Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

Central Office, Bangalore
Sec: Jr. JEE APEX Date:06-07-2024
Time: 9:00 AM to 12:00 PM JEE-MAINS Max. Marks: 300
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KEY SHEET
PHYSICS
1 3 2 3 3 2 4 2 5 2
6 3 7 2 8 3 9 4 10 2
11 4 12 4 13 4 14 4 15 3
16 3 17 4 18 2 19 4 20 2
21 4 22 80 23 8 24 20 25 33
26 17 27 24 28 1300 29 1 30 4

CHEMISTRY
31 2 32 3 33 2 34 3 35 1
36 1 37 2 38 3 39 3 40 4
41 2 42 4 43 3 44 4 45 4
46 2 47 1 48 3 49 2 50 1
51 4 52 4 53 5 54 3 55 2
56 4 57 4 58 0 59 4 60 4

MATHEMATICS
61 2 62 3 63 2 64 1 65 4
66 1 67 1 68 3 69 4 70 3
71 2 72 3 73 1 74 1 75 2
76 2 77 4 78 3 79 2 80 2
81 1 82 4 83 1 84 5 85 1
86 0 87 16 88 3 89 26 90 2
 SOLUTIONS
PHYSICS

1. Time taken to travel first half distance

2. Let L be the length of escalator

3. In the graph (b) for one value of displacement there are two timings. As a result of it for one time the average
velocity is positive and for other time is equal but negative due to it the average velocity for timings can vanish.

4.

5.
6.

7. If r makes an angle  with x-axis, the component of r along x-axis = rcos  .it will be maximum if cos

 = maximum = 1 or  = 00 i.e. r is along positive x-axis.

8. In two dimensional motion if instantaneous speed is a positive constant, then the acceleration of the

particle is necessarily in the plane of motion

TatalDisplacement
9. Average Velocity =
TotalTime

2(120)
=
60

= 4 m/s

10. If | A + B |=| A |, then either B = 0 or B = - 2 A . Both are satisfied when A and B are anti-parallel.

11.

12.
 𝑡𝑜𝑡𝑎𝑙 𝑑𝑖𝑠𝑡𝑎𝑛𝑐𝑒
13. Average speed =
𝑡𝑜𝑡𝑎𝑙 𝑡𝑖𝑚𝑒

𝑣−𝑢
14. a=
𝑡


P + VQ2
15. V mid point =
2

𝑣−𝑢
16. 𝑣 2 -𝑢2 =2as and a=
𝑡

1
17. h = −(u sin  ) + gt 2
2

u 2 sin 2
18. R1=R2 =
g
u2
h1 + h2 =
2g

𝑣 = 𝑣𝑥𝑖̂+ vyjˆ
19. ⃗⃗⃗
⃗⃗⃗ = u𝑖̂+(g t) ĵ
𝑣
2
|𝑣 |= √𝑢2+(𝑔𝑡)

20. 𝑣𝑐
⃗⃗⃗⃗ = 25𝑖̂
vTC = vT − uC  vT = vTC + vC
v = 25iˆ + 25 3Tˆ
T

vT = (25)2 + 25( 3)2 = 50kmph

21. change in velocity =area under a-t graph v= (4)1-2(1)

V= 2m\sec

v2
22. r=
g cos
1
vx = u x = u cos 60 = 20 = 101ˆ
2
vy = u y − gt = [20sin 60 −10t ] ˆj
 3
= (20   ) -10t ] 𝑗̂
 2 
Vy = (10 3 − 10t ) 𝑗̌
∴𝑢⃗ .𝑣=0
( 10 𝑖̌+ 10 √3𝑗̌). (10 𝑖̌+ (10 )
3 − 10t 𝑗̌]=0
4
= t sec
√3
 4 −10 ˆ
v y = 10 3 − 10 = j
3 3
10 ˆ
u = vxiˆ + v y ˆj = 101ˆ − j
3
100 400
| u |= vx2 + v y 2 = 100 + =
3 3
u2 400 / 3
r= =
g cos 3
10.
2
80 
= =
3 3 3 3
= x = 80

