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ACTC ADVANCED CHEMISTRY TUITION CENTRE, NAGERCOIL, KK DIST 9940847892
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IMPORTANT QUESTIONS- QUESTION BANK 2022-23

LESSON 1 METALLURGY
1. Difference between ore and mineral. (2) BB (S20) M22 2M
2. Write the ores of copper, silver, Aluminium, Iron, zinc (3)
3. What are all the steps involves in metallurgical process?(2)
4. Write note on gravity separation.(3) M22 5Mi
5. What is Gangue?(3)
6. Explain froth floatation.(6) (A21) 5M
7. Describe the underlying principle of forth floatation process. (4) PTA 2M
8. Give the depressing agents used in the froth floatation process and why we use depressing
agents in that process? (OR)Role of depressing agent in froth floatation process?(4) PTA2M
9. which type of ores can be concentrated by froth flotation method give two example (J20)
10.What are leaching process?(4)
11.Explain Cyanide leaching.(4)
12.Explain how gold ore is leached by cyanide process. (4) GM5Mi
13.What is Cementation?(4)
14.What is Ammonia leaching.(4)
15.What is Acid leaching?(4) J22 3M
16.Explain magnetic separation.(6)
17.How will you manage sulphur dioxide produced during roasting process?(7)
18.Define the following terms (i) Roasting (6) (ii) Calcination (7) PTA3M
19.What is smelting? (8)
20.What is the role of limestone in the extraction of iron from its oxide Fe2O3.(8) (J20) (BB)
ANS: Used As Flux. (Govt. key)
21.Explain the following terms with suitable example. a)Gangue b) Slag.(BB) PTA3M(S20)
22.Explain extraction of copper from copper pyrites.(8) PTA5M i
23.What is meant by blistered copper.(9)
24.Give one example for (i) Acidic flux (ii) Basic flux (8)
25.CO is reducing agent. Justify with an example.(8)& (LN 2 43) PTA 2M
26.Reduction by hydrogen, carbon, metal(9)
27.How Cr2O3 is reduced to Cr by Al powder? (10) PTA 5M ii
28.Explain Auto reduction.(10)
29.Define, observation, application & Limitations of Ellingham diagram.(13)
30.Extraction of Aluminium-Hall -Herold process. (14)
31.Define refining process(15)
32.Write note on distillation. (15)
33.Write note on Liquation. (15)
34.Explain electro refining process. (15)
35.Explain electrolytic refining of silver. (16) PTA5M ii (Explain the principle of electrolytic
refining with an example. J22 5M)
36.Explain zone refining process.(16) M20 5M, PTA 3M
37.Explain Mond process. (Describe the method for refining of Nickel.)(16) PTA5M ii, M22
5Mii
38.Explain Van-Arkel method. (17)
39.Application of Al, Zn, Fe, Cu & Au. & Revise Book Back (Evaluation) Question Answer
E.MUTHUSAMY MSc(Che)., MSc(Psy)., MEd., MPhil., MA(Eng)., MA(T)., MA(PA)., MA(Soc)., BLISc., DMLT.
B. SARANYA MUTHUSAMY BE., BEd., You Tube: ACTC Chemistry Whatsapp: 9940847892
 www.nammakalvi.com
ACTC ADVANCED CHEMISTRY TUITION CENTRE, NAGERCOIL, KK DIST 9940847892
PLAN! PREPARE!! PRESENTATION!!!
