Previous Page: TABLE 2.20 2.20 Physical Constants of Organic Compounds (Confznuea

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E
2.202
0
N
TABLE 2.20 Physical Constants of Organic Compounds (Continued)

(Confznuea
Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

Solubility in 100
100
No. Name Formula weight reference €m-
g/mL index point, °C
point. OC point. °C
point, OC point. °C
point, OC parts solvent
m245 4,4'-Merhylenebis- 254.38 13. 239 88-89
(A',l!h'-dimethyl-
aniline)
m246 1.1 '-Merhylenebis(3- 210.37 0.887 1,473420 1605Wm >I10
methylpipendine)
m247 4.4'-Merhylenebis- 250.26 13.3, 461 1.180 42-44 20033"" > 110
(phenylisocyanate)
m248 hlethylene blue 313 90 27, 393 190 dec 4 aq; 1.3 alc: s chl
m249 4,4'-Methylenedi- 198.26 13, 238 89-91 399 221 v s alc, bz. eth: sl s aq
aniline
m250 3,4-Methylenedioxy- 150.13 19, 115 31 264 >110 0.2 aq; v s alc, eth
benzaldehyde
m25 I 1,2-Methylenedioxy- 122.12 19, 20 1.064 1.5398 173 55
benzene
111252 3,4-Methylenedioxy-6- 338.45 1g3, 179 1.059 1.498 180'"" 171 misc alc, br, geons
propylbenzyldi-
ethyleneglycol butyl
ether
m253 Methylenesuccinic H2C=C(C02H)CH,C02H 130.10 2,760 1.573 167 8.2 aq; 20 alc; v sl s
acid bz, chl, eth, PE
m254 N-Methylethylene- CH,hXCH2CH2NH2 74.13 4l, 415 0.841 1.439520 114- 116 42
diamine
m255 N-Methylfomamide HC( =O)KHCH, 59.07 4, 58 0.9988" 1.43W -4 199.5 98 misc aq
m256 N-Methylformanilide C,H5N(CH3)CH0 135.17 12,234 1.095 1.561P0 8-13 244 126
m257 Methyl fomate HC02CH, 60.05 2, 18 0.981515 1.346515 - 99 31.7 - 19 30 aq; misc alc
m258 5-Methylfuraldehyde 110.11 17,289 1.1072i8 1.526320 187 72 s aq; v s alc; misc eth
m259 2-Methylfuran 82.10 17, 36 0.915:O 1.4332'O - 88 63-66 - 22 0.3 aq
m25s-a Methyl 2-furoate 126.11 18,274 1.17920 1.487920 181 73 s alc, eth; sl s aq
m260 Methylgemanium CH,GeBr, 327.35 2.6337a0 1.57702O 168
hibromide
m26 1 N-Methylglucamine 195.22 Merck: 128- 129 100 1.2 alc"]
12, 6154
m262 Methyl-a-D-gluco- 194.18 31, 179 1.46ao 168 20002- 63 aq; 1.6 alc; i eth
pyranoside
m263 (?)-2-Methylglutaro- NCCH2CH2CH(CH,)CN 108.14 2, 656 0.950 1.434020 - 45 269-271 126
nihile
m264 N-Methylglycine CH,NHCH2CO2H 89.09 4,345 208 dec 42 aq; sl s alc
m265 Methyl glycolate HOCH,CO,CH, 90.08 3, 236 1.168i8 1.417P0 74 151 67 s aq; misc alc, eth
m266 Methyl heptanoate 144.22 2,339 0.8815z0 1.411520 -55.8 173.5 52 s alc, eth; sl s aq
111267 5-Methyl-2-heptanol 130.23 1,421 0.803 1.424W0 172 67
m268 5-Methyl-3-heptanone 128.22 l', 363 0.823 1.414220 157-162 43
111269 6-Methyl-5-hepten-2- 126.20 1'. 3010 0.855F 1.439220 - 67 7310- 50 misc alc, eth
one
m269a Methyl hexadecanoate 270.46 2,372 0.852 1.451220 32-34 19615- >110 s alc, chl, eth
m270 Methyl hexanoate 130.19 2,323 0.9038: 1.403g2, -71 151 45 v s alc, eth
m271 5-Methyl-2-hexanone 114.19 12, 756 0.88820 1.406220 -73.9 144 3641 0.5 aq; misc alc, eth
m272 1-Methylhexylamine 115.22 4, 194 0.766518 1.417520 144 54 sl s aq; s alc, eth
m273 1-Methylhydantoin 114.10 24,244 157 sub1 s aq, alc; 3 eth
m274 Methylhydrazine 46.07 42, 957 0.866 1.422520 - 52.4 87.5 21 misc aq, alc; s PE
111275 Methyl hydrazino- 90.08 3l, 46 70-73 108'lmm
carboxylate
111276 Methyl hydrogen 146.14 22, 565 1.169 1.438lZ0 1511hm >110
glutarate
m277 Methyl hydrogen 160.17 2,652 1.081 1.440120 8-9 162'"- >110 s alc
hexanedioate
m278 Methyl hydrogen 132.12 2,608 56-59 15I2Omm v s aq, alc, eth
succinate
m279 Methyl hydroperoxide 48.04 12,270 1.997a5 1.364215 3865m misc aq, alc, eth, s bz
m280 Meth ylhydroquinone 124.14 6,874 128-130
111281 Methyl 4-hydroxy- 152.15 10, 158 126-128 270 dec v s alc, eth, acet; 0.25
benzoate aq
m282 Methyl 2-hydroxy- 118.13 32,223 1.023 1.411220 127 42 v s aq, alc
isobutyrate
111283 Methyl 4-hydroxy- 166.18 10,191 57-60 1635mm
phenylacetate
111284 2-Methylimidazole 82.11 23,46 1.030 1.496OZo - 60 198 92 misc aq
m285 2-Methylimidazole 82.11 23, 65 142-143 268
111286 4-Methylimidazole 82.11 23.69 53-56 263 >110
111287 2-Methyl- Iff-indole 131.18 20,311 1.07t0 58-60 273 v s alc, eth; s hot aq
m288 2-Methylindoline 133.19 20,279 1.023 1.568120 229 93
m289 N-Methylisatoic 177.16 27.265 165 dec
anhydride
111290 Methyl isobutyrate (CH,),CHCO,CH, 102.13 2,290 0.89lzo - 84.7 92.5 3 misc alc, eth; sl s aq
m29 1 Methyl isocyanate CH,NCO 57.05 4, 77 0.967 -45 39 -6 s aq
m292 Methyl isodehydr- 182.18 18,410 68-70 16714-
acetate
(Continued)
(Continued)
2.203
2.204
N
0
P
TABLE 2.20 Physical Constants

Constants of Organic Compounds (Continued)
(Conrinued)
Formula Beilstein Density, Refractive Melting- Boiling Flash Solubility

Solubility in 100
100
No. Name Formula weight reference
reference g/mL
g/mL index point. °C
m293 N-Methylisopropyl- (CH,),CHNHCH, 73.14 4', 153 0.702 1.384020 50-53 -31
amine
m294 Methyl isothiocyanate CHJCS 73.12 4, 77 1.069 1.5258,' 35 118 32 v s alc, eth; sl s aq
m295 5-Methylisoxazole 83.09 27, 16 1.018 1.43862a 122 30
m296 Methyl lactate CH,CH(OH)CO,CH, 104.10 3, 280 1.088:O 1.413lzo 144-145 49 s aq (dec), alc, eth
m297 Methyl mandelate C,H,CH(OH)CO,CH, 166.18 10,202 1.175620 54-56 13512mrn >110 s aq, alc, bz, chl
111298 Methyl mercapto- HSCH2C02CH, 106.14 1.187 1.465720 4310m- 30 s alc, eth
acetate
m299 Methyl 3-mercapto- HSCH,CH,CO,CH, 120.17 3,, 214 1.085 1.466020 5514rnm 60
propionate
m300 Methyl methacrylate H,C=C(CHJCO,CH, 100.12 2,, 398 0.943320 1.414P0 - 48 100 10 1,6 aq; s ketones.
esters, CCI,
m301 Methyl methane- CH,SO,OCH, 110.13 4, 4 1.2943ao 1.413820 202-203 104 20 aq; 100 DMF
sulfonate
m302 Methyl methoxyacetate CH,0CH,C02CH, 104.11 3,236 1.0511$0 1.391%~~ 130 35 v s alc, eth; sl s aq
111303 Methyl 4-methoxy- CH,OCH,COCH,CO,CH, 146.14 34, 1939 1.129 1.431620 898.5- 89
acetoacetate
m304 Methyl 2-methoxy- CH,0C6H,C02CH, 166.18 10, 71 1.157 1.5335,O 248 >I10
benzoate
111305 Methyl 4-methoxy- CH,OC,H,CO,CH, 166.18 10, 159 51 245 >I10
benzoate
111306 Methyl 4-methoxy- CH,OC,H,CH,CO,CH, 180.20 10, 191 1.135 1.516Y0 158'9"" 36
phenylacetate
m307 Methyl 4-methoxy- CH,OCH,CHICO,CH, 118.13 3, 291 1.009 1.4020 142-143 47
propionate
m308 1-Methylk-(methyl- 128.22 0.882 1.467220 55
amino)piperidine
m309 Methyl 2-methyl- CH,C,H,CO,CH, 150.18 9,463 1.073 1.519P0 207-208 82
benzoate
m310 Methyl 3-methyl- CH,C,H,CO,CH, 150.18 9,475 1.063 1.516ff0 11327mm 95
benzoate
m311 Methyl 4methyI- CH,C,H,CO,CH, 150.18 9,484 33-36 10415- 90
benzoate
m312 Methyl 2-methyl- C,H,CH(CH,)CO,CH, 116.16 2, 304 0.885 1.393120 115 32 sl s aq; misc alc, eth
butyrate
m313 2-Methyl-6-methylene- C,H,C(=CH,)(CH,),C(CH,)20H 156.27 0.784 1.443lZo 84l- 76
2-octanol
m314 Methyl 2-methyl-3- 140.14 1.116 1.473020 75- 63
furancarboxylate
m315 Methyl S-methylthio- CH3S(=O)CH2SCH3 124.22 1.191 952.5- >I10
methyl sulfoxide
m316 Methyl 3-(methyl- CH3SCH,CH2C02CH3 134.20 1.077 75'3-3 72
thi0)propionate
m317 4-Methylmorpholine 101.15 27, 6 0.920 1.434920 - 66 116 23 s aq, alc, eth
m318 1-Methylnaphthalene 142.20 5,566 1.020220 1.61702O - 30.4 245 82 v s alc, eth
111319 2-Methylnaphthalene 142.20 5,567 1.029f 1.602640 34.4 24 1 97 v s alc, eth
m320 Methyl l-naphthalene- 200.24 93. 3206 1.142 1.596lZ0 1625mm >110
acetate
m321 2-Methyl-1,Cnaphtho- 172.18 72, 656 105- 107 1.4 alc; 10 hz; s chl
quinone
m322 Methyl 1-naphthyl 170.21 7,401 1.13364 1.6284,O 11 302 >110 s alc, eth, i aq
ketone
m323 Methyl 2-naphthyl 170.21 7.402 53-55 301 >110 sl s alc; s CS,
ketone
111324 Methyl nitrate 77.04 1,284 1.2075io 1.374gZ0 - 83 64 expl sl s aq; s alc, eth
m325 Methyl nitrite 61.04 1,284 0.991(Iq) - 17.3 s alc. eth
m326 N-Methyl-4-nitro- 152.15 12,714 152-154
aniline
m327 2-Methyl-3-nitro- 152.15 12.848 88-90 305
aniline
m328 2-Methyl-4-nitro- 152.15 12,846 1.1586Ip 131-133 v s alc; s hz
aniline
m329 2-Methyl-5-nitro- 152.15 12,844 104-107 s alc, acet, eth
aniline
111330 4-Methyl-2-nitro- 152.15 12, loo0 115-116 v s alc; s eth
aniline
m331 Methyl 2-nitro- 181.15 9,372 1.280 1.5340M - 13 1060.'"" >110 8 alc, eth
benzoate
m332 Methyl 3-nitro- 181.15 9,378 78-80 279
benzoate
m333 Methyl 4-nitro- 181.15 9,390 94-96
benzoate
(Continued)
(Continued)
2.205
2.206

(Continued)

Solubility in 100
100
reference g/mL
m334 2-Methyl-3-nitro- CH,C,H,(N02)C02H 181.15 9,471 182-184
benzoic acid
m335 3-Methyl-4-nitro- CH3C6H3(N02)C02H 181.15 9, 481 216-218
benzoic acid
m336 4-Methyl-3-nitro- CH,C,H,(NO,)CO,H 181.15 9,502 187-190
benzoic acid
m337 5-Methyl-2-nitro- CH3C,H3(N02)C0,H 181.15 9,482 134-136
benzoic acid
m338 2-Methy1-5-nitro- 127.10 23), 23 252-254
imidazole
m339 3-Methyl-4-nitro- CH,C,H,(NO,)OH 153.14 6, 386 127- 129
phenol
m340 4-Methyl-2-nitro- CH,C,H,(NO,)OH 153.14 6,412 1.24w 1.574'0 32-35 12522- 108 v s alc, eth
phenol
m341 2-Methyl-2-nitro-1- O,NC(CH,),CH,OH 119.12 1,378 86-89 951- 350 aq
propanol
m342 2-Methyl-2-nitroprop yl H,C=C(CH&O,CHZ- 187.20 2', 1288 1.087 1.45W0 1024- >I10
methacrylate C(CHJJO2
m343 N-Methyl-N-nitroso-4- CH,C6H4S0,N(CH,)N0 214.24 I l l , 29 62
toluenesulfonamide
m344 Methyl 2-nonynoate CH3(CH2)5C=CCOzCH, 168.24 2,490 0.915 1.4484*O 12120mm 100
m345 Methyl-5-norbomene- 178.19 1j2,461 1.232 1.50602° >110
23dicarboxylic
anhydride
m346 Methyl octadecanoate CH,(CH,),,CO,CH, 298.51 2,379 38 215'*"" >110 s alc, eth
m347 Methyl cis-9-octa- CH,(CH,)-CH=CH- 296.50 2,467 0.839*O 1.452I2O - 19.9 1682tnm > 110 misc abs alc. eth
decenoate (CH,),C02CH3
m348 7-Methyl-l,6-octadiene (CH3),C=CH(CHJ3CH=CH, 124.23 14, 1049 0.753 1.436020 143-144 26
m349 ,Methyl octanoate CH,(CHWO,CH, 158.24 2, 348 0.8775i0 1.41602' - 40 192.9 72 Y s alc, eth: i aq
m350 Methyl 2-octynoate CH,(CH,),CECCO,CH, 154.21 2,487 0.920 1.446OZo 217-220 88
m351 3-Methyl-2- 101.11 1.170 1.4541'o 15 901"" > 110
oxazolidinone
m352 2-Methyl-2-oxazoline 85.11 27. 13 1,005 1.4340'0 110 20
m353 3-Methyl-3-oxetane- 102.13 Ij3, 1128 1.024 1.446Oio 8040"" 98
methanol
m354 Methyl 2-0xoc)clo- (O=)C5H,COICH, 142.16 10. 597 1.145 1.456Ozo 105"'" >110
pentanecarboxylate
m355 Methyl 2-0x0- CH,C( =O)CO,CH, 102.09 3,616 1.130 1.406520 134-137 39 misc alc, eth; sl s aq
propionate
m356 trans-2-Methyl- 1,3- CH,CH=CHC(CH,)=CH, 82.15 1,255 0.718 1.4469,O 75-76 - 12
pentadiene
m357 2-Methylpentme CH3CH,CH,CH(CHJ2 86.18 1, 148 0.6532,O 1.3725,O - 154 60.3 1-29
m358 3-Methylpentane (CH,CH,),CHCH, 86.18 1, 149 0.664320 1.376520 - 163 63 <-7
m359 2-Methyl-l,5-pentane- H,N(CH,),CH(CH,)CH,NH, 116.21 4,270 0.860 1.459020 80
diamine
m360 2-Methyl-2,4- (CH,),C(OH)CH,CH(OH)CH, 118.18 1,486 0.9216:O 1.421O2" - 50 198 102 misc aq
pentanediol
m361 4-Methylpentanenitrile (CH,),CHCH,CH,CN 97.16 2, 329 0.8035:O -51.1 156.5 45 s alc; misc eth
m362 Methyl pentanoate CHdCHJ,CO2CH, 116.16 2,301 0.875 128 22 sl s aq; misc alc, eth
m363 2-Methylpentanoic CH,CH2CH,CH(CH3)C0,H 116.16 2,- 288 0.9242:; - 85 196.4 107 1.3 aq
acid
m364 2-Methyl- 1-pentanal CH3CH,CH,CH(CH,)CH,0H 102.18 1,409 0.826220 1.418OZ0 148 54 s alc, eth
m365 3-Methyl-3-pentan01 (CH,CHz)zC(CHJOH 102.18 1,411 0.828120 1.4186,O -23.6 123 46 misc alc, eth; sl s aq
m366 4-Methyl-Z-pentanol (CH,),CHCH,CH(OH)CH, 102.18 1,410 0.8080*O 1.4112,O - 90 132 41 1.6 aq
m367 4-Methyl-2-pentanone (CH,),CHCH,COCH, 100.16 1,691 0.7978,O 1.395X20 - 84 116.5 18 1.7 aq; misc alc, bz,
eth
m368 2-Methyl-Zpentenal CH,CH,CH=C(CH,)CHO 98.15 14, 3471 0.861 1.4503,O 138 31 s alc
m369 4-Methyl-2-pentenoic (CH,),CHCH=CHCO,H 114.14 2,. 406 0.9529 1.4489 35 1152D"" 46 i aq; v s alc
acid
111370 4-Methyl-3-penten-2- (CH,),C=CHCOCH, 98.15 1,736 0.865320 1.444020 - 59 129.5 31 3.1 aq
one
m37al 4-Methyl-2-pentyl (CH,),CHCH2CH(CH,)02CCH, 144.21 0.8805" 1.398ffo 147.5 45
acetate
111371 1-Methylpentylamine 101.19 4, 190 0.767f0 - 19 116-118 13 s aq, alc, PE
m372 3-Methyl-1-pentyn-3-01 98.15 12, 506 0.86882O 1.431x20 -30.6 122 26 13 aq, misc bz, acet
PE, EtOAc; s eth
m373 4-Methylphenetole CH,C,H.,OCH,CH, 136.19 6,393 0.945 1.504420 189-191 70
111374 N-(CMethylphenyl)- CH,C,H,NHCOCH, 149.19 12,920 1.21215 150-153 307 s alc, EtOAc, HOAc
acetamide
111375 Methyl phenylacetate C,H5CH2C0,CH, 150.18 9,434 1.044 1.507520 218 90 i aq; misc alc, eth
m376 2-Methyl- 1-phenyl-2- CH+,H,CH,C(CH,),OH 150.22 6, 523 0.974 1.5 1402 25-26 96'8mm 81
propanol
m377 1-Methyl-3-phenyl- C,H,CH,CH,CH(CH,)NH, 149.24 12, 1165 0.922 1.5 12320 222 91
propylamine
(Continued)
(Continued)
2.207
2.208

