3602XX251 - Clearshield CSX 5000 GLOSS - WORLD - EN - 3 - REP265637

Safety data sheet in accordance with regulation (EC) No 1907/2006
Trade name: Clearshield CSX 5000 GLOSS

Version: 3 / Date revised: 19.06.2015
Substance number: 3602XX251 WORLD
Replaces Version: 2 / WORLD Print date: 24.06.16
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Clearshield CSX 5000 GLOSS
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/preparation
Liquid laminate
1.3. Details of the supplier of the safety data sheet
Address
Marabu North America
2460A Remount Road
29406 North Charleston, SC
Telephone no. 843-886-0094
Information provided Department product safety
by / telephone
E-mail address of [email protected]
person responsible
for this SDS
1.4. Emergency telephone number
CHEMTREC 703-527-3887 CCN5004
SECTION 2: Hazards identification ***

2.1. Classification of the substance or mixture
This product is not classified hazardous in accordance with Regulation (EC) No 1272/2008.
2.2. Label elements
Labelling according to regulation (EC) No 1272/2008
Hazardous component(s) to be indicated on label (Regulation (EC) No. 1272/2008)
EUH208 Contains A mixture of: 5-Chloro-2-methyl-2h-isothiazol-3-one [EC-no. 247-500-7] and
*** 2-Methyl-2H-isothiazol-3-one [EC-no. 220-239-6] (3:1),
1,2-Benzisothiazol-3(2h)-one, May produce an allergic reaction.
Supplemental information
**
*
EUH210 Safety data sheet available on request.

2.3. Other hazards
No special hazards have to be mentioned.
SECTION 3: Composition/information on ingredients ***

3.2. Mixtures
Chemical characterization
Water containing liquid laminate based on polyurethane
Hazardous ingredients ***
1,2-Benzisothiazol-3(2h)-one
CAS No. 2634-33-5
EINECS no. 220-120-9
Concentration < 0,05 %
Page 1(9)

Classification (Regulation (EC) No. 1272/2008)

Aquatic Acute 1 H400
Skin Sens. 1 H317
Acute Tox. 4 H302
Skin Irrit. 2 H315
Eye Dam. 1 H318
Acute Tox. 2 H330
Aquatic Chronic 2 H411
Concentration limits (Regulation (EC) No. 1272/2008)

Skin Sens. 1 H317 >= 0,05
A mixture of: 5-Chloro-2-methyl-2h-isothiazol-3-one [EC-no. 247-500-7] and
2-Methyl-2H-isothiazol-3-one [EC-no. 220-239-6] (3:1)
CAS No. 55965-84-9
Concentration < 0,0015 %
Classification (Regulation (EC) No. 1272/2008)

Acute Tox. 3 H331
Aquatic Chronic 1 H410
Aquatic Acute 1 H400
Skin Sens. 1 H317
Skin Corr. 1B H314
Acute Tox. 3 H311
Acute Tox. 3 H301
Concentration limits (Regulation (EC) No. 1272/2008)

Skin Corr. 1B H314 >= 0,6
Eye Irrit. 2 H319 <= 0,06 < 0,6
Skin Irrit. 2 H315 <= 0,06 < 0,6
Skin Sens. 1 H317 >= 0,0015
SECTION 4: First aid measures

4.1. Description of first aid measures
General information
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person. If unconscious place in recovery position and seek medical advice.
After inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, administer
artificial respiration.
After skin contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use recognised skin
cleanser. Do NOT use solvents or thinners.
After eye contact
Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart for at least 10
minutes and seek immediate medical advice.
After ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is conscious) and obtain
immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Until now no symptoms known so far.
4.3. Indication of any immediate medical attention and special treatment needed
Page 2(9)

