SAFETY DATA SHEET

No. SDS : P-442

Revision : 01
Effective Date : 28/03/2023

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : PUH-21 LY FD
Product use : Hardener
Manufacture’s Name : PT. PROPAN RAYA ICC
Address : JL. GATOT SUBROTO KM 6.5 JATAKE
TANGERANG 15136 BANTEN - INDONESIA
TELP. : + 62-21-5919577 (HUNTING)
FAX. : + 62-21-5919022/24/25
E-mail : + [email protected]

2. HAZARD IDENTIFICATION REGULATION (EC) No. 1272/2008

SYMBOL REQUIRED FOR LABEL
Flammable (F) Harmful (Xn) Irritant (Xi) Toxic (T)

Hazard statements : Highly flammable liquid and vapour – H225

Causes skin irritation – H315
May cause drowsiness or dizziness – H336

Precautionary statements : Keep away from heat, sparks, open flames and/or hot surfaces.
No smoking. -P210
Keep container tightly closed. -P233
Keep cool -P235
Ground and/or bond container and receiving equipment. -P240
Use explosion-proof -electrical, ventilating and/or lighting equipment. -P241
Prevention : Use only non-sparking tools -P242
Take precautionarymeasures againts static discharge. -P243
Avoid breathing dust, fume, gas, mist, vapours and/or spray. -P261
Wash thoroughly after handling. -P264
Use only outdoors or in a well-ventilated area. P-271
Wear protecttive gloves/protective clothing/eye protection/face protection. -P280
Response : In case of fire : Use appropriate media for extinction. -P370+P378
IF INHALED :Remove victim to fresh air and keep at rest in a position comfortable for
breathing. -P304+P340
Call a Poison Center or doctor/physician if you feel unwell. -P312
IF ON SKIN : Wash with plenty of soap and water. -P302+P352
Rinse skin with water/shower. -P353
Take off contaminated clothing and wash before reuse. -P362
If skin irritation occurs: Get medical advice/attention. -P332+P313
Specific treatment, see supplemental first aid information. -P321
Storage/Disposal : Dispose of content and/or container in accordance with local, regional. National,
and/or international regulations. -P501
Store in a well-ventilated place. Keep container tightly closed. -P403+P233

WARNING
Clear liquid. Can cause eye and skin irritation upon contact. Inhalation of vapors can cause anesthetic effect leading
to death in poorly ventilated areas.
PROTECTIVE MEASURES
Avoid contact with the skin, eyes and wear proper skin protection.

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3. INGREDIENTS
% max
INGREDIENT COMPONENTS CAS # EINECS #
(by weight)
Poly HDI 20 11132-83-5 -
Poly TDI 40 528598-79-0 -
Xylene 20 1330-20-7 215-535-7
Ethyl Acetate 20 141-78-6 205-500-4

4. FIRST AID MEASURES

GENERAL
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
EYES
Remove contact lenses. Flush eyes with clear running water for 15 minutes while holding eyelids open; if irritation
persists, seek medical attention.
SKIN
Remove contaminated clothing; wash affected area with soap and water; launder contaminated clothing before
reuse; if irritation persists, seek medical attention.
INGESTION
Give two glasses of water for dilution; induce vomiting by sticking fingers down throat; never give anything by
mouth to an unconscious person; seek medical attention.
INHALATION
Remove affected person to fresh air; provide oxygen if breathing is difficult; if affected person is not breathing,
administer CPR and seek emergency medical attention.

5. FIRE FIGHTING MEASURES

GENERAL HAZARDS
Product is flammable. Products of combustion include compounds of carbon, hydrogen and oxygen, including
carbon monoxide.
EXTINGUISHING MEDIA
Carbon dioxide, water fog, dry chemical, chemical foam.
FIRE FIGHTING PROCEDURES
Self - contained respiratory equipment; cool containers to prevent pressure buildup and explosion when exposed to
extreme heat. Caution - material is flammable.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Closed containers can explode due to buildup of pressure when exposed to extreme heat. Vapors may cause a
flash fire or ignite explosively. Vapors may travel a considerable distance to a source of ignition and flash back.
HAZARDOUS COMBUSTION PRODUCTS
Smoke, fumes, oxides of carbon.

6. ACCIDENTAL RELEASE MEASURES

STEP TO BE TAKEN IN CASE MATERIAL IS RELEASE OR SPILLED: CAUTION - FLAMMABLE - Evacuate
and ventilate area; confine and absorb into absorbent; place material into approved containers for disposal; do
not discharge into lakes, ponds, streams, or public waters.

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7. HANDLING AND STORAGE

PRECAUTION TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect
containers from abuse; protect from extreme temperatures. CAUTION - FLAMMABLE - keeps away from all sources
of ignition. “Empty” containers may contain residue, which may form explosive vapors. Do not weld or cut near
empty container that has not been professionally reconditioned. Use non-sparking tools when opening and closing
containers. Maintain well-ventilated work areas to minimize exposure when handling this material.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

