Aqa 8464C1H QP Jun19

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GCSE
COMBINED SCIENCE: TRILOGY
Higher Tier
H
Chemistry Paper 1H
Thursday 16 May 2019 Morning Time allowed: 1 hour 15 minutes

Materials
For Examiner’s Use
For this paper you must have:
• a ruler Question Mark
• a scientific calculator 1
• the periodic table (enclosed). 2
Instructions 3
• Use black ink or black ball-point pen. 4

• Fill in the boxes at the top of this page. 5
• Answer all questions in the spaces provided.
6
• Do all rough work in this book. Cross through any work you do not want to be
marked. TOTAL
• In all calculations, show clearly how you work out your answer.
Information
• The maximum mark for this paper is 70.
• The marks for questions are shown in brackets.
• You are expected to use a calculator where appropriate.
• You are reminded of the need for good English and clear presentation in your answers.
*jun198464c1h01*
IB/M/Jun19/E11 8464/C/1H
2
Do not write
outside the
0 1 This question is about reactions of metals. box
Figure 1 shows what happens when calcium, copper, magnesium and zinc are added
to hydrochloric acid.
Figure 1
0 1 . 1 What is the order of decreasing reactivity of these four metals?

[1 mark]
Tick () one box.
Zn Ca Cu Mg
Ca Cu Mg Zn
Cu Zn Ca Mg
Ca Mg Zn Cu
*02*
IB/M/Jun19/8464/C/1H
3
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outside the
A student wants to make a fair comparison of the reactivity of the metals with box
hydrochloric acid.
0 1 . 2 Name two variables that must be kept constant.

E
metal
- o
←
Hollaq)
[2 marks]
1 size ofmetal Ins8 .
2 xolloneof HCl
COMG -
cf 4Olerre .
0 1 . 3 What is the independent variable in this reaction?

[1 mark]
Metals ,
0 1 . 4 Predict the reactivity of beryllium compared with magnesium.
Give a reason for your answer.
Use the periodic table.

[2 marks]
Beryllium 7
µ
The mcrease dewn the
Reason
reactixuty in
gras a
grarp .
0 1 . 5 A solution of hydrochloric acid contains 3.2 g of hydrogen chloride in 50 cm3
Calculate the concentration of hydrogen chloride in g per dm3

[3 marks]
(50÷100
家
孕
0
C÷ LO
=
? 3
Concentration = g per dm3

gdm 3 9
Turn over ►
*03*
马
4
Do not write
outside the
0 2 This question is about salts. box
Ammonium nitrate solution is produced when ammonia gas reacts with

nitric acid.
0 2 . 1 Give the state symbol for ammonium nitrate solution.

[1 mark]
caq ]
0 2 . 2 What is the formula of nitric acid?
[1 mark]
Tick () one box.
HCl
HNO3 v
H2SO4
NH4OH
0 2 . 3 Ammonia gas dissolves in water to produce ammonia solution.
Ammonia solution contains hydroxide ions, OH–
A student adds universal indicator to solutions of nitric acid and ammonia.
What colour is observed in each solution?

[2 marks]
Colour in nitric acid Red ,
Colour in ammonia solution

punple ,
red green purple
*04*
5
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outside the
0 2 . 4 The student gradually added nitric acid to ammonia solution. box
Which row, A, B, C or D, shows the change in pH as the nitric acid is

added until in excess?
[1 mark]
Tick () one box.
pH of ammonia pH after addition of

solution at start excess nitric acid
A 10 7
B 2 10
C 7 1
D 10 2 v
0 2 . 5 Calculate the percentage by mass of oxygen in ammonium nitrate (NH4NO3).
Relative atomic masses (Ar): H=1 N = 14 O = 16
Relative formula mass (Mr): NH4NO3 = 80

[3 marks]
14 + 4 (1 ) + 14 + 3 [ 16)
16 ×
=
8
瓷号
Percentage by mass of oxygen = 00% %
Question 2 continues on the next page
Turn over ►
*05*
。
二
爻
6
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outside the
0 2 . 6 Describe a method to investigate how the temperature changes when box
different masses of ammonium nitrate are dissolved in water.
You do not need to write about safety precautions.

[6 marks]
thermometer watl
ueasure l0
g
14
*06*
7
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outside the
Turn over for the next question box
DO NOT WRITE ON THIS PAGE

ANSWER IN THE SPACES PROVIDED
Turn over ►
*07*
8
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outside the
0 3 This question is about oxygen. box
0 3 . 1 Hydrogen reacts with oxygen.
2 H2 (g) + O2 (g) → 2 H2O (g)
Figure 2 shows the relative energies of the reactants and products at a

certain temperature.
Figure 2
→
时
80
i
v
actiuatia
energy
HO
→
Label the activation energy on Figure 2.

