Classroom Contact Programme: Enthusiast SRG Test - 02

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CLASSROOM CONTACT PROGRAMME

TARGET : JEE (M + A) : 2023


ENTHUSIAST SRG TEST - 02
TEST TYPE: OFFLINE DATE : 29.05.2022 PATTERN : JEE ADVANCED
Time : 3 Hours Maximum Marks : 198

INSTRUCTIONS
READ THE INSTRUCTIONS CAREFULLY
QUESTION PAPER FORMAT AND MARKING SCHEME
1. The question paper has three parts : PHYSICS, CHEMISTRY and MATHEMATICS. Each part has THREE SECTIONS.
2. Carefully read the instructions given at the beginning of each section.
3. Section I(i): This section contains SIX questions. The Answer to each question is a ONE OR MORE THAN ONE CORRECT

OPTIONS.

Marking scheme : +4 for correct answer, 0 if not attempted and –2 in all other cases.

Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option.
4. Section II: This section contains SIX questions. The answer to each question is a NUMERICAL VALUE.
Marking scheme : +4 correct answer, 0 if not attempted and 0 in all other cases.
5. Section III: This section contains SIX questions. The answer to each question is a SINGLE DIGIT INTEGER.
Marking scheme : +3 for correct answer, 0 if not attempted and –1 in all other cases.
SOME USEFUL CONSTANTS
Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13,
P = 15, S = 16, Cl = 17,Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16,
F = 19, Na = 23, Mg = 24, Al = 27, P = 31, S = 32, Cl = 35.5,
Ca = 40, Fe = 56, Br = 80, I = 127, Xe = 131, Ba = 137,
Ce = 140,
Boltzmann constant k = 1.38 × 10–23 JK–1

Coulomb's law constant


��
Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
Speed of light in vacuum c = 3 × 108 ms–1
Stefan–Boltzmann constant = 5.67 × 10–8 Wm–2–K–4
Wien's displacement law constant b = 2.89 × 10–3 m–K
Permeability of vacuum µ0 = 4 × 10–7 NA–2

Permittivity of vacuum =
0

Planck constant h = 6.63 × 10–34 J–s

IIT(M + A) ENTHUSIAST SRG TEST 2022-23

TEST - 02 DATE: 29.05.2022

SYLLABUS
PHYSICS : Electrostatics
1.0 Electric charge 1.1 Specific Properties of Charge
1.2 Methods of Charging 2.0 Coulomb’s Law
2.1 Equilibrium of Charged Particles 3.0 Electric field
3.1 Electric Field Intensities due to Various Charge Distributions
3.2 Electric Field Strength at a General Point due to a Uniformly
Charged Rod 3.3 Electric Field due to a Uniformly Charged Ring
3.4 Electric Field Strength due to a Charged Circular Arc at its
Centre 3.5 Electric Field Strength due to a Uniformly Surface
Charged Disc 3.6 Electric Lines of Force 4.0 Electric flux
4.1 Electric Flux through a Circular Disc 4.2 Electric flux through
the Lateral Surface of a Cylinder due to a Point Charge
5.0 Gauss’s Law 5.1 Electric Field due to Solid Conducting
or Hollow Sphere 5.2 Electric Field due to an Infinite Line
Distribution of Charge 6.0 Dielectric in Electric field
7.0 Electric Potential 7.1 Electric Potential due to a Point Charge
in its Surrounding 7.2 Electric Potential due to a Charged Rod
7.3 Electric Potential due to a Charged Ring 7.4 Electric Potential
due to a Uniformly Charged Disc 7.5 Potential Difference between
Two Points in Electric Field 7.6 Electric Potential due to Hollow
or Conducting Sphere 7.7 Electric Potential due to Solid non
Conducting Sphere 7.8 Equipotential Surfaces 7.9 Electric Potential
Gradient 8.0 Electrostatic Potential Energy 9.0 Electric Dipole
9.1 Dipole Placed in Uniform Electric Field 9.2 Work done in
Rotation of a Dipole in Electric field 9.3 Force on an Electric
Dipole in Non-uniform Electric Field 9.4 Electric Potential due to
Dipole 9.5 Electric Field due to an Electric Dipole Friction,
Circular Motion
CHEMISTRY : Liquid Solutions, Stoichiometry (I & II), Chemical Equilibrium
MATHS : Functions, Sequence & Series
PART-1 : PHYSICS
SECTION–I(i) : (Maximum Marks : 24)
� This section contains SIX questions.
� Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these
four option(s) is (are) correct option(s).
� For each question, choose the correct option(s) to answer the question.
� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
� For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result in +4
marks. Selecting only two of the three correct options (e.g. the first and fourth options), without
selecting any incorrect option (second option in this case), will result in +2 marks. Selecting only
one of the three correct options (either first or third or fourth option), without selecting any incorrect
option (second option in this case), will result in +1 marks. Selecting any incorrect option(s) (second
option in this case), with or without selection of any correct option(s) will result in –2 marks.
1. The electric potential in a region of space varies with its x, y and z co-ordinates as