(Confznuea
Formula Beilstein Density,

Density. Refractive Melting Boiling Flash Solubility
Solubility in 100
100
No. Name Formula weight reference g/mL
km- index point, °C
"C point, °C
"C point, °C
"C parts solvent
m378 3-Methyl-1-phenyl-2- 174.20 24, 20 129-130 287265m
pyrazolin-5-one
m379 Methyl phenyl sulfide C,H,SCH, 124.21 6, 297 1.058 1.588220 - 15 188 57 i aq; s alc
m380 N-Methyl-N-phenyl- C6H,N(CH,)C0,CH,CH, 179.22 12,417 1.074 1.514920 243-244 ZllO
urethane
m381 N-Methylpiperazine 100.17 0.903 1.465520 138 42 v s aq, alc, eth
m382 2-Methylpiperazine 100.17 23, 17 65-67 155.6 65 78 aq; 37 acet; 32 bz
m383 N-Methylpipendine C5Hl$JCH3 99.19 20,19 0.816 1.437gZo 106-107 3 v s aq; misc alc, eth
m384 2-Methylpiperidine CH3C5H&' 99.19 20,95 0.844 1.445920 -5 119 8 v s aq; misc alc, eth
m385 3-Methylpipendine CH,C,H,N 99.19 20, 100 0.845 1.447020 126 17 v s aq
m386 4-Methylpipendine CH,C,H&' 99.19 20,101 0.838 1.445g20 124 7 v s aq
m387 1-Methyl-3-piperdine- 129.20 212, 8 1.013 1.477220 140-145 94
methanol
m388 1-Methyl-4-piperidone 113.16 212, 215 0.920 1.4614,O 60
m389 2-Methylpropan- (CHJ2CHCH0 72,ll 1, 671 0.7891'O 1.372720 - 65 64.1 - 40 9 aq; misc alc, bz, chl,
aldehyde eth
m390 2-Methylpropane (CHACH 58.12 1, 124 1.3810-25 - 138 - 11.7 - 87 13 mL aq; 1320 mL
alc; 2890 mL eth
m391 N-MethyI-l,3-propane- H,NCH,CH,CH,NHCH, 88.15 4), 419 0.844 1.44158~~ 139-141 35
diamine
m392 2-Methyl-1 ,I-propane- (CHACRIH,)CH,SH, 88.15 4, 266 0.841 1.441020 23
diamine
m393 2-Methyl-l,3-propane- HOCH,CH(CH,)CH,OH 90.12 1,480 1.015 1.445020 -91 12520mm tllO
diol
m394 1-Methyl- 1-propane- CH,CH,CH(SH)CH, 90.19 1, 373 0.824625 1.433825 - 165 84-85 21 sl s aq; v s alc, eth
thiol
m395 2-Methyl-1-propane- (CH,),CHCH,SH 90.19 1, 378 0.8357,O 1.4396,O - 79 88.5 -9 v s alc, eth
thiol
m396 2-Methyl-2-propane- (CHACSH 90.19 1,383 0.79431, 1.419825 1.1 64.1 -4 i aq
thiol
m397 2-Methyl-1-propano1 (CH,),CHCH,OH 74.12 1, 373 0.801620 1.395g20 - 108 108 28 10 aq; misc alc, eth
m398 2-Methyl-2-propanol (CHXOH 74.12 1, 379 0.788820 1.3877,O 25.8 82.4 11 misc aq, alc, eth
m399 2-Methylpropene (CH,),C=CH, 56.11 1, 207 0.6266$? - 140 - 6.9 v s alc. eth
m400 2-Methyl-2-propen- H2C=C(CH,)CH20H 72.11 1, 443 0.857 1.426020 113-115 33
1-01
m40 1 Methyl propionate CH,CH,CO,CH, 85.11 2, 239 0.9 15:O 1,377020 - 88 79.7 6 6 aq; misc alc, eth
m402 Methyl propionyl- 130.15 3,. 1212 1.037 1.42202" 745- 71
acetate
m403 4'-Methylpropio- CH,C,H,COCH,CH, 148.21 7, 317 0.993 1.52802" 7.2 238-239 96
phenone
m404 Methyl propyl ether CH,CH,CH,OCH, 74.12 1, 354 0.738" 39.1 sl s aq; misc ale, eth
111405 2-Methyl-2-propyl- CH,CH,CH,C(CH,)(CHzOH), 132.20 l', 254 58-60 232 >110
1,3-propanediol
111406 Methyl propyl sulfide CH,SCH,CH,CH, 90.18 13, 1432 0.8424'' 1.4442''' - 113.0 95.5
111407 Methyl 2-propynyl CH,OCH,C=CH 70.09 1, 4541 0.830 1.39612" 62 - 18
ether
m408 2-Methylpyrazine 94.12 23, 94 1.030 1.504220 -29 135 50 v s aq, alc, eth
111409 2-Methylpyridine 93.13 20, 234 0.9443'' 1.4957'' - 66.7 129 39 misc aq; s alc, eth
m410 3-Methylpyridine 93.13 20, 239 0.95156~' 1.50402' - 18.3 144 36 misc aq,alc, eth
m411 CMethylpyridine 93.13 20, 240 0.954820 1.50372'' 3.8 145 57 misc aq, alc, eth
m412 Methyl 3-pyridine- 137.14 22, 39 39 209 s aq, alc, bz
carboxylate
m413 Methyl 4-pyridine- 137.14 22, 46 1.001 1.512220 8.5 207-209 82
carhoxylate
m414 1-Methyl-2-pyridone 109.13 21, 268 1.112 1.56902'' 30-32 250'- >110
111415 Methyl 3-pyridyl- 152.15 2Z3, 4076 121-123
carbarnate
m416 2-[3-(6-Methyl-2- 195.26 1.052 1.51502' >I10
pyridy1)propoxy I-
ethanol
m417 N-Methylpyrrole 81.12 20, 163 0.914 1.4875" -57 112-113 15 i aq; misc alc, eth
111418 N-Methylpyrrolidine 85.15 20, 4 0.819i'' 1.424720 80-81 -21 misc aq, eth
m419 N-Methyl-2- 99.13 21. 237 1.027925 1.468OZ5 - 24.4 202 96 misc aq,alc, bz, eth
pyrrolidinone
m420 2-Methylquinoline 143.19 20, 387 1.058 1.610820 -2 248 79 i aq; s chl, etb
m421 4-Methylquinoline 143.19 20, 395 1.08262' 1.62Wo 9-10 263 >110 misc ale, bz, eth
111422 6-Methylquinoline 143.19 20, 397 1.063 1.61402" 259 >110
m423 2-Methylquinozaline 144.18 23', 44 1.118 1.615620 180 245-247 107 misc aq
111424 Methyl salicylate HOC,H,CO,CH, 152.15 10, 70 1.18312' 1.53602' -8 223 96 0.7 aq; misc alc,
HOAc; s chl, eth
111425 a-Methylstyrene C,H5C(CH,)=CH2 118.18 5, 484 0.909 1.537S2" -24 165.5 45
111426 4-Methylstyrene CH,C,H,CH=CH2 118.18 5, 485 0.897 1.5412*' 170-175 45
m427 mono-Methyl succinate H02CCH2CH162COzCH3 132.12 2, 608 56-59 151Zmm
111428 Methyl tetradecanoate CHdCHdizCOzCH, 242.40 Z2, 326 0.855 1.436220 18.4 323 >110 misc alc, bz, eth
(Continued)
(Continued)
2.209
2.210

(Continued)

Solubility in 100
100
reference g/mL
"C point, °C
"C point, °C
"C parts solvent
m429 2-Methyltetrahydro- 86.13 17, 12 0.85522u I .4056*O 78 -11
furan
m430 3-Methyltetrahydro- 100.16 17', 77 0.863 1.420420 109733m 6
PYran
m43 1 3-Methyltetrahydro- 134.20 1.191 1.477ZZu 276 >110
thiophene-1,I dioxide
m432 4-Methy lthiazole 99.16 27.16 1.090 1.525720 134 32
m433 4-Methyl-5-thiazole- 143.21 27,3, 1754 1.196 1.550820 1357""" >110
ethanol
m434 2-Methyl-2-thiazoline 101.17 27, 13 1.067 1.52Ooz0 - 101 145 37
m435 (Methy1thio)aceto- CH,SCH2CN 87.14 1.039 1.482620 6315- 67
nitrile
m436 3-(Methylthio)aniline CH,SC,H,NH, 139.22 13l, 141 1.130 1.6423" 16516- >110
m437 C(Methy1thio)benz- CH,SC&,CHO 152.22 81, 533 1.144 1.645ZZo 901- >110
aldehyde
m438 2-(Methy1thio)benzo- 181.28 27,109 43-46 >110
thiazole
m439 3-(MethyIthio)-2- CH,CH(SCH,)COCH, 118.20 14,3993 0.975 1.47 102" 50-5420mm 44
butanone
m440 Methyl thiocyanate CH,SCN 73.12 3, 175 1.06SZ0 1.46802" -5 133 38 i aq; misc alc, eth
m441 2-Methylthiophene 98.17 17,37 1.0193" 1.51992'' -63 113 7
m442 3-Methylthiophene 98.17 17,38 1.021S2" 1.51802" -69 115.4 11 i aq; misc alc, eth
m443 5-Methyl-2-thiophene- 126.18 17l, 151 1.170 1.586OZ0 11425m 82
carboxaldehyde
m444 N-Methyl-2-thiourea CH,NHC( =S)NH, 90.15 4, 70 119-121 v s aq, alc
m445 N-Methyl-o-toluamide CH,C,H,CONHCH, 149.19 9,465 1.1581s 69-71
m446 N-Methyl-p-toluene- CH,C6H4S0,NHCH, 185.25 11, 105 76-79
sulfonamide
m447 Methyl p-toluene- CH,C,H,SO,OCH, 186.23 11.99 1.234 27.5 14S"" >110
sulfonate
m448 Methyltriacetoxysilane CH,Si(O,CCH,), 220.26 43,1896 1.175:O 1.408" 40-45 883- 85
m449 Methyl trichloro- Cl,CCO,CH, 177.42 2,208 1.488 1.455820 153 72
acetate
m450 Methyltrichlorosilane CH,SiCl, 149.48 4,. 1896 1.273 1.41lozo 66 - 15
m45 1 Methyltriethoxysilane CH,Si(OCH,), 178.30 4, 629 0.895 1.384020 141-143 23
m452 Methyl trifluoro- F,CCO,CH, 128.05 Z3, 421 1.273 1.290720 43 -7
acetate
m453 Methyl trifluoro- 164.10 34, 34 1.450 1.324420 94-99 38
methanesulfonate
m454 Methyl 3,4,5-tn- 184.15 10, 483 201-203
hydroxybenzoate
m455 Methyltrimethoxy- 136.22 44, 4203 0.955 1.3703'O I02 11
silane
m456 Methyl trimethyl- 116.16 2, 320 0.873 1.390020 101 6
acetate
m457 N-Methyl-N-(tri- 199.25 1.075 1.3802'O 132 25
methylsi1yl)tri-
fluoroacetamide
m458 (Methy1)uiphenyl- [CH,P(C,H,),I' Br- 357.24 16, 760 230-234
phosphonium
bromide
m459 2-Methylundecanal CH,(CH,),CH(CH,)CHO 184.32 0.830i5 1.432I2O 171 93 s alc, eth
m460 Methyl urea CH,NHCONH, 74.08 4, 64 1.204 101-102 v s aq, alc; i eth
m461 N-Methyl-N-vinyl- CH,CON(CH,)CH=CH, 99.13 4,, 442 0.959 1.482920 7021m 58
acetamide
m462 Methyl vinyl ether CH,OCH=CH, 58.08 13, 1857 0.7511~c 1.3947 - 123 5.5 - 56 0.8aq; v s alc
m463 Morpholine 81.12 27, 5 1.000520 1.4548*O - 4.9 128 375 misc aq, alc, bz, eth
m464 4-Morpholinepropio- 140.19 27,. 337 1.037 1.471520 21 1212-
nitrile
m465 N-Morpholino-1-cyclo- 167.25 0.995 1.512g20 1201- 68
hexene
m466 3-(N-Morpholino)-1,2- 161.20 1.157 37-38 191,- >110
propanediol
m467 Myrcene 136.24 1. 264 0.80132c 1.4709'O 167 39 s alc, chl, eth, HOAc
nl 1-h'aphthaldehyde 156.18 7, 400 1.150:O 1.652020 1-2 161'5m >110 s alc, eth
n2 Naphthalene 128.17 5. 531 1.162iC 1.58211w 80 217.7 79 0.3 aq; 7 alc; 33 bz; 50
chl
n3 l-h'aphthalene- 172.18 9, 647 160-162 300 sl s aq; v s h o t alc, eth
carboxylic acid
n4 1,5-Naphthalene- 158.20 13, 203 185- 187 s h o t aq, hot alc
diamine
n5 1,8-Naphthalene- 158.20 13. 204 1.1265p 1.682899 66.5 205!27~" sl s aq; s alc, eth
diamine
(Continued)
(Conrinued)
2.211
2.212
TABLE 2.20 Physical Constants of Organic

Organic Compounds (Continued)

Solubility in 100
100
point, OC point, °C
point. OC parts solvent
solvent
n6 1-Naphthalenesulfonic C1d7S03H 208.24 11, 155 90 de- v s aq, alc; sl s eth
acid hydrates
n7 2-Naphthalenesulfonic C1d7S03H 208.24 11, 171 124 de- v s aq, alc
acid hydrates
n8 l&Naphthalic 198.18 17,521 268 sl s HOAc

