Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

SAFETY DATA SHEET

Coal Tar
According to Regulation (EC) No 1907/2006, Annex II, as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Coal Tar

Chemical name TAR, COAL, HIGH-TEMP.

Internal identification 00228270

Synonyms; trade names Crude Coal Tar

REACH registration number 01-2119511615-46

CAS number 65996-89-6

EU index number 648-082-00-2

EC number 266-024-0

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Raw material for production of several products through distillation. This substance is handled
under strictly controlled conditions in accordance with REACH regulation Article 18(4) for
transported isolated intermediates.

Uses advised against Restricted to professional users.

1.3. Details of the supplier of the safety data sheet

Supplier

1.4. Emergency telephone number

Emergency telephone NCEC +44 1865 407333

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Sens. 1 - H317 Muta. 1B - H340 Carc. 1A - H350 Repr. 1B - H360

Environmental hazards Aquatic Chronic 2 - H411

Classification Notes This is a UVCB substance of variable composition. Classification is based on information from
the REACH dossier and not the conventional method based on the classification of the
individual components.

1/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

2.2. Label elements

EC number 266-024-0

Pictogram

Signal word Danger

Hazard statements H317 May cause an allergic skin reaction.

H340 May cause genetic defects.
H350 May cause cancer.
H360 May damage fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P201 Obtain special instructions before use.

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

Supplemental label RCH002a Restricted to professional users.

information

Contains TAR, COAL, HIGH-TEMP.

Supplementary precautionary P202 Do not handle until all safety precautions have been read and understood.
statements P261 Avoid breathing vapours.
P272 Contaminated work clothing should not be allowed out of the workplace.
P302+P352 IF ON SKIN: Wash with plenty of water.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.

2.3. Other hazards

This substance is not classified as PBT or vPvB according to current EU criteria. May cause photosensitivity.

SECTION 3: Composition/information on ingredients

3.1. Substances

TAR, COAL, HIGH-TEMP. 100%

CAS number: 65996-89-6 EC number: 266-024-0 REACH registration number: 01-
2119511615-46
This is a UVCB substance of variable composition.

Classification
Skin Sens. 1 - H317
Muta. 1B - H340
Carc. 1A - H350
Repr. 1B - H360
Aquatic Chronic 2 - H411

2/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

NAPHTHALENE < 25%

CAS number: 91-20-3 EC number: 202-049-5
M factor (Acute) = 1 M factor (Chronic) = 1
This is a constituent contained in a UVCB substance.

Classification
Flam. Sol. 2 - H228
Acute Tox. 4 - H302
Carc. 2 - H351
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

BENZENE < 2%
CAS number: 71-43-2 EC number: 200-753-7
This is a constituent contained in a UVCB substance.

Classification
Flam. Liq. 2 - H225
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Muta. 1B - H340
Carc. 1A - H350
STOT RE 1 - H372
Asp. Tox. 1 - H304

ANTHRACENE < 2.5%

CAS number: 120-12-7 EC number: 204-371-1
M factor (Acute) = 100 M factor (Chronic) = 100
This is a constituent contained in a UVCB substance.

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
STOT SE 3 - H335
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

3/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

BENZO[A]PYRENE < 2%
CAS number: 50-32-8 EC number: 200-028-5
M factor (Acute) = 1 M factor (Chronic) = 1
This is a constituent contained in a UVCB substance.

Classification
Skin Sens. 1 - H317
Muta. 1B - H340
Carc. 1B - H350
Repr. 1B - H360FD
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

The full text for all hazard statements is displayed in Section 16.
Product name Coal Tar

Chemical name TAR, COAL, HIGH-TEMP.

REACH registration number 01-2119511615-46

EU index number 648-082-00-2

CAS number 65996-89-6

EC number 266-024-0

Ingredient notes Constituents listed in this section are relevant to PBT classification and substance
classification.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Immediate first aid is imperative. Move affected person to fresh air and keep warm and at rest
in a position comfortable for breathing. Show this Safety Data Sheet to the medical personnel.