V � x, y, z � � A x 2 � 2y 2 � z 2 � where A is a constant. Then choose the correct option(s):
(A) Locus of equipotent curve in a plane parallel to x-z plane is hyperbola
(B) Locus of equipotent curve in a plane parallel to x-z plane is circle
(C) Locus of equipotent curve in a plane parallel to x-y plane is parabola
(D) Locus of equipotent curve in a plane parallel to x-y plane is hyperbola

Space for Rough Work


2. An electric dipole of dipole moment ‘p’ is kept at the origin along ‘x’ axis and is fixed. A bead of mass
‘m’ and charge ‘q’ can slide on a fixed smooth rod kept along line x = c. Bead is given a gentle push so
that it starts moving along +y direction from point P as shown. Whole arrangement is kept in gravity
free space. (Given ‘c’ is very large in comparison to length of the dipole).

p P q, m

(A) A co-ordinate of point where normal force between bead and the rod is zero is c, � 2c �
(B) Speed of the bead where the normal force between the bead and the rod is zero is

pq � 1 �
�1 � �
2�� 0 mc 2 � 3 3�
(C) Acceleration of the bead where the normal force between the bead and the rod is zero is
pq
12 3 ��0 mc3

pq
(D) Normal force between the bead and the rod at point P is 2�� c3
0

Space for Rough Work


3. A particle of weight W rests on a rough fixed inclined plane that makes an angle � with the horizontal,
as shown in figure. If the coefficient of static friction � � 2 tan �. A horizontal force H is acting
transverse to the slope of the plane (see figure)

(A) If H � 2 3 W sin � the particle will move on the incline plane


(B) If H = 0.5 W sin � the particle will move on the incline plane
(C) If H � 3 W sin � the direction � in which the block can goes, relative to H is 30°
(D) If H = 0.5 W sin � the direction � in which the block can goes, relative to H is 60°
4. A short electric dipole of dipole moment p is placed at centre of a cylindrical gaussian surface of length
� � 2R and radius R. Net electric flux linked with
(A) The curved surface will be zero if the dipole is placed along axis of the cylinder
(B) The curved surface will be zero if the dipole is placed perpendicular to the axis
�p
(C) One of the plane surface is if the dipole is placed along the axis
4 2�0 R

�p
(D) One of the plane surface is if the dipole is placed perpendicular to the axis
2�0 R

Space for Rough Work


5. Three point positive charges each of charge ‘q’ are placed as shown. Select correct alternative/s:
B

q a
A
C
q
E
D
a q a
F

q
(A) Electric flux passing through CDEF is 8�
0

q
(B) Electric flux passing through CDEF is 24�
0

(C) Electric potential at point C is less than potential at point D


(D) Electric potential at point C is more than potential at point D
6. A non conducting uniform thin shell of mass m and radius R is having uniform charge density �� on
one half and �� on another half as shown in figure. It is placed on a rough non conducting horizontal
��
plane. At t = 0 a uniform electric field E � � E �j N/C is switched on and the solid sphere starts rolling
0
without slipping. Then which of the following is/are correct.
y