anhydride
n9 1-Naphthol 144.17 6,596 1.0954y 1.620699 96 288 v s alc, bz, chl, eth
n10 2-Naphthol 144.17 6,627 1.2174 123 285 161 0.1 aq; 125 alc; 6 chl;
77 eth; s alk
nll 1,4-Naphthoquinone 158.16 7,724 1.422 126 s bz, chl, eth, hot alc
1112 (2-Naphthoxy)acetic 202.21 6,645 155-157
acid
1113 2-( 1-Naphthyl). 185.23 9,666 182 i aq; s bz, CS,
acetamide
1114 1-Naphthyl acetate 186.21 6,608 43-46 >110 s alc, eth
n15 1-Naphthylacetic acid 186.21 9,666 135 dec 3.3 alc; v s chl, eth
1116 1-Naphthylacetonitrile 167.21 9, 667 1.619220 33-35 19418mm >110 s alc
1117 1-Naphthylamine 143.18 12,1212 1.123:: 1.6703 50 301 157 0.2 aq; v s alc, eth
1118 1-Naphthyl isocyanate 169.19 12, 1244 1.177 1.6344,O 4 267 >110
1119 Nicotine 162.24 23, 117 1.0097:" 1.588Z2' -79 12311mm 101 misc aq; v s alc, eth,
PE
1120 Nitrilotriacetic acid N(CHzCOzH), 191.14 4,369 242 dec 0.1 aq; s hot alc
1121 3 '-Nitroacetophenone O,NC,H,COCH, 165.15 7,288 76-78 202 s alc, eth
n22 4'-Nitroacetophenone 0,NC,H4COCH3 165.15 7,288 78-80 202 s alc
1123 2-nitro aniline 0,NC6H4CH, 138.13 12,687 1.44215 71 284 s hot aq, alc, chl
n24 3-Nitroaniline 0,NC6H4CH, 138.13 12,698 1.43 114 306 0.1 aq; 5 alc; 6 eth
112.5 4-Nitroaniline 0,NC6H4CH, 138.13 12, 711 1.43714 147 332 165 4 alc; 3.3 eth, s bz
n26 3-Nitrobenzaldehyde 0,NC,H4CH0 151.12 7,250 1.2792:'' 58 16423mm s alc, chl, eth
n27 4-Nitrobenzaldehyde 02NC6H4CH0 151.12 7,256 1.496 106-107 s alc, bz, HOAc
n28 2-Nitrobenzamide 0,NC&14CONH, 166.12 9,373 1.46Z3, 174-178 317 s h o t aq, hot alc, eth
1129 3-Nitrobenzamide 0,NC6H4CONH, 166.12 9,381 140-143
1130 Nitrobenzene C,HJOz 123.11 5,233 1.205i5 1.554615 5.8 210.8 88 v s alc, bz, eth
n3 1 3-Nitrobenzene-1,2- OZNC~H~CO~H)~ 211.13 9,823 216 dec 2 aq; v s hot alc
dicarboxylic acid
n32 5-Nitrobenzene-1,3- OZNC~H~(CO& 211.13 9,840 260 0.15 aq; v s alc, eth
dicarboxylic acid
1133 2-Nitrobenzenesulfonyl O,NC,H,SO,Cl 221.62 11,67 65-67 s eth; d hot aq, alc
chloride
n34 5-Nitrobenzimidazole 163.14 23, 135 207-209 s alc, acid
n35 2-Nitrobenzoic acid 0,NC6H4C0,H 167.12 9,370 1.58 146-148 0.7 aq; 33 alc; 22 eth
1136 3-Nitrobenzoic acid O,NC,H,CO,H 167.12 9,376 1.494 140-142 0.3 aq; 33 alc; 40 acet
n37 4-Nitrobenzoic acid 0,NC6H4C0,H 167.12 9,389 1.58 242.8 9 alc; 2 eth; 5 acet
1138 4-Nitrobenzonitrile O,NC,H,CN 148.12 9,397 146-149 s HOAC; sl s aq, alc
n39 3-Nitrobenzoyl 0,NC6H4COC1 185.57 9,381 32-35 275-278 >I10 dec aq, alc; v s eth
chloride
1140 4-Nitrobenzoy l 0,NC6H4COCl 185.57 9,394 75 205105""" dec aq, alc; s eth
chloride
n4 1 2-Nitrobenzyl alcohol 0,NC6H4CH,0H 153.14 6, 447 70-72 270
n42 3-Nitrobenzyl alcohol 02NC6H4CH,0H 153.14 6, 449 30-32 1803- >I10 s aq, alc, eth
n43 4-Nitrobenzyl alcohol 0,NC6H4CH,0H 153.14 6,450 92-94 18S2- v s alc, eth; sl s aq
n44 4-Nitrobenzyl bromide O,NC,H,CH,Br 216.04 5,334 98-100 2 alc; v s eth
n45 4-Nitrobenzyl chloride OzNC6H4CH,Cl 171.58 5,329 70-73 8 alc; s eth
n46 2-Nitrobiphenyl 02NC6H4C6H5 199.21 5,582 1.447 1.613= 36.7 325 179 s alc, acet, CCI,
n47 4-Nitrobiphenyl O,NC,H4C& 199.21 5,583 112-114 340 sl s alc; s chl, eth
n48 1-Nitrobutane CH,CH,CH,CH,NO, 103.18 1, 123 0.975:; 1.4112 -81.3 152.8 47 sl s aq; misc alc, eth
n49 3-Nitro-2-butanol CH,CH(NO,)CH(OH)CH, 119.12 1,373 1.1296p 1.441420 921hm 91
n50 3-Nitrocinnamic acid O,NC,H,CH=CHCO,H 193.16 Merck: 200-201 1 alc
12,6692
n5 1 2-Nitrodiphenylamine O,NC,H,NHC,H, 214.22 12,690 76 i aq; s alc
n52 Nitroethane CH,CH,NO, 75.07 1, 99 1.0528:; 1.39202O - 90 114 28 4.5 aq; misc alc, eth; s
alk, chl
n53 5-Nitro-Z-furaldeh yde 198.14 173,4467 242-244 s alk, chl, alk; 0.2 alc
semicarbazone
n54 1-nitroguanidine O,NNHC(=NH)NH, 104.07 3, 126 dec >225 0.4 aq; sl s MeOH
n55 5-Nitro- IH-indazole 163.14 23, 129 207-209 s alc, bz, eth, acet
n56 Nitromethane CH,NO, 61.04 1, 74 1.1322p 1.379525 -28.4 101.2 35 11 aq; s alc, eth
1157 1-Nitronaphthalene CIJH,NO, 173.17 5,553 1.223 59-60 304 s alc; v s chl, eth
n58 3-Nitro-2-pentanol CH,CH,CH(NO,)CH(OH)CH, 133.15 1,385 1.0818p 1.443020 1001h"m 90
1159 2-Nitrophenol O,NC,H,OH 139.11 6,213 1.495 45 216 s alc, bz, eth, alk
n60 4-Nitrophenol O,NC,H,OH 139.1 1 6,226 1.27O1:O 113-114 279 s aq; v s alc, chl, eth
n6 1 4-Nitrophenyl acetate O,NC,H,O,CCH, 181.15 6,233 77-79 s aq; v s alc, bz, eth
n62 2-Nitrophenylacetic O,NC,H,CH,CO,H 181.15 9,454 139-142 s hot aq, alc
acid
n63 4-Nitrophenylacetic 02NC,H,CH,C0,H 181.15 9,455 153-155 s alc, bz, eth; sl s aq
acid
(Continued)
(Continued)
2.213
2.214

(Confznuea

Solubility in 100
100
No. Name Formula weight reference g/mL index point, °C
"C point, °C
"C point, °C
"C parts solvent
n64 4-Nitrophenylaceto- 162.15 9,456 115-117 s alc, eth; i aq
nitrile
1165 2-Nitro-1,Cphenylene- 153.14 13, 120 137-140
diamine
1166 4-Nitro-l,2-phenylene- 153.14 13,29 199-201 sl s aq; s HCI
diamine
n67 4-Nitrophenyl- 153.14 15,468 156 dec s alc, chl, eth, hot bz
hydrazine
n68 2-Nitrophenyl phenyl 02NC6H40CsH5 215.21 222 < -20 1848m s alc, eth
ether
n69 4-Nitrophenyl phenyl 02NC6H40CsH5 215.21 6,232 53-56 320 >110 s bz, eth
ether
n70 3-Nitro-1,2-phthalic 211.13 9, 823 213-216
acid dec
n7 1 4-Nitro-1.2-phthalic 211.13 9,828 170-172
acid
1172 3-Nitrophthalic 193.11 17,486 163-i65 sl s aq, bz
anhydride
1173 1-Nitropropane 89.09 1, 115 1.000920 1.401620 - 108 131.1 36 1.4 aq; misc org solv
1174 2-Nitropropane 89.09 1, 116 O.982lm 1.394g20 -91.3 120.3 24 1.7 aq; misc org solv
n75 2-Nitro-1-propano1 105.09 1,358 1.1841f 1,437g2" 991- 100 s aq, alc, eth
n76 4-Nitropyridine-N- 140.10 203,2528 159-162
oxide
n77 Nitrosobenzene 107.11 6,230 67-69 5918-
n78 N-Nitrosodimethyl- 74.08 8, 84 1.0048$ 1.436g20 151 61 v s aq, alc, eth
amine
n79 4-Nitrosodipheny l- 198.22 Merck 144-145 v s alc, bz, chl, eth
amine 12, 6737
n80 1-Nitroso-2-naphthol 173.16 7,712 109-110 3 alc; s bz, eth, alk;
0.1 aq
n8 1 1-Nitroso-2-naphthol- 377.26 112, 190 >300 2.5 aq; sl s alc
3.6-disulfonic acid
disodium salt
hydrate
1182 4-Nitrosophenol HOC&14N0 123.11 7,622 126 dec 144 s aq; v s alc, eth, ex-
plodes on contact
with conc acid, alk,
or fire
1183 2-Nitrotoluene 137.14 5,318 1.1622;; 1.547220 - 10 222 106 s alc, bz
n84 3-Nitrotoluene 137.14 5,321 1,1581p 1.545g20 15.5 231.9 101 misc alc, eth, s bz
n85 4-Nitrotoluene 137.14 5,323 1.392 52 238 106 s alc, bz, chl, eth
n86 2-Nitro-cr,rr,cr-tri- 191.11 52,251 31-32 10520mm 95 v s alc, bz
fluorotoluene
n87 3-Nitro-a,cr,a-tri- 191.11 5.327 l.436i6 1.47 1520 - 2.4 200-205 87 s alc, eth
fluorotoluene
n88 5-Nitrouracil 157.09 24,320 >300
n89 Nonadecane CH&Hz)i&H3 268.51 1,174 0.7776i2 32 330 168 Seth; sl s alc
n90 Nonane CH&W,CH, 128.26 1,165 0.7178 - 53.5 150.8 31 s abs alc, eth
n9 1 1,9-Nonanediamine &N(CH2)&'& 158.29 4,272 37-38 258 >110
1192 Nonanedinitri1e NC(CH2),CN 150.23 2,709 0.929 1.446P0 17611m" >110 v s alc, bz, eth
n93 1,9-Nonanedioicacid HOzC(CH2),COzH 188.22 2,707 1.029y 106.5 286lWmm 0.24 aq; v s alc; 3 eth
1194 1,9-Nonanediol HO(CH3,OH 160.26 1,493 47-49 17715- >110
1195 Nonanenitde CH3(CHa7CN 139.24 2,354 0.851v 1.42602" - 34.2 224.0 81 s alc, eth
1196 Nonanoic acid CH3(CHz),cOzH 158.24 2,352 0.906f 1.43302O 12.5 254.5 100 s alc, chl, eth
1197 y-Nonanoic lactone 156.23 17,245 0.976 1.447520 1226- >110
n98 1-Nonanol CH3(CH&0H 144.26 1,423 0.8279z0 1.4338" - 5.5 215 75 0.6 aq; misc alc, eth
1199 2-Nonanone CH3(CHd6COCH3 142.24 1,709 0.832 1.42102O - 21 192743mm 64
nlOO 3-Nonanone CH3(CH&COCHzCH3 142.24 1,709 0.821 1.420420 187-188 67
nlOl 5-Nonanone (CH3CHZCH2CHz),CO 142.24 1,710 0.806$0 1.41902O - 50 186-187 60 misc alc, eth
n102 Nonanoyl chloride CH,(CHz),COCI 176.69 2,353 0.946i5 1.437720 - 60.5 215.4 95 dec aq, alc; s eth
11103 3-Nonen-2-one CH3(CHJ4CH=CHCOCH3 140.23 1'. 3017 0.848 1.448420 85lZm 81
n104 Nonyl aldehyde CH3(CH3,CH0 142.24 1,708 0.82718 1.42402" 185 63
1110.5 Nonylamine cH3(CHdWz 143.27 4,198 0.782 1.43302O 201 62 sl s aq;s alc, eth
n106 Nopol 166.26 63, 396 0.973 1.49302O 230-240 98
n107 Norbomane 96.17 51.45 82-84 s alc
n108 2-Norbomanone 110.16 7,57 94-96 168-172 33
n109 exo-2-Norbomyl 140.18 6.3, 219 1.048 1A2220 6716"" 53
formate
nllO ( +)-Norephedrine C6H5CH(OH)CH(CH3)NH2 151.21 132,371 51-54 1110
01 cis,cis-9,12-0ctadeca- CH3(C&),CH=CHC&- 280.44 2,496 0.9025i0 1.4699" -5 230'- v s eth; 10 PE; s abs
dienoic acid CH=CH(CHz),C02H alC
(Continued)
(Continued)
2.215
2.216

(Continued)

Density. Refractive Melting Boiling Flash Solubility in 100
100
"C point, °C
"C point, °C
"C parts solvent
02 Octadecanamide 283.50 2,383 102-104 251'- s hot alc, hot eth
03 Octadecane 254.50 1, 173 0.7767i8 1.4367,, 28.2 316.3 165 s acet, eth; sl s alc
04 1-Octadecanethiol 286.57 1,3, 1838 1.4648 31-35 360 185 s eth; sl s alc
05 Octadecanoic acid 284.48 2,377 0.847'O 1.429980 69 383 4.9 alc; 20 bz; 50 chl;
3.9 acet; 16.6 CC1,;
s toluene, pentyl
acetate
06 1-Octadecanol CHdCHJi70H 270.50 1,431 0.8123z8 1.438g2O 59.6 20310mm s alc, eth
07 9,12,15-0ctadecatri- CH,(CH,CH=CHJ$H,- 278.44 2,499 0.914iB 1.48002O 23Oi7- >110 s alc, bz, eth
enoic acid (CHMO8
08 1-Octadecene CH,(CHJ11CH=CH2 252.49 1,226 0.791i8 1.4439,O 17.7 314.9 148 s hot acet
09 9-Octadecen- 1-amine CH,(CHJ,CH=CH(CHJ,NH, 267.50 0.813 1.4596,O 154
010 cis-9-Octadecenoic CH,(CH,),CH=CH(CHJ,CO,H 282.47 2,463 0.8936p 1.458120 13.4 360 189 s alc, bz, chl, eth
acid
01 1 trans-9-Octadecenoic CH3(CH2),CH=CH(CH2),C02H 282.47 22, 441 0.85179 1.430899 44-45 2881WrnZ s bz, chl, eth
acid
012 cis-9-Octadecen- 1-01 CH,(CH,),CH=CH(CH,),OH 268.49 1,453 0.850:O 1.461020 13-19 1958"rn >I10 s alc, eth; i aq
013 9-Octadecenoyl CH,(CH2),CH=CH-(CH2),COC1 300.92 2, 469 0.912 1.463020 1803rm >I10
chloride
014 Octadecyl acrylate H2C=CHC02(CH,),,CH, 324.55 Z4, 1468 0.800 32-34 >I10
015 Octadecylamine CH~(CH,)I,~K 269.52 4, 196 0.777,' 55-57 232,:" >I10 s alc, bz, eth
016 Octadecyl isocyanate CH,(CH,),,NCO 299.51 43. 439 0.847 1.450120 15-16 173'""' 148
017 Octadecylmchloro- CH,(CH,) ,,SiCl, 387.94 0.984 1.460220 223Icm" 89
silane
018 Octadecyl vinyl ether CH,(CH,),,OCH=CH, 296.54 0.821:O 1.4440'0 28 1875-m 177
019 1,7-Octadiene H,C=CH(CH,),CH=CH, 110.20 0.746 1.422020 114-121 9
020 I H , lH,5H-Octafluoro- HCF,CF,CF,CF,CH,OH 232.07 lo, 1648 1.664720 1.317X20 140-141 75
I-pentanol
021 Octamethylcyclotetra- 296.62 43, 1885 0.956 1.395820 17-18 176 60
siloxane
022 Octamethyltrisiloxane 236.54 43, 1879 0.8200'0 1.3848,O ca. -80 I53 29 s bz, PE; sl s alc
023 Octane 114.23 1, 159 0.7028:O 1.397420 - 56.8 125.7 22 s eth; sl s alc
024 1,8-Octanediamine 144.26 4,271 50-52 225-226 165
025 1.8-Octanedioic acid 174.20 2,691 140-144 23OLSm 0.16 aq; 0.6 eth, s alc
026 1,2-Octanediol 146.23 13,2217 36-38 132'""' >110
027 1,8-0ctanediol 146.23 1,490 59-61 17220m v s alc; sl s aq, eth
028 Octanenitrile 125.22 2,349 0.813520 1.42OZ2O -45.6 198 73 s eth; sl s alc
029 1-Octanethiol 146.30 13, 1710 0.843 1.452520 -49.2 199.0 68 s alc
030 Octanoic acid 144.21 2,347 0.90881O 1.427gZ0 16.6 239 >110 0.07 aq; v s alc, chl,
eth, PE
031 y-Octanoic lactone 142.20 17,244 0.981 1.444020 234 >llO
032 1-Octanol CHdCHz),OH 130.23 1,418 0.82581O 1.429020 - 15.5 195 81 0.06 aq; misc alc, chl,
eth
033 (?)-ZOCtanOl CH,(CH,),CH(OH)CH, 130.23 1,419 0.8193:" 1.42022" -31.6 175 71 0.1 aq; misc, alc, eth
034 3-Octanol CH,(CH,),CH(OH)CH,CH, 130.23 1'. 208 0.819 1.426OZo 174-176 65
035 4-O c tan o l CH,(CH2),CH(OH)CH,CH,CH, 130.23 0.8 19Z20 1.4252'' 176.6 71
036 2-Octanone CH,(CH,),COCH, 128.22 1, 704 0.819i0 1.415OZ0 - 16 173 52 i aq; misc alc, eth
037 3-Octanone CH,(CH,),COCH,CH, 128.22 1,706 0.8220i0 1.41502O 167-168 46 i aq; misc alc, eth
038 4-Octanone CH,(CH,),COCH,CH,CH, 128.22 1,706 0.809 1.4139" 164 45
039 Octanoyl chloride CH,(CH,),COCl 162.66 2,348 0.955 1.43502O < -70 195 80 dec aq, alc; s eth
040 1-Octene CH,(CH,),CH=CH, 112.22 1.221 0.7149:O 1.40872'' - 102 121 21 i aq; misc alc, eth
041 2-Octen-1-ylsuccinic 210.27 1.000 1.469420 8-12 168'- >110
anhydride
042 Octyl acetate 172.27 2, 134 0.868 1.418520 211 88 sl s aq; misc alc
043 Octyl aldehyde 128.22 1, 704 0.821f 1.418320 12-15 171 51 sl s aq; misc alc
044 Octylamine 129.25 4, 196 0.782 1.42902O -51-1 175- 177 62 i aq; s alc, eth
045 Octyl cyanoacetate 197.28 0.934 1.44902" 950.11mm >110
046 Octyl gallate 282.34 lo3, 2079 101-104
047 1-Octyl-2-pyrrolidine 197.32 0.920 1.46502'' - 25 172L5m >110
048 Octyltrichlorosilane 247.67 4,. 1907 1.0702" 1.44732u 22673hnm 96
049 1-Octyne 110.19 1,258 0.74572'' 1.4159,O - 79.3 126.2 17 i aq; s alc, eth
050 1-Octyn-3-01 126.20 13, 1996 0.864 1.441020 831qmm 63
051 L-(+)-&thine 132.16 4,420 140 v s aq, alc; sl s eth
052 Oxalic acid 90.04 2,502 190 dec 14 aqZ0;40 alc; 1.3 eth
053 Oxalic acid dihydrate 126.07 2,502 - 2H,O, 14 aq; 40 alc; 1 eth
102
(Continued)
(Continued)
2.217
2.218

