STAPA® 适用于涂料的金属效果颜料

Metallic Aluminium Pigments

for Paint and Coating Industry
为亚洲及中国设计
Designed for Asia and China

HYDROMIC N 溶剂型 - 水性
Solvent borne - Water borne
目录
Contents

金属效果颜料 / Metallic Effect Pigments 4

生产工艺 / Production Process 5

色特丽® 和色特亮® 的生产 / The Production of SILTALLIC® and SILTALLUX® 6

应用推荐及图例 / Application Recommendations and Pictograms 7

产品 / Products


STAPA® SILTALLIC® SILTALLUX®
适用于溶剂型涂料的标准铝浆
Standard aluminium pigments for solvent borne paint applications 8

色特丽® 和色特亮® 一览
Overview of SILTALLIC® and SILTALLUX® 10

STAPA® HYDROMIC N
适用于水性涂料的钝化铝浆
Passivated aluminium grades for waterborne paint system 12

STAPA® SILTALLIC® SILTALLUX®
适用于溶剂型涂料的标准铝浆 - 低 PAHS 型号
Standard aluminium pigments for solvent borne paint applications - low PAHS grades 14

质量控制及检测方法 / Quality Control and Test Methods 16 – 18

筛分标准对照表 / Comparative table of sieving standards 19

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金属效果颜料 生产工艺
Metallic Effect Pigments Production Process

金属效果颜料应用于涂料当中，不但可以获得漂亮的金属外观，还可 Metallic effect pigments are used in the paints and coatings 许多情况下，金属颜料的各种特性都可由生产工艺决定。目前铜金粉 In many cases the properties of metallic effect pigments can be
以达到某些独特的功能。金属效果颜料往往呈片状，颗粒直径比一 industry for both their optical effects as well as for their 都是在球磨机中 (Hametag工艺) 干法研磨而成。而鉴于安全原因，现 deduced directly from the production process. The gold bronze
般彩色颜料的大。普通颜料的直径通常都在可见光的波长范围内，而 functionality. Effect pigments are always lamellar (flakes) and their 代的铝颜料都采用 Hall 工艺在溶剂中湿法研磨。 pigments are dry milled in ball mills (Hametag process), but for
具有特殊金属效果的片状颜料的直径一般约在 5 – 55 µm之间。 particle diameter is larger than the one of colour pigments. While safety reasons aluminium pigments are produced almost
the particle size of colour pigments is in the wavelength range of 先将原料进行熔融喷雾，得到纯度不低于 99.5% (按照EN 576标准) exclusively in a wet milling process adding white spirit
visible light, the flake d
­ iameter of effect pigments is generally 的不规则喷雾粉。然后经注入了润滑剂的球磨机研磨成片状颗粒。 (Hall process).
around 5 – 55 µm.
研磨的参数和润滑剂的种类由颜料的最终用途决定。研磨后得到的 The raw material - atomized, spattered aluminium with a minimum
颜料浆再经筛分、压滤和混合后，对应不同产品规格，得到固体分为 purity of 99.5 % according to EN 576 – is milled respectively shaped
60-70%，溶剂为 30-40% 的标准颜料浆。 to flake-like particles in ball mills, filled with grinding aids
(lubricant).

The milling parameters and the lubricant are determined by the

application for which the pigment is intended. The pigment ­slurry
is screened, pressed on filter presses and adjusted in mixers to a
ratio of 60-70% solids and 30-40% solvent depending on the spe-
cific grade.

生产流程 / Production Process

图 1 / Fig. 1

1 铝 / AL min. 99,5 % DIN 1712

2 熔融 / Melting

3 雾化 / Atomizing 1

4 筛分 / Sieving

5 球磨 / Ball mill 2 7

- 溶剂 / Mineral spirit

- 润滑剂 / Lubricant
3 5 8
6 筛分 / Sieving

7 压滤 / Filterpress

8 混合 / Mixer 4 6 9
9 STAPA® 铝浆 / Aluminium paste

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 推荐应用 / Applicatino Recommendations