53�

36 ��E 0 R 2
(A) The acceleration of the topmost point of the hollow sphere at t = 0, is
25 m
18
(B) The magnitude of frictional force at t � 0 is ��E 0 R 2
25
12
(C) The acceleration of centre of mass of the hollow sphere at t = 0, is ��E 0 R 2
25
9
(D) The magnitude of frictional force at t = 0 is ��E 0 R 2
25
Space for Rough Work
SECTION-II : (Maximum Marks: 24)
� This section contains SIX questions.
� The answer to each question is a NUMERICAL VALUE.
� For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777.....
then both 11.36 and 11.37 will be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.

+ – + –
0 0 0 0 0 0 0 0 0 0 0 0
1 1 1 1 1 1 1 1 1 1 1 1
2 2 2 2 2 2 2 2 2 2 2 2
3 3 3 3 3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4 4 4 4 4
5 5 5 5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9 9 9 9 9

� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
7. The figure shows the velocity (v0) and acceleration (a) of a point like body at the initial moment of its
motion. The acceleration vector of the body remains constant. The minimum radius of curvature is
trajectory of the body in metre is

v 0 � 16 m/s
� � 150�

a � 4 m/s 2

8. A thin circular loop of radius R rotates about its vertical diameter with a constant angular velocity
g
��2 . A small bead of mass m is initially at lowest point of the loop and it is given a gentle push on
R
one of the side. What will be the maximum angle (in degree) made by the radius vector joining the
centre of the loop to the small bead in the loop with vertical downward direction. (Neglect friction)
� �
9. Assume that an electric field E � 40x 3 i N / C exists in space. The charge density at x = 2m is

z�0 c/m3 then find value of z


Space for Rough Work
2�
10. A point charge ‘q’ is placed at a distance (on the y-axis) vertically above the x-z plane. The flux
3
of electric field passing through the triangular plate which lies in the x-z plane as shown in figure, is
q
. Find the value of m.
10m�0

y � 2� �
q �� 0, , 0 ��
� 3 �

O x
B ��, 0, 0�
� � 3 �
�� � ,0, � �� A
� 2 2 �

11. Two charged particle (m, q) and (2m, –2q) are placed in a gravity free space where a uniform electric
field E exists as shown in figure. After the particles are released they stay at a constant distance from
each other. What is the distance between them in meter? (Neglected the gravitational interaction).
kq 27
(K is electrostatic constant and take � )
E 8
E

��2q,2m � �q,m �
12. A non-conducting shell of radius R carrying charge Q, (Uniformly distributed over surface) another
charge Q is placed at 3R distance from centre of shell. If the potential at point P inside the shell is
14 KQ
, Then the value of 20n is
2n R

3R
R

O P Q
R /2

Space for Rough Work


SECTION-III : (Maximum Marks: 18)
� This section contains SIX questions.
� The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
� For each question, darken the bubble corresponding to the correct integer in the ORS.
� For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : –1 In all other cases.
13. A non-conducting rod AB of length 5m. having uniformly distributed charge of charge density 10�3 c / m is
kept in x-y plane as shown. Electric field at orgin due to rod is directed along the line OC. If line OC
makes an angle � � �10a � b � degree with positive x-axis as shown. Find the value of (a+b). (a & b
are positive integers)
Y

C
B � X
O

� 37�

14. For what value of P following electrostatic field is possible to exist in a space.
� � �
E � Px 2 y i � 2x 3 j
15. A particle P is moving on a circle under the action of only one force, which always acts towards a fixed
2
d2� � d� �
point O lying on the circumference. Find ratio of to � � at the moment when � � 45�.
� dt �
2
dt
(C is centre of circle)
P