[1 mark]
*08*
。
9
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outside the
0 3 . 2 Determine the overall energy change for the reaction between hydrogen and oxygen box
shown in Question 03.1
Use Figure 2.
exothermic [2 marks]
400 -
800 form bond
= -
40 OKJ
Energy change = 4O kJ
0 3 . 3 Oxygen is in Group 6 of the periodic table.
Figure 3 shows the outer energy levels in one molecule of oxygen (O2).
Draw the electrons in the outer energy levels in Figure 3.

[2 marks]
Figure 3
XX 00
M 0
d
Turn over ►
*09*
爻
10
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outside the
0 3 . 4 The equation shows the decomposition of hydrogen peroxide. box
)
2(H–O –O–H → 2 H–O –H + O=O
xra a ↑ * 了
Table 1 shows the bond energies.
Table 1
Bond O–O O=O O–H
Bond dissociation
138 496 463
energy in kJ per mole
Calculate the overall energy change for the reaction.

[3 marks]
Energy change
=
(22) [463) * 4a6 ]

-
2 [463 + 138+ 463 ]
2348 -2 ( 2
=
=t -2
OKJ
Energy change = 220 kJ
*10*
。
11
Do not write
outside the
0 4 This question is about elements in the periodic table. box
0 4 . 1 What order did scientists use to arrange elements in early periodic tables?
[1 mark]
Atomic weight
0 4 . 2 In the early periodic tables some elements were placed in the wrong groups.
Mendeleev overcame this in his periodic table.
Give one way Mendeleev did this.

[1 mark]
left gaps
Turn over ►
*11*
12
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outside the
Table 2 shows the boiling points of fluorine, chlorine and bromine. box
Boiling N melting Table 2
what
bends
-
Element Boiling point in °C
ω
hg low 1 wng high Fluorine –186
forced
Chlorine –34
weak - . …
Bromine +59
strong -
force
0 4 . 3 Explain why the boiling points in Table 2 are low.
[2 marks]
-
simple copalent bond

4 weak uann intermdecular fres
.
prek
srequire les
energy to
thQ bond
0 4 . 4 Explain the trend in the boiling points in Table 2.

[3 marks]
thebaling fluorine
inorease from
-
a te
Bremine ① inrease
. themolecularsireofBron
②
員 fram
flurorine 比 Bromine
③ Theinterndecalar force iargf
*12*
。。
一
一
13
Do not write
outside the
0 4 . 5 Explain why neon is unreactive. Nobel gas ,
box
Give the electronic structure of neon in your answer.

nobel
grapo = [2 marks]
→
otor electron shells
filled table
8
It doesnitgarn 11ose electras

→
.
0 4 . 6 How many atoms are there in 1 g of argon?
The Avogadro constant is 6.02 × 1023 per mole.
Relative atomic mass (Ar): Ar = 40

[2 marks]
NNo c
. atems ,
6 O 2× L023
=
0 X .
Number of atoms in 1 g =
11
Turn over for the next question
Turn over ►
*13*
。
14
Do not write
outside the
metald
0 5 This question is about electrolysis.
*
box
ian
0 5 . 1 Some metals are extracted from molten compounds using electrolysis.
Why is electrolysis used to extract some metals?

[1 mark]
metal is reaticetobe extiaoted

using carbd
0 5 . 2 Aluminium is produced by electrolysis of a molten mixture.
What two substances does the molten mixture contain?

[2 marks]
1 Aluminium oxide
2 crgclite
0 5 . 3 Copper and chlorine are produced when molten copper chloride is electrolysed.
Complete the half equation for the reaction at each electrode.

[2 marks]
Half equation at negative electrode
Cu2+ + 2e → ca
Half equation at positive electrode
2 Cl– → 12
C
e
+2
*14*
15
Do not write
outside the
Figure 4 shows the apparatus a student used to electrolyse copper chloride solution. box
Figure 4
cathode ,
Anode
redlEfion
-
世 1e wxidatian
The student:
• measured the mass of copper deposited on the negative electrode

after 60 minutes
• compared the mass deposited with the expected value.
0 5 . 4 Suggest two reasons why the mass deposited was different from the expected value.
[2 marks]
1
impurities in s0 lution .
2 xolUm φ
Turn over ►
*15*
。
16
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outside the
0 5 . 5 Figure 5 shows the expected mass of copper produced each minute. box
Figure 5
时
Determine the expected mass of copper after 24 hours.
Use Figure 5.
k [3 marks]
=×
→
“ 60
330
上
Mass = mg
*16*
17
Do not write
outside the
Silver nitrate solution is electrolysed. box
Figure 6 shows the change in mass of the negative electrode over 10 hours.
Figure 6
进
i
a 25-
.
-
←
① 5
-
0 5 . 6 Determine the mass of the negative electrode at the start of the experiment.
Use Figure 6.
[1 mark]
4 75
.
0 5 . 7 Calculate the gradient of the line in Figure 6.
Give the unit.