Const-xs of Organic Compounds (Continued)
(Conrinued)
a
0)
Solubility in 100
100
054 Oxalyl bromide BrC(=O)C(=O)Br 215.84 2l, 236 1.52202O - 19 103'20m;i none
055 Oxalyl chloride clc(=o)c(=o)cl 126.93 2. 542 1.455 1.429N0 - 10 64 none s eth; viol dec aq, alc
056 Oxalyl dihydrazide H:NNHC(=O)C( =O)NHKH, 118.10 2.559 240 dec s hot aq; sl s alc, eth
057 Oxamic hydrazide H,KC(=O)C(=O)%H, 103.08 2, 559 218 dec s atk; sl s aq; i eth
058 Oxamide H,NC(=O)C(=O)NH, 88.07 2.545 1.667ao dec 350 sl s hot aq, alc
059 2-Oxazolidone 87.08 21, 135 86-89 22oL8""
060 2-Oxobutyric acid CH,CH,C(=O)CO,H 102.09 3, 629 1.200~7 1.3972'O 32-34 8216- 81 Y s aq, alc; v sl s eth
061 2-Oxohexamethylene- 113.16 212, 216 1.02;' 69.2 270 125 84 aq; v s alc, eth,
imine chlorinated HC's
062 5-Oxohexanonitrile CH,CO(CH,),CN 111.14 33, 1234 0.975 1.432g20 240 107
063 4-Oxopentanoic acid CH,COCH,CH,CO,H 116.12 3, 671 1.1447:' 1.439620 33-35 246 137 v s aq, alc. bz, eth
064 2-Oxopropionaldehyde CH,C(=O)CHO 72.06 1, 762 1.015524 1.420920 72 none s aq, alc
065 2-Oxopropionic acid CH,C( =O)CO,H 88.06 3, 608 1.2671* 1.431 5 2 0 11.8 165 dec 82 misc aq, alc, eth
066 2-0x0- 1-pyrrolidine- 138.17 1.120 1.48802O 140° 3m >110
propionitrile
0662. 2.2'-0xybis[2-rnethyl]- 130.23 0.7658 1.394920 107 dec acids
propane
067 2,2'-0xydiacetic acid 134.09 3, 234 142-145 dec v s aq, alc; sl s eth
068 4,4'-0xydianiline 200.24 13,441 190-192 218
069 3,3'-Oxydipropio- 124.14 1.043 1.440520 1120.S"rn >110
nitrile
PI Paraformaldehyde 1, 566 165 dec 71 s(s10w) aq; s alk; i alc,
eth
P2 Paraldehyde 132.16 19,385 0.998415 1.4049" 12.6 124 11 aq; misc alc, chl
P3 Parathion 291.27 1.26j5 1.537025 6 375 v s alc, bz, eth
p4 Pentabromophenol 488.62 6,206 223-226 sl s alc, eth
P5 Pentachloroacetone 230.31 1,690 1,656 1.496720 21 ( d y d ) 192 none i aq; v s acet
P6 Pentachlorohenzene 250.34 5,205 1.834216 82-85 215-217 none v s bz, chl, eth
P7 Pentachloroethane 202.30 1, 87 1.6712j5 1.5030zo - 29.0 160 none 0.05 aq; misc alc, eth
~8 Pentachloronitro- 295.34 5, 247 1.718,Y 140-143 s bz, chl
benzene
P9 Pentachlorophenol 266.34 6, 194 1.978z2 190-191 310 v s alc; s bz; 148 eth
PI0 Pentachloropyridine 251.33 20,232 124-126
PI1 Pentadecane 212.42 1,172 0.76841 1.4319*O 9.9 210 132 v s alc, eth
PI2 Pentadecanenitrile 223.40 2l, 163 0.825 1.442010 20-23 322 >110
P13 8-Pentadecanone 226.40 1, I11 41-43 118 >110 s alc
3-Pentadecylphenol 304.52 50-53 195'- >110
1.2-Pentadiene 68.12 1, 251 0.6926p 1.42092O - 137.3 44.9
cis-l.3-Pentadiene 68.12 1, 251 0.691010 1.436320 - 140.8 44.1 - 28
tram-1,3-Pentadiene 68.12 1, 251 0.676020 1.430lZ0 -87.5 42.0 - 28
1.4-Pentadiene 68.12 1, 251 0.6608,Y 1.38W0 - 148.3 26.0 4
Pentaqthritol 136.15 1, 528 1.38,Y 1.548 260 6 aq; v sl s alc; i eth
Pentaerythritol 510.72 1.018 29-31 >110
diacrylate
monostrearate
Pentaerythritol 298.30 1.180 1.48&lZ0 >110
hiacrylate
Pentaerythrityl 316.15 12, 602 1.1773p 140 explodes s acet; sl s eth, alc
tetranitrate on
shock
P23 Pentaethylenehex- 232.38 44, 1245 0.950 1.509620 >110
amine
P24 Pentamethylbenzene 148.25 5, 443 0.917$0 1.52720 54.4 231 91 v s alc, bz
~ 2 5 1.2.3.4.5-Pentamethyl- 136.24 0.870 1.473320 5813- 44
cyclopentadiene
N,N,N ',N ',N"-Penta- 173.30 4,4, 1245 0.830 1.44202O -20 198 53
methyldiethylene-
triamine
P27 1.5-Pentamethylene- 138.17 2@. 213 59-61 19412mm
tetrazole
P28 Pentanal CH3CH2CHzCK,CH0 86.13 1, 676 0.8095io 1.3942" - 92 103 12 1.4 aq; misc alc, eth
P29 Pentane CH3CH2CHzCHzCH3 72.15 1, 130 0.6262a0 1,357520 - 129.7 36.0 - 49 misc alc, eth
P30 1,5-Pentanediamine HJ(CHANH2 102.18 4, 266 0.873z5 1.459120 - 129.7 178-180 62 s aq, alc; sl s eth
P3 1 1,Z-Pentmediol CH3CH2CHzCH(OH)CH20H 104.15 12, 548 0.971 1.439720 206 104
P32 1,5-Pentanediol HO(CH,),OH 104.15 1,481 0.994lZ0 1.449420 - 18 239 129 s aq, alc; sl s eth
P33 2,3-Pentanedione CH,CH,C( =O)C( =O)CH, 100.11 1, 776 0.957 1.406820 - 52 110-112 19
P34 2,4-Pentanedione CH,COCH,COCH, 100.11 1, 777 0.9721" 1.451P0 -23.1 138 34 17 aq; misc alc, eth
P35 Pentanenitrile CH,CH,CH,CH,CN 83.13 2, 301 0.8035:5 1.399115 - 92 141.3 40 i aq; s alc, eth
P36 1-Pentmesulfonic acid, CH,(CHJ,SO: Na' 174.19 4,, 23 > 300 4 a¶
sodium salt
(Continued)
(Continued)
2.219
2.220

(Conrme~

100
reference g/mL
"C point, °C
"C point, °C
"C parts solvent
P37 1-Pentanethiol CH,(CH,).$H 104.22 1,384 0.840 1.4460zo - 75.7 126.6 18 i aq; misc alc, eth
P38 Pentanoic acid CHdCHWOzH 102.13 2,299 0.9390i0 1.408OZ0 - 33.7 186 96 2.4 aq; v s alc, eth
P39 1-Pentanol CHdCHJW 88.15 1,383 0.8146z0 1.410W0 - 79 137.5 33 2.7 aq2z;misc alc, eth
p40 2-Pentanol CH,CH,CH,CH(OH)CH, 88.15 1,384 0.80981O 1.405420 - 73 119.3 34 16.6 aqZ0;misc alc, eth
p41 3-Pentanol CH,CH,CH(OH)CH,CH, 88.15 1,385 0.8150:' 1.407725 - 69 116 41 5.5 aq20; s alc, eth
p42 2-Pentanone CH,CH,CH,COCH, 86.13 1,676 0.809520 1.390OZ0 -76.8 102 7 misc acet, bz, eth, PE
P43 3-Pentanone CH,CH,COCH,CH, 86.13 1,679 0.814320 1.3920" - 39.0 102.0 13 3.4 aq
p44 Pentanophenone C~H,CO(CHZ)$H, 162.23 7,327 0.988 1.5143M 107'- 102 s alc, eth
p45 Pentanoyl chloride CH,(CH,),COCl 120.58 2,301 1.016 1.421bM 125-127 32
P46 1,4,7,10,13-Pentaoxa- [-C%CHzO-l5 220.27 1.109 1.465OZ0 135°.2""" >110
cyclopentadecane
P47 2,5,8,11,14-Pentaoxa- CH3(OCHzCH,),0CH, 222.28 l', 2107 1.0087i0 1.433020 - 27 275-276 140 s aq; misc hydrocarbon
pentadecane solvents
P48 1-Pentene CH,CH,CH,CH=CH, 70.14 1,210 0.6429z0 1.3714,O - 165 30.1 - 18 misc alc, bz, eth
P49 cis-2-Pentene CH3CH2CH=CHCH, 70.14 1,210 0.6503~0 1.381320 - 151 37.0 - 20 misc alc, eth
P50 trans-2-Pentene CH,CH,CH=CHCH, 70.14 1,210 0.6482f 1.379ZZ0 - 140 36.3 -45 misc alc. eth
P5 1 cis-Z-Pentenenitrile CH,CH,CH=CHCN 81.12 Z2, 400 0.820 1.4269,O 128 23
P52 trans-3-Pentenenitrile CH,CH=CHCH,CN 81.12 2,427 0.837 1.422120 144-147 40
P53 Pentyl acetate CHdCHAOzCCH3 130.19 2, 131 0.8753M 1.402OZ0 - 70.8 149.2 16 0.17 aq; misc alc, eth
P54 Pentylamine CH~(CHZ)J'W 87.16 4, 175 0.754420 1.44820 - 55 104 -1 v s aq; misc eth; s alc
P55 Pentylbenzene CH,(CHZ)~CJ% 148.25 5,434 0.8594:O 1.488SZ0 -78.3 202.2 65 s alc, misc bz, eth
P56 2-Pentylcinnam- C&i5CH=C[(CH,)4CH3]CH0 202.30 7,, 310 0.970 1.557lM 290 >I10
aldehyde
P57 4-tert-Pentylphenol CH,CH,C(CH,),C&OH 164.25 6,548 0.962j0 93 262 s alc, eth
P58 1-Pentyne CH,CH,CH,C=CH 68.11 1,250 0.690 1f 1.385ZZo - 106 40.2 - 34 v s alc; misc eth
P59 Perfluoro-1-octane- CF,(CFz),SOzF 502.12 Z4, 996 1.824 1.301OZ0 154- 155 none
sulfonyl fluoride
P60 Peroxyacetic acid CH,C( =O)CO,H 76.05 2, 169 1.226:' 1.387bZ0 - 0.2 110 41 v s aq, alc, eth
P6 1 Petroleum ether Principally pentanes and hexanes Merck: 0.640 1.363OZ0 35-60 - 49 misc bz, chl, eth, CC&;
12,1329 s glacial HOAc
P62 Phenanthrene 178.23 5,667 1.063 100 340 1.6 alc; 50 bz; 30 eth
P63 1,lo-Phenanthroline 180.21 23,221 114-117 0.3 aq; 1.4 bz; s alc,
acet
P64 Phenethylisobutyrate (CH3),CHC0,CH2CH,C6H, 192.26 b2,451 0.988 1 .488OZ0 250 108
~ 6 5 Phenol C6H,0H 94.11 6,110 1.05761' 1.541g4' 41 182 79 6.7 aq; 8.2 bz; v s alc,
chl, eth, alk
P66 Phenolphthalein 318.33 18, 143 1.299 261-263 8.2 alc; 1 eth
P67 Phenothiazine 199.28 27,63 185.1 371 v s bz; s eth; sl s alc
P68 Phenoxyacetic acid C6H,0CHzCOzH 152.15 6,161 98-100 285 sl dec 1.3 aq; v s alc, hz,
HOAc, CS,, eth
P69 Phenoxyacetyl chloride C6H50CHzCOC1 170.60 6, 162 1.235 1.534020 225-226 108 dec aq, alc; s eth
P70 4-Phenoxyaniline c6H50c6H4m2 185.23 13,438 84 189l"- s hot aq; v s alc, eth
P7 1 2-Phenoxybutyric acid CH3CHzCH(OC6H5)COzH 180.20 6, 163 79-83 258 sl s aq
P72 2-Phenoxyethanol C6H50CHzCHzOH 138.17 6, 146 1.10257 1.537OZo 14 245.2 >110 s aq; v s alc, eth
P73 1-Phenoxy-2-propanol C6H50CH,CH(OH)CH3 152.19 6', 85 1.063p 1.52320 13-18 240 135
P74 2-Phenoxypropionic CH3CH(OC6H5)COzH 166.18 6, 163 116-119 265 s alc; sl s aq
acid
P75 3-Phenoxypropyl C6H50(CHz)3Br 215.10 6, 142 1.365 1.54602O 134l"- 96
bromide
P76 3-Phenoxytoluene C6H50C6H4CH3 184.24 6,377 1.051 1.572720 271-273 >110
P77 Phenylacetaldehyde C6H5CHzCH0 120.15 7,292 1.0273 1.52902O 33-34 195 86 sl s aq; s alc, eth
~ 7 8 Phenylacetaldehyde C6H5CHzCH(OCHJz 166.22 7,293 1.004 1.49302O 221 83
dimethyl acetal
P79 Phenylacetaldehyde 164.21 194,220 1.100 1.522OZ0 12012mm 107
ethylene acetal
P80 Phenyl acetate C6H50zCCH3 136.15 6, 152 1.073 1.50302O 196 76 misc alc, eth, chl
P81 Pbenylacetic acid C6H5CH2COzH 136.15 9,431 1.091:' 76.5 265.5 s hot aq, alc, eth
~ 8 2 Phenylacetonitrile C&H,CHzCN 117.15 9, 441 1.0214 1.523320 - 23.8 233.5 101 i aq; misc alc, eth
P83 Phenylacetyl chloride C6H5CH2COC1 154.60 9,436 1.169 1.5325" 9512- 102 dec aq, alc
P84 Phenylacetylene C6H,C=CH 102.14 5,511 0.9300 1.547OZ0 - 44.9 142.4 31 misc alc, eth
~ 8 5 Phenylacetylurea C6H5CHzCONHCONH, 178.19 Merck 212-216 sl s alc, hz, chl, eth
12,7343
(?)-3-Phenylalanine C6H5CH2CH(NH2)C0,H 165.19 14,495 27 1-273 1.4 aq
Phenyl4-amino- H2NC6H3-2-(OH)COzC6Hs 229.24 Merck; 153 0.7 mg aq
salicylate 12,7426
4-Phenylazoaniline C6HSN=NC6H4NH, 197.24 16', 310 123-126 >360 v s alc, bz, chl, eth
Phenylazoformic acid C&N=NCONHNHC&H, 240.27 16, 24 156-159
2-pbenylhydrazide dec
~ 9 0 CPhenylazophenol C&N=NC,,H40H 198.23 16.96 150-152 2302- v s alc, eth
P91 2-Phenylbenzimidazole 194.24 23,230 293-296 s abs alc; sl s bz, chl
P92 Phenyl benzoate ~ ~ s ~198.22 9,~116 z1.235 ~ ~69-72 ~ 298-299 ~ v s hot alc; sl s eth
P93 N-Phenylbenzylamine C6H5CH2NHC6& 183.25 12, 1023 1.061 35-38 306-307 >110 s alc, chl, eth
P94 tmns-4-Phenyl-3- C&CH=CHCOCH, 146.19 7, 364 1.0097i5 1.583645 41.5 260-262 65 v s alc, bz, chl, eth
buten-2-one
(Continued)
(Continued)
2.221
2.222

(Conrme~
N
N
Formula Beilstein Density, Refractive
Refractive Melting Boiling Flash Solubility in 100
100
reference g/mL
P/mL index point, °C
P95 2-Phenyl-3-butyn-Z-ol CH,C(OH)(C,H,)C=CH 146.19 62, 559 47-49 217-218 96 0.8 aq; s alc, bz, acet
P96 3-Phenylbutyraldehyde CH3CH(C6H5)CH,CH0 148.21 7', 168 0.997 1.517920 9416- 96
P97 2-Phenylbutyric acid CH3CH2CH(C6Hs)C02H 164.20 g2, 356 1.055 1.516020 42-44 270-2 ZllO s bz, eth
P98 2-Phenylbutyronitrile CH3CH2CH(C6Hs)CN 145.21 9,541 0.974 1.508620 11415- 105
P99 Phenyl chloroformate cJr502cc1 156.57 6, 159 1.248 1.510720 7 1- 75
PI00 Phenyl dichloro- C6H50P(0)Cl2 210.98 6, 179 1.412 1.52302O 241-243 ZllO
phosphate
PI01 N-Phenyldiethanol- 181.24 12, 183 1.120% 56-80 350 sl dec 5 aq; v s alc; 29 eth;
amine 25 bz
PI02 4-Phenyl-l,3-dioxane 164.21 19l, 616 1.111 1.53002" 250-251 >llO
p103 2-Phenyl-l,3-dioxolane 150.18 1.106 1.526020 80"'- 98
PI04 1,2-Phenylenediamine 108.14 13, 6 103 257 v s alc, chl, eth; sl s aq
p105 1,3-Phenylenediamine 108.14 13, 33 1.13915 63.5 285 s aq, alc, acet, chl
p106 1,4-Phenylenediamine 108.14 13, 61 146 267 156 1 aq; s alc, chl, eth
p107 1,4-Phenylene diiso- 160.13 13, 105 97-98 260 >I10
cyanate
PI08 1-Phenyl- 1,2- 138.17 6,907 66-68 272-274 v s aq, alc, bz, eth, chl,
ethanediol HOAc
PI09 1-Phenylethanol 122.17 6,475 1.013020 1.52702" 20 204 85 2.3 aq
PI10 2-Phenylethanol 122.17 6,478 1.023;: 1.531720 - 27 221 102 2 aq; misc alc, eth
plll 2-Phenylethyl acetate 164.20 9,510 0.984 1.49852" 238-239 101 2 aq; misc alc, eth
PI12 2-Phenylethylamine 212.18 12, 1096 0.9640,y 1.529P5 10 197.5 90 80 aq"; s alc; i eth
pl13 1-Phenylethyl 178.23 S, 1680 1.007 1.489520 925m 94
propionate
p114 (+.)-2-Phenylglycine 151.17 14,460 sub1 255 s org solvents, alk
p115 I-Phenylheptane 176.30 5,451 0.860 1.48502" 233 95
pl16 I-Phenylhexane 162.28 52, 337 0.861 1.48601O - 61 226 83 misc eth
p117 Phenylhydrazine 108.14 1 j 2 , 44 1.0978ao 1.608O2" 19.5 243 88 misc alc, bz, chl, eth
PI18 Phenyl l-hydroxy-2- 264.28 10, 332 94-96
naphthoate
pl19 Phenyl3-hydroxy-2- 264.28 10,335 129-132 261'-
naphthoate
p120 2-Phenylimidazole 144.18 23, 182 144-147
pl2l 2-Phenyl-2-imidazoline 146.19 23, 154 94-99
p122 2-Phenyl-1.3- 222.28 7,808 148-150
indandione
p123 2-Phenylindole 193.25 20,467 188-190 25OLomm
p124 Phenyl isocyanate C,H,NCO 119.12 12,437 1.535020 - 30 162-163 55 dec aq, alc; s eth
p125 Phenyl isothiocyanate C,H,NCS 135.19 12,453 1.649720 - 21 221 87 i aq; s alc, eth
p126 N-Phenylmaleimide 173.17 21.400 85-87 163'2m s alc, chl, eth
p127 Phenylmalonic acid C&CWCOzH)z 180.16 153 dec
p128 Phenylmercury(II) C,H5Hg02CCH, 336.74 Merck 150-152 0.17 aq; s alc, bz, acet
acetate 12,7453
p129 Phenylmercury(II) C,H,HgCl 313.15 Merck 250-252 s bz, eth, pyr
chloride 12,7454
p130 Phenylmercuty(II) C6H5HgOH 294.70 16,952 190 dec
hydroxide
p131 N-Phenylmorpholine 163.22 27, 6 1.058270 51-54 268 >I10 1.0 aq; v s hot alc
p132 N-Phenyl- 1- 219.29 12, 1224 60-62 22615mm s alc, bz, chl, eth
naphthylamine
PI33 N-Phenyl-2- 219.29 12, 1275 107-109 395
naphthylamine
p134 2-Phenyl-2-oxazoline 147.18 27.47 1.118 1.56702" 12 750,3mm
p135 2-Phenylphenol 170.21 623