O
C

Space for Rough Work


16. Two point charges q and –q are fixed in space at separation a. The electric flux through infinite plane
a 2q
perpendicular to line joining the charges at a distance from +q is . Find the value of k.
3 k� 0

�q �q

a 2a
3 3

17. Consider a rectangular prism with cross section of a right angled triangle as shown. Co-ordinates of

vertices are A, B, C, D and E are � ��


2,0,0 , �� �� �
2, 2,0 , 0, 2, 2 , 0,0, 2 and 0, 2,0 � �
� � �
respectively. If there is a electric field x i � 2y j � k N/C everywhere. If charge enclosed by the
10N
prism is N��0 then, find the value of . (use 2 � 1.4)
17

y
E
B
xy
C
y
O x
A

Z D

18. There are two non-conducting centric hollow spheres of radii a and 2a respectively. The inner shell
has net charge Q on its surface. The outer shell inner surface has –Q and outer surface has +Q
charge. The total energy of the system is U. If the outer shell outer surface charge is removed than
change in the magnitude of total energy is U/x. Find x. (All the changes and uniformly distributed over
surface)
Space for Rough Work
PART-2 : CHEMISTRY
SECTION–I(i) : (Maximum Marks : 24)
� This section contains SIX questions.
� Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these
four option(s) is (are) correct option(s).
� For each question, choose the correct option(s) to answer the question.
� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
� For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result in +4
marks. Selecting only two of the three correct options (e.g. the first and fourth options), without
selecting any incorrect option (second option in this case), will result in +2 marks. Selecting only
one of the three correct options (either first or third or fourth option), without selecting any incorrect
option (second option in this case), will result in +1 marks. Selecting any incorrect option(s) (second
option in this case), with or without selection of any correct option(s) will result in –2 marks.
1. Which of the following is NOT a balanced chemical reaction
(A) 2MnO 4– � H 2 O 2 � 6H � � 2Mn �2 � 3O 2 � 4H 2 O

(B) 3P4S3 � 38NO 3– � 8H 2 O � 20H � � 12H 3 PO 4 � 9SO 4–2 � 38NO

(C) 5SO3–2 � 2MnO 4– � 6H � � 5SO 4–2 � 2Mn �2 � 3H 2O


(D) K 2 Cr2 O 7 � 14HCl � 2KCl � 2CrCl3 � 3Cl2 � 7H 2 O
2. Following two equilibria are established on mixing two gases A2 and C.
(i) 3A 2 (g) � A 6 (g), K p � 1.6 atm –2
(ii) A 2 (g) � C(g) � A 2 C(g)
A2 and C are mixed 2 : 1 molar ratio in seal container at a constant temperature. If the total pressure
of the reaction mixture is given to be 1.4 atm and partial pressure of A6 to be 0.2 atm at equilibrium,
then identify the correct statements (s) of the following:
(A) Equilibrium partial pressure of A2(g) is 0.5atm
(B) Equilibrium partial pressure of ‘C’ is 0.4 atm
(C) Equilibrium partial pressure of A2C (g) is 0.3 atm
(D) KP of reaction (ii) is 1.5 atm–1
Space for Rough Work
3. Which of the following statement is/are correct ?
(A) CrI3 � KOH � Cl2 ��
� K 2 CrO 4 � KCl � KIO 4 � H 2 O
In the balanced chemical reaction, stiochiometric, coefficient of KOH is 64.