23. x = 2t + 4𝑡 2 y = 5t
Vx=2+8t vy = 5
A x= 8 ay = 0
a ax2 + ay2 = 82 + 02 = 8

24. v = u + at = 40+(-10)2
= 20 m\sec

3v1v2v3
25. average speed =
v1v2 + v2v3 + v3v1

26. ⃗ =ux𝑖̌+uy𝑗̌=9 iˆ + 9 3Jˆ

𝑢
u = uiˆ + (u sin  − 9t ) Jˆ
u = 91ˆ + (9 3 − 10t ) Jˆ
| u |= p 2 + (9 3 − 10t 2
(15) 2 = 92 + (9 3 − 10t ) 2
152 − 92 = (9 3 − 10t ) 2
144 = 9 3 − 10t
12 = 9 3 − 10t
9 3 − 10
t= = 0.357
10
 0.4
4 2
= =
10 5

27.
u y = 10 Jˆ
a = ax1ˆ + a y Jˆ = 81ˆ + 2 Jˆ
ay = 2
t=2
 1
s y = u y + a yt 2
2
1
= 10(2) + (2)(2)2
2
= 20 + 4 = 24

28.
s = 121ˆ + 3Tˆ + 4kˆ
| s |= 144 + 9 + 16
= 169
= 13m
= 1300cm

29.
 1
s1 = u − g 1 − 
 2
= g − g (1/ 2) = g / 2
42 g 2
s2 = = = g/2
2g 2g
s1 g / 2 1
= = =1
s2 g / 2 1

30.
1 2
h +1 = gt AC
2
1 2
h= gt AB
2
t AC = t AB + t BC
t BC = 0.2sec
t AC = t AB + 0.2
1
h +1 = g (t AB + 0.2)
2
1 1 1
gt AB + 1 = g (t AB ] + g (0.2) 2 + gt AB (0.2)
2 2 2
10
1 =  0.04 + 2t AB
2
10
t AB =  0.04 + 2t AB
2
2 
t AB = =
5 5
=2
 CHEMISTRY

31 Covalent radius decreases along a period . Therefore , B(110pm) has larger covalent
radius than N (70pm).

32 K+( 19-1=18), C𝑙 − ( 17+1=18),

C𝑎2+ (20-2=18) , S𝑐 3+ (21-3=18)represent a collection of isoelectronic species .

33 Be has filled 2s –subshell (2 𝑠 2 ) and therefore shows little tendency to accept an

extra electron to form B𝑒 − .

34 In general , as the nuclear charge increase from left to right in a period , the
ionization enthalpy increase accordingly . But ionization enthalpy of N is higher than
that of O due to greater stability of the exactly half filled electronic configuration of the
2p- orbitals (1𝑠 2 2𝑠 2 2𝑝1 x2𝑝1 y2𝑝1 z)in N atom . Therefore , among N,O and F atoms ,
the ionization enthalpy of O is the lowest , i.e. option (c) is correct .
35 Please note that the numerical value of electron affinity (EA) is the reverse of
electron gain enthalpy (∆ eg H). since EA increases along a period , therefore ,EA of CI
> S. But due to electron- electron repulsions within the small atom of O, EA of S > O.
However , due to extra stability of exactly half-filled electronic configuration ,N has the
least EA . Thus, the overall EAs of the four atoms increase in the order : N<O<S <Cl ,
i.e., option ( a) is correct .
36 As we move from left to right , across a period , first ionization enthalpy (∆iH1) generally
increases . But ∆iH1 of A1 is lower that of Mg because in case of Mg , an electron is to be
removed from fully filled more stable 3s-orbital while in case of AI,3p-electron has to be
removed . since removal of a s-electron requires more energy more energy than a p-electron of
the same shell , therefore ,∆ iH1 AI is lower than that of Mg. In other words , ∆iH1 elements
follows the order ;
: Na < Mg > Al < Si, i.e.., option ( a) is correct .

37 Polarising power  charge on the ion

𝑇𝑜𝑡𝑎𝑙 𝑐ℎ𝑎𝑟𝑔𝑒 −3
38 Formal charge on each O-atom = = = - 0.75.
𝑁𝑜.𝑜𝑓 𝑜−𝑎𝑡𝑜𝑚 4
2
39 Hybridisation in graphite = s𝑝

40 Ionic compounds are readily soluble in polar solvents like water .

41 Smaller cation causes more polarization of anion .
42 Conceptual .
43 Polarisability ∝ charge of cation
44 Ionic character arises due to E.N difference between the ions .
 E.N difference is highest between CS and f , CSF has highest percentage of
ionic character in its bonding .
45 All boran halides are covalent halides
46 Zn (30) =1 𝑠 2 2𝑠 2 2𝑝6 3𝑠 2 3𝑝6 3𝑑10 4𝑠 2
𝜎 = ( 0.35×1)+( 0.85× 18)+ (1×10) = 25. 65
Z eff = Z- 𝜎=30-25.65 = 4.35

