Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758

SAFETY DATA SHEET

Intergard 475HS Part B

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : Intergard 475HS Part B
SDS code : EVA056

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Professional use
Industrial use

Uses advised against

All other uses

Product use : Two component coating for interior and exterior use.

1.3 Details of the supplier of the safety data sheet

International Färg AB International Paint Ltd.
Holmedalen 3 Stoneygate Lane
Aspereds Industriomrade Felling
SE-424 22 Angered Gateshead
Sweden Tyne and Wear
Tel: +46 (0) 31 928500 NE10 0JY UK
Fax: +46 (0) 31 928530 Tel: +44 (0)191 469 6111
Fax: +44 (0)191 438 3711
e-mail address of person : [email protected]
responsible for this SDS

1.4 Emergency telephone number

National advisory body/Poison Center
Telephone number : +44 (0)344 892 0111
Supplier
Telephone number : Tel: +46 (0) 31 928500
Hours of operation : 24 hours

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Dam. 1, H318
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.

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Intergard 475HS Part B

SECTION 2: Hazards identification

See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Flammable liquid and vapor.
Causes skin irritation.
Causes serious eye damage.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Wash
hands thoroughly after handling.
Response : Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with
plenty of water. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately
call a POISON CENTER or doctor.
Storage : Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Hazardous ingredients : butan-1-ol
2,4,6-tris(dimethylaminomethyl)phenol
ethylenediamine
Supplemental label : Contains ethylenediamine. May produce an allergic reaction.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : May cause endocrine disruption.
not result in classification

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Intergard 475HS Part B

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture
Specific Conc.
Product/ingredient name Identifiers % Classification Type
Limits, M-factors
and ATEs
Reaction mass of REACH #: <10 Flam. Liq. 3, H226 ATE [Dermal] = [1] [2]
ethylbenzene and xylene 01-2119488216-32 Acute Tox. 4, H312 1100 mg/kg
EC: 905-588-0 Acute Tox. 4, H332 ATE [Inhalation
Skin Irrit. 2, H315 (gases)] = 5000
Eye Irrit. 2, H319 ppm
STOT SE 3, H335
STOT RE 2, H373
Asp. Tox. 1, H304
Aquatic Chronic 3,
H412

butan-1-ol REACH #: ≤3 Flam. Liq. 3, H226 ATE [Oral] = 500 [1]

01-2119484630-38 Acute Tox. 4, H302 mg/kg
EC: 200-751-6 Skin Irrit. 2, H315
CAS: 71-36-3 Eye Dam. 1, H318
Index: 603-004-00-6 STOT SE 3, H335
STOT SE 3, H336

2,4,6-tris REACH #: ≤3 Acute Tox. 4, H302 ATE [Oral] = 500 [1]

(dimethylaminomethyl) 01-2119560597-27 Skin Corr. 1C, H314 mg/kg
phenol EC: 202-013-9 Eye Dam. 1, H318
CAS: 90-72-2

ethylenediamine REACH #: <1 Flam. Liq. 3, H226 ATE [Oral] = 500 [1] [3]
01-2119480383-37 Acute Tox. 4, H302 mg/kg
EC: 203-468-6 Acute Tox. 3, H311 ATE [Dermal] =
CAS: 107-15-3 Acute Tox. 4, H332 300 mg/kg
Skin Corr. 1B, H314 ATE [Inhalation
Eye Dam. 1, H318 (vapours)] = 11 mg/
Resp. Sens. 1, H334 l
Skin Sens. 1, H317
Aquatic Chronic 3,
H412
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance of equivalent concern
Occupational exposure limits, if available, are listed in Section 8.

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Intergard 475HS Part B

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses if easy to do. Continue to rinse for at
least 10 minutes. Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated
promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly
before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains ethylenediamine. May produce an allergic reaction.

Over-exposure signs/symptoms

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Intergard 475HS Part B

SECTION 4: First aid measures

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate.
Put on appropriate personal protective equipment.