(B) (NH 4 ) 2 Cr2 O 7 �� � N 2 � Cr2 O3 � 4H 2 O
n factor of (NH4)2 Cr2O7 is 12

� Fe(CN)6 � � Fe3� � CO 2 � NO3–


��
3–
(C)

n–factor for � Fe(CN)6 �


3–
is 60

(D) MnO 42– ��
H
� MnO 4– � MnO 2
Eq.wt. of MnO 2–
4
is 178.5 (if Atomic mass of ‘Mn’ is 55)
4. A dilute solution contains ‘m’ mol of solute A in 1 kg of a solvent with molal elevation constant Kb. The
solute dimerises in solution as:
2A � A 2
Select the correct expression of equilibrium constant ‘K’ for the dimer formation (Assume molarity =
molality) [� = degree of dimerisation of ‘A’]
K b (K b m – �Tb ) �
(A) K � (K m � 2�T ) 2 (B) K � 2m(1 – �)2
b b

K b (K b m – �Tb ) 2(K b m – �Tb )


(C) K � (2�T – K m) 2 (D) K � Kb m
b b

Space for Rough Work


5. Consider the following graph and choose the correct option:

P 0B

Vapour Pressure of Benzene


Vapour Pressure of Toulene
E

C F
A
D
P 0T

O 1
Mole fraction of Benzene

(A) A represent vapour composition and B represent liquid composition


(B) At the state E of the system the vapour phase start forming and its vapour phase composition will
correspond to the point C
(C) At the state C of the system the vapour phase just start forming its vapour phase composition will
correspond to the point D
(D) A and B both represent vapour composition.
6. If for an equation like N2O2(g) � 2NO2(g), the �G (reaction) expression given is

�� P 2 NO2 ��
�G = 4.73 KJ mol + 2.5 KJ mol
–1 –1 �n � � then
� PN2O4 �
(A) If small amount of N2O4 is introduced in a closed container, then reaction moves in forward
direction spontaneously
(B) Initially �G° value is negative for the given decomposition
� – �G � �
(C) A equilibrium, QP = KP = antilog �
� RT ��
(D) The reaction can proceed in any direction even if mole fraction of N2O4 is large at any given point
in reaction

Space for Rough Work


SECTION-II : (Maximum Marks: 24)
� This section contains SIX questions.
� The answer to each question is a NUMERICAL VALUE.
� For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777.....
then both 11.36 and 11.37 will be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.

+ – + –
0 0 0 0 0 0 0 0 0 0 0 0
1 1 1 1 1 1 1 1 1 1 1 1
2 2 2 2 2 2 2 2 2 2 2 2
3 3 3 3 3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4 4 4 4 4
5 5 5 5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9 9 9 9 9

� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
7. Henry’s law constant for O2 and N2 dissolved in water at 273 K are 2.0 × 108 Pa and 5.0 × 108 Pa,
respectively. A sample of water at a temperature just above 273 K was equilibrated with air (21%
oxygen and 79% N2) at 1 bar. The dissolved gas was separated from a sample of this water and then
dried. Determine the composition of N2 in percentage.(1 bar = 105 Pa)
8. For equilibrium
LiCl.3NH2 (s) � LiCl.NH3 (s) � 2NH3 (g), KP = 16 atm2 at 27°C. A 5 litre vessel contains 0.2 mole of
LiCl. NH3(s). How many moles of NH3 should be added to the flask at this temperature of drive the
backward reaction to completion: [R = 0.08 litre atm mol–1 K–1]
9. The chromium in a 1.0 g sample of chromite (FeCr2 O4) was oxidized to Cr+6 state by fusion with
Na2O2. The fused mixture was treated with excess of water and boiled to destory the excess of
peroxide. After acidification, the sample was treated with 50 mL of 0.16 M FeSO4 solution. 3.67 mL
of 0.05 M Cr2O72– solution was required to oxidize the Fe2+ ion left unreacted. Determine the mass %
of chromite in the original sample [Cr=52, Fe= 56]
10. 3.6 gm of Mg is burnt in limited supply of oxygen. The residue was treated with 100 ml of H2SO4
(35% by mass, 1.26g/ml density), 2.463 litre of H2 at 760 mm Hg at 27°C was evolved. Assume
MgSO4 is completely soluble. Find the % of mass of final H2SO4 .
(At wt. of Mg = 24; R = 0.0821 lit atm mol–1 K–1)
Space for Rough Work
11. The following equilibrium constant were determined at 1120 K:
2CO(g) � C(s) � CO 2 (g) ; K P1 � 10 –14 atm –1