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Loosen tight clothing such as collar, tie or belt. Get medical attention if symptoms
are severe or persist.

Ingestion Never give anything by mouth to an unconscious person. Rinse mouth thoroughly with water.
Do not induce vomiting unless under the direction of medical personnel. Get medical
attention.

Skin contact It is important to remove the substance from the skin immediately. In the event of any
sensitisation symptoms developing, ensure further exposure is avoided. Remove
contamination with soap and water or recognised skin cleansing agent. Get medical attention
if symptoms are severe or persist after washing.

Eye contact Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention.

Protection of first aiders First aid personnel should wear appropriate protective equipment during any rescue.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

Inhalation Vapour may irritate respiratory system/lungs.

4/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Ingestion May cause irritation. May cause stomach pain or vomiting.

Skin contact Prolonged contact may cause redness, irritation and dry skin. May cause skin sensitisation or
allergic reactions in sensitive individuals.

Eye contact No specific symptoms known. May irritate eyes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

Specific treatments No specific chemical antidote is known to be required after exposure to this product. Persons
suffering from asthma, eczema or skin problems should avoid contact, including dermal
contact, with this product.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Foam, carbon dioxide or dry powder. Dry chemicals,
sand, dolomite etc. Water spray, fog or mist.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Toxic gases or vapours.

5.3. Advice for firefighters

Protective actions during Avoid breathing fire gases or vapours. Evacuate area. Keep upwind to avoid inhalation of
firefighting gases, vapours, fumes and smoke. Ventilate closed spaces before entering them. Cool
containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk. Cool containers exposed to flames with water until well after the fire is out.
If a leak or spill has not ignited, use water spray to disperse vapours and protect men stopping
the leak. Control run-off water by containing and keeping it out of sewers and watercourses. If
risk of water pollution occurs, notify appropriate authorities.

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing. Firefighter's clothing conforming to European standard EN469 (including helmets,
protective boots and gloves) will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No action shall be
taken without appropriate training or involving any personal risk. Avoid inhalation of vapours
and contact with skin and eyes. Provide adequate ventilation.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. Avoid discharge to the
aquatic environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if safe to do so. Do not touch or walk into spilled material. Absorb in vermiculite, dry
sand or earth and place into containers. Containers with collected spillage must be properly
labelled with correct contents and hazard symbol.

6.4. Reference to other sections

5/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Wear protective clothing as described in
Section 8 of this safety data sheet. Do not eat, drink or smoke when using this product. Avoid
spilling. Avoid contact with skin and eyes. Avoid inhalation of vapours. Wear protective skin
cream on exposed skin before and during work shift. To reduce sun sensitivity a sun-blocking
lotion (SPF 15+) can also be applied prior to application of a protective cream. Good personal
hygiene procedures should be implemented. Wash hands and any other contaminated areas
of the body with soap and water before leaving the work site. Pregnant or breastfeeding
women should not work with this product if there is any risk of exposure.

Advice on general Wash promptly if skin becomes contaminated. Take off contaminated clothing and wash it
occupational hygiene before reuse.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep only in the original container. Keep container tightly closed, in a cool, well ventilated
place. Keep away from heat, sparks and open flame. Store away from the following materials:
Oxidising agents.

Storage class Miscellaneous hazardous material storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
BENZENE
Long-term exposure limit (8-hour TWA): WEL 1 ppm 3.25 mg/m³
Carc, Sk
WEL = Workplace Exposure Limit
Carc = Capable of causing cancer and/or heritable genetic damage.
Sk = Can be absorbed through the skin.

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation. Ensure the ventilation system is
controls regularly maintained and tested. Good general ventilation should be adequate to control
worker exposure to airborne contaminants. Observe any occupational exposure limits for the
product or ingredients. All handling should only take place in well-ventilated areas.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield. Eyewear complying with an
approved standard should be worn if a risk assessment indicates eye contact is possible.
Personal protective equipment for eye and face protection should comply with European
Standard EN166.