47 Ionization potential decreases down the group so I.P of k is lesser than that of Na .

48 3 Electrons remove from a to get octet configuration ;

2 electrons needed to ‘B’ to complete octet

∴ A+3 B-2 => A 2B3

49 On moving down the group IV A , the stability of “ +2” oxidation state increases
due to inert pair effect
50 conceptual .
51 Lanthanoids are also called rare earth elements .
52 Se: 1s 22s 22p 63s23p63d104s24p4
53 . Si, Ge, As, Sb, Te are metalloids
54. 3Rd group
55. The difference in I.P2 and I.P3 is maximums so its valency =2 ,
group 2 has valency 2.
𝑛𝑜 𝑜𝑓 𝜎 𝑏𝑜𝑛𝑑𝑠 12 4
56. = = =4
𝑛𝑜 𝑜𝑓 𝜋 𝑏𝑜𝑛𝑑𝑠 3 1
57. O=C=C=C=O
No. of covalent bonds between carbon atoms =4
Formal charge =  N A − N L.P − N B.P  = 6 − 4 − (4) = 0
1 1
58.
 2  2

59. [ Cu( H2O)4 ] SO4.H2O

60. H-C ≡ N, total 4 bonds are formed

MATHEMATICS

4 5  
61. cos( A + B ) = , cos( A − B) = and A, B  0, 
5 13  4

0 A
4

 A
3 12 0B 4
Tan( A + B ) = Tan( A − B ) = 4
4 5 
 B
A+ B  4
2
A + B  Q1
A – B  Q1
 Tan( A + B) + Tan( A − B) 56
Tan 2A = Tan [(A+B) + (A+B)] = =
1 − Tan( A + B)Tan( A − B) 33

p Q −b  p Q Q
62. Tan + Tan = P + Q + R = 180 Tan  +  = cot
2 2 a 2 2 2
p Q
Tan + TAn
p Q c
Tan Tan = P + Q = 180 – R 2 2 = 1( R =  = 90)
2 2 a p Q 2
1 − Tan Tan
2 2
−b c
P Q R +
+ = 90 −  a a =1  c = a + b
2 2 2  −b  c 
1 −   
 a  a 
5
63. 2sin A + 3 sin B = (1)
2
3 3
3 sin A + 2sin B = (2)
2
Solve 1 and 2

 B = 60
 3 5
 2sin A + 3   =  A = 30
0

 2  2
Then C = 900
c
cot = cot 45 = 1
2

TanA + sec A − 1 TanA + secA− (sec2 A − Tan2 A)

64. =
TanA − sec A + 1 TanA − sec A + 1

(sec A + TanA) − (sec A + TanA)(sec A − TanA)

TAnA − sec A + 1
1 sin A 1 + sin A
= sec A + TanA = + =
cos A cos A cos A

m 1
+
Tan + Tan
65. Tan( +  ) = = m + 1 2m + 1 = 1
1 − TanTan 1 − m  1
m + 1 2m + 1

 +  =
4
x x
1 − cos x 2sin 2 sin
66. (i) = 2 = 2 = Tan x
sin x x x x 2
2sin cos cos
2 2 2
2 x

1 + cos x 2cos 2 x
(ii) = = cot 2
1 − cos x 2sin 2
x 2
2
 x

2cos 2
1 + cos x 2 x
(iii) = = cot
sin x x x 2

2sin cos
2 2
(iv) 1 + sin 2 x = cos2 x + sin 2 x + 2sin x cos x = (cos x + sin x) 2 =| cos+ sin x |

 1 
67. sin 4  + 2sin 2  1 − 2 
+ cos 4 
 cosec  
= sin  + 2sin  (1 − sin  ) + cos 4 
4 2 2

= sin 4  + 2sin 2  cos 2  + cos 4 

= sin 4  + cos 4  + 2sin 2  cos 2 
= 1 − 2sin 2  cos 2  + 2sin 2  cos 
=1

68. sin A = sin 2 B, 2cos2 A = 3cos2 B

2(1 − sin 2 A) = 3(1 − sin 2 B)
2 − 2sin 2 A = 3 − 3sin 2 B
2 − 2sin 2 A = 3 − 3sin A
2sin 2 A − 3sin A + 1 = 0
2sin A(sin A − 1) − 1(sinA − 1) = 0
1
sinA = 1,sin A =
2
A = 90, A = 30
 A = 30