CO(g) � Cl 2 (g) � COCl 2 (g) ; K P2 � 6 � 10 –3 atm –1


The equilibrium constant KC for the following reaction at 1120 K is 3.31 × 10x M–1.
C(s) � CO 2 (g) � 2Cl2 (g) � 2COCl 2 (g)
Then find the value of ‘x’ ?
12. An aqueous solution containing 5% by weight of urea and 10% by weight of glucose. What will be the
�Tf of solution ? K’f for H2O is 1.86 K mol–1 kg

SECTION-III : (Maximum Marks: 18)


� This section contains SIX questions.
� The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
� For each question, darken the bubble corresponding to the correct integer in the ORS.
� For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : –1 In all other cases.

13. 1.3245 g of monobasic acid when dissolved in 100 g of water lowers the freezing point by 0.2046°C.
N
0.2 g of the same acid when dissolved and titrated required 15.1 ml of alkali.
10
(Assuming molarity = molality) the pH of acid solution is (Kf of water 1.86 K kg mol–1)
14. A definite amount of solid NH4HS is placed in a flask already containing ammonia gas at a certain
temperature and 0.1 atm pressure. NH4HS decomposes to give NH3 and H2S and at equilibrium the
total pressure in flask is 1.1 atm. If the equilibrium constant KP for the reaction
NH4HS(s) � NH3 (g) + H2S(g) is represented on z×10–1 then z = ?
15. A 50 ml 1.92% (w/v) solution of a metal ion Mn+ (at.wt = 60) was treated with 5.332g hydrazinehydrate
(N2H4 . H2O) (90% pure) and the mixture was saturated with CO2 gas when entire metal gets precipi-
tated as a complex [M(NH2–NHCOO)n] the complex was filtered of and the filtrate was titrated with
M/10 KIO3 in the presence of conc. HCl according to the following equation
N2 H4 +IO3– � 2H � � Cl – � ICI � 3H 2 O � N 2 � .
The volume of M/10 KIO3 solution needed for end point to arrive was 480 ml. Find the value of n.

Space for Rough Work


16. How many of following mixture(s) show(s) minimum boiling azeotrope :
1. Acetone and benzene
2. Aceone and carbon disulphide
3. Acetone and ethanol
4. Acetone and aniline
5. Carbon tetra chloride and silicon tetra chloride
6. Carbon tetra chloride and chloroform
7. Benzene and chloroform
8. Diethyl ether and chloroform
9. n-butyl chloride and n-butyl bromide
17. Pressure over an ideal binary liquid - mix containing 10 moles each of liquid (A) and liquid (B) is
gradually decreases isothermally, and PA0 = 200 mm Hg and PB0 � 100 mm Hg.
If pressure at which, half of the total amount of liquid mixture will get converted into vapour is ‘X’ mm
� X � 41.6 �
Hg then determine the value of �
� 100 ��
18. A compound ‘A’ in aqueous phase dissociates to form unknown number of moles of gaseous products.
Find the number of moles of gaseous products formed per mole of ‘A’ reacted if Kp of the reaction is
2
the reaction is 8 and KC = 2 at temperature of Kelvin (Where R = gas constant)
R

Space for Rough Work


PART-3 : MATHEMATICS
SECTION–I(i) : (Maximum Marks : 24)
� This section contains SIX questions.
� Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these
four option(s) is (are) correct option(s).
� For each question, choose the correct option(s) to answer the question.
� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen,
both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 In all other cases.
� For Example : If first, third and fourth are the ONLY three correct options for a question with
second option being an incorrect option; selecting only all the three correct options will result in +4
marks. Selecting only two of the three correct options (e.g. the first and fourth options), without
selecting any incorrect option (second option in this case), will result in +2 marks. Selecting only
one of the three correct options (either first or third or fourth option), without selecting any incorrect
option (second option in this case), will result in +1 marks. Selecting any incorrect option(s) (second
option in this case), with or without selection of any correct option(s) will result in –2 marks.
1. Let A � �1, 2,3,4,5,6� . Suppose