LESSON 2 p-block elements-I
1. Explain general characteristics(properties) of p-block elements. (27)
2. Write note on metallic nature of p-block elements. (28)
3. Give one example for Icosogens, Tetragen, pnictogen, chalcogen. (28)
4. What are the anomalous properties of the first elements of the p-block elements. (29) S20
A21
5. There is only a marginal difference in decrease in ionization enthalpy from Aluminium to
Thallium – Explain why? (29)M20 Compulsory 3 mark
6. What is inert pair effect.(30) M22 5Mi
7. Occurrence of Group 13 (Boron group) elements. (31)
8. Chemical properties of Boron. (X2, N2, O2, H2SO4, HNO3, NaOH) (33)
9. A hydride of 2nd period alkali metal (A) on reaction with compound of Boron (B) in the
presence of ether to give a reducing agent (C). Identify A, B and C. J20 2M Compulsory
10.Uses of Boron. (22)
11.Preparation, properties & uses of Borax. (33,34)
12.Preparation of Boric acid. (34)
13.How will you identify borate radical? Write the reactions involved.(35) PTA3M, GM2M
14.How will you convert Boric acid to boron nitride?(35) PTA2M
15.Structure of Boric acid.(35)
16.What are the Uses of Boric acid. (35) J22 3M, M22 5Mii
17.How does borane react with H2O & NaOH? ( 36 )
18. How will you prepare borazine? (37)
19.Explain structure of diborane. (37)
20.Mention the uses of diborane (38)
21.How will you prepare BF3? ( 38 )
22. Write note on McAfee process ( 39 )
23.Mention the uses of Aluminium chloride ( 39 )
24.How to prepare potash alum & uses. (40) J20, PTA 5M ii
25.What is burnt alum.(40)
26. Occurrence of Group 14 (Carbon group) elements.(40)
27.What is catenation? Write the conditions for catenation property. (41) J22 5M Substantiate
this statement. (41) S20 2M Write any two conditions for catenation. M20 2M
28.What are allotropes of carbon, difference between graphite & diamond. (41)
29.Write note on fullerenes.(42)
30.Write note on nanotubes.(42)
31.Write note on graphene.(43)
32.What is producer gas, water gas? (43,45)
33.Write note on Fischer Tropsch synthesis.
34.Write note on structure & uses of CO & CO2 (44, 45)
35.How does SiCl4 react with alcohol & NH3? (46)
36.Explain the preparation, uses of silicone. (47 & 48)
37.What are the types, properties of silicones. (47)
38.Explain types of silicates. (48)
39.Explain Zeolites. (50)
ALL CHEMICAL EQUATION & Revise Book Back (Evaluation) Question Answer
E.MUTHUSAMY MSc(Che)., MSc(Psy)., MEd., MPhil., MA(Eng)., MA(T)., MA(PA)., MA(Soc)., BLISc., DMLT.
B. SARANYA MUTHUSAMY BE., BEd., You Tube: ACTC Chemistry Whatsapp: 9940847892
 www.nammakalvi.com
ACTC ADVANCED CHEMISTRY TUITION CENTRE, NAGERCOIL, KK DIST 9940847892
PLAN! PREPARE!! PRESENTATION!!!
25.Explain Valence Bond theory (VB Theory) & limitations. (S20, J22 2M, PTA)(149 &152)
26.Apply VB theory in [Ni(CO)4] , [Ni(CN)4]2-(S20), [Co(CN)6]3- , [Co(F)6]3-(M20) (149-151)
27.Explain crystal field theory. (153)
28.In an Octahedral crystal field, draw the figure to show splitting of d orbitals (154) J20 3M
29.In a tetrahedral crystal field, draw the figure to show splitting of d orbitals (155)
30. Write note on spectrochemical series (156)
31.Calculate the CFSE value of [Fe(H2O)6]3+ in high spin and low spin complexes. (157)
32. Calculate the CFSE value of [Fe(CN)6]3- in high spin and low spin complexes. (158)
33.[Sc(H2O)6]3+ is colourless – Explain. M20 3M (Explain about d-d transition) (159,160)
34.How is metal carbonyls classified based on the number of metal atom? (161)
35. How is metal carbonyls classified based on the structure ? (161, 162)
36. How can the stability of coordination complexes be interpreted? (163)
37.Define Labile, inert complexes. (163)
38.What is meant by stability constants? (163) significance of stability constants? (164)
39.Explain the importance and application of coordination compounds (166)
40.Mention the metal complexes and its metal ions are used in biological system (167) S20 3M
41.Give one test to differentiate [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl. (BB) PTA 2M