6/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Hand protection Wear protective gloves. The most suitable glove should be chosen in consultation with the
glove supplier/manufacturer, who can provide information about the breakthrough time of the
glove material. For exposure up to 4 hours, wear gloves made of the following material: Nitrile
rubber. To protect hands from chemicals, gloves should comply with European Standard
EN374. Considering the data specified by the glove manufacturer, check during use that the
gloves are retaining their protective properties and change them as soon as any deterioration
is detected. The breakthrough time for any glove material may be different for different glove
manufacturers. Frequent changes are recommended.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact. Refer to European
protection Standard EN 1149 for information on material and design requirements and test methods.

Hygiene measures Provide eyewash station. Promptly remove any clothing that becomes wet or contaminated.
Wash promptly with soap and water if skin becomes contaminated. Contaminated clothing
should be placed in a closed container for disposal or decontamination. Warn cleaning
personnel of any hazardous properties of the product. Wash hands and any other
contaminated areas of the body with soap and water before leaving the work site. When using
do not eat, drink or smoke.

Respiratory protection Wear a respirator fitted with the following cartridge: Combination filter, type A2/P3. Ensure all
respiratory protective equipment is suitable for its intended use and is ‘CE’-marked. Check
that the respirator fits tightly and the filter is changed regularly. Gas and combination filter
cartridges should comply with European Standard EN14387. Full face mask respirators with
replaceable filter cartridges should comply with European Standard EN136. Half mask and
quarter mask respirators with replaceable filter cartridges should comply with European
Standard EN140.

Thermal hazards Contact with hot product can cause serious thermal burns. If there is a risk of contact with hot
product, all protective equipment worn should be suitable for use with high temperatures. To
protect hands from high temperatures, gloves should comply with European Standard EN407.

Environmental exposure Keep container tightly sealed when not in use. Emissions from ventilation or work process
controls equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to
the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Brown. Black.

Odour Coal tar.

Odour threshold No information available.

pH No information available.

Melting point -9°C

Initial boiling point and range 80 - 350°C @ 1013 hPa

Flash point > 61°C Closed cup.

Evaporation rate No information available.

Flammability (solid, gas) No information available.

Upper/lower flammability or Lower flammable/explosive limit: 1 g/100 g Upper flammable/explosive limit: 6 g/100 g
explosive limits

7/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Vapour pressure 1.091 kPa @ 20°C The vapour pressure is estimated from the vapour pressure curve at high
temperature.

Vapour density No information available.

Relative density 1.10 - 1.30 @ 20°C

Solubility(ies) Miscible with water. 0.0135 g/100 g water @ 20°C

Partition coefficient No information available.

Auto-ignition temperature > 560°C

Decomposition Temperature > 400°C

Viscosity 1.33 cSt @ 20°C

Explosive properties Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No information required.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended. Stable under the
prescribed storage conditions.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition.

10.5. Incompatible materials

Materials to avoid Strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Heating may generate the following products: Toxic gases or vapours. Oxides of carbon.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) LD₅₀ : > 2000 mg/kg, Rat, Based on available data the classification criteria are not met.

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation

8/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Animal data Based on available data the classification criteria are not met.

Human skin model test Erythema/eschar score: Very slight erythema - barely perceptible (1). Irritating. Occupational
experience. Irritation in the presence of UV light.

Serious eye damage/irritation

Serious eye damage/irritation Based on available data the classification criteria are not met.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Local Lymph Node Assay (LLNA) - Mouse: Sensitising. Skin Sens. 1 - H317 May cause an
allergic skin reaction.

Germ cell mutagenicity

Genotoxicity - in vitro Bacterial reverse mutation test: Positive. Muta. 1B - H340 May cause genetic defects.

Carcinogenicity
Carcinogenicity NOAEL ~ 36 mg/kg/day, Oral, Mouse LOAEC ~ 120 mg/kg/day, Oral, Mouse Read-across
data. Carc. 1A - H350 May cause cancer.