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Intergard 475HS Part B

SECTION 6: Accidental release measures

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
precautions drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations. Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance.
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only
with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.
Seveso Directive - Reporting thresholds
Danger criteria

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Intergard 475HS Part B

SECTION 7: Handling and storage

Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
Reaction mass of ethylbenzene and xylene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 441 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
butan-1-ol EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 154 mg/m³ 15 minutes.
STEL: 50 ppm 15 minutes.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
Reaction mass of ethylbenzene and DNEL Long term Oral 1.6 mg/kg General Systemic
xylene bw/day population
DNEL Long term 14.8 mg/m³ General Systemic
Inhalation population
DNEL Long term 77 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 108 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 180 mg/kg Workers Systemic
bw/day
DNEL Short term 289 mg/m³ Workers Local
Inhalation

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SECTION 8: Exposure controls/personal protection

DNEL Short term 289 mg/m³ Workers Systemic
Inhalation
butan-1-ol DNEL Long term Oral 1.5625 mg/General Systemic
kg bw/day population
DNEL Long term Dermal 3.125 mg/ General Systemic
kg bw/day population
DNEL Long term 55.357 mg/General Systemic
Inhalation m³ population
DNEL Long term 155 mg/m³ General Local
Inhalation population
DNEL Long term 310 mg/m³ Workers Local
Inhalation
2,4,6-tris(dimethylaminomethyl) DNEL Long term Oral 0.075 mg/ General Systemic
phenol kg bw/day population
DNEL Short term Dermal 0.075 mg/ General Systemic
kg bw/day population
DNEL Long term Dermal 0.075 mg/ General Systemic
kg bw/day population
DNEL Short term 0.13 mg/m³ General Systemic
Inhalation population
DNEL Long term 0.13 mg/m³ General Systemic
Inhalation population
DNEL Long term Dermal 0.15 mg/ Workers Systemic
kg bw/day
DNEL Long term 0.53 mg/m³ Workers Systemic
Inhalation
DNEL Short term Dermal 0.6 mg/kg Workers Systemic
bw/day
DNEL Short term 2.1 mg/m³ Workers Systemic
Inhalation
ethylenediamine DNEL Long term 25 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 3.6 mg/kg Workers Systemic
bw/day
DNEL Long term 12.5 mg/m³ General Systemic
Inhalation population
[Consumers]
DNEL Long term Oral 0.275 mg/ General Systemic
kg bw/day population
[Consumers]
DNEL Long term Oral 0.275 mg/ General Systemic
kg bw/day population
DNEL Long term Dermal 3.6 mg/kg Workers Systemic
bw/day
DNEL Long term 12.5 mg/m³ General Systemic
Inhalation population
DNEL Long term 25 mg/m³ Workers Systemic
Inhalation
PNECs
Product/ingredient name Compartment Detail Value Method Detail
ethylenediamine Fresh water 0.016 mg/l Assessment Factors
Marine water 0.002 mg/l Assessment Factors
Sewage Treatment 0.5 mg/l Assessment Factors
Plant
Fresh water sediment 7.68 mg/kg dwt Equilibrium Partitioning
Marine water sediment 0.768 mg/kg dwt Equilibrium Partitioning
Soil 4.36 mg/kg dwt Equilibrium Partitioning
Secondary Poisoning 4.9 mg/kg Assessment Factors

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SECTION 8: Exposure controls/personal protection

8.2 Exposure controls

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
When prolonged or frequently repeated contact may occur, a glove with a
protection class of 6 (breakthrough time >480 minutes according to EN374) is
recommended. Recommended gloves: Viton ® or Nitrile, thickness ≥ 0.38 mm.
When only brief contact is expected, a glove with protection class of 2 or higher
(breakthrough time >30 minutes according to EN374) is recommended.
Recommended gloves: Nitrile, thickness ≥ 0.12 mm.
Gloves should be replaced regularly and if there is any sign of damage to the glove
material.

