Oil Spill Dispersant WB

Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Date of issue: 3/6/2013 Revision date: 7/1/2018 Supersedes: 2/17/2016 Version: 1.2

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Product name : Oil Spill Dispersant WB
Product code : 1110100
Product group : Alkaline mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Industrial use

1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet
Star Marine Chemicals
Bunschotenweg 134
3089 KC Rotterdam - The Netherlands
T +31(0)105925831
[email protected] - www.starmarine.nl
1.4. Emergency telephone number
Country Organisation/Company Address Emergency number Comment
Netherlands Nationaal Vergiftigingen Huispostnummer B.00.118 +31 30 274 88 88 Only for the purpose of
Informatie Centrum Postbus 85500 informing medical personnel
3508 GA Utrecht in cases of acute intoxications

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Mixture: SDS < 2015 : Show CLP information only
Skin corrosion/irritation, Category 1B H314
Corrosive to metals Not classified
Full text of H-statements: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP) :

GHS05
Signal word (CLP) : Danger
Hazardous ingredients : Ethanolamine; Sodium hydroxide
Hazard statements (CLP) : H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, face protection, eye protection.
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P363 - Wash contaminated clothing before reuse.
2.3. Other hazards
No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

3.2. Mixture

Name Product identifier % Classification according Classification

to Directive 67/548/EEC according to
Regulation (EC) No.
1272/2008 [CLP]
Alcohols, C12-14, Ethoxylated (CAS-No.) 68131-39-5 5 - 15 Xn; R22 Acute Tox. 4 (Oral), H302
(EC-No.) Polymer Xi; R41 Eye Dam. 1, H318

Ethanolamine (CAS-No.) 141-43-5 <5 Xn; R20/21/22 Acute Tox. 4 (Oral), H302
(EC-No.) 205-483-3 C; R34 Acute Tox. 4 (Dermal),
(EC Index-No.) 603-030-00-8 H312
(REACH-no) 01-2119486455- Acute Tox. 4 (Inhalation),
28 H332
Skin Corr. 1B, H314
STOT SE 3, H335
Aquatic Chronic 3, H412
2-(2-butoxyethoxy)ethanol (CAS-No.) 112-34-5 <5 Xi; R36 Eye Irrit. 2, H319
(EC-No.) 203-961-6
(EC Index-No.) 603-096-00-8
(REACH-no) 01-2119475104-
44
Sodium hydroxide (CAS-No.) 1310-73-2 <5 C; R35 Met. Corr. 1, H290
(EC-No.) 215-185-5 Skin Corr. 1A, H314
(EC Index-No.) 011-002-00-6
(REACH-no) 01-2119457892-
27
Full text of R- and H-statements: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : In all cases of doubt, or when symptoms persist, seek medical attention.
First-aid measures after inhalation : In case of serious or continous discomfort, provide fresh air and seek medical advice.
First-aid measures after skin contact : Wash with plenty of water and if necessary take medical advice.
First-aid measures after eye contact : Wash with plenty of water and if necessary take medical advice.
First-aid measures after ingestion : Rinse mouth out with water. Transport to hospital immediately.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after skin contact : Pungent. Severe burns. Pain. Redness.
Symptoms/effects after eye contact : Pungent. Pain. Redness. Blurred vision.
Symptoms/effects after ingestion : Caustic, lack of breath, vomiting, blisters on lips and tongue, burning pain in mouth and
throat, gullet and stomach.
4.3. Indication of any immediate medical attention and special treatment needed
None.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Water spray, powder, foam, CO2.
Unsuitable extinguishing media : None.
5.2. Special hazards arising from the substance or mixture
Fire hazard : None.
Explosion hazard : None.
5.3. Advice for firefighters
Precautionary measures fire : No special precautions required.
Firefighting instructions : No specific firefighting instructions required.
Protection during firefighting : No specific measures are necessary.
Other information : None known.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : When using do not eat, drink or smoke. Keep container tightly closed. Keep out of reach of
children.

6.1.1. For non-emergency personnel

No additional information available
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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
6.1.2. For emergency responders
No additional information available
6.2. Environmental precautions
Prevent entry to sewers and public waters.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : In case the undiluted product is discharged accidentally, neutralize to pH 7.
6.4. Reference to other sections
See Headings 8 and 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Handle carefully. Avoid spillage.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed and in well ventilated place. Keep out of frost.
Packaging materials : Do not use metal containers.
7.3. Specific end use(s)
Cleaning product.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
No additional information available
8.2. Exposure controls
Personal protective equipment:
Gloves. Safety glasses. Protective clothing.

Hand protection:
chemical resistant gloves.

Eye protection:
Safety glasses

Skin and body protection:

Wear suitable protective clothing

Personal protective equipment symbol(s):

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Colour : Colourless.
Odour : Characteristic.
Odour threshold : No data available
pH : 13.5
Relative evaporation rate (butylacetate=1) : 0.3
Melting point : < 0 °C
Freezing point : No data available
Boiling point : 100 - 233 °C
Flash point : Not applicable.
Critical temperature : No data available.
Auto-ignition temperature : 200 °C
Decomposition temperature : No data available.
Flammability (solid, gas) : Not applicable.
Vapour pressure : 2332 kPa at 20 °C.
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1.06 kg/l at 20 °C.