fj2, 1.213 57-59 282 123 s alc, chl, eth, alk
p136 4-Ph e n y l ph e n o l 170.21 6,674 165- 167 321 165 s alc, chl, eth, alk
p137 N-Phenyl-1,4- 184.24 13.76 73-75
phenylenediamine
p138 Phenylphosphinicacid 142.09 16,791 85-87
p139 Phenylphosphonicacid 158.09 16,803 163-166
p140 Phenylphosphonic 194.99 16,804 1.375 1.56002° 3 258 >110
dichloride
p141 N-Phenylpiperazine 162.24 233,49 1.0621y 286 >llO i aq; misc alc
p142 1-Phenylpiperidine 161.25 20,22 1.001 3-4 257-258 106
p143 2-Phenyl-1.2- CH,C(CsH,)(OH)CH20H 152.19 6,930 44-45 16226mm >110
propanedio1
PI44 3-Phenyl-l- CsH,CH2CH2CHzSH 152.26 6l,253 1.010 1.549420 1091- 90
propanethiol
p145 1-Phenyl-1-propanol CJ5CH(OH)CH2CH, 136.19 6,502 0.9915,Y 1.52002° 219 90 misc alc, bz
p146 3-Phenyl- 1-propanol C.&CH2CH2CH2OH 136.19 6,503 1.008 1.5257M - 18 235 109 s aq; misc alc, eth
p147 1-Phenyl-2-propanone C&15CH2COCH3 134.18 72, 233 1.01572O 1.516020 27 10013- 84 v s alc, eth; misc bz
p148 2-Phenylpropion- CH3CH(Cd-15)CH0 134.18 7,305 1.009:o 1.517520 202-205 76 i aq; s alc
aldehyde
(Continued)
(Continued)
2.223
2.224
N
N
P

Solubility in 100
100
p149 3-Phenylpmpion- C&.CH2CH2CH0 134.18 7, 304 1.019 1.523oM 9812m 95
aldehyde
p150 3-Phenylpropionic acid C6H5CH2CHzCOzH 150.18 9,508 1.047lp 47-49 280 >110 0.6 aq; s bz, alc, chl,
eth, HOAc, PE
p151 l-Phenyl-3- 162.19 24. 2 121-123 10 hot aq; s hot alc,
pyrazolidinone alk, acid
p152 2-Phenylpyridme 155.20 20.424 1.086 1.633220 268-270 > 110 s alc, eth
p153 2-Phenyl-4-quinoline- 249.27 22, 103 214-215 0.8 alc; 1 eth, 0.3 chl
carboxylic acid
p154 Phenyl salicylate 214.22 10.76 1.25 44-46 173lZm >I10 17 alc; 66 bz; s acet,
chl, eth, 0.015 aq
p155 Phenylsuccinic acid 194.19 9,865 167-169 -H20, s hot aq, alc, eth
> 168
p156 (Pheny1thio)aceticacid 168.21 6,313 64-66
p157 S-Phenyl thio- 152.22 6,4, 1524 1.056 1.54602" 129'Omm >I10
isobutyrate
p158 1-Phenyl-2-thiourea 152.22 12,388 1.3 154 0.25 aq; s alc, alk
p159 Phenyltrichlomsilane 211.55 16,911 1.32g20 1.5230" 20 1 91
PI60 Phenyltriethoxysilane 240.38 16,911 0.996 1.4604" 113'"" 42
p161 Phemylhimethoxy- 198.30 1b4, 1556 1.062 1.4680" 233 99
silane
p162 Phenyltrimethyl- 216.13 12, 158 215 dec v s aq;s hot alc
ammonium bromide
p163 PhenyItrimethy 1- 171.67 12, 158 237 sub1 s aq;v s alc; sl s eth
ammonium chloride
PI@ Phenyltrimethyl- 263.12 12, 159 227 sub1 s aq, alc; sl s acet
ammonium iodide
p165 Phenyltrimethyl- 375.95 12, 159 114-116
ammonium tribro-
mide
p166 Phenyltrimethylsilane 150.30 16', 525 0.873 1.49072n 168-170 44
p167 Phenylurea 136.15 12,346 1.302 145-147 238 s hot aq, hot alc, eth
p168 1,2-Phthalic acid C,H,- 1,2-(C02H), 166.13 9,791 1.593$ 230 rapid 0.6 aq; ;10 alc; 0.5 eth;
heating vslscbl
p169 Phthalic anhydride 148.12 17,469 1.53 131-134 295 151 0.6 aq(dec); s alc
p170 Phthalide 134.13 17,310 1.164y 72-74 290 s alc
p171 Phthalimide 147.13 21,458 234-236 v s alk,v sl s hz, PE
p172 1,2-Phthaloyl C6H,-l,2-(COCI), 203.02 9,805 1.409*O 1.568420 15-16 280-282 >110 dec by aq, alc; s eth
dichloride
p173 Phthalylsulfathioazole 403.44 Merck 272-277 s alk,sl s alc; i chl
12,7533
p174 Picric acid 2,4,6-(O,N),C,H,OH 229.1 1 6,265 1.763f 122-123 explodes 1.3 aq; 8.2 alc; 10 hz;
> 300 2.9 chl; 1.6 eth
p175 (+)-a-Pinene 136.24 5, 146 0.8591i0 1.465020 - 62 156 35 misc alc, eth
p176 (-)-p-Pinene 136.24 5, 154 0.859OZ0 1.47802O -61 166 38
p177 a-Pinene oxide 152.24 5, 152 0.964 1.469020 10350mm 65
p178 Piperazine 86.14 23, 4 1.446'13 108-110 145-146 109 v s aq; 50 alc; i eth
p179 1,CPiperazinebis- 302.37 Merck >300
(ethanesulfonic 12.7633
acid)
p180 Piperidine 85.15 20, 6 0.8622f - 13 106 4 misc aq; s alc, bz, chl
p181 1-Piperidinecarbo- 110.16 20.56 0.951 1021- 97
nitrile
p182 N-Piperidmeethanol 129.20 20,25 0.8732% 1.4804,O 199-202 68 misc aq; s alc
p183 2-Pipendineethanol 129.20 21, 2 1.01017 38-40 234 102 v s aq, alc, eth
p184 1-Pipendinepropionic 157.21 203, 1049 105-110 1080.5-
acid
p185 Pipexidinepropionitrile 138.21 0.933 1.4695,O 102
p186 Z-(Z-Pipendineethyl)- 190.29 0.985 1.526020 >110
pyridine
p187 L-Roline 115.13 22, 2 228 dec
p188 Propane CH,CH,CH, 44.10 1,103 0.584-42 1.340-" - 188 -42.1 - 104 volumes per 100 vols
solvent: 6.5 aq; 790
alc; 926 eth, 1300
chl; 1450 bz
p189 1,2-Ropanediamine CH,CH(NH,)CH,NH, 74.13 4,257 0.87815 1.44602O 119-120 33 misc aq, bz; s alc, eth
p190 1,3-Propanediamine H,NCH,CH,CH,NH, 74.13 4,261 0.884p 1.4575" - 12 140 48 misc alc, eth, s aq
p191 1,2-Propanediol CH,CH(OH)CH,OH 76.10 1,472 1.0364y 1.433lZo - 60 188 107 misc aq, acet, chl, s
alc, eth
p192 1.3-Ropanediol HOCHzCHzCHzOH 76.10 1,475 1.0538'O 1.4396,O - 27 214 79 misc aq, alc
(Continued)
(Continued)
2.225
2.226
N
N
N
0,

(Continued)
Formula Beilstein
Beilstein Density, Refractive
Refractive Melting Boiling Flash Solubility
Solubility in 100
100
"C point, °C
"C point, °C
"C parts solvent
p193 1,3-Propanediolhis- CH2(CHZCO,CC6H4NH,), 314.34 14,, 1034 1.140 124-127
(4-aminohenzoate)
p194 1,Z-Propanediol C,H,CO,CH,CH(CH,)- 284.31 9, 129 1.160 1.545020 -3 232L2m >110
dihenzoate O,CC,H,
p195 1,3-Propanedithiol HSCH,CH,CH,SH 108.23 1,476 1.0772;" 1.540520 ~ 79 172.9 58 misc alc, bz, eth, chl
p196 1-Propanesulfonyl CH,CH,CH,SO,CI 142.60 4,8 1.2864i5 1.4542," 668m 80 dec hot aq, hot alc
chloride
p197 1,3-Propane snltone 122.14 19,. 4 1.392 31-33 180,- >110
p198 1-Propanethiol CH,CH,CH,SH 76.16 1,359 0.836i5 1.43802" ~ 113 67-68 - 20 s alc, eth
p199 2-Propanethiol CH,CH(SH)CH, 76.16 1,367 0.809:5 1.425520 - 131 52.6 - 34 misc alc, eth, sl s aq
p200 1,2,3-Propanetriol H,CCO,CH(CH,O,CCH,), 218.21 2, 147 1.15802O 1.430Z2" ~ 78 259 138 7.2 aq; misc alc, bz,
tris(acetate) chl, eth
p201 1-Propanol CH,CH,CH,OH 60.10 1,350 0.803720 1.38402" - 127 97.2 23 misc aq, alc, eth
p202 2-Propanol (CH,),CHOH 60.10 1,360 0.7855t0 1.377Zz0 - 89.5 82.4 12 misc aq, alc, chl, eth
p203 2-Propenal H,C=CHCHO 56.07 1,725 0.841:O 1.401720 - 88 52.6 - 18 21 aq; s alc, eth
p204 Propene H,C=CHCH, 42.08 1, 196 0.610-,4* 1.3567-" - 185.2 - 47.7 - 108 vols in 100 vols
solvent: 45 aq; 1200
alc; 500 acet
p205 2-Propene-1-thiol H,C=CHCH,SH 74.15 1,440 0.925f 1.4765," 67-68 21 misc alc, eth
p206 irans-l,2,3-Propene- 174.11 2,849 190 dec 50 aqZ; 50 88% alcI2;
tricarhoxylic acid sl s eth
p207 1-Propen-2-yl acetate H,C=C(O,CCH,)CH, 100.12 0.909 1.40W0 97 18
p208 4-( 1-Propenyloxy- 158.16 1.100 1.461Ozo 251-252 >I10
methyl). 1,3-dioxo-
Ian-2-one
p209 2-Propenylphenol CH,CH=CHC,H,OH 134.18 6l, 279 1.044 1.578Ozo 230-231 90
p210 PPropiolactone 72.06 17l, 130 1.1460;O 1.413 lz0 ~ 33.4 162 70 37 aq(hyd); misc alc
(reacts);hz, eth,
acet
p211 Propionaldehyde CH,CH,CHO 58.08 1,629 0.8071io 1.3636,O -81 48 - 30 30 aq; misc alc, eth
p212 Propionamide CH,CH,CONH, 73.10 2,243 0.9597:O 1.4160J'0 79 222.2 v s aq, alc, chl, eth
p213 Propionic acid CH,CH,CO,H 74.09 2,234 0.9934Zn 1.380920 - 20.5 141.1 52 misc aq; s alc, chl, eth
p214 Propionic anhydride [CH,CH,C( =0)120 130.14 2,242 1.011020 1.4037,O ~ 45 170 63 dec aq; s alc, chl, eth
9215 Propionitrile CH,CH,CN 55.08 2,245 0.7818:O 1,3658," - 92.8 97.2 2 10 aq; misc alc, eth
p216 Propionyl chloride CH,CH2COCI 92.53 2,243 1.065:" 1.4O5lz0 ~ 94 80 11 dec by aq, alc
p217 Propiophenone C,H,COCH,CH, 134.18 72, 231 l.0105$n 1.525820 21 218.0 87 misc hz, eth, ahs alc
p218 2-Propoxyethanol CH,CHZCH20CH2CH20H 104.15 1,468 0.913 1.413OZn - 75 150-153 48
p219 2-(2-Propoxyethyl)- C,H4NCH,CH,0CH,CH2CH, 165.24 0.954 1.48802" 95
pyridine
p220 1-Ropoxy-2-propanol C5H,NCH2CH20CH2CH(OH)CH3 118.18 12, 536 0.885 1.41lPo 140-160 48
Ropoxytrimethylsilane CH,CH,CH,OSi(CHJ, 132.28 4,4, 3994 0.7682O 1.384PO 100735m.n -2
p221
p222 Ropy1 acetate CH3CH2CH,02CCH3 102.13 2, 129 0.8878 1.3844'O - 93 101.6 13 2.3 aq; misc alc, eth
p223 Ropylamine CH3CH2CH2NH2 59.11 4, 136 0.717320 1.387220 - 83 42.2 - 31 misc aq, alc, eth
p224 2-(Propylamino)- C,HlNHCH2CH20H 103.17 4,282 0.900 1.441520 1827d6m 78
ethanol
p225 Propylbenzene CH,CH,CH,C,H: 120.20 5, 390 0.8621:O I.4912,O - 99.2 159.2 47 s alc, eth
p226 Propyl benzoate C6H,C02CH,CH2CH3 164.20 9, 112 1.03220 1.501ff0 -51.6 230 98 i aq; s alc, eth
p227 Propyl butyrate CH3CH2CH2C02CH2CH2CH, 130.19 2, 271 0.879i5 1.40W0 - 95 143 38 sl s aq; misc alc, eth
p228 Propyl chloroformate C1C02CH,CH2CH, 122.55 3, 11 1.090 1.403420 105-106 28 misc bz, chl, eth
p229 Propylc yclohexane CH,CH,CH,C,H,, 126.24 5,, 23 0.7929:O 1.431ff0 - 94.9 156.7 35 s bz, eth
p230 Propylene carbonate 102.09 l9,, 1564 1.204120 1.421ff0 -48.8 242 135 v s aq, alc, bz, eth
p23 1 Propyleneimine CH,CH-CH, 57.09 20, 3 0.801725 1.4084" 66.0 - 15 misc aq, alc, PE
'Ni
p232 1,2-Propyleneoxide CH,CH-CH, 58.08 17, 6 0.828720 1.36602O - 112 34 - 35 41 aq; misc alc, eth
\O/ (CC)
p233 Propylene sulfide CH,CH-CH, 74.15 172, 15 0.946 1.476ffo 72-75 10
\s/
p234 Propyl formate CH,CH2CH202CH 88.10 2, 21 0.905820 1.377920 - 92.9 80.9 -3 2 aq; misc alc, eth
p235 Propyl4-hydroxy- HOC,H,C02CH2CH2CH, 180.20 10. 160 95-98 0.05 aq; \ s alc, eth
benzoate
p236 Propyl isocyanate CH,CH,CH,NCO 85.11 4', 366 0.908 1.394020 83-84 0
p237 Propyl lactate CH,CH(OH)C02CH2CH2CH, 132.16 3, 265 0.99620 1.416725 86401m s aq, alc. eth
p238 Propyl nitrate CH3CH,CH,0N0, 105.09 I, 355 1.0538Z0 1.397620 - loo 110.1 23 (may s alc. eth
ex-
plode
on
heat-
ing)
p239 2-Propylpentanoic acid (CH3CH,CH2),CHC02H 144.21 2, 350 0.921 1.425ffO 220 111
p240 2-Propylphenol CH,CH2CH,C6H,0H 136.19 6,499 1.01520 1.527g20 224-226 93 s alc, eth
p241 Propylphosphonic CH3CH2CH2P(0)C12 160.97 4. 596 1.290 1.464320 9P- >I10
dichl oride
p242 Propyltrichlorosilane CH,CH,CH,SiCI, 177.53 4, 630 1.18512O 1.42920 123-124 2
p243 I-Propyl-4-piperidone 141.22 0.936 1. 4 6 W o 56'- 75
p244 Propyl propionate CH,CH,CO,CH,CH,CH, 116.16 2, 240 0.88320 1.393520 - 76 122.5 19 0.5 aq; 103 alc; 83 eth
(Continued)
(Continued)
2.227
2.228
N
N
N
0)

(Continued)