The performance or effectiveness of the glove may be reduced by physical/

chemical damage and poor maintenance.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves. Refer to
European Standard EN 1149 for further information on material and design
requirements and test methods.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

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SECTION 8: Exposure controls/personal protection

Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Color : White.
Odor : Amine-like.
Odor threshold : Not available.
Melting point/freezing point : Not available.
Boiling point, initial boiling : 139°C (282.2°F)
point, and boiling range
Flammability : Not available.
Lower and upper explosion : Greatest known range: Lower: 1.4% Upper: 11.3% (butan-1-ol)
limit
Flash point : Closed cup: 31°C (87.8°F) [Pensky-Martens]
Auto-ignition temperature :
Ingredient name °C °F Method
butan-1-ol 355 671 EU A.15

2,4,6-tris(dimethylaminomethyl)phenol 382 719.6 EU A.15

ethylenediamine 405 761 DIN 51794

Decomposition temperature : Not available.

pH : Not applicable. [DIN EN 1262]
Viscosity : Kinematic (room temperature): 63 mm2/s [DIN EN ISO 3219]
Kinematic (40°C): 110 mm2/s [DIN EN ISO 3219]
Solubility(ies) :
Media Result
cold water Not soluble [OESO (TG 105)]

Partition coefficient: n-octanol/ : Not applicable.

water
Vapor pressure :
Vapor Pressure at 20˚C Vapor pressure at 50˚C
Ingredient name mm Hg kPa Method mm Hg kPa Method
ethylenediamine 10.5 1.4

butan-1-ol <7.5 <1 DIN EN 13016-2

Reaction mass of ethylbenzene 6.7 0.89

and xylene

Density : 1.734 g/cm³ [DIN EN ISO 2811-1]

Vapor density : Not available.
Particle characteristics
Median particle size : Not applicable.

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SECTION 9: Physical and chemical properties

Percentage of particles with : 0
aerodynamic diameter ≤ 10
μm

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

10.5 Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapor concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains ethylenediamine. May produce an allergic reaction.

Acute toxicity
Conclusion/Summary : Not available.
Acute toxicity estimates
N/A
Irritation/Corrosion
Conclusion/Summary : Not available.
Sensitization
Conclusion/Summary : Not available.
Mutagenicity
Conclusion/Summary : Not available.
Carcinogenicity
Date of issue/Date of revision : 29-9-2021 Version : 1.01
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Intergard 475HS Part B

SECTION 11: Toxicological information

Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
Teratogenicity
Conclusion/Summary : Not available.
Specific target organ toxicity (single exposure)
Not available.

Specific target organ toxicity (repeated exposure)

Not available.
Aspiration hazard
Product/ingredient name Result
Reaction mass of ethylbenzene and xylene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
Conclusion/Summary : Not available.
General : No known significant effects or critical hazards.

Date of issue/Date of revision : 29-9-2021 Version : 1.01

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Intergard 475HS Part B

SECTION 11: Toxicological information

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

11.2 Information on other hazards

11.2.1 Endocrine disrupting properties
Not available.
11.2.2 Other information
No additional information.

SECTION 12: Ecological information

12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
not classified as hazardous to the environment, but contains substance(s) hazardous to the environment. See section
3 for details.
Conclusion/Summary : Not available.

12.2 Persistence and degradability

Conclusion/Summary : Not available.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
Reaction mass of 3.12 8.1 to 25.9 low
ethylbenzene and xylene
butan-1-ol 1 - low
2,4,6-tris 0.219 - low
(dimethylaminomethyl)
phenol
ethylenediamine -7.02 - low

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

Not available.

12.7 Other adverse effects

No known significant effects or critical hazards.