色特丽和色特亮铝浆特别适用于 Siltallic and Siltallux Aluminium pastes are ideal to be used in

工业涂料 金属效果涂料 Industrial coatings Metal effect coatings

· 底涂 · Primer
· 卷钢涂料、罐听涂料 装饰涂料 · Coil coatings, Can coatings Decorative coatings
· 普通喷漆 · Aerosols
汽车涂料 · 自助装饰漆等 Automotive coatings · Diy etc.
· 汽车原厂漆 · OEM coatings
· 汽车修补漆 其它涂料 · Refinish coatings Miscellaneous coatings
· 部件漆 · 纸张涂布 · Accessories · Paper coatings
· 织物涂布 · Textile coatings
· 塑料涂料 · Plastic coatings

金属效果铝银浆
应用图例 / Application Pictograms
Aluminium pastes for metallic effects

色特丽和色特亮是全球领先的金属效果颜料生产商爱卡专门为中国 Siltallic® and Siltallux®, are brands of two new series of Aluminium 汽车原厂漆和修补漆
和亚洲市场创立的两个铝银浆品牌，产品由爱卡特殊效果颜料(珠 Pastes manufactured by ECKART, the leading international Automotive OEM, RefinishingCoatings
海)有限公司在中国生产。 ­manufacturer of metallic pigments. Produced by ECKART Zhuhai
Co., Ltd. South China, Siltallic® and Siltallux® are specifically 罐听涂料
­developed for the China and Asian markets. Can Coatings

秉承爱卡高品质铝银浆的理念并立足于中国市场的要求，色特丽和 In accordance with ECKART’s philosophy of high quality ­Aluminium 建筑、墙面和装饰涂料

色特亮采用和德国相同的设备和技术生产。它们与爱卡其它品牌的 Pastes, Siltallic and Siltallux are developed and manufactured using Architectural, Wall and Decorative Coatings
金属效果颜料一样可以广泛应用于各种涂料领域，特别推荐用于汽 the same production equipment and expertise taken from our
车涂料和工业涂料。 German operations. Siltallic and Siltallux are suitable for a large 卷钢、外墙和家具涂料
variety of coating applications, specifically in Automotive and Coil, Facades and Furniture Coatings
Industrial Coatings.
防腐、船舶和保护涂料
在提供稳定的色特丽和色特亮产品同时，我们也为客户提供创新、专 To support our product offering, ECKART provides innovative and Corrosion, Marine and Protective Coatings
业的技术服务。通过设立在珠海的技术应用实验室，我们可以和客户 professional technical services to our clients. With technical appli­
共同研发涂料新产品，提供及时、灵活、并且以市场为导向的解决方 cation laboratory established in Zhuhai, ­ECKART is suitably positi- 塑料、电子消费品和原厂轮毂涂料
案。 oned to work on joint projects together with our clients providing Plastic, Consumer Eletronic and OEM Trim Coatings
on-time, flexible, market orientated solutions.

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STAPA®

适用于溶剂型涂料的标准铝浆
Standard aluminium pigments for solvent borne paint applications

色特亮和色特丽是采用德国专业技术在中国生产的高品质铝银浆系列，它们都拥有众多的规格型号，提供各种不同的出色银色效果。
如需更多色彩信息，请参考我们另外提供的色卡。

STAPA® SILTALLUX and STAPA® SILTALLIC are the quality brands of China manufacturing site. With German manufacturing methods and
expertise we produce high quality grades with distinctive effect results over a wide silver colour range.
For more detailed colour/effect information please refer to our fan deck which we can provide additionally.

STAPA® 颜料含量 溶剂类型 粒径分布 特点 推荐应用

SILTALLIC® / Pigment content Type of solvents Particle size Comments Recommended application
SILTALLUX® distribution

检测仪器
determined with
CILAS 1064

D50 近似值
型号 / Type ± 2% approx. [µm]