Density Refractive Melting Boiling Flash Solubility in 100
100
"C point, °C
"C point, °C
"C parts solvent
P245 Ropy1 3,4,5-t1i- (HO),C,&IzCOzCH2CH2CH, 212.20 Muck 150 0.35 aq; 1 alc; 83 eth
hydroxybenzoate 12,8044
P246 Propyne CH,CECH 40.06 1, 246 0.691-j0 1.3725-" - 102.8 - 23.2 v s alc; 3000 mL eth
P247 2-Propynyl benzene- C6H,SO,CHzC=CH 196.23 113.37 1.243 1.52502O - 30 1421mm 100
sulfonate
P248 2-Propynoic acid HCECC0,H 70.05 2,477 1.138p 1.4320" 9 1022- 58 s aq, alc, eth
P249 2-Propyn-1-01 HCECH,OH 56.06 1,454 0.947820 1.432010 -51.8 114 36 misc aq, alc, bz, chl
p250 (+)-Pulegone 152.24 7, 87 0.93461, 1.4870" 224 85 misc alc, chl, eth
p251 Pyrazine 80.09 23.91 1.031i1 1.49536' 55 115 55 v s aq, alc, eth
p252 Pyrazinecarbonitrile 105.10 25,, 777 1.174 1.5340" 876m 96
p253 Pyrazinecarboxylic 124.10 25, 125 225 dec sl s hot aq; 0.008 abs
acid alc; i bz, chl, eth
p254 Pyrazole 68.08 23.39 1.4203 68 187 s aq, alc, bz, eth
p255 Pyrene 202.26 5,693 1.27lZ3 151 404 s org solvents
p256 Py ridazine 80.09 23.89 1.10351, 1.523OZ3 -8 208 85 misc aq, bz; v s alc,
eth
p257 Pyridine 79.10 20, 181 0.98271, 1.5067= -41.6 115.2 20 misc aq, alc, eth
p258 Pyridine-d, 84.14 20,. 2305 1.050 1.5092" 114.4 20
p259 2-Pyridinealdoxime 122.13 211,288 110-112
p260 4-Py ri di n e al d o xi m e 122.13 130-133
p261 2-Pyridinecarbox- 107.11 211,287 1.126 1.537010 181 54
aldehyde
p262 3-Pyridinecarbox- 107.11 211,288 1.135 1.5493" 9715- 60
aldehyde
p263 CPyridinecarbox- 107.11 21,287 1.122 1.544020 7812- 54 s aq, eth
aldehyde
P264 3-Pyridinecarboxamide 122.13 22.40 1.400 1.466 130-133 100 aq; 66 alc
p265 2-Pyridinecarboxylic 123.11 22.33 134-136 sublimes s aq, alc, bz; v s
acid HOAc
p266 3-Pyridinecarboxylic 123.11 22.38 1.473 236.6 sublimes 1.4 aq; s alk; v s hot
acid aq, hot alc
p267 4-Pyridinecarboxylic 123.11 22,45 319 2601,"" 0.52 aq; i alc, bz, eth
acid
p268 2.3-F'yridinedi- 167.12 22, 150 188-190 0.56 aq; s alk
carboxylic acid dec
p269 2,5-Pyridinedi- 167.12 22, 153 256 dec shot acid
carboxylic acid
p270 2.6-q.ridinedi- 167.12 22, 154 248-250 sl s aq; v sl s alc
carboxylic acid dec
p27 1 F'yridine-N-oxide C,H,NO 95.10 202, 131 61-65 270
p272 Pyridinium p-toluene- C,H,NH+ -O,SCJ.,CH, 251.31 202, 129 117-119
sulfonate
p273 2-F'yridylcarbinol (C,H,N)-Z-CHZOH 109.13 211, 203 1.131 1.54202'' >llO v s aq, alc, eth
p274 3-F'yridylcarbinol (C,H,N)-3-CH20H 109.13 21, 50 1.124 1.544520 >110 v s aq, eth
p275 3-(3-F'yridyl)-l- (CSH,N)-3-CH,CH,CH,0H 137.18 213, 549 1.063 1.530W0 >110
propanol
p276 3-(4-Pyridyl)-1- (C,H4N)-4-CHzCH,CH,0H 137.18 214, 550 1.061 35-39 289 >110
propanol
p277 Pyrimidine 80.09 23, 89 1.016 1.50402" 22 124 31 misc aq; s alc, eth
p278 2,4( 1H,3H)- 112.09 24, 312 335 0.3 aq; s alk
Pyrimidinedione
p279 Pyrrole 67.09 20, 159 0.9691:'' 1.5085'" -23.4 130 39 4.5 aq; v s alc, eth
p280 Pyrrolidine 71.12 20, 4 0.8586''' 1.4431'" -58 86.5 3 misc aq; s alc, chl, eth
p28 1 1-F'yrrolidinebutyro- 138.21 0.926 1.4605''' 1151smm 99
nitrile
p282 1-F'yrrolidinecarbo- 164.29 153-155
dithioic acid, am-
monium salt
p283 1-Pyrrolidinecarho- 96.13 0.954 1.4690'" 771.8- 101
nitrile
p284 1-Pyrrolidino-l- 151.25 0.940 1.522S2" 115's- 39
cyclohexene
p285 2-Pyrro1idinone 85.11 21, 236 1.116:, 1.480625 25 25 1 129 misc aq, ale, hz, chl,
eth, EtOAc
p286 3-(N-Pymolidino)- 145.20 20', 4 46-48 15836"" >110
1,Z-propanediol
ql Quinhydrone 218.20 7, 617 1.401:" 171-173 shot aq, alc, eth
q2 Quinine 324.44 23,511 1.625 173-175 125 ale; 1.2 bz; 83 chl
q3 Quinoliine 129.16 20, 339 1.095f 1.6273''' -15 237 101 0.6 aq; misc alc, eth
q4 Quinoxaline 130.15 23, 176 1.334:8 1.623148 29-32 220-223 98 v s aq, ale, bz, eth
q5 2-Quinoxalinol 146.15 24, 147 271-272
rl D-Raflinose penta- 594.52 31, 462 80-82 dec 118 14 aq; 10 MeOH
hydrate
r2 Resorcinol 110.11 6, 796 1.272 110-1 12 280 111 aq; 111 ale; v s
eth
r3 Resorcinol 1,3- 194.19 6, 816 1.178 1.5030''' 14612""" >110
diacetate
(Continued)
(Continued)
2.229
2.230

Solubility in 100
100
No.
No Name Formula weight reference g/mL
"C point, °C
"C point, °C
"C parts solvent
r4 Resorcinol CH3C0,C6H,-3-(OH) 152.15 6, 816 1.223 1.537OZ0 ca 283 >110 i aq; misc alc, bz, chl,
monoacetate acet; s alk OH'S
r5 Resorcinol C6H,C0,C6H,-3-(OH) 214.20 133-135
monobenzoate
r6 Rhodamine B 479.02 19,345 210-211 v s aq, alc
dec
r7 Rbodanine 133.19 27,242 0.868 167- 170 v s hot aq, alc, eth
may ex-
plode
on rapid
heating
r8 Riboflavin 376.37 Merck: dec 278- v s alk(dec); i acet, bz,
12, 8367 282 eth; sl s pentyl ace-
tate, cyclobexmol
l
9 D-Ribose 150.13 1, 859 88-92 s aq; sl s alc
sl Saccharin 183.19 27, 168 0.828 228-230 0.34 aq; 3 alc; 8 acet
s2 Safrole 162.19 19,39 1.09520 1.537OZ0 11.2 232-234 97 v s alc; misc chl, eth
s3 Semicarbazide HJWHCONH, . HC1 111.53 3, 98 175-177 v s aq, alc; i eth
hydrochloride dec
s4 L-Serine HOCH,CH(NHJCO,H 105.09 4, 505 222 dec s aq; v sl s alc, eth
s5 D-Sorbitol 182.17 1,533 1.472-, 98-100 if 83 aq; s hot alc, acet
hY-
drated;
111 an-
hYd
s6 L-Sorbose 180.16 1,927 1.65', 163-165 55 aq; v sl s alc
s7 Squalane 422.83 l', 72 0.8115IS 1.453015 - 38 350 218 s bz, chl, eth, PE
s8 Squalene 470.73 l', 130 0.8584z0 1.496P - 75 285zsm 200 v s eth, acef PE
s9 trans-Stilbene 180.25 5,630 0.970 122-124 307 v s bz, eth

s10 (-)-Strychnine 334.42 27,, 723 1.36i0 284-286 2705"" 0.66 alc; 20 chl; 0.55
bz; 0.15 mg aq
sll Styrene C,H,CH=CH, 104.15 5,474 0.906OZ0 1.546320 -31 145 31 s alc, acef eth, CS,
s12 Styrene oxide H$-CHC6HS 120.15 17,49 1.054 1.533820 - 37 194 19

Y
s13 Succinamic acid H,NCOCH,CH,CO,H 117.10 2,614 153-156 s aq; sl s alc; i eth
s14 Succinamide H,NCOCH,CH,CONH, 116.12 2,614 265 dec 0.45 aq; i alc, eth
s15 Succinic acid H02CCH,CH2C0,H 118.09 2,601 1.552 188 235 dec 7.7 aq; 5.4 alc; 2.8
acet; 0.88 eth; i bz
s16 Succinic anhydride 100.07 17,407 119.6 261 s alc, chl; v sl s eth
s17 Succinimide 99.09 21,369 1.41 123-125 285-290 33 aq; 4 alc; i eth
s18 Succinonihile NCCH,CH,CN 80.09 2,615 O.98WW 1.417360 54.5 266 132 see b456
s19 Succinyl chloride ClCOCH,CH,COCl 154.98 2,613 1.395:5 1.47315 16-17 190 76 dec by aq, alc; s bz
s20 Sucrose 342.30 31,424 1S87i5 185- 187 200 aq; 0.59 alc
s21 Sulfadiazine 250.28 Merck 252-256 sl s aq, alc, acet; v s dil
12,9071 InineIalacids, alk
s22 Sulfamethazine 278.34 Merck 198-201 0.15 aq; s alk
12,9083
s23 Sulfamic acid HSO,NH, 97.09 Merck 2.15 205 dec 13 aq; s1 s alc, acet; s
12, 9090 bases
s24 Sulfanilamide H,NC6H,S0,NH, 172.21 14,698 164-166 0.76 aq; 2.7 alc; 20
acet; s acid, alk
s25 Sulfanic acid 4-(H,N)-C,H,SO,H 173.19 14,695 d 288 1.45 aq; sl s hot
MeOH
s26 Sulfoacetic acid HCO,CH,SO,H 140.11 4, 21 84-86 245 dec s aq, alc; i eth, chl
s27 2-Sulfobenzoic acid 184.17 19, 110 18618"" s bz, chl, eth, i aq
cyclic anhydride
s28 4,4'-Sulfonylbis(2,6- [2,6-(Br),-C&I,0H],S02 565.88 6,865 303-306
dibromophenol)
s29 4,4'-Sulfonylhis(methyl (CH,O,CC,H,),SO, 334.35 lo2, 109 195-196
benzoate)
s30 4,4'-Sulfonyldiphenol (HOC,H,),SO, 250.27 6,861 1.366315 245-247 s alc, eth, acet; i aq
s31 5-Sulfosalicylic acid HO,SC,H,(OH)CO,H 254.21 11,411 120 anhyd v s aq, alc; s eth
tl tartaric acid 150.09 3,520 1.7598a0 172-174 139 as"; 59 MeOH;
33 EtOH; s glyc;
0.4 eth
t2 tartaric acid 150.09 3,481 1.7598i0 168-170 139 aq20;59 MeOH;
33 EtOH; s glyc;
0.4 eth
t3 meso-Tartaric acid HO,CCH(OH)CH(OH) 168.11 3,528 1.666f; 140; also 125 aq"
monohydrate CO,H. H,O 1.737 159-160
also
(Continued)
(Continued)
2.231
2.232

Solubility in 100
100
No.
g/mL- index point, °C
0C point, °C
"C point, °C
"C parts solvent
t4 D L - T ~ acidC HO,CCH(OH)CH(OH). 168.11 3,522 1.697a0 210-212 20.6 aqZo;5 alcz5; 1 eth
monohydrate C02H H,O
t5 Tmazine 534.37 25, 252 v s aq
t6 Terephthaldicarbox- CsH4-1,4-(CHO), 134.13 7,675 115-116 245-248
aldehyde
t7 m-Terphenyl CsH5-CsH,-C6H5 230.31 5,695 1.195 87 363
t8 o-Terphenyl C6H5-CsH4-C6H5 230.31 j2, 611 1.16 56.2 332 >110
t9 p-Terphenyl CsH5-CsH4-CsH5 230.31 5 , 695 1.213 210 376 >110
t10 a-Terpinene 136.24 5, 126 0.83751O 1.477520 174 46 misc alc, eth
tll y-Terpinene 136.24 5, 128 0.853i5 1.475416 183 51
t12 Terpinen-4-01 154.25 6, 55 0.93381O 1.48202O 36.4 906- 79 v s alc. eth
t13 a-Terpineol 154.25 6, 57 0.9337,O 1.481320 40.5 220 90
t14 1,2,4,5-Tetrabromo- CsHzBr, 393.72 5,214 180-182
benzene
t15 3,4,5,6-Tetrabromo- CH,C,Br.,(OH) 423.75 6,362 205-208 s alc, eth, alk
cresol
t16 1,1,2,2,-Tetrabromo- Br,CHCHBr, 345.67 1, 94 0 243.5 none misc alc, chl, eth,
ethane HOAc
t17 Tetrabromophthalic 463.72 17,485 274-276 sl s bz; i aq, alc
anhydride
t18 a,a,a',a' -Tetrabromo- 421.77 5, 367 114-116 v s chl
o-xylene
t19 a,a,a',a'-Tetrabromo- 421.77 5,375 105-108
m-xylene
t20 a,a,a',a'-Tetrabromo- 421.77 5, 386 254-256
p-xylene
t21 Tetrabutylammonium 322.38 4,, 634 102-104
bromide
t22 Tetrabutylammonium 277.92 43, 292 73-75
chloride
t23 Tetrabutylammonium 339.54 171-173
hydrogen sulfate
t24 Tetrabutylammonium 369.38 4, 157 145-147 sl s aq; s alc, eth
iodide
t25 Tetrabutylammonium 329.28 4), 293 160-162
tetrafluoroborate
06 Tetrabutylammonium 482.20 44, 557 74-76
tribromide
t27 N,N,N',N'-Tetrabutyl- 340.64 0.820 1.45102O 832- 57
1,6-bexanediamine
t28 Tetrabutyl ortbo- 320.55 l2, 398 O,899in 1.413120 275 78
silicate
t29 Tetrabutyl pbos- 339.35 100-103
phonium bromide
t30 Tetrabutyltin 347.15 1.057 1.474P - 97 107
t31 1,1,3,3,-Tetrachloro- 195.86 1, 656 l.624i5 1.497l8 none v s acet, chl
acetone
t32 1,2,3,4-Tetrachloro- C6HZC14 215.89 5, 204 46-47 254 >110 v s eth; sl s alc
benzene
t33 1,2,4,5-Tetrachloro- C6H2C14 215.89 5. 205 1.85822 139-142 240-246 >110 s bz, chl, eth
benzene
t34 Tetracbloro- 1.2- C,Cl,-l ,2-(
=O), 245.88 7, 602 127-129
benzoquinone
t35 Tetrachloro-1.4-benzo- C6C1,-1,4-(=O), 245.88 7, 636 290 dec s eth, sl s chl; i aq
quinone
t36 Tetrachloro-1,2- C12CFCFC12 203.83 1.6447= 1.413025 26.0 92.8 0.012 aq
difluoroethane
t36a l,l,l,Z-Tetrachloro- CICH,CCl, 167.85 1, 86 1.54062n 1.482120 - 70.2 130.5 47
ethane
t37 1,l,Z,ZTetrachloro- C12CHCHC1, 167.85 1, 86 1.5866y 1.491025 -44 147 62 0.3 aq; misc alc, chl,
ethane eth, PE
t38 Tetrachloroethylene C1,C=CC12 165.83 1, 187 1.62302n 1.505720 - 22 121 45 misc alc, chl, eth
t39 2,3,5,6-Tetrachloro- HC,Cl,NO, 260.89 5 , 247 1.74425 98-101 304 s alc, bz, chl
nitrohenzene
t40 Tetrachlorophthalic 285.90 17, 484 254-258 371 dec hot aq; sl s eth
anhydride
t41 Tetracosane 338.66 1, 175 0.778651 1.4283'O 51 391 >110 9.4 chl; s eth
t42 Tetradecafluorohexane 338.05 1'. 388 1.669 1.25152n -4 58-60 none
t43 Tetradecane 198.40 1, 171 0.7627p 1.429ffO 5.5 253.6 99 v s alc, eth
t44 Tetradecanoic acid 228.38 2, 365 0.8525~0 1.42737" 54 250'- v s bz, chl, eth, s alc
t45 1-Tetradecanol 214.39 1, 428 O.815l5O 1.435X5O 39.5 289 >110 s eth; sl s alc
t46 Tetradecanoyl chloride 246.82 2, 368 0.908 1.449W0 -1 16815- >110 dec aq, alc; s eth
t47 1-Tetradecene 196.38 I, 226 0.775i5 1.43602" - 12.9 251.2 115 v s alc, eth
t48 Tetraethoxysilane 208.33 1, 334 0.934$ 1.3832n - 77 168 46 dec aq; s alc
t49 Tetraethylammonium 210.16 4, 104 1.39720 285 dec v s aq, alc, acet, chl
bromide
(Continued)
(Continued)
2.233
2.234

