Assessment - 90 (Chemistry) S

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0.

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1. For H, rH  r3  r2    9  4
1
0.529
For Li2 , rLi2  r3  r2  9  4 
3
rH 3
 
rLi2 1

2. 2Cu2S  3O2 
 2Cu2 O  2SO2
Cu2O  FeS  FeO  Cu2 S
2FeS  3O2  2FeO  2SO2
FeO  SiO2  FeSiO3  Slag

4. This is a 3o and resonance stabilized carbocation.

5. Cumulated diene is least stable, evolve max heat in the hydrogenation reaction.

11. Number of revolution made by an electron per sec


 
 
vn 2Ze2
  
2rn   n2h2 
 nh  2  2  
  4mZe 
42mZ 2 e4 42me4  Z 2 
   
n3h3 h3  n3 
Z2 1
 3
 6.66  1015   6.66  1015
n 8
= 8.3 × 1014

13. Vapour pressure depends on temperature not on size of container.

14. There is no intermolecular forces of attraction in ideal gases.

16. 3A  B 
 2C
1 dA  d B  1 d C 
r    K   A B 
3 dt dt 2 dt
dA 
  3K   A B   K  A B
dt
i.e. K  3K 
d C  2
So that  2K   A B  = K  A B 
dt 3

17. KP  PCO2 , which will depends temperature of the system only.


+ -
18. Water will be neutral as [H ] = [OH ]

20. Zinc is more electropositive than silver therefore, it displaces less electropositive silver.

21. Carnalite is a double salt KCl.MgCl2.6H2O which give test of K+, Mg+2 and Cl.

22. 2Cu2  2CN  2Cu   CN2


3KCN
Cu   CN  CuCN   K 3 Cu  CN 4 

23. Mass number change only by -particles and atomic number reduces by 2 unit by each -particle
and increase by 1 unit by -particle.

27. CH 2OH CH 2OH


H O OH
OH O O
H OH
H H
OH OH
H H
H
H OH H OH
Galactose unit Glucose unit

28. The 1st step is electrophilic addition i.e. rate determining step, more stable will be the intermediate
better will be the rate of reactions.

29. O CH2OH
,dry HCl O O O
CH2OH
CH2 C OEt CH2 C OEt
O

LAH / THF

O
O O

CH2
H
CH2 OH  

CH2 CH2 OH  EtOH
H2 O

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