极粗银元型，极强闪烁 / Very coarse Silver

SILTALLUX® 8620 70 TE/SA 54
dollar, extreme sparkling
粗银元型
SILTALLUX® 8640 70 TE/SA 36
Coarse Silver dollar
粗银元型，高不透明度
SILTALLUX® 7650 70 TE/SA 34
Coarse Silver dollar, good opacity
中粗银元型，强闪烁效果 / Medium coarse
SILTALLUX® 8755 70 TE/SA 23
Silver dollar, good sparkling, good effect
中等银元型，强效果
SILTALLUX® 8765 70 TE/SA 19
Medium Silver dollar, strong effect
中等银元型，强效果高不透明度 / Medium
SILTALLUX® 8767 70 TE/SA 19
Silver dollar,good effect, good opacity
中细银元型，强效果
SILTALLUX® 8775 70 TE/SA 16
Medium fine Silver dollar, good effect
中细亮白银元型，极高不透明度 / Medium-
SILTALLUX® 8380 65 TE/SA 15
fine whitish Silver dollar, very good opacity
细银元型，极强效果
SILTALLUX® 6880 65 TE/SA 12
Fine Silver dollar, very good effect
细银元型，高不透明度，强效果 / Fine
SILTALLUX® 8790 65 TE/SA 12
Silver dollar, good opacity, good effect

粗玉米片型
SILTALLIC® 8638 70 TE/SA 41
Coarse Cornflake
中粗玉米片型，亮白效果
SILTALLIC® 8150 65 TE/SA 23
Medium coarse Cornflake, whitish effect
中等玉米片型，高不透明度
SILTALLIC® 8160 65 TE/SA 17
Medium cornflake, good opacity
中等玉米片型，突出亮白效果 / Medium
SILTALLIC® 8040 60 TE/SA 16
Cornflake, pronounced whitish effect
中-细玉米片型，强不透明度 / Medium/
SILTALLIC® 8180 65 TE/SA 15
Fine Cornflake with good opacity
细玉米片型，优秀不透明度
SILTALLIC® 8080 60 TE/SA 12
Fine Cornflake, very good opacity

TE = Mineral Spirit / 200#溶剂汽油

SA = Solvent Naphtha / 石脑油溶剂
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STAPA®

色特丽 / 色特亮铝浆一览
Overview of Siltallic® / Siltallux® aluminium pastes

色特丽 / Siltallic® 色特亮 / Siltallux®

括号中的数字为粒径 D50 值 / Figures in the brackets are particle size D50 values

)
m
4μ
)
m
)

(5
1μ
m

)
m
6μ

(4
9μ

20
(3

(1

86
38
20

40

86
65
86

87
)

)
m

m
9μ

3μ
)
m

(1

(2
4μ
18

(3

67

55
87

87
05
76
)
m
6μ
(1
16

) 5
m 77
2μ 8
随角异色值
Flop-Index

(1
m
3μ
14

80
(2

68
)
m
50
5μ
81
(1
80
)

83
m

12
1μ

)
m
)
m

(1

7μ
5μ

90

(1
(1

87

60
)
m

80

81
2μ

81
(1

10
80

)
m
80

6μ
(1
40
80

8
115 120 125 130 135 140 145 150 155 160 165

亮度 L* 值 (15°) Lightness L* (15°)

说明

1. 以上图表同时显示了各规格颜料的粒径、亮度值和随角异色值。 Explanations
2. 铝颜料的光学特性以其对光线直接反射的随角异色效果来衡量。该种直接反射的亮度值常被称为 L* 值。
3. 通常使用 5 角度或 6 角度分光光度计来测定涂层的光反射性以及色值。 1. In above chart, 3 indicators of different pigments can be easily referred, i.e. Particle Size, Lightness and Flop.
4. 肉眼对颜色的感受很大程度上取决于反射光线和观察角度之间的夹角。 2. The reflection behaviour of Aluminium Pigments is defined by the flop effect because of directed reflection (L* values)
光源固定时，不同的物体放置位置以及不同的观察角度都会带来视觉上不一样的亮度和色泽变化。 3. Spectral photometer with 5 or 6 observation angles to determine the light reflection and the colour values of paint
5. 以上图表的测量条件为： 4. Colour perception depends on illumination/viewing geometry which leads to light-dark flop and colour flop.
· 测试涂料：丙烯酸聚酯体系、添加 CAB、低固含量、施工粘度约 20% 5. Measuring conditions of above diagram:
· 空气喷涂，未添加除铝颜料外的其它颜料，外罩清漆 · Paint system: Acrylic, PE, CAB low solid system, application viscosity approx 20%
· 使用分光光度计重点测量亮度最高的 15° 的亮度数值 · Pneumatic application as pure silver colour, with clear coat
· 分光光度计可以记录 L* 值 · Measurement with spectral photometer, emphasize on 15° (most lightest angle with highest value)
· 多数分光光度计可同时计算出随角异色值 · L* values are taken from the spectral photmeter values after measuring the effect
· Most spectral photmeters offer direct output of Flop Index