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
Relative gas density : Not applicable.
Solubility : Completely soluble in water.
Log Pow : No data available
Viscosity, kinematic : 1 mm²/s at 20 °C.
Viscosity, dynamic : 1 mPa·s at 20 °C.
Explosive properties : Not applicable.
Oxidising properties : Not applicable.
Explosive limits : 0.85 - 24.6 vol %
9.2. Other information
VOC content : 1.27 %

SECTION 10: Stability and reactivity

10.1. Reactivity
None.
10.2. Chemical stability
Do not bring in contact with acids.
10.3. Possibility of hazardous reactions
Acids.
10.4. Conditions to avoid
Handle carefully. Avoid spillage.
10.5. Incompatible materials
metals.
10.6. Hazardous decomposition products
Do not bring in contact with acids.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

Ethanolamine (141-43-5)
LD50 oral rat 1089 mg/kg
LD50 dermal rabbit 2504 mg/kg
LC50 inhalation rat (mg/l) 11 mg/l/4h

2-(2-butoxyethoxy)ethanol (112-34-5)
LD50 oral rat 3305 mg/kg
LD50 dermal rabbit >= 2764 mg/kg
LC50 inhalation rat (mg/l) >= 50 mg/l/4h

Sodium hydroxide (1310-73-2)

LD50 oral rat >= 5000 mg/kg
LD50 dermal rabbit >= 5000 mg/kg

Alcohols, C12-14, Ethoxylated (68131-39-5)

LD50 oral rat < 2000 mg/kg
LC50 inhalation rat (mg/l) > 5 mg/l
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 13.5
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 13.5
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified
Aspiration hazard : Not classified

Oil Spill Dispersant WB

Viscosity, kinematic 1 mm²/s at 20 °C.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : No data available.
Acute aquatic toxicity : Not classified
Chronic aquatic toxicity : Not classified

Ethanolamine
LC50 fish 1 349 mg/l (Cyprinus carpio, 4d)
EC50 Daphnia 1 65 mg/l
EC50 72h algae (1) 2.1 - 2.8 mg/l
NOEC chronic fish 1.24 mg/l (Oryzias latipes, 41d)
NOEC chronic crustacea 0.85 mg/l (21d)
NOEC chronic algae 1 mg/l (72h)

2-(2-butoxyethoxy)ethanol
LC50 fish 1 1300 mg/l
EC50 Daphnia 1 > 100 mg/l
ErC50 (algae) > 100 mg/l

Sodium hydroxide
LC50 fish 1 35 - 189 mg/l
EC50 Daphnia 1 33 - 450 mg/l

Alcohols, C12-14, Ethoxylated

LC50 fish 1 < 1 mg/l
ErC50 (algae) 1 - 10 mg/l
12.2. Persistence and degradability
Oil Spill Dispersant WB
Persistence and degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability
criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this
assertion are held at the disposal of the competent authorities of the Member States and
will be made available to them, at their direct request or at the request of a detergent
manufacturer.
12.3. Bioaccumulative potential
Oil Spill Dispersant WB
Bioaccumulative potential No data available.
12.4. Mobility in soil
Oil Spill Dispersant WB
Mobility in soil WGK 2
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
Other adverse effects : No data available.
Additional information : No data available

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Regional legislation (waste) : Comply with local regulations for disposal.
Waste treatment methods : In case the undiluted product is discharged accidentally, neutralize to pH 7.
Product/Packaging disposal recommendations : Disposal must be done according to official regulations.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 1719
14.2. UN proper shipping name
Proper Shipping Name (ADR) : caustic alkali liquid, n.o.s.
Transport document description (ADR) : UN 1719 caustic alkali liquid, n.o.s. (mixture with sodiumhydroxide), 8, II, (E)
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) :8
Danger labels (ADR) :8

14.4. Packing group

Packing group (ADR) : II
14.5. Environmental hazards
Dangerous for the environment : No
Other information : No supplementary information available
14.6. Special precautions for user
Special transport precautions : Risk of ignition, May react violently with acids.
Overland transport
Hazard identification number (Kemler No.) : 80
Orange plates :

Tunnel restriction code (ADR) :E

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations

Contains no REACH substances with Annex XVII restrictions

Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
Contains no substance subject to REGULATION (EU) No 649/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 4 July 2012
concerning the export and import of hazardous chemicals.
Substance(s) are not subject to Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April 2004 on persistent organic
pollutants and amending Directive 79/117/EEC.

VOC content : 1.27 %

15.1.2. National regulations

Netherlands
SZW-lijst van kankerverwekkende stoffen : 2-(2-butoxyethoxy)ethanol is listed
SZW-lijst van mutagene stoffen : None of the components are listed

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Borstvoeding
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Vruchtbaarheid
NIET-limitatieve lijst van voor de voortplanting : None of the components are listed
giftige stoffen – Ontwikkeling
15.2. Chemical safety assessment
No data available

SECTION 16: Other information

Indication of changes:

Section Changed item Change Comments

12.3
12.6

Full text of R-, H- and EUH-statements:

Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Met. Corr. 1 Corrosive to metals, Category 1
Skin Corr. 1A Skin corrosion/irritation, Category 1A
Skin Corr. 1B Skin corrosion/irritation, Category 1B
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R22 Harmful if swallowed
R34 Causes burns
R35 Causes severe burns
R36 Irritating to eyes
R41 Risk of serious damage to eyes
C Corrosive
Xi Irritant
Xn Harmful

SDS EU (REACH Annex II)

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Oil Spill Dispersant WB
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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