(Confznued

Solubility in 100
100
No.
"C point, °C
"C point, °C
"C parts solvent
t50 Tetraethylammonium 165.71 4, 104 1.08Ol~' 141 aq; s alc; 8.2 chl
chloride
61 Tetra(ethy1ene glycol) 194.23 1,468 1.125:; 1.457720 -6 328 182 misc aq, alc, bz, eth
t52 Tetra(ethy1ene glycol) 302.33 1.110 1.465020 >I10
diacrylate
63 Tetra(ethy1ene glycol) 250.34 13, 2107 0.970 1.432420 15911m~ >I10
diethyl ether
t54 Tetra(ethy1ene glycol) 330.37 2', 1531 1.080 1.463020 220 >I10
dimethacrylate
t55 Tetra(ethy1ene glycol) 222.28 13, 2107 1.0087ao 1.433020 - 30 215-276 140 s aq
dimethyl ether
t56 Tetra e th y 1ene- 189.31 4,3, 543 0.999:; 1.505520 - 40 340 185 misc aq, alc, eth
pentamine
67 N,N,N',N '-Tetraethyl- 172.32 4, 251 0.808 1.434320 189-192 58
ethylenediamine
t58 Tetraethylgermanium 188.84 4, 631 0.998 1.442020 ~ 90 165.5 35 s alc, eth; i aq
t59 Tetraethyllead 323.45 4, 639 1.653:O 1.519020 - 136 8515" 72 s bz; misc eth
160 Tetraethylsilane 14434 4, 625 0.765820 1.426g20 ~ 82 154.7 26 i aq
t6 1 N,N,N',N'-Tetraethyl- 208.33 4, 129 1.030 1.448020 249-251 >I10
sulfamide
t62 Tetraethylthiuram 296.54 4,122 1.30 7 1-72 3.8 alc; 7.1 eth; s bz,
disulfide acet, chl; 0.02 aq
t63 Tetraethyltin 234.94 4, 632 1.19920 1.47302O - 112 181 53 i aq; s eth
164 1,111,2-Tetrafluoro- 102.03 1,4, 123 - 26.5
ethane
t65 Tetratluoroethylene 100.02 l', 638 1,151 - 142.5 - 76 i aq
166 2.2,3,3-Tetrafluoro- 1- 132.06 14, 1438 1.4853z0 1.319720 - 15 109-110 43
propanol
167 1.2,3,6-Tetrahydro- 110.16 7l, 48 0.940 1.4745,O 163-164 57
benzaldehyde
168 1,2,3,4-Tetrahydro- 171.24 20, 416 118-120 325-330
carbazole
169 Tetrahydrofuran 72.11 17, 10 0.8892z0 1.405220 - 108.5 65 - 14 misc aq, alc, eth, PE
170 2,5-Tetrahydrofuran- 132.16 1.1542p 1.476625 <-so 265 misc aq, alc, bz, chl; s
dimethanol eth
t7 1 Tetrahydro-2-furan- 102.13 172, 106 1.052420 1.452OZo 1-80 178 75 misc aq, alc, bz, chl,
methanol eth, acet
t72 Tetrahydro-2-furan- 101.15 1g2, 415 0.980 1.45602O 1547"- 45
methylamine
t73 Tetrahydrofhryl 144.17 172, 107 1.061 1.43702O 196 84
acetate
t74 Tetrahydrofumuyl 156.18 173, 1104 1.064 1.46W0 87- ZllO
acrylate
t75 Tetrahydrofumuyl 120.58 173, 61 1.110 1.45502O 150-151 47
chloride
t76 Tetrahydrofurfury1 170.21 173, 1105 1.044 1.458WC 52c.4mm 90
methacrylate
t77 2(3)-(TetrahydrofuryI- 186.25 1.030 1.461020 97
oxy)tetrahydropyran
t78 1,2,3,4Tetrahydro- 133.19 20, 275 1.064 1.5668" -30 232-233 98
isoquinoline
t79 Tetrahydrolinalool (CH,),CHCH,CHzCH2- 158.29 1, 426 0.826 1.434PC 76 735mm 76
C(CH3)(OH)CH2CH3
t80 1,2,3,4-Tetrahydro- C1812 132.21 5, 491 0,970210 1.541420 -35.8 207.6 77 misc alc, bz, chl, eth,
naphthalene acet, PE
t81 cis- 1,2,3,6-Tetrahydro- 152.15 17. 462 97-103 157
phthalic anhydride
t82 cis-l,2,3,6-Tetrahydro- 151.17 129-133
phthalimide
t83 Teuahydropyran 86.14 17, 12 0.88141O 1,42OO2O - 45 88 - 155 misc aq, alc, eth
t84 Tetrahydropyran-2- 116.16 1.0254" 1.45802O -70 187 93 misc aq, alc, bz, eth
methanol
t85 3,4,5,6-Tetrahydro- 116.19 24. 5 210-212
pyrimidinethiol
t86 1,2,3,4-Tetrahydro- 133.19 20, 262 1.061 1.59402O 15-16 249 100 s aq; misc alc, eth
quinoline
t87 Tetrahydrothiophene 88.17 17', 5 0.998720 1.504020 -96 121 12 misc alc, eth; i aq
t88 2,2',4,4'-Tetrahydroxy- 246.22 8,496 200-203
benzophenone
t89 Tetrakis(dimethy1- 200.23 44, 167 0.861 1.48Wo 5909mm 53
amino)ethylene
t90 N,N,N ',N '-Tetrakis(2- 292.40 44, 1685 1.013 1.481220 1810.8"" ZllO
hydroxypropy1)-
ethylenediamine
t9 1 1,1,8,8-Tetramethoxy- 234.34 0.949 1.43W0 1305- 52
octane
t92 1,1,3,3-TeUamethoxy- 164.20 0.997 1.408lZ0 183 54
propane
(Continued)
(Conrinued)
2.235
2.236

(Conrinued)

Density Refractive Melting Boiling Flash Solubility in 100
100
t93 Tetramethyl- 154.06 4, 51 1.56 >300 55 aq
ammonium bromide
t94 Tetramethyl- 109.60 4, 51 1.1691O >300 s aq, hot alc
ammonium chloride
t95 Tetramethyl- 201.06 4. 51 1.829 >300 sl s aq; v s abs alc
ammonium iodide
t96 N,N-3,5-Tetramethyl- 149.24 12, 1131 0.913 1.544320 226-228 90
aniline
t97 1,2,3,4Tetramethyl- 134.22 5,430 0.905fO 1.518720 - 6.2 205.0 68 misc alc, eth
benzene
t98 1,2,3,5-Tetrlmethyl- 134.22 5,430 0.8906f 1.513420 - 23.7 198.0 63 s alc; v s eth
benzene
t99 1,2,4,5-Tetramethyl- 134.22 5.431 0.838:' 79.3 196.8 73 v s alc. bz, eth
benzene
tlOO 2,2,3,3-Tetramethyl- 114.23 1, 165 0.824220 - 100.7 106.5 4
butane
tlOl N,N,N',N'-Tetra- 144.26 43, 570 0.787 1.43182n 165 40
methyl-],3-butane-
diamine
t102 N,N,N ,' N '-Tetra- 144.26 4,265 O.78fj2O 1 .428020 169 46 s aq, alc, etb
methyl-1,Cbutane-
diamine
t103 1,1,3,3-Tetramethyl- 129.25 4, 198 0.805 1.424020 137-143 32 s alc, eth, PE; i aq
butylamine
t104 1,3,5,7-Tetramethyl- 240.51 44, 4099 0.99 12in 1.387020 - 69 134-135
cyclotetrasiloxane
t105 N,N,N: "-Tetra- 102.18 4, 54 0.749 1.400520 85 - 12
methyldiamino-
methane
t106 1,1,3,3-Tetramethyl- 134.33 4,, 3991 0.757i0 1.370O2" 70-71 - 10
disiloxane
t107 Tetramethylene 120.17 17', 5 1.26061O 1.48203" 27.6 285 117 misc aq, acet, toluene;
sulfone s octanes, olifines,
naphthenes
t108 N,N,N ',N '-Tetra- 116.21 4.250 0.770 1.41792u - 55 120-122 10
methylethylene-
diamine
t109 Tetramethyl- 132.73 4,2, 1008 0.978 1.389020 -88 43.4 - 37
germanium
tllO 1,1,3,3-Tetramethyl- 115.18 4'. 335 0.918 1.469220 163 60
guanadine
tlll N,N,N',N'-Tetra- 172.32 4l, 423 0.806 1.4359'" 209-210 73
methyl- 1,6-hexane-
diamine
t112 Tetramethyl lead 261.33 4, 639 1.995:'' - 27.5 110 38 misc alc, eth
t113 N,N,N',N'-Tetra- 102.18 4, 54 0.749 1.400520 85 - 12
methylmethane-
diamine
t114 2,6,10,14-Te@a- 268.53 Merck: 0.7827:O 1.438520 - 100 296 ZllO s bz, chl, eth, PE
methylpentadecane 12,1932
t115 2,2,6,6-Tetramethyl- 156.25 36-40 67
piperidinyl- 1-oxy
(free radical)
t116 N,N,N',N '-Tetra- 130.24 4. 262 0.779 1.423420 145-146 31
methyl- 1,3-propane-
diamine
t117 Tetramethylpyrwine 136.20 23, 99 84-86 190
t118 Tetramethylsilane 88.23 4, 625 0.6411:o 1.358020 -99.5 26.5 - 21 v s alc, eth
t119 1,1,3,3-TetramethyI- 132.23 4l, 336 75-77 245 0.002 alc, 0.002 eth;
2-thiourea 0.012 acet; 0.025
bz; s chl
t120 Tetramethylthiuram 240.43 4, 76 1.29 155-156
disulfide
t121 Tetramethyltin 178.83 4, 631 1.314gU 1.5201 -54 74-75 - 12
t122 1,1,3,3-Tetramethyl- 116.16 4, 74 0.9687t0 1.449325 - 0.6 116-117 77 misc aq, common org
urea solvents
t123 Tetranitromethane 196.03 1, 80 1.6229p 1.435825 13.8 126 >llO v s alc, eth, alk
t124 1,4,7,1O-Tetraoxa- 176.21 1.089 1.46302" 16 70°,5m > 110
cyclododecme
(12-Crown-4)
t125 2,4,8,10-Temoxa- 160.17 19, 436 52-55 83',5m 108
spir0[5S]undecane
t126 Tetraphenylboron (C6H5),B- Na* 342.23 Merck: > 300 v s aq, acet; s chl
sodium 12, 8839
(Continued)
(Continued)
2.237
2.238

(Conrinued)

Solubility in 100
100
t127 1,1,4,4-Tetraphenyl- (C$-15),C=CHCH=C(C,H,), 358.49 5,750 207-209
1.3-butadiene
t128 Tetraphenyltin (C$-15)& 427.11 1.490° 224-227 >420 110
t129 Tetrapropoxysilane (C3H7o),Si 264.4 1,355 0.916: 1.40lZo 945- 95
t130 Tetrapropylammonium (CH,CH,CH,)a+ Br- 266.27 41, 364 270 dec s aq
bromide
t131 lH-Tetrazole 70.06 26,346 157-158 s aq, alc, acet
t132 2-Thenoy ltrifluoro- 222.18 40-44 9g8-
acetone
t133 Theobromine 180.17 26,457 357 sublimes 100 aq; 0.045 alc; s
290- alk, i bz, chl, eth
295
t134 Theophylline 180.17 26,455 274-275 0.83 aq; 1.25 alc; 0.9
chl; s hot aq, alk,
dil acids
t135 Thiamine HCl 337.27 Merck dec 260 100 aq; 1 alc; 5.5 glyc
12,9430
t136 Thiazole 85.13 27, 15 1.200 1.S39OZ0 117-118 22 s alc, eth; sl s aq
t137 W-(2-Thiazolyl)- 255.32 273,4623 202 0.06 aq; 0.52 alc; s
sulfanilamide acet, dil mineral
acids, alkalis
t138 Thioacetamide CH,C( =S)NH, 75.13 2,232 112-114 16 aq; 16 alc; sl s eth
t139 Thiobenzoic acid C,H,C( =O)SH 138.19 9,419 1.174 1.605O2O 15-18 1223- >110 misc eth; v s alc; i aq
t140 4,4’-Thiobis(Z-tert- 358.54 6,. 6043 163-165 316-” 240
butyl-6-methyl-
phenol)
t141 Thiocarbanilide C,H,NHC( =S)NHC,H, 228.32 12,394 1.3ZZ4 152-155 v s alc, eth
t142 p-Thiocresol HSC6H,CH, 124.21 6,416 42-44 195 68 s alc, eth; i aq
t143 2,2’-Thiodiacetic acid (H02CCHhS 150.15 3,253 128-131 s aq, alc
t144 2.2’-Thiodiethanol (HOCH,CH,),S 122.19 1,470 1.1824i0 1.520320 - 10.2 282 160 misc aq, alc; sl s eth
t145 4,4’-Thiodiphenol (HOC&)zS 218.27 6, 860 154-156
t146 3.3’-Thiodipropionic (HO,CCH,CH,),S 178.21 131-134 3.7 aq; v s hot aq, alc,
acid acet
t147 Thiolacetic acid CH,C(=O)SH 76.12 2,230 1.065 1.4630 < -17 88-91 11 s aq; v s alc
t148 N-Thionylaniline C,H,N=SO 139.18 12,578 1.236 1.627020 200 84
t149 Thionyl bromide SOBr, 207.88 Merck 2.683 1.675OZo - 52 138 misc bz, chl, CCl,; hyd
12,9484 by aq
t150 Thionyl chloride SOCl, 118.97 Merck 1.635 1.517,'' - 101 76 none mix hz, chl, CCl,; hyd
12,9485 hY aq
t151 Thiophene GH,S 84.14 17,29 1.05732 1.525725 - 39.4 84 -1 misc alc, eth, i aq
t152 2-Thiopheneacetic acid (C,H,S)CH,CO,H 142.18 18,293 63-67 16022mm
t153 2-Thiophenecarbony1 (C,H,S)COCI 146.60 18,290 1.371 1.590020 206-208 90
chloride
t154 2-Thiophenecarbox- (C,H,S)CHO 112.15 17,285 1.200 1.59002'' 198 77 s eth
aldehyde
t155 2-Thiophenecarboxylic (C4H3S)COJ 128.15 18,289 127- 130 260 s aq, chl; v s alc, eth
acid
t156 Thiophenol C6H5SH 110.18 6,294 1.073 1.58802" - 14.9 169 50 v s alc; misc bz, eth
t157 Thiophenoxyacetic C&SCH,CO,H 168.21 6,313 64-66
acid
t158 Thiophosphoryl PSCl, 169.40 1.668 1.555020 - 36 (P) 125 none s bz, chl, CCl.,, CS,
chloride -40 (a)
t159 Thiopropionic acid CH,CH,C( =O)SH 90.14 2, 264 1.014 1.4640" 108-110 11
t160 3-Thiosemicarbazide HZNC(=S)NHNH, 91.14 3, 195 182-184 s aq, alc
t161 Thiourea H,NC( =S)NH, 76.12 3, 180 1.405 176-178 9 aq; s alc; sl s eth
t162 Thioxanthen-9-one '212.27 17,357 212-213 373715- v s bz, chl, hot HOAc
t 162a Thymol 150.22 6,532 0.9699p 1.5227M 51.5 233 102 0.1 aq; 100 alc; 140
eth; s HOAc, alk
OH
t163 Titanium(IV) ethoxide 228.15 1,335 1.088 1.5043,O 15Z10mm 28
t164 Titanium(IV) iso- 284.26 12,382 0.963 1.466020 18-20 220 22 s bz, chl, eth
propoxide
t165 Titanium(IV) propox- 284.26 13, 1423 1.033 1.4986,O 170,- 42
ide
t166 Toluene 92.14 5,280 0.8660:" 1.496020 - 94.9 110.6 4 misc alc. chl, eth, acet,
HOAc; 0.067 aq
t167 2,4-Toluenediamine 122.17 13, 124 99 292 s hot aq, alc, eth
t168 2,5-Toluenediamine 122.17 13, 144 64 273-274 v s aq, alc, eth
t169 2,6-Toluenediamine 122.17 13, 148 104-106 s aq, alc
t170 3.4-Toluenediamine 122.17 13, 148 91-93 15618mn v s aq
t171 Toluene-2,4-diiso- 174.16 13,138 1.2244f 1.5689,O 20-21 25 1 132 dec aq, alc; misc acet,
cyanate bz, eth
t172 p-Toluenesulfinic acid 156.21 11, 9 85 v s alc, eth, sl s aq
t173 o-Toluenesulfonamide 171.22 11,86 156-158
t174 p-Toluenesulfon- 171.22 11,104 138-140 0.2 aq; 3.6 alc
amide
(Continued)
(Continued)
2.239
Ee
2.240

(Conrinued)