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STAPA®
HYDROMIC N

适用于水性涂料的钝化铝浆
Passivated aluminium grades for waterborne paint system

STAPA® HYDROMIC N 是爱卡向涂料行业当今以及未来越来越高的环保要求所提供的解决方案之一。它采用爱卡领先的水性铝颜料技术生

产，可有效增强铝颜料在水性体系中的发气稳定性。HYDROMIC N 所添加的溶剂通用于一般工业漆和汽车漆，且不含 APEO 或重金属，在
德国和中国都有生产。如需更多信息欢迎随时查询。

STAPA® HYDROMIC N is one of our answers to the paint industry for environmental demands of today and in future. It is one part of
ECKART's leading technology expertise on aluminium pigments for waterborne coatings. HYDROMIC N aluminium grades can reduce
gassing tendency in water borne coating to a workable limit. It is APEO free and contains no heavy metals. The used solvent is very much
universal for the paint industry such as general industry or automotive coating. HYDROMIC N is a global ECKART product manufactured in
Germany and also locally at our production site in China. For more application details and guiding formulation please contact our experts.

STAPA® 颜料含量 溶剂类型 粒径分布 颗粒形状 推荐应用

Pigment content Type of solvents Particle size Particle shape Recommended application
distribution

检测仪器
determined with
CILAS 1064

D50 近似值
型号 / Type ± 2% approx. [µm]

银元型
HYDROMIC N 8620 76 BG 54
Silver dollar
银元型
HYDROMIC N 8640 76 BG 36
Silver dollar
银元型
HYDROMIC N 8755 76 BG 23
Silver dollar
银元型
HYDROMIC N 8765 76 BG 19
Silver dollar
银元型
HYDROMIC N 8775 76 BG 16
Silver dollar
银元型
HYDROMIC N 8790 72 BG 12
Silver dollar

玉米片型
HYDROMIC N 8150 65 BG 23
Cornflake
玉米片型
HYDROMIC N 8180 65 BG 15
Cornflake

BG = 乙二醇丁醚 / Butyl glycol

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STAPA®

适用于溶剂型涂料的标准铝浆 - 低 PAHS 型号
Standard aluminium pigments for solvent borne paint applications
- low PAHS grades

爱卡的低 PAHS 颜料可满足不含芳香烃的体系要求。在该系列颜料的生产过程中，不使用任何含芳香烃的成分，所以它们能够满足如玩具

涂料等有特殊法规要求的应用场合。

ECKART low PAHS grades fullfill the requirement for aromatic free grades. During the manufacturing process all aromatic components can
be kept out in order to fulfill regulatory demands in these specific application fields. (e.g. toys coating)

STAPA® 颜料含量 溶剂类型 粒径分布 颗粒形状 推荐应用

SILTALLIC® / Pigment content Type of solvents Particle size Particle shape Recommended application
SILTALLUX® distribution

检测仪器
determined with
CILAS 1064

D50 近似值
型号 / Type ± 2% approx. [µm]

银元型
SILTALLUX® 8641 73 TE 36
Silver dollar
银元型
SILTALLUX® 8766 73 TE 20
Silver dollar
银元型
SILTALLUX® 8776 73 TE 16
Silver dollar
银元型
SILTALLUX® 8791 65 TE 12
Silver dollar

玉米片型
SILTALLIC® 8151 65 TE 23
Cornflake
玉米片型
SILTALLIC® 8181 65 TE 15
Cornflake

TE = Mineral Spirit / 200#溶剂汽油

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质量控制及检验方法
Quality Control and Testing Methods