Hints for the physician / treatment

Treat symptomatically
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Recommended: alcohol resistant foam, CO2, powders, water spray/mist, Not be used for safety reasons:
water jet
5.2. Special hazards arising from the substance or mixture
In the event of fire the following can be released: Carbon dioxide (CO2); Carbon monoxide (CO); dense
black smoke; Nitrogen oxides (NOx)
5.3. Advice for firefighters
Special protective equipment for fire-fighting
Cool closed containers exposed to fire with water. Do not allow run-off from fire fighting to enter drains or
water courses.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Avoid breathing vapours. Refer to protective measures listed in Sections 7 and 8.
6.2. Environmental precautions
Do not allow to enter drains or waterways. If the product contaminates lakes, rivers or sewage, inform
appropriate authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite,
diatomaceous earth and place in container for disposal according to local regulations (see section 13).
Clean preferably with a detergent - avoid use of solvents.
6.4. Reference to other sections
Information regarding Safe handling, see Section 7. Information regarding personal protective measures,
see Section 8. Information regarding waste disposal, see Section 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking
shall be prohibited in application area. For personal protection see Section 8. Never use pressure to
empty: container is not a pressure vessel. Always keep in containers of same material as the original
one. Comply with the health and safety at work laws. Do not allow to enter drains or water courses.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Store in accordance with national regulation
Hints on storage assembly
Store away from oxidising agents, from strongly alkaline and strongly acid materials.
Further information on storage conditions
Store between 15 and 30 °C in a dry, well ventilated place. Keep container tightly closed. No smoking.
Prevent unauthorised access. Containers which are opened must be carefully resealed and kept upright
to prevent leakage.
Page 3(9)

7.3. Specific end use(s)

Liquid laminate
SECTION 8: Exposure controls/personal protection

8.2. Exposure controls
Exposure controls
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local
exhaust ventilation and good general extraction.
Respiratory protection
Not applicable.
Hand protection
There is no one glove material or combination of materials that will give unlimited resistance to any
individual or combination of chemicals.
For prolonged or repeated handling nitrile rubber gloves with textile undergloves are required.
Material thickness > 0,5 mm
Breakthrough time < 30 min
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use, storage, maintenance and
replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/ chemical damage and poor
maintenance.
Barrier creams may help to protect the exposed areas of the skin, they should however not be applied
once exposure has occurred.
Eye protection
Use safety eyewear designed to protect against splash of liquids.
Body protection
Not applicable.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Form Pasty
Colour whitish
Odour odourless
Odour threshold
Remarks No data available
pH value
Remarks not determined
Melting point
Freezing point
Initial boiling point and boiling range
Value appr. 100 °C
Pressure 1.013 hPa
Source Literature value
Flash point
Value > 100 °C
Page 4(9)

Method ASTM D 6450 (CCCFP)

Evaporation rate (ether = 1) :
Flammability (solid, gas)
Not applicable
Upper/lower flammability or explosive limits
Vapour pressure
Vapour density
Density
Solubility in water
Remarks miscible
Partition coefficient: n-octanol/water
Remarks Not applicable
Ignition temperature
Viscosity
Remarks
Explosive properties
evaluation no
Oxidising properties
evaluation None known
9.2. Other information
Other information
The physical specifications are approximate values and refer to the used safety relevant component(s).
SECTION 10: Stability and reactivity

10.1. Reactivity
No hazardous reactions when stored and handled according to prescribed instructions.
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7).
10.3. Possibility of hazardous reactions
Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid
exothermic reactions.
10.4. Conditions to avoid
When exposed to high temperatures may produce hazardous decomposition products.
10.5. Incompatible materials
No hazardous reactions when stored and handled according to prescribed instructions.
10.6. Hazardous decomposition products
See chapter 5.2 (Firefighting measures - Special hazards arising from the substance or mixture).
Page 5(9)

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Aspiration hazard
No special hazards have to be mentioned.
Experience in practice
The liquid splashed in the eyes may cause irritation and reversible damage. This takes into account,
where known, delayed and immediate effects and also chronic effects of components from short-term
and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Other information
There are no data available on the mixture itself.
The mixture has been assessed following the conventional method of the Dangerous Preparations
Directive 1999/45/EC and not classified.
SECTION 12: Ecological information

12.1. Toxicity
General information
There are no data available on the mixture itself.Do not allow to enter drains or water courses.The
mixture has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is not classified as dangerous for the environment.
12.2. Persistence and degradability
General information
12.3. Bioaccumulative potential
General information
Partition coefficient: n-octanol/water
Remarks Not applicable
12.4. Mobility in soil
General information
12.5. Results of PBT and vPvB assessment
General information
12.6. Other adverse effects
General information
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Disposal recommendations for the product
Do not allow to enter drains or water courses.
Wastes and emptied containers should be classified in accordance with relevant national regulation.
The European Waste Catalogue classification of this product, when disposed of as waste is
EWC waste code 08 03 12* waste ink containing dangerous substances
Page 6(9)