� 6

S1 � �f : A � A | � f � i � is even,i � A �
� i �1 �

S2 � �f : A � A | f �1� � f � 2 � � f � 6 ��

S3 � �f : A � A | f � i � � f � j� fori � j wherei, j� A�
[Note: f : A � A denotes function from A � A and n(S) is number of elements in set S] Then
(A) n �S1 � � n � S3 � (B) n �S2 � � n �S1 �
(C) n � S3 � � n � S2 � (D) n �S1 � � n � S2 �

Space for Rough Work


2. Let f � x � �

� sin � �x � � ln x � x 2 � 1 � is defined for x ����, �� . Consider the sets A and B as fol-
x � cos � �x � � x
2 3

lows:
A � �� : f � � � � f � x � �x � � ��, ���
B � �� : f � � � � f � x � �x � � ��, � ��

Let � � S� and � � S� denotes number of elements and sum of elements of set ‘S’ respectively. Then the
FALSE statements are:
(A) � � A � � � � B � � 0 (B) � � A � � � � B � � 0
(C) � � A � � � � B� � 3 (D) � � A � � � � B � � 0

� x � ��� x � e � � � x � e �� x � 1� � � x � 1�� x � � �
Let f � x � � . If f1 � x � � f � x � and
�1 � ���1 � e � � � � e �� � � 1� � e � 1�� e � � � �x � R
3.

f n �1 � x � � f � f n � x � � �n � 1, n � N . Then which among below is TRUE?

(A) f 2022 � x � � 2023 has 2024 real roots


20 30

(B) � f �k� � � f �k�


k �10
30
k � 20
10

(C) There are infinitely many real x such that f10 � x � ,f15 � x � , f17 � x � are in A.P..
(D) There are infinitely many real x such that f10 � x � ,f15 � x � , f17 � x � are in G.P..

Space for Rough Work


1 3 5 223
4. Let R � � � � .... �
2 4 6 224
2 4 6 224
S � � � � .... �
3 5 7 225
Then the TRUE relation between R and S is
1 1
(A) R � (B) S �
15 17
(C) R � S (D) R � S
f �x� g�x�
Let f ,g : � � � be two functions such that e x � f x � e x � g x �x � � . Which of the following
5.
� � � �
holds true?
(A) f � x � � g � x � must be true �x � � (B) f � x � � g � x � may not true �x � �
(C) f � i � � g � i � for all i ��0,2,4,6� (D) f � i � � g � i � for all i ��1,3,5,7�


Let f � x � � �1 � x � �1 � x ��1 � x � ... 1 � x
�8 �
�... �x � �0,1� . Then the correct statements are:(Here
k
8 64
6.

f–1 denotes inverse function)

� � � �
� 5 � 16 � � 625
� �� 5
(A) f �1
(B) f �1
� ��
� � 2 � � 4 � � 625 � � 2 � � 4 � � 16
� 3f � 5 � f � 25 � � � 3f � 5 � f � 25 � �
� � � � �� � � � � ��

� 1� � 1� �1� �1� � 1� � 1 �
(C) f � � f � � f � � � 2 (D) f � � f � � f � � � 2
� 2� � 4� �8� � 2 � � 4 � � 16 �

Space for Rough Work


SECTION-II : (Maximum Marks: 24)
� This section contains SIX questions.
� The answer to each question is a NUMERICAL VALUE.
� For each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to
the second decimal place; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777.....
then both 11.36 and 11.37 will be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.