(A  (0, )
2
1
 sin 2 B = sin A = sin 30 =
2
1
 sin B =  B = 450
2
Tan( A + B) = Tan(30 + 45) = Tan750 = 2 + 3

 sin  = 1 − sin 2 
69. sin  + sin  = 1
2

 sin  = cos 2 
a cos12  + b cos10  + e cos8  + d cos6  = 1

a sin 6  + b sin5  + c sin 4  + d sin3  = 13

= ( son + sin 2  )3
= sin 3  + sin 6  + 3sin 4  + 3sin 5 
= sin 6  + 3sin 5  + 3sin 4  + sin 3 
a = 1, b = 3, c = 3, d = 1
b + c 3+3 6
= = =3
a + d 1+1 2

70.
 80 − 10 = 70
Tan(80 − 10) = Tan700
Tan800 − Tan100
= Tan700
1 + Tan80Tan10
Tan80 − TAn100 = 2Tan700
tan80 − Tan100
=2
Tan70

71.
3Tanx = 4Tany sin( x + y ) = sin x cos y + cos x sin y
sin x sin y
3 =4 1 3
= +
cos x cos y 4 16
3sin x cos y = 4cos x sin y 4+3
=
1 16
3   = 4cos x sin y
4 =
7
3 16
= cos x sin y
16

72.
2sin A sinC
TanB =
sin( A + C )
1 2sin A sinC
=
cot B sin( A + C )
sin( A + C )
cot B =
2sin A sinC
2cot B = cotC+ cot A
cot A,cot B,cotC are in A .P
 TanA TanB, Tan C are in H.P

73. Conceptal

74.
3sin 2 A + 2sin 2 B = 1 3sin 2 A = 2sin 2 B
3sin A = 1 − 2sin B
2 2
3
sin 2 B = sin 2 A
3sin 2 A = cos 2 B 2

cos( A + 2B) = cos Acos2B − sin Asin 2B

3 
= cos A(3sin 2 A) − sinA  sin 2 A 
2 
3
= 3cos A(1 − cos 2 A) − sin A))2sin A cos A)
2
= 3cos A − 3cos A − 3cos A + 3cos A + 3cos 2 A
=0
 sec80 − 1 1 − cos80 cos 4 2sin 2 4 .cos 4
75. =  =
sec 40 − 1 cos80 1 − + cos 4 cos8 .2sin 2 2
sin 4 .sin 4 .cos 4
=
cos8 .sin 2 .sin 2
2sin 2 .cos 2 .sin 4
=
cos8 .sin 2 .sin 2
sin 8 cos 2
= 
cos8 sin 2
= Tan8 .cot 2

3 1
76. 3corec 200 − sec 200 = −
0
sin 20 cos 200
 3 1 
2 cos 20 − sin 20 
3coa 20 − sin 20
0 0
 2 2 
= =
0
sin 20 cos 20 0 1
(2sin 20cos 20)
2
2sin(600 − 200 ) 4sin 40
= = =4
1 0 sin 40
sin 40
2

77. sin 200 sin 400 sin 600 sin800

= sin 60sin 20sin 40sin80
1
= sin 20sin(60 − 20)sin(60 + 20)
2
1 1
= . sin 3(20)
2 4
1 1 1
= . .
2 4 2
1
=
16

78.
3
cos A =
4
A 5A  A 5A 
32sin sin = 16  2Sin sin 
2 2  2 2 
  5A A   5 A A 
= 16 cos  −  − cos  + 
  2 2  2 2 
= 16  cos 2 A − cos3 A
= 16  2cos 2 A − 1 − 4cos3 A + 3cos A
 9  27   3  
= 16  2   − 1 − 4   + 3   
  16   16   4  
18 − 16 − 27 + 36 
= 16  
 16
= 2+9
= 11
 2   2 
79. x = k cos , y = k cos   −  , z = k cos   + 
 3   3 
   2   2 
x + y + z = k cos + cos   −  + cos   + 
  3   3 
= k  cos + cos(120 − 0) + cos(120 + 0) 
= k (0)
=0