比色 Colourimetry 质量控制 Quality Control

金属涂料的视觉效果很大程度上取决于于观察角度和光线条件。条 The visual appearance of metallic coatings strongly depends on the 对金属效果颜料的质量控制，除了要针对其产品技术数据表列举的 The quality control of metallic effect pigments comprises tests of
件发生变化，视觉效果也随之变化。可以使用多角度分光测光仪 viewing angle and the light conditions. A spectrophotometer for 各项参数数据外，还应针对其光学特性。对颜料本身和对颜料应用 optical properties – additionally to the quality criteria mentioned in
(BYK-Gardner BYK-mac) 通过比色来测量金属涂料的效果。对效果 metallic colours (e.g. BYK-Gardner BYK-mac) helps to 效果的检测要区分开来。 the technical data sheets. A distinction is drawn between the tests
的 评 价 需 要 同 时 考 虑 不 同 方 面 的 测 量 结 果 ，包 括 白 度 colourimetrically measure a metallic coating. The characterisation of the pigment and on the application.
L* 值 vs 色强度值 (Chroma C*) 以及红绿轴值 a* vs 黄蓝轴值 b*。 requires a simultaneous consideration of different measurements, 对颜料的检测：
测量通常会通过三个角度进行：25°、45° 和 75°。结果以色彩模型系 such as brightness L* vs. colour strength (chroma C*), red green · 依据 DIN 53196 和 ASTM 11 进行筛析 Tests of the pigment:
统如 CIEL*a*b* 或 L*C*h° 来表示。 value a* vs. yellow blue value b*. For standard products the angles · 依据 ISO 13320-1 进行粒径分布的激光测量 · Screen analysis (near-mesh sieving) according to DIN 53196
of 25°, 45° and 75° are measured. Subsequently, the results are · 依据 DIN 55923 测量挥发份和非挥发份含量 respectively ASTM 11
presented in a colourimetric system, such as CIEL*a*b* or L*C*h°. · Particle size distribution by laser granulometry according to
对颜料应用效果的检测： ISO 13320-1
· 金属效果 (随角异色性) · Volatile and non-volatile content on the basis of DIN 55923
· 白度
· 鲜映度 (DOI) Tests on the application:
· 色饱和度 · Metallic effect (flop)
· 着色力 · Brightness
· 遮盖力 · Distinctiveness of image (DOI)
· 光亮度 · Colour saturation
质量标准的保证 Guarantee of Quality Standard · 闪烁度 · Tinting strength
为了确保品质，不同规格各个批次的爱卡产品都要经过严格的检查， The quality control of the batches is done by means of differential · Hiding power
确保其符合各方面的对应质量标准。所有产品的所有批次都要同时 measurement against the defined corresponding standard. It is a 另外，对应水性铝浆还采用内部标准程序测试其发气稳定性。 · Measuring of gloss
符合应用和环保的要求，各产品本身的一致性都要最大化。 precondition that the samples are simultaneously applied in the · Measuring of effect (sparkle)
same coating system and under constant environmental
基于高度的技术能力和丰富的经验，爱卡依据颜料有效期来设立和 parameters. In doing so, processing related variations of the Aluminium pigment pastes for water-based coating systems are
持续调整每个产品及其不同批号的效果标准。由此，爱卡可以赋予 sample application are minimized. additionally tested on gassing stability according to internal stand-
各产品高度的质量稳定性。 ardized testing procedure.
With a very high degree of experience and competence ECKART
will set and revise standards of each effect (according to the shelf
life cycle) of a batch/quality. With this ECKART maintains constant
quality of a each product continuously.

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 筛网标准对照表
粒径分布的激光测定
Comparative table of sieving standards
Determination of the Particle Size Distribution by
Laser Granulometer 筛网孔径 µm = w/Mesh aperture in µm = w