ALL IUPAC Name, Apply VB Theory & Revise Book Back (Evaluation) Question Answer
PHYSICAL CHEMISTRY LESSON 6 SOLID STATE
1. Write General characteristics of solids. (177)
2. Difference between crystalline solids and Amorphous solids.(178)PTA 3M, M22 5M
3. Define Isotropy and anisotropy.(178) (S20)
4. Explain ionic solids. (Introduction, NaCl diagram, Characteristics)(179)
5. What are the characteristics of Ionic solids? (179) PTA 5M i
6. What are covalent solids? (179) M22 2M
7. Explain molecular solids. (179)
8. What are Metallic solids? (180)
9. Classify the following into covalent, molecular, ionic and metallic solids.( A21) 3MARK C
(i) Diamond (ii) Brass (iii) NaCl (iv) Naphthalene (v) Glucose (vi) SiO2
10. Define unit cell. (180) J22 2M
11. What is meant by term “Coordination Number”? What is the Coordination Number of atoms
in a bcc structure? (180) A21 3MARK, M22 2M
12. Define primitive& non-primitive unit cells? (181)
13. Define the terms crystal lattice and unit cell. (180) PTA3M
14. Write note on SC. (183)
15. Write note on BCC. (183)
16. Sketch Face Centered cubic unit cell(FCC) and Calculate the number of atoms present in it.
(184) PTA3M
17. What is Bragg’s equation? (184) PTA 2M
18. How will you calculate the density of the unit cell? (185)
19. Barium has a body centered cubic unit cell with a length of 508pm along an edge. What is
the density of barium in g cm-3? (185)
20. An element has a face centered cubic unit cell with a length of 352.4 pm along an edge. The
density of the element is 8.9 gcm-3. How many atoms are present in 100 g of an element.
(186)
E.MUTHUSAMY MSc(Che)., MSc(Psy)., MEd., MPhil., MA(Eng)., MA(T)., MA(PA)., MA(Soc)., BLISc., DMLT.
B. SARANYA MUTHUSAMY BE., BEd., You Tube: ACTC Chemistry Whatsapp: 9940847892
 www.nammakalvi.com
ACTC ADVANCED CHEMISTRY TUITION CENTRE, NAGERCOIL, KK DIST 9940847892
PLAN! PREPARE!! PRESENTATION!!!
21. What is packing efficiency? (187) PTA 5M ii, J22 5Mi
22. How will you calculate the packing efficiency for simple cubic?(187
23. Calculate the percentage efficiency of packing in body centered cubic system (188)PTA3M
24. What is void and its type? (190)
25. Note on radius ratio (192)
26. If the radius of the compound is between 0.155 – 0.225, find out the co-ordination number
an structure of the compound. (192) J20 5Mi
27. If the no. of close packed sphere is 6, calculate the number of Octahedral voids and
Tetrahedral voids generated. (M20) 2MARK
ANS: Octahedral voids (n)=6 Tetrahedral voids(2n)=2x6=12
28. Calculate the percentage efficiency of packing in face centered cubic system (192)
29. Outline the classification of point defects. (193) PTA5M ii
30. Explain Schottky defect (GM5M, S20)& Frenkel defect. (M20, PTA3M, J22 5Mii)
(Stoichiometric defects) (193)
31. Explain ‘f’ centers with a neat diagram.(194) PTA5M ii
32. Explain Metal excess defect, metal deficiency defect. (Non-Stoichiometric defects) (194)
33. Write note on Impurity defect. (195)
34. Atoms X and Y form BCC crystalline structure. Atom X is present at the corners of the
cube and Y is at the centre of the cube. What is the formula of the compound? (BB)PTA 5M
i
35. An atom crystallizes in FCC crystal lattice and has a density of 10gcm-3 with unit cell edge
length of 100pm. Calculate the number of atoms present in 1g of crystal. (BBQ22201) 5M