NIOSH ACGIH
HAZARDOUS COMPONENTS TWA TWA STEL STEL TWA TWA STEL STEL
ppm mg/m3 ppm mg/m3 ppm mg/m3 ppm mg/m3
Poly HDI - - - - 0.005 0.035 - -
Poly TDI - - - - 0.005 0.035 - -
Xylene 100 435 150 655 100 - 150 -
Ethyl Acetate 400 - - - 400 - - 400
VENTILATION SYSTEM
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the
contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual of Recommended practices, most recent edition, for details. Use
explosion-proof equipment.
PERSONAL RESPIRATORS (NIOSH APPROVED)
If the exposure limit is exceeded, a half-face organic vapor respirator may be worn for up to ten times the exposure
limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. A full-face piece organic vapor respirator may be worn up to 50 times the exposure limit or the
maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is
lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-
pressure, air-supplied respirator. Warning: Air-purifying respirators do not protect workers in oxygen-deficient
atmospheres.
SKIN PROTECTION
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent
skin contact.
EYE PROTECTION
Maintain eye wash fountain and quick-drench facilities in work area. Use chemical safety goggles and/or full-face
shield where dusting or splashing of solutions is possible.
WORK/HYGIENIC PRACTICES
Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Clear Liquid
Flash Point : 26°C
Odor : Mild
Solubility : Not dilutable in water
PH : -
Specific gravity : 0.98 ± 0.02 g/cc

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10. STABILITY AND REACTIVITY

STABILITY CONDITION TO AVOID
Product is stable under normal operating and Extreme temperatures, open flames, spark.
storage conditions.
INCOMPATIBILITY (MATERIAL TO AVOID): water, strong oxidizers, strong acids, strong alkalis.
HAZARDOUS DECOMPOSITION OR BY PRODUCTS: Decomposition will not occur if handle and stored properly.
In case of a fire, oxides of carbon, hydrocarbons, fumes, and smoke may be produced.
HAZARDOUS POLYMERIZATION CONDITION TO AVOID
Will not occur. None

11. TOXICOLOGY INFORMATION

LD50 of Ingredient LC50 of Ingredient Hazard RISK PHRASES
Hazardous Components
(Specify Species and Route) (Specify Species) Symbol Full Text Section 16
Hexamethylene di- >5000 mg/kg R-20, 36/37/38, 40,
- T, Xn
isocyanate (HDI) Oral - rat 42/43,
>2000 mg/kg 110 mg/m3/4H R-20, 23, 26, 36/37/38,
di-isocyanate toluene (TDI) T, Xn
Oral – rat Inhalation - rat 40, 42/43, 52/53
>2000 mg/kg >5000 ppm/1H
Xylene F, Xn R-10, 20/21, 38
Oral - rat Inhalation - rat
45 g/m³/2 H
Ethyl Acetate 5620 mg/kg oral-rat F, Xi R-11, 36, 66, 67
inhalation-mus
INHALATION
The inhalation of solvent vapor or dust spray may cause irritation of the respiratory tract.
SKIN CONTACT
These components of the preparation have irritating properties. Prolonged or repeated contact with skin or mucous
membrane may result in irritation symptoms such as redness, blistering, dermatitis, etc cases of allergic skin
reactions have been observed.
EYE CONTACT
The liquid splashed in the eyes may cause irritation.
IGNESTION
Ingestion may cause nausea, weakness and central nervous system effects.

12. ECOLOGICAL INFORMATION

No data are available on the adverse effects of this material on the environment. Neither COD nor BOD data are
available. Based on the chemical composition of this product it is assumed that the mixture can be treated in an
acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be
evaluated and approved for each specific biological system. The preparation has been assessed following the
conventional method of the Dangerous Preparations Directive 1999/45/EC and is classified for eco - toxicological
properties accordingly. See section 2 and 15 for details.

13. DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product
may produce hazardous vapors or fumes in a closed disposal container creating a dangerous environment. Refer to
“40 CFR Protection of Environment Parts 260-299” for complete waste disposal regulations. Consult your Local,
State, or Federal Environmental Protection Agency before disposing of any chemicals. Do not flush to sanitary sewer
or waterway.

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14. TRANSPORT INFORMATION

Proper Shipping Name : Paint
DOT Hazard Class : UN1263 Class 3
Label : FLAMMABLE LIQUID
Hazard Symbol : F, Xn, Xi, T
Packing Group : III
Environmental Hazard
- Marine Polutant : No

15. REGULATORY INFORMATION

This product is classified according to EU regulation
RISK PHRASES: SAFETY PHRASES:
R10 Flammable S2 Keep out of the reach of children.
R20 Harmful by inhalation S23 Do not breathe vapor and spray mist.
R23 Toxic by inhalation S24 Avoid contact with skin.
R26 Very toxic by inhalation S26 In case of contact with eyes, rinse immediately
R36/37/38 Irritating to eyes, respiratory system and skin with plenty of water and seek medical advice.
R40 Possible risk of irreversible effects S28 After contact with skin, wash immediately with
R42/43 May cause sensitization by inhalation and skin plenty of soap and water.
contact S29 Do not empty into drains.
R52/53 Harmful to aquatic organisms, may cause long-term S37 Wear suitable gloves.
adverse effects in the aquatic environment S51 Use only in well ventilated areas.
R66 Repeated exposure may cause skin dryness or cracking S57 Use appropriate containment to avoid
R67 Vapors may cause drowsiness and dizziness environmental contamination.

16. OTHERS INFORMATION

Notes and full R-Phrases text
-
HMIS HAZARD RATINGS HEALTH 1 0 = Insignificant
FLAMMABILITY 3 1 = Slight
REACTIVITY 1 2 = Moderate
PERSONAL PROTECTIVE EQUIPMENT B Safety glasses, Gloves 3 = High
4 = Extreme
This information is based on our present states knowledge. It should not therefore be construed as guaranteeing
specific properties of the products described or their suitability for – a particular application.

Date of issue : March 28, 2023

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