80.
Tan( x + 8 x + 27 x + ....... + n3 x)
= Tan(13 + 23 + 33 + ....... + n3 ) x
n 2 (n + 1) 2
= Tan x
4
  4
= = =
|a| n (n + 1)
2 2
n (n + 1) 2
2

81.
k = (sec A + TanA)(sec B + TanB)(sec c + Tanc)
k = (sec A − TanA)(sec B − TanB)(sec c − Tanc)
k 2 = (sec2 A − Tan 2 A)(sec2 B − Tan 2 B )(sec2 c − Tan 2c )
= (1)(1)(1)
k 2 = 1  k = 1
| k |= 1
82.
sin x + cos x
3
= aTan3 x + bTan 2 x + cTanx + d
cos x
cot x = 450
1 1
+
2 2 = a+b+c+d  a+b+c+d = 4
1
2 2

83.
3 3 min = (5cos x − 12cos+ 19)
=
5cos x − 12cos x + 19 min[5cos x − 12cos + 19]
= c − a 2 + b2
3
=
6 = 19 − 25 + 144
1 k = 19 − 13
= = ( given)
2 2 =6
 k =1

84. sin x + cos x = 0  sin x = cos 2 x  sin x = 1 − sin 2 x  sin 2 x + sin x − 1 = 0

−1  1 − 4(1)(−1) −1  5 5 −1
 sin x = = =
2(1) 2 2
5 −1 −( 5 + 1)
 sin x = or
2 2
k −1 5 −1
=
2 2
k =5
85.
Tanx = 2k , Tany = 3k , Tanz = 5k
x+ y+ z =
x+ y = −z
Tan( x + y ) = Tan( − z)
Tanx + Tany
= −Tanz
1 − Tanx tan y
2 3 5
Tanx = , Tany = =
3 3, Tanz 5
Tanx + Tany + Tanz = TanxTanyTanz Tan 2 x + Tan 2 y + Tan 2 z =
38
2k + 3k + 5k = 2k 3k 5k 3k
38 38
10 K = 30 K 2 .K =
3 3k
1 1 3k = 3
K2 =  K =
3 3 k =1
86.
 9 3 5
2cos cos + cos + cos
13 13 13 13
  9    −9  3 5
= cos  +  + cos   + cos + cos
 13 13   13 13  13 13
10 8 3 5
= cos + cos + cos + cos
13 13 13 13
 10 3    8 5  
=  cos + cos  +  cos  + cos  
 13 13    13 13  
= 0+0
=0
A+ B =
= cos A + cosB = 0

87. m = TanA + sin A n = TanA − sin A

m + n = TanA + sin A + TanA − sin A = 2TanA mn = (m cos A + sin A)(TanA − sin A)
m − n = TanA + sin A − TanA + sin A = 2sin A = m cos 2 A − sin 2 A
(m2 − n 2 ) (m + n) 2 (m − n) 2 (4Tan 2 A)(4sin 2 A)  1 − cos 2 A  sin 2 A sin 2 A
= = = Sin A 
2
=
mn mn sin 2 A.sin 2 A 2
 cos A  cos 2 A
cos 2 A sin 2 A.sin 2 A
sin 2 A cos 2 A =
= 16 .sin 2
A  cos 2 A
cos 2 A sin 2 A.sin 2 A
= 16.
 Tanx + sec x = 2cos x
sin x 1
+ = 2cos x
cos x cos x
sin x + 1 = 2cos 2 x
sin x + 1 = 2(1 − sin 2 x)
2sin 2 x + sin x − 1 = 0
2sin 2 x + 2sin x − sin x − 1 = 0
2sin x(sin x + 1) − 1(sin x − 1) = 0
1
sin x =
2

x=
3

x = n + (−1) 2
6
 5
x = ..... ,
88. 6 6

  
x= , , [6,2 ]
3 6 6
No of solution = 3

89.
6[sin x − cos x]4 + 12[sin x + cos x]2 + +8[sin 6 x + cos 6 x]
letx = 900
6(1 − 0) 4 + 12(1 + 0) 2 + 8(1 + 0) = 6 + 12 + 8 = 26

90.
 5 7
k = sin sinsin
18 18 18
= sin10sin 50sin 70
= sin10sin(60 − 10)sin(60 + 10)
1 1 1  1
= sin 30 =   =
3 3 2  6
1
= 12k = 12  
6
=2