德国 / 美国/ 英国/ 法国 / 荷兰 /
Germany USA Great Britain France Netherlands

DIN 4188 ASTM ASTM BS 410 AFNOR NENORM ISO

E 11 E 11 X11-501 R-565
粒径分布 PSD (典型值) 的测定方法根据 ISO 13320-1 标准，采用 The measuring of the particle size distribution PSD (typical value) Tyler
激光粒度测定仪测定。 follows the method of the laser granulometry according to mesh mesh
ISO 13320-1. w w no inch w mesh w w w
测定结果很大程度上取决于颜料分散的状况。因此，使用高相容的
36 – – – – – – 38 –
溶剂并让颜料恰当分散十分关键。为保证分散效果，应密切关注输 The measurement is highly dependent on the accuracy of the dis-
– 38 400 400 38 400 – – –
入的超声波能量以及颜料和溶剂的比例。如果输入不适当的超声波 persion of pigment. The usage of a high compatible solvent to 40 – – – – – 40 45 –
能量，颜料可能会因剪切过高而破碎，也可能会因剪切过低而结聚， disperse and to maintain dispersibility is essential. To achieve good 45 45 325 325 45 350 – – 45
最终造成粒径分布得不到准确测定。 dispersion the energy input and pigment/solvent ration is of high 50 – – – – – 50 53 –
significance. Inappropriate energy intake can either damage pig- – 53 270 – 53 300 – – –
爱卡所使用的详细检验方法 (测试指南) 可来函索取。 ment (too high shearing) or keep flocculates (too low shearing) and 56 – – – – – – 63 –
eventually misleads the result of PSD. 63 63 230 250 63 240 63 – 63
71 – – – – – – 75 –
– 75 200 200 75 200 – – –
A detailed description of the testing method (test instruction) of
80 – – – – – 80 – –
ECKART can be obtained upon request.
90 90 170 170 90 170 – 90 90
100 – – – – – 100 – –
112 106 140 150 106 150 – 106 –
125 125 120 120 125 120 125 125 125
140 – – – – – – – –
– 150 100 100 150 100 – 150 –
160 – – – – – 160 – –
180 180 80 80 180 85 – 180 180
200 – – – – – 200 – –
224 212 70 70 212 72 – 212 –
250 250 60 60 250 60 250 250 250
280 – – – – – – – –
– 300 50 48 300 52 – 300 –
315 – – – – – 315 – –
355 355 45 42 355 44 – 355 355
400 – – – – – 400 – –
450 425 40 35 425 36 – 425 –
500 500 35 32 500 30 500 500 500
560 – – – – – – – –
– 600 30 28 600 25 – 600 –
630 – – – – – 630 – –
710 710 25 24 710 22 – 710 710
800 – – – – – 800 – –
– 850 20 20 850 18 – 850 –
900 – – – – – – – –
1000 1000 18 16 1000 16 1000 1000 1000
– 1180 16 14 – – – – –
– – – – – – – 1200 –
– – – – – – 1250 – –
1400 1400 14 12 1400 12 – 1400 1400
– – – – – – 1600 – –
– 1700 12 10 1700 10 – – –
2000 2000 10 9 2000 8 – – 2000

18 ECKART 19
ECKART
ECKART GmbH 谨致友好问候
Guentersthal 4 With compliments
91235 Hartenstein, Germany
Tel.: +49 9152 77-0
Fax: +49 9152 77-7008
E-Mail: [email protected]
www.eckart.net

爱卡(亚洲)有限公司 台湾/Taiwan
香港湾仔皇后大道东248号3706-08室 电话/Tel.: + (886 3) 357 0838
ECKART Asia Ltd. 传真/Fax: + (886 3) 357 0702
Unit 3706-08
248 Queen's Road East 越南/Vietnam – Ho Chi Minh City
Wanchai, Hong Kong 电话/Tel.: + (84 28) 3824 3371
电话/Tel.: +852 3102 7200 传真/Fax: + (84 28) 3824 4918
传真/Fax: +852 2882 5366
E-Mail: [email protected]
爱卡特殊效果颜料(珠海)有限公司
上海/Shanghai 中国广东省珠海市
电话/Tel.: + (86 21) 5385 5300 高栏港经济区精细化工区
传真/Fax: + (86 21) 5306 5220 ECKART Zhuhai Co. Ltd.
Fine Chemical Area
广州/Guangzhou Gaolan Port Economic Zone
电话/Tel.: + (86 20) 8387 8860 Zhuhai, P.R.China
传真/Fax: + (86 20) 8384 7584 邮政编码/Postal Code : 519050

1/October 2017.5 CO PRC

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