+ – + –
0 0 0 0 0 0 0 0 0 0 0 0
1 1 1 1 1 1 1 1 1 1 1 1
2 2 2 2 2 2 2 2 2 2 2 2
3 3 3 3 3 3 3 3 3 3 3 3
4 4 4 4 4 4 4 4 4 4 4 4
5 5 5 5 5 5 5 5 5 5 5 5
6 6 6 6 6 6 6 6 6 6 6 6
7 7 7 7 7 7 7 7 7 7 7 7
8 8 8 8 8 8 8 8 8 8 8 8
9 9 9 9 9 9 9 9 9 9 9 9

� Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
7. Define the functions, N, I, C, E as follows:
N � x � � 24x
I � x � � 12x 2 � 12x
C � x � � 4x 3 � 12x 2 � 8x
E � x � � x 4 � 6x 3 � 11x 2 � 6x
10 � N �k � � I�k � � C�k � � E �k� �
Compute ��
k �1 �
11 �
C 2 � 12 C3 � 13 C4 � 14 C 5 �

Space for Rough Work


8. The number of real values of x satisfying the equation 2022�x � � 2022�x� � 2.2022x / 2 is
(where [.] denotes greatest integer function and {.} is fracitonal part function)
1
9. Consider f � n � �
2021 � 2021
n

2
� 2021 �
compute � � f � n � �
� n � �2020 �

Let f � x � � x � ax � � b � k � x � � c � k � . Suppose a,b,c forms geometric progression with non–zero


3 2 2 4
10.
common ratio k and the roots of f(x) are non–zero which forms arithmetic progression with common
difference k. Then k is––––––
� �
1
11. If A � �
1 B�� Then
A
equals ––––
� 2n � 1� � 2n �
4 4
n �1 n �1 B

12. Let �a i � be a sequence of positive real numbers satisfying a1= 9 and a �na�n1�ln an � � a �nan � for all positive

1
integers n. If k � �
1
. Then k is –––––
a
n �1 n
e

Space for Rough Work


SECTION-III : (Maximum Marks: 18)
� This section contains SIX questions.
� The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
� For each question, darken the bubble corresponding to the correct integer in the ORS.
� For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : –1 In all other cases.
13. Let f : A � A be a bijective function on set A � �1, 2,3, 4,5,6,7� . Define
7
S � � max �f �1� , f � 2 � ,f � 3� ,....f � n �� . Let N be number of functions f such that S = 47.
n �1

[Here max(a, b, c...) is maximum among a, b, c,....] Then sum of digits of N is


22
14. Let f : � � Q (rational) be a continuous function with f � � � � and
7
2022

2f � x � sin � cos x � � � f � x � � f � cos � sin x � � �x � � . Then � � x � i � x � i � 1 � � f � x � has exactly


i �1

N real roots, N equals ––––––––

15. Let f : N � N and x 2 � x1 � f � x 2 � � f � x1 � �x1 , x 2 � N .If f � f � n � � � 3n �n � N. Then f(2) is ––––

Space for Rough Work


16. Consider the following functions:
A � x � : � � �;A � x � � sin � x � cos x �

L1 � x � : N � �;L1 � x � � sin x

x3 x 2
L2 � x � : � � �;L 2 � x � � � � x � cos x � 1
3 2

E � x � : � � �;E � x � � 10sin x � x

N � x � : � � �; N � x � � x � x � sin x �
Then the number of correct statements among following is:
(1) L1 � x � is many–one

(2) � : � � �, � � x � � A � x � L 2 � x � E � x � N � x � is many–one function


(3) A(x) is periodic
(4) L2(x) is bijective
(5) N(x) is one–one
(6) N(x) is onto

��� x � , x � � �2, �1�


f �x� � �
� x � 1, x � � �1, 2�
17.

��� x � , x � � ��,0 �
g�x� � �
�sin x, x � � 0, ��

The number of integral points in the range of g � f � x � � is ––––––––––


18. Consider the following function f : � � � such that f(1) = 1 and
f � x � y � � 2022 x f � y � � 2023y f � x � �x, y � � .Suppose K ��2,3, 4,5, 6,7,8, 9,10� the number of K

for which f � x � � K x has exactly one real solution in x is ––––––


Space for Rough Work

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