If this product is mixed with other wastes, the original waste product code may no longer apply and the
appropriate code should be assigned.
For further information contact your local waste authority.
Disposal recommendations for packaging
Using information provided in this safety data sheet, advice should be obtained from the relevant waste
authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Not emptied containers are hazardous waste (waste code number 150110).
SECTION 14: Transport information

Land transport ADR/RID
Non-dangerous goods
14.1. UN number
UN -
14.2. UN proper shipping name
-
14.3. Transport hazard class(es)
Class -
Label -
14.4. Packing group
Packing group -
Transport category 0
14.5. Environmental hazards
-
Marine transport IMDG/GGVSee
The product does not constitute a hazardous substance in sea transport.
14.1. UN number
UN -
-
Class -
Subsidiary risk -
14.4. Packing group
Packing group -
no
Air transport ICAO/IATA
The product does not constitute a hazardous substance in air transport.
14.1. UN number
UN -
-
Class -
Subsidiary risk -
14.4. Packing group
Packing group -
-
Information for all modes of transport
14.6. Special precautions for user
Transport within the user's premises:
Always transport in closed containers that are upright and secure.
Page 7(9)

Ensure that persons transporting the product know what to do in the event of an accident or spillage.
Other information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
no
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance
or mixture
Other information
The product does not contain substances of very high concern (SVHC).
15.2. Chemical safety assessment
For this preparation a chemical safety assessment has not been carried out.
SECTION 16: Other information

Hazard statements listed in Chapter 3
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
CLP categories listed in Chapter 3
Acute Tox. 2 Acute toxicity, Category 2
Aquatic Acute 1 Hazardous to the aquatic environment, acute, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment, chronic, Category 1
Aquatic Chronic 2 Hazardous to the aquatic environment, chronic, Category 2
Eye Dam. 1 Serious eye damage, Category 1
Skin Corr. 1B Skin corrosion, Category 1B
Skin Irrit. 2 Skin irritation, Category 2
Skin Sens. 1 Skin sensitization, Category 1
Supplemental information
Relevant changes compared with the previous version of the safety data sheet are marked with: ***
This information is based on our present state of knowledge. However, it should not constitute a
guarantee for any specific product properties and shall not establish a legally valid relationship.
The information in this Safety Data Sheet is based on the present state of knowledge and current
legislation.
It provides guidance on health, safety and environmental aspects of the product and should not be
construed as any guarantee of technical performance or suitability for particular applications.
The product should not be used for purposes other than those shown in Section 1 without first referring
to the supplier and obtaining written handling instructions.
As the specific conditions of use of the product are outside the supplier’s control, the user is responsible
for ensuring that the requirements of relevant legislation are complied with.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risks, as required by other health and safety legislation.
Page 8(9)

Page 9(9)

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Safety data sheet in accordance with regulation (EC) No 1907/2006

Trade name: Clearshield CSX 5000 GLOSS

SECTION 1: Identification of the substance/mixture and of the

SECTION 2: Hazards identification ***

EUH210 Safety data sheet available on request.

SECTION 3: Composition/information on ingredients ***

Trade name: Clearshield CSX 5000 GLOSS

Classification (Regulation (EC) No. 1272/2008)

Concentration limits (Regulation (EC) No. 1272/2008)

Classification (Regulation (EC) No. 1272/2008)

Concentration limits (Regulation (EC) No. 1272/2008)

SECTION 4: First aid measures

Trade name: Clearshield CSX 5000 GLOSS

Hints for the physician / treatment

SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

SECTION 7: Handling and storage

Trade name: Clearshield CSX 5000 GLOSS

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

SECTION 9: Physical and chemical properties

Trade name: Clearshield CSX 5000 GLOSS

Method ASTM D 6450 (CCCFP)

SECTION 10: Stability and reactivity

Trade name: Clearshield CSX 5000 GLOSS

SECTION 11: Toxicological information

SECTION 12: Ecological information

SECTION 13: Disposal considerations

Trade name: Clearshield CSX 5000 GLOSS

SECTION 14: Transport information

Trade name: Clearshield CSX 5000 GLOSS

SECTION 15: Regulatory information

SECTION 16: Other information

Trade name: Clearshield CSX 5000 GLOSS

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