reatant)
A in time

NOTE Un'ts mol dn3


timg
-

s/min
muJt Averae vate = A in wnc. of areactant/ pvocluet over a speutic time ine vval
Pou1 TIVE
lnitatneouw rae = vatt ot veactiun at pecific point of tine
- draw tungent s forn cAlc gvoad
(mod )
lniial vate = instantanevus vate at time zeVo (t su)
A approx aveae vate over snovt tie ievval
Crtactant
A /nitial vat =

tneveY CRate Lan)


Wvittn Kate Eauatiun elaeJ Vate ot reacion tu tmeCoNonUt yeatuntt Vais eu to tne
in ermj appropviae p0wer
ot cweff ?A and Bare RBAcTANTS
of enemical - u n : mui cAm3 -!
ime

Order f rea ctiun wrt a neactant is tne poer to wnicn nc ut reucta nt iJ vais ed
in exevinentolly aetevmined nte eUA
Ovevau ovder t veatn = umm ut individual ovdeys wut tu ecan reatAnt

t Small Rate c n s t t k wnitat uf pupovtionalíty in ate eaA


leter k munematiay culo tbr ik unit
indeoendent ut [reutantsl BuT ‘temp add catalyst wil Tk
E - a tivatun enevy
k A ItempRT
C\t wns tunt
arrnenius wnstan+

SBI
VGaph ’ kineics
O zevo- ov dev veactiovn Fi4- Uvdev 2eactiun
at of haton i pogovti unal to CAJ
(icatA 2Cvo Uvcldy wrt independ
reatt A)
ent of CAJ =qe e vopct u,divecty

Rea ta RaeCA
proceeos at onstan rae k k
RatC

)tReatant immin unit: s-'/min/hee


|Reuto hus wnitant halt- |'fe t4
CReatantj
Lonstaut t+

timp
CPvoductJ
time
( CPho duct

t= ta
fae
> time
time
ratk

To Reactant >(eactonrJ gvad wntt


oV
ov7

Halt tifetine taken fov on to tO


halt otits unc
6) Secod-ordey Reacin
(n 2 foumula
’ onts fov IovcLer veactA
RAe kCA7 calc.
unit of : -con-ut
indepe nclent of initial canc .of
veactant reateant
CReactant J
Conc t reatant at t Elee
ti ta half-lc not cwnitntJ
Co
t4 qet yreatev in tuct wnc of reatant at t o [oviginal]
’timAe
ti t

Iorodu

A
tit

time
ti

Ratt Rae

[Reactunt]

dvaw tvú when 4n hus Lveautat

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