Reproductive toxicity
Reproductive toxicity - fertility Repr. 1B - H360 May damage fertility.

Reproductive toxicity - Repr. 1B - H360 May damage the unborn child.

development

Specific target organ toxicity - single exposure

STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

SECTION 12: Ecological Information

12.1. Toxicity
Toxicity Aquatic Chronic 2 - H411 Toxic to aquatic life with long lasting effects.

Acute aquatic toxicity

Acute toxicity - fish LL₅₀, 96 hours: > 250 mg/l, Brachydanio rerio (Zebra Fish)
NOELR, 96 hours: 25 mg/l, Brachydanio rerio (Zebra Fish)
LOELR, 96 hours: 50 mg/l, Brachydanio rerio (Zebra Fish)

Acute toxicity - aquatic EL₅₀, 48 hours: 72 mg/l, Daphnia magna

invertebrates EL₁₀₀, 48 hours: 250 mg/l, Daphnia magna
NOELR, 48 hours: 25 mg/l, Daphnia magna
LOELR, 48 hours: 50 mg/l, Daphnia magna

Acute toxicity - aquatic plants NOELR, 72 hours: 5 mg/l, Desmodesmus subspicatus

LOELR, 72 hours: 25 mg/l, Desmodesmus subspicatus
EL₅₀, 72 hours: 36 mg/l, Desmodesmus subspicatus
EL₁₀₀, 72 hours: ~ 50 mg/l, Desmodesmus subspicatus

12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product.

9/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Phototransformation Highly insoluble in water.

Biodegradation Scientifically unjustified.

12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.

Partition coefficient No information available.

12.4. Mobility in soil

Mobility The product has poor water-solubility.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information The generation of waste should be minimised or avoided wherever possible. Reuse or recycle
products wherever possible. Residues and empty containers should be taken care of as
hazardous waste according to local and national provisions. When handling waste, the safety
precautions applying to handling of the product should be considered. Care should be taken
when handling emptied containers that have not been thoroughly cleaned or rinsed out.
Empty containers or liners may retain some product residues and hence be potentially
hazardous.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Waste, residues, empty containers, discarded work clothes
and contaminated cleaning materials should be collected in designated containers, labelled
with their contents.

Waste class 05 06 03

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TAR, COAL, HIGH-
(ADR/RID) TEMP.)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TAR, COAL, HIGH-
TEMP.)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TAR, COAL, HIGH-
TEMP.)

10/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TAR, COAL, HIGH-
TEMP.)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9 (N2, CMR, S)

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90

(ADR/RID)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Pollution category: Cat X Ship type: 2
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

11/12
Revision date: 22/05/2017 Revision: 5 Supersedes date: 13/12/2013

Coal Tar

EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) 2015/830 of 28 May 2015.

Authorisations (Title VII No specific authorisations are known for this product.
Regulation 1907/2006)

Restrictions (Title VIII Entry number: 28-30 Restricted to professional users.

Regulation 1907/2006)

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Classification procedures Skin Sens. 1 - H317, Carc. 1A - H350, Muta. 1B - H340, Repr. 1B - H360, Aquatic Chronic 2 -
according to Regulation (EC) H411: Expert judgement.
1272/2008

Revision comments Commission Regulation (EU) No 2015/830 of 28 May 2015.

Revision date 22/05/2017

Revision 5

Supersedes date 13/12/2013

SDS number 10026

Hazard statements in full H225 Highly flammable liquid and vapour.

H228 Flammable solid.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H351 Suspected of causing cancer.
H360 May damage fertility or the unborn child.
H360FD May damage fertility. May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

The information set forth in this Safety Data Sheet does not purport to be all-inclusive and should be used only as a
guide.Whilst the information and recommendations set forth herein are believed to be accurate,the company makes no
warranty regarding such information and recommendations and disclaims all liability from reliance thereon.

12/12