[3 marks]
Gradient
Unit
14
Turn over ►
*17*
文
一
尸一
18
Do not write
outside the
0 6 This question is about sodium. box
0 6 . 1 Sodium reacts with chlorine.
What is the balanced equation for the reaction?

[1 mark]
Tick () one box.
Na
1 + 7 -
Na + Cl → NaCl v
Na + Cl时
2 → NaCl2
&
2 Na + Cl2 → 2 NaCl
0
2 Na + Cl → Na2Cl
Alt O3 → AlO
3 ,
0 6 . 2 Hot sodium is put in a gas jar of chlorine.
哭
Describe the observations made before, during and after the reaction.
[3 marks]
Before reaction
During reaction xellw liahr

yellow flame
After reaction white sold
Naclt
*18*
。
19
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0 6 . 3 Explain why sodium is less reactive than potassium. box
[4 marks]
Pod
PassI
sodium (
oorgor mdecularsi :e than
strongr intermdecdar force
reqired mere energy
electrons 10se less
rapidlython
Turn over ►
*19*
20
Do not write
outside the
0 6 . 4 Chlorine reacts with sodium and with hydrogen. box
gTant
□
Compare the structure and bonding in sodium chloride and hydrogen chloride.
[6 marks]
Nacl → iOni
& structure
7
giant ianic bnd
-
strenger
4
HCl simple molealur structure -
→ Cacalent bond
7
weakr
END OF QUESTIONS 14
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Please write clearly in block capitals.

Centre number Candidate number

Thursday 16 May 2019 Morning Time allowed: 1 hour 15 minutes

• Use black ink or black ball-point pen. 4

0 1 . 1 What is the order of decreasing reactivity of these four metals?

0 1 . 2 Name two variables that must be kept constant.

1 size ofmetal Ins8 .

0 1 . 3 What is the independent variable in this reaction?

0 1 . 4 Predict the reactivity of beryllium compared with magnesium.

Give a reason for your answer.

Use the periodic table.

0 1 . 5 A solution of hydrochloric acid contains 3.2 g of hydrogen chloride in 50 cm3

Calculate the concentration of hydrogen chloride in g per dm3

Concentration = g per dm3

Ammonium nitrate solution is produced when ammonia gas reacts with

0 2 . 1 Give the state symbol for ammonium nitrate solution.

0 2 . 3 Ammonia gas dissolves in water to produce ammonia solution.

Ammonia solution contains hydroxide ions, OH–

A student adds universal indicator to solutions of nitric acid and ammonia.

What colour is observed in each solution?

Colour in nitric acid Red ,

Colour in ammonia solution

red green purple

Which row, A, B, C or D, shows the change in pH as the nitric acid is

pH of ammonia pH after addition of

0 2 . 5 Calculate the percentage by mass of oxygen in ammonium nitrate (NH4NO3).

Relative atomic masses (Ar): H=1 N = 14 O = 16

Relative formula mass (Mr): NH4NO3 = 80

Question 2 continues on the next page

different masses of ammonium nitrate are dissolved in water.

You do not need to write about safety precautions.

DO NOT WRITE ON THIS PAGE

0 3 . 1 Hydrogen reacts with oxygen.

2 H2 (g) + O2 (g) → 2 H2O (g)

Figure 2 shows the relative energies of the reactants and products at a

Label the activation energy on Figure 2.

shown in Question 03.1

0 3 . 3 Oxygen is in Group 6 of the periodic table.

Draw the electrons in the outer energy levels in Figure 3.

Question 3 continues on the next page

Bond O–O O=O O–H

Calculate the overall energy change for the reaction.

(22) [463) * 4a6 ]

Energy change = 220 kJ

Mendeleev overcame this in his periodic table.

Give one way Mendeleev did this.

Question 4 continues on the next page

Boiling N melting Table 2

Element Boiling point in °C

simple copalent bond

0 4 . 4 Explain the trend in the boiling points in Table 2.

Give the electronic structure of neon in your answer.

It doesnitgarn 11ose electras

0 4 . 6 How many atoms are there in 1 g of argon?

The Avogadro constant is 6.02 × 1023 per mole.

Relative atomic mass (Ar): Ar = 40

Turn over for the next question

0 5 . 1 Some metals are extracted from molten compounds using electrolysis.

Why is electrolysis used to extract some metals?