36. A face centred cubic solid of an element (atomic mass 60 gmol-1) has a cube edge of 4A°.
Calculate its density.(186) GM3M
37. What is piezoelectricity? (195)
ALL INSIDE PROBLEM & Revise Book Back (Evaluation) Question Answer
LESSON 7 CHEMICAL KINETICS
1. Define chemical kinetics. (205)
2. Define Rate of a chemical reaction. (205)
3. Write note on stoichiometry and rate of a reaction.(206)
4. Define average rate and instantaneous rate. (BB)207
5. Define rate law and rate constant. (BB)208
6. Give the difference between rate of a reaction and rate constant.(209) PTA,A21
7. What is an elementary reaction? (210)
8. Explain the rate determining step with an example. (210) PTA 3M
9. Define order and molecularity of a reaction. (210) J22 3M
10.Give the differences between order and molecularity of a reaction. (210)
11.The rate of the reaction x + 2y → product is 4 × 10-3 mol L-1s-1, if [x] = [y] = 0.2M and rate
constant at 400k is 2 × 10-2s-1, what is the overall order of the reaction?(211) (J20) 2 MARK
12.Derive integrated rate law for a first order reaction A → product.(212) (PTA,M20) 5MARK
13. Derive and describe the graphical representation of first order reaction.(212)
14.Give examples for the first order reaction. (213) M22 2M
15.Explain pseudo first order reaction with an example. (214)GM3M
16.Derive integrated rate law for a zero order reaction A→product & Example (214) A21 5M,
J22 5M
E.MUTHUSAMY MSc(Che)., MSc(Psy)., MEd., MPhil., MA(Eng)., MA(T)., MA(PA)., MA(Soc)., BLISc., DMLT.
B. SARANYA MUTHUSAMY BE., BEd., You Tube: ACTC Chemistry Whatsapp: 9940847892
 www.nammakalvi.com
ACTC ADVANCED CHEMISTRY TUITION CENTRE, NAGERCOIL, KK DIST 9940847892
PLAN! PREPARE!! PRESENTATION!!!
17.Define half life period of reaction. Show that for a first order reaction half life period is
independent of initial concentration. (215) PTA 5M i
18.Calculate the half period for a zero order reaction.(215)PTA 2M
19.Write Arrhenius equation and explains the terms involved. (220) M22 3M
20.Write the rate law for the following reactions. (BB)
(a) A reaction that is 3/2 order in x and zero order in y.
(b) A reaction that is second order in NO and first order in Br2.
21.The rate constant for a first order reaction is 1.54x 10-3 s-1. Calculate its half life time.(BB
231) (PTA, J20)
22.Identify the order for the following reactions (BB)
(i) Rusting of Iron
(ii) Radioactive disintegration of 92U 238
1
(iii) 2A + 3B → products ; rate = � � 2 [B]2
23.Write any three differences between order and molecularity.(210) 5M i
24.Explain about collision theory (217, 218)
25.Derive Arrhenius equation to calculate activation energy from the rate constant k1 and k2 at
temperature T1 and T2 respectively. (220,221) PTA3MC
26.What are the factors affecting the reaction rate? (222)
27. Explain the effect of catalyst on reaction rate with an example. (222) S20 5Mi
28.Powdered CaCO3 reacts much faster with dilute HCl than with the same mass of CaCO3 as
marble. Give reason. J20 3M COMPULSORY
29.The rate of formation of dimer in a second order reaction is 7.5 × 10-3 mol L-1s-1 at 0.05 mol
L-1 monomer concentration. Calculate the rate constant. (BB) 5M i
30.For the general reaction A → B. Plot of concentration of A Vs time is given in the graph
below. Answer the following Questions on the basis of this graph. (214) PTA3M
[A] i) What is the order of the reaction?
ii) What is the slope of the curve?
iii) What is the Unit of rate constant?
t
31.a first order reaction is 40% complete in 50 minutes. Calculate the value of the rate constant.
In what time will the reaction be 80% complete? (BBQ30231) GM5Mi
ALL INSIDE PROBLEM & Revise Book Back (Evaluation) Question Answer
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E. MUTHUSAMY & SARANYA MUTHUSAMY
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E.MUTHUSAMY MSc(Che)., MSc(Psy)., MEd., MPhil., MA(Eng)., MA(T)., MA(PA)., MA(Soc)., BLISc., DMLT.
B. SARANYA MUTHUSAMY BE., BEd., You Tube: ACTC Chemistry Whatsapp: 9940847892