Date of issue/Date of revision : 29-9-2021 Version : 1.01

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SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no
longer apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
European waste catalogue (EWC)
The European Waste Catalogue classification of this product, when disposed of as waste, is:
Waste code Waste designation
EWC 08 01 11* waste paint and varnish containing organic solvents or other hazardous substances
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from
the relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or
national legal provisions.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapor from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID IMDG IATA
14.1 UN number UN1263 UN1263 UN1263
or ID number
14.2 UN proper PAINT PAINT PAINT
shipping name
14.3 Transport 3 3 3
hazard class(es)

14.4 Packing III III III

group

Date of issue/Date of revision : 29-9-2021 Version : 1.01

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SECTION 14: Transport information

14.5 No. No. No.
Environmental
hazards
Additional information
ADR/RID : Tunnel code (D/E)
IMDG : Emergency schedules F-E, _S-E_
IMDG Code Segregation group SGG18 - Alkalis

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not applicable.

according to IMO
instruments

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB) /REACH
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
Intrinsic property Ingredient name Status Reference Date of
number revision
Substance of ethylenediamine Candidate ED/61/2018 6/27/2018
equivalent concern for
human health
Endocrine disrupting ethylenediamine Candidate ED/61/2018 6/27/2018
properties for human
health
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
VOC : The provisions of Directive 2004/42/EC on VOC apply to this product. Refer to the
product label and/or technical data sheet for further information.
VOC for Ready-for-Use : Not available.
Mixture
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Air
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Water
Ozone depleting substances (1005/2009/EU)

Date of issue/Date of revision : 29-9-2021 Version : 1.01

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SECTION 15: Regulatory information

Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Persistent Organic Pollutants
Not listed.
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c

National regulations
Biocidal products regulation
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.

15.2 Chemical Safety : No Chemical Safety Assessment has been carried out.
Assessment

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Irrit. 2, H315 Calculation method
Eye Dam. 1, H318 Calculation method

Date of issue/Date of revision : 29-9-2021 Version : 1.01

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SECTION 16: Other information

Full text of abbreviated H statements
H226 Flammable liquid and vapor.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if
inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H373 May cause damage to organs through prolonged or repeated
exposure.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 3 ACUTE TOXICITY - Category 3
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 3 AQUATIC HAZARD (LONG-TERM) - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Carc. 1B CARCINOGENICITY - Category 1B
Eye Dam. 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Muta. 2 GERM CELL MUTAGENICITY - Category 2
Resp. Sens. 1 RESPIRATORY SENSITIZATION - Category 1
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED
EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) -
Category 3
Date of printing : 18-12-2023
Date of issue/ Date of : 29-9-2021
revision
Date of previous issue : 29-9-2021
Version : 1.01
Unique ID : 0E4D234B630B1EDEA7B2C69F465E46CC
Notice to reader
FOR PROFESSIONAL USE ONLY
IMPORTANT NOTE The information in this data sheet is not intended to be exhaustive and is based on the present
state of our knowledge and on current laws: any person using the product for any purpose other than that specifically
recommended in the technical data sheet without first obtaining written confirmation from us as to the suitability of the
product for the intended purpose does so at his own risk. It is always the responsibility of the user to take all necessary
steps to fulfill the demands set out in the local rules and legislation. Always read the Material Data Sheet and the
Technical Data Sheet for this product if available. All advice we give or any statement made about the product by us
(whether in this data sheet or otherwise) is correct to the best of our knowledge but we have no control over the quality
Date of issue/Date of revision : 29-9-2021 Version : 1.01
Date of previous issue : 29-9-2021 17/18
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SECTION 16: Other information

or the condition of the substrate or the many factors affecting the use and application of the product. Therefore, unless
we specifically agree in writing otherwise, we do not accept any liability whatsoever for the performance of the product
or for any loss or damage arising out of the use of the product. All products supplied and technical advice given are
subject to our standard terms and conditions of sale. You should request a copy of this document and review it
carefully. The information contained in this data sheet is subject to modification from time to time in the light of
experience and our policy of continuous development. It is the user's responsibility to verify that this data sheet is
current prior to using the product.

Brand names mentioned in this data sheet are trademarks of or are licensed to Akzo Nobel.

Date of issue/Date of revision : 29-9-2021 Version : 1.01

Date of previous issue : 29-9-2021 18/18