100
"C point, °C
"C point, °C
"C parts solvent
t175 p-Toluenesulfonyl- CH3C&S02NHNH, 186.23 112, 66 110 dec
hydrwide
t176 p-Toluenesulfonic acid CH,C,H,SO,H 172.20 11,97 107 anhyd 1402mm 67 aq; s alc, eth
t177 p-Toluenesulfonyl CH,CsH4SO2C1 190.65 11, 103 67-69 134Imm v s alc, bz, eth; i aq
chloride
t178 p-Toluenesulfonyl CH,C,H,SO,F 174.19 112, 54 41-42 1121"m 105
fluoride
t179 p-Toluenesulfonyl CH,C,H,SO,NCO 197.21 1.435520 1441- >I10
isocyanate
t180 rn-Toluidine CH,C,H,NH, 107.16 12,853 0.989f 1.56802O -31 203 85 (CC) misc alc, eth
t181 o-Toluidine CH,C6H,NH2 107.16 12,772 0.99820 1.57202O - 16.3 200 85 1.7 aq; s alc, eth
t182 p-Toluidine CH3C6H4M12 107.16 12,880 0.961920 1.553ZS9 43.8 200 87 7.4 aq; v s alc, eth
t183 rn-Tolunitrile CH,C6H,CN 117.15 9,477 0.97615 1.525620 - 23 210 86 0.09 aq; v s alc, eth
t184 o-Tolunieile CH,C,H,CN 117.15 9,466 0.989 1.527g20 - 13 205 84 i aq; misc alc, eth
t185 p-Tolunitile CH,C6H,CN 117.15 9,489 0.9785a0 29.5 217 85 i aq; v s alc, eth
t186 2-@-Toluoyl)benzoic CH3C6H4COC6H4CO2H 240.26 10,759 137-139 v s alc, bz, eth, acet
acid
t187 rn-Toluoyl chloride CH,C,H,COCl 154.60 9,477 1.173 1.548520 865mm 76
t188 o-Toluoyl chloride CH,C,H,COCi 154.60 9, 464 1.185 1.5549,O g012mm 76
t189 p-Toluoyl chloride CH,C,H,COCl 154.60 9,484 1.169 1.55302O -2 225-227 82
t190 p-Tolyl acetate CH,C02C6H,CH3 150.18 6, 397 1.048 1.501Pu 210-211 90
t191 I -(o-Toly1)biguanide CH,C,H,NHC( =NH)NH. 191.24 l2), 1873 143-145 >I10
C( =NH)hX,
t192 m-Tolyl isocyanate CH,C,H,NCO 133.15 12, 864 1.033 1.53052u 7612mm 65 s ale, eth; i aq
t193 1,2,4-Triacetoxy- C6H,(02CCH,), 252.22 6, 1089 98-100
hen z en e
t194 Triacetoxyvinylsilane (CH,CO,),SiCH=CH, 232.26 1.167 1.422P0 1282'm 76
t195 Triallyiamine (H,C=CHCHZ),N 137.23 4, 208 0.790 1.45lPu 150-151 30
ti96 Triallyi- I ,3,5-triazine- 249.27 1.159 1.512920 152""" >I10
2,4,6(IH,3HSH)-
trione
t197 iH-l,2,4-Triazole 69.07 26, 13 119-121 260 s aq, alc
t198 Trihenzylamine (CJkCHJP 287.41 12, 1038 0.991p5 91-94 65 s hot ale, eth
t199 Tribromoacetaidehyde Br,CCHO 280.76 1, 626 2.665 1.585020 174 65 s aq, alc, chl, eth
t200 Trihromoacetic acid Br,CCO,H 296.76 2,220 130-133 245 s aq, ale, eth
t201 2,4,6-Trihromoaniline Br3C6H,KH2 329.83 12, 663 2.35 120- 122 300 s hot ale, chl, eth
002 2.2,2-Tnbromoethanol Br,CCH,OH 282.77 12, 338 73-19 93'hT 2 aq; s alc, hz, eth
t203 1,1.2-Trihromo- BrCH=CBr, 264.74 1. 191 1.70Z2l I .624125 162.5
ethy Ien e
t204 Tribromomethane 252.77 1, 68 2.9O0OL5 1.600515 8.1 149.6 83 0.3 aq; misc eth,
MeOH
t205 2,4,6-Tribromophenol 330.82 6,203 2.55 87-89 290746rnm s alc, cbl, eth, i aq
t206 1,2,3-Tribromopropane 280.78 1,112 2.390 1.58418 16.5 220 93 s alc, eth
t207 Tributoxyborane 230.16 12, 398 0.8567''' 1.409220 < - 70 234 93 hYd a¶
t208 Tributylamine 185.36 4, 157 0.7784 1.428OZo -70 216 86 v s alc, eth; s acet
t209 Tributylhorane 182.16 42, 1022 0.747 10920"" -36 i aq; s most org solv
t210 2,4,6-Tri-terf-butyl- 262.44 0.864:' 129-132 277
phenol
t211 Tributyl phosphate 266.32 12, 397 0.9727= 1.422615 -79 289 146 0.04 aq; misc org solv
t212 Tributyl phosphite 250.32 l', 187 0.925:O 1.4326,O 125'"" 91 misc alc, bz, eth, PE
t213 Trihutyltin chloride 325.49 43, 1926 1.200 1.490S2O 1732s"" >110
t214 Trihutyltin ethoxide 335.10 1.098 1.467ZZo 920.1mrn 40
t215 Trihutyltin hydride 291.05 44, 4312 1.082 1.473OZo 80°4mrn 40
t216 Tributyltin methoxide 321.07 44, 4331 1.115 1.472020 97OO6- 98
t217 Trichloroacetamide 162.40 2,211 141-143 238-240
a18 Trichloroacetaldehyde 147.40 Merck: 1.510:" 1.455720 - 57.5 97.8 dec aq, alc; s eth
12,9755
t219 Trichloroacetic acid 163.39 2,206 1.6291' 1.620ffO 57.5 196.5 >llO 120 aq; v s alc, eth
t220 Trichloroacetic 308.75 2,210 1.690 1.483820 141""" none
anhydride
t221 1,1,3-Trichloroacetone 161.42 1,655 1.508 1.489Z20 13-15 172 79
t222 Trichloroacetonitrile 144.39 2,212 1.4403f 1.440920 -42 86 none
t223 2,2',4'-Trichloro- 223.49 7,283 52-55 13S4""' >110
acetophenone
t224 Trichloroacetyl 181.83 2,210 1.629 1.468920 - 146 118
chloride
t225 2,4,5-Trichloroaniline Cl,C,H,NH, 196.46 12,627 93-95 270 s alc
t226 2,4,6-Trichloroaniline C1,C6H,NH, 196.46 12,627 73-75 262 s alc, eth
t227 1,2,3-Trichlorohenzene C6HK13 181.45 5,203 1.69 1.57761° 53-55 218-220 126 v s bz, CS,; sl s alc
t228 1,2,4-Trichlorobenzene c6H,c13 181.45 5, 204 1.45420 1.570720 17 213-214 110 misc bz, eth, PE
t229 1,3,5-Trichlorobenzene CJ3CL 181.45 5, 204 1.66 1.566219 63.5 208 107 v s bz, eth, PE
t230 Trichloro-3-chloro- Cl(CH,),SiCI, 211.98 1.350 1.466620 181-183
propylsilane
t231 1,1,1-Trichloroethane CH,CCl, 133.41 1, 85 1.33902O 1.4379" - 30.4 74 -1 s acet, bz, eth
t232 1,l,Z-Trichloroethane CICHICHC1, 133.41 1, 85 1.4397" 1.471420 -37 114 32 misc alc, eth
t233 2,2,2-Trichloroethanol Cl,CCH,OH 149.40 1.338 1.557 1.49W0 18 151-153 8 aq; misc alc, eth
t234 2,2,2-Trichloroethyl ClCO,CH,CCI, 211.86 1.539 1.4703,O 171 172
~
chloroformate
(Continued)
(Continued)
2.241
i
ER
2.242

Solubility in 100
100
"C point, °C
"C point, °C
"C parts solvent
t235 Trichloroethylene ClCH=CCI, 131.39 1,187 1.4642" 1.477320 - 84.8 81 32 0.1 aq; misc alc, chl,
eth
t236 Trichloroethylsilane C,H,SiCl, 163.51 4,630 1.2373" 1.42562O - 105.6 100.5 22
t237 Trichlorofluoro- C1,CF 137.37 Merck 1.48521 1.384" - 111 23.8 0.14 aq; s alc, eth
methane 12,9770
t238 a,a,2-Trichloro-6- ClC6H,(F)CHC1, 213.47 5,, 701 1.446 1.55062O 228-230 > 110
fluorotoluene
t239 Trichloroisocyanuric 232.41 25,256 249-251
acid
t240 Trichloromethane- C1,CSCl 185.89 3, 135 1.7002," 1.543@O 146-148.
sulfenyl chloride
t241 l,l,l-Trichloro-2- (CH,)zC(OH)CCl, 177.46 1,382 99 anhyd 167 s alc, bz, chl, eth
methyl-2-propanol
t242 Trichloromethylsilane CH,SiCl, 149.48 4,. 1896 1.273i0 1.410820 - 90 66 -9
t243 1.2.4~Trichloro-5- C1,C6HzNOz 226.45 5, 246 1.79Ozo 49-55 288 >110 v s bz. eth
nitrobenzene
t244 2,4,5-Trichlorophenol C1,C6HzOH 197.45 fj2,180 67-69 253 615 acet; 163 bz; 525
eth; 615 MeOH, i
89
t245 C1,C6H20H 197.45 6, 190 1.4901p 69 246 none 525 acet; 113 bz; 354
eth, 525 MeOH, i
aq
t246 (2,4,5-Trichloro- C1,C6HzOCH,CO2H 255.49 6,, 702 154-158 s alc; v sl s aq
phenoxy)acetic acid
t247 1,2,3-Trichloropropane CICHzCH(Cl)CHzCl 147.43 1, 106 1.388gzo 1.48541O - 14.7 157 71 misc alc, eth, i aq
t248 2.4.6-Trichloro- 183.43 23, 90 1.570020 23-25 >110
pyrimidine
t249 Trichlorosilane HSiC1, 135.45 Merck 1.342 1.400OZ0 - 127 31-32 - 13 dec aq; s bz, chl
12,9776
t250 4-(Trichlorosily1)- CI,Si(CH,),CN 202.54 4,4, 4212 1.300 1.463OZ0 237-238 92
butyronitrile
t25 1 a,a,a-Trichlorotoluene C6H5CC1, 195.48 5,300 1.372320 1.558OZ0 -5 219-223 127 s alc, bz, eth
t252 a,2,4-Trichlorotoluene ClzC,H,CH2Cl 195.48 819 1.407 1.5760" - 2.6 248 >110
t253 a,2,6-Trichlorotoluene C12C,H,CHzCl 195.48 1.576lzo 36-39 11914- >110 v s alc, eth
t254 a,3,4-Trichlorotoluene ClzC6H3CH2Cl 195.48 5,300 1.411 1.576620 12414"'"' >110
t255 2,4,6-Trichloro-1.33- 184.41 26.35 146-148 190 i aq; s alc
triazine
t256 l,l,l-Trichlo~hi- Cl,CCF, 187.38 1.579 1.3699" 13-14 46
fluoroethane
t257 1,1,2-Trichlorotri- Cl,CFCClF, 187.38 13, 157 1.563525 1.355725 - 35 47.7 0.017 aq
fluoroethane
t258 TrichlorovinyMane H2C=CHSiC1, 161.49 1.270 1.436OZ0 - 95 90 10
t259 Tri~y~l0[5.2.1.02.~]- 136.24 5, 164 77-79 193 40
decane
t260 Tricycl0[5.2.1.02~~]- 150.22 7', 133 1.063 1.5025" 13230mm
decan-&one
t261 Tridecane 184.37 1, 171 0.75631 .425620 -5 to - 4 235 70 v s alc, eth
t262 Tridecanoic acid 214.35 2, 364 41-42 236'- >110 v s alc, eth; i aq
t263 2-Tridecanone 198.35 1,715 0.822 ,435020 29-31 134Ihm >110
t264 7-Tridecanone 198.35 1,715 0.825 30-32 264 >110
t265 1-Tridecene 182.35 1,225 O.765S2O ,434020 - 13 232.8 79 s alc; v s eth
t266 Triethanolamine 149.19 4,285 1.12421 .485320 20.5 335.4 179 misc aq, alc, acet; 4.5
bz; 1.6 eth, s chl
t267 3,4,5-Triethoxybenzoic 254.29 10,481 110-112
acid
t268 Triethoxyborane 145.99 1.335 0.864 1.374020 117- 118 11 dec aq
t269 Triethoxysilane 164.28 1,334 0.890 1.377020 134-135 26
t270 3-(Triethoxysilyl)- 217.34 44, 4271 0.979 1.41402O 224 100
propionitri1e
t27 1 3-(Triethoxysilyl)- 247.37 0.999 1.42W0 283 77
propyl isocyanate
t272 TriethoxyvinyMane 190.32 0.9031O 1.397820 160-161 34
t273 Triethylaluminum 114.17 4, 643 0.832= - 50 194 - 18 dec aq, air
t274 Triethylamine 101.19 4, 99 0.7275" 1.40102O - 114.7 88.8 -7 5.5 aq; misc alc, eth, s
acet, EtOAc
t275 Triethylantimony 208.94 4,618 1.32416 1.42 - 29 159.5
t276 Triethylarsine 162.11 4,602 11.50$' 140736mm i aq; misc alc, eth
t277 Triethylborane 98.00 4, 641 0.6961" 1.39702O - 02.9 95 i aq; dec by air
t278 Triethyl citrate 276.29 3,568 1.137 1.442020 127Imm >110
t279 Triethylenediamine 112.18 233,484 158-160 62 45 aq; 13 acet; 77 alc;
51 bz
t280 Tri(ethy1eneglycol) (HOCH2CH2OCH2-)2 150.17 1,468 1.127415 -7 285 177 misc aq, alc, bz
t281 Tri(ethy1ene glycol) [H,C=C(CH,)CO,CH,- 286.33 Z4, 1531 1.092 17Z5- 1110
dimethacrylate CH2OCH2-12
t282 Tri(ethy1ene glycol) (CH3OCH,CH2OCH2-), 178.23 Merck 0.9902,o - 45 216 111 misc aq, hydrocarbon
dimethyl ether 12,9820 solvents
(Continued)
(Continued)
2.243
2.244


Solubility in 100
100
solvent
t283 Tri(ethy1ene glycol) H2C=CH(OCH2H2),0CH=CH2 202.25 13,2106 0.990 1.453OZ0 12618mm >110
divinyl ether
t284 Tri(ethy1ene glycol) CH3(OCH2CH2),0H 164.20 13,2105 1.026 1.439920 1221- >110
monomethyl ether
t285 Triethyleneteaamine 146.24 4,255 0.982 1.4971 12 266 143
t286 Triethylgallium 156.91 1.057630 - 82.3 142.6
t287 1,3,5-Triethylhexa- 171.20 26, 2 0.894 1.459520 207-208 80
hydro- 1.3.5-triazine
t288 Triethylindium 202.01 1.2602O 1.53S20 - 32 144
t289 Triethyl orthoacetate 162.23 2, 129 0.8847F 1.39502s 142 36 misc alc, chl, eth
t290 Triethyl orthoformate 148.20 2, 20 0.891:O 1.39102O - 76 146 30 dec aq; s alc, eth
t291 Triethyl ortho- 176.26 2,240 0.876 1.399520 155-160 60 v s alc, eth
propionate
t292 Triethyl phosphate 182.16 1,332 1.069520 1.405XZ0 - 56 215 115 s aq(dec), alc, eth
t293 Triethylphosphine 118.16 4,582 0.800:5 1.456320 - 88 128-129 - 17 i aq; misc alc, eth; py-
rophoric
t294 Triethyl phosphite 166.16 1,330 0.969:O 1.413OZ0 156 54 i aq(hyd); misc alc,
acet, bz, eth, PE
t295 Triethyl phosphono- 224.19 4l, 513 1.130 1.43lozo 14S9- >110
acetate
t296 Triethyl phosphono- 212.17 32, 103 1.110 1.432OZ0 13512m" >110
formate
t297 Triethylsilane 116.28 4,625 0.731z0 1.41Z20 107-108 -3 i aq; misc alc, eth
t298 Triethyl thiophosphate 198.22 1,333 1.082 1.44802O 10016mm 107
t299 2.2.2-Trifluoro- 113.04 Z2, 186 70-75 162.5
acetamide
000 Trifluoroacetic acid 114.02 22, 186 1.489Ozo 1.28502" - 15.3 73 misc aq
001 Trifluoroacetic 210.03 Z2, 186 1.487 < 1.300 - 65 39-40
anhydride
002 1,l. 1-Trifluoroacetone 112.05 12,717 1.252 <1.30 22 - 30
003 1,3,5-Trifluorobenzene 132.09 1.277 1.415OZ0 - 5.5 75-76 -7
t304 n,n,n-Trifluoro-m- 162.11 6'. 187 1.333 1.458SZ0 - 1.8 178-179 73
cresol
005 2,2,2-Trifluoroethanol 100.04 1'. 1342 1.3842f 1.290720 -43.5 74 29
t306 2,2,2-Trifluoroethyl 196.05 2,. 427 1.4725:* 1.281218 - 65.5 55 0
trifluoroacetate
t307 Trifluoromethane 70.01 1, 59 1.52-LM - 160 - 84 75 mL aq; 500 mL alc
t308 Trifluoromethane- 150.07 34, 34 1.69SZs 1.325Oz5 34 162 none v s aq; misc eth
sulfonic acid
009 Trifluoromethane- 282.13 34. 35 1.677 1.321ZZ0 84 none dec aq, alc
sulfonic anhydride
t310 3-(Trifluoromethy1)- 161.13 12, 870 1.290 1.480OZ0 5-6 187 85
aniline
t311 cu,a,cu-Trifluorotoluene 146.11 5,290 1.188620 1.414F0 - 29 102 12
t312 Trihexyl O-acetyl- 486.65 1.005 1.44702O >110
cimte
t313 Trihexylamine 269.52 4, 188 0.794 1.4415" 163-265 >110 v s alc, eth, i aq
t314 Trihexyl O-butyl- 514.71 0.993 1.448OZ0 - 55 >110
cihate
t315 Trihexylchlorosilane 319.12 0.871t0 1.45620 1555m
t316 Trihexylsilane 284.60 44, 3915 0.799 1.448M 161 >110
t317 1.2.3-Trihydr0~~- 126.11 6, 1071 1.45 133 309 59 aq; 77 alc; 62 eth
benzene
t318 1,3,5-Trihydroxy- 126.11 6, 1092 218-221 1 aq; 10 alc; s eth
benzene
t319 3,4,5-Trihydroxy- 170.12 10,470 258-265 1.1 aq; 17 alc; 1 eth;
benzoic acid 20 acet; i bz, chl,
PE
t320 2,3,4-Trihydroxy- 230.22 8,417 140-142
benzophenone
t321 1,2,6-Trihydroxy- 134.18 14,2784 1.109 1.47602" 17gSM" 79
hexane
t322 Triisobutylaluminum 198.33 4,643 0.786 1.449420 4-6 86l- - 18 pyrophoric
023 Triisobutylamine 185.36 4, 166 0.766 1.42302O 192-193 57
t324 Triisodecyl phosphite 502.80 0.884 1.4600zo <O 166 235
t325 Triisopropanolamine 191.27 43, 762 0.9996:; 48-52 305.4 152 v s aq
026 Triisopropoxyhorane 188.08 1,363 0.815 1.376420 139-141 10
t327 1,3,5-Triisopropyl- 204.36 5,458 0.845 1.4880" 232-236 86
benzene
t328 Triisopropyl ortho- 190.29 23,39 0.854 1.397020 6618- 42
formate
t329 Triisopropyl phosphite 208.24 1,363 0.9 14j0 1.41l P 0 6411- 67 i aq(s1 hyd)
t330 Triisopropylsilane 158.36 43, 1851 0.773 1.434420 8635mm 37
t331 3.4.5-Trimethoxy- 196.20 8,391 73-75 165'-
benzaldebyde
t332 1,2,3-Trimethoxy- 168.19 6, 1081 1.112 43-45 241 >I10
benzene
(Continued)
(Continued)
2.245
2.246

Solubility in 100
100
t333 1,2.4-Trimethoxy- 168.19 6, 1088 1.126 1.533OZ0 241 >I10
benzene
t334 1.3,5-Tnmethoxy- 168.19 6, 1101 5 1-53 255 85
benzene
t335 3,4,S-Tnmethoxy- 212.20 10,481 168-171 2211b v s ale, eth; s chl
benzoic acid
036 3,4,S-Trimethoxy- (CH,0),C6HzCOC1 230.65 10,487 31-84 18518-
benzoyl chloride
t337 3,4,5-Trimethoxy- (CH,0),C6H2CH20H 198.22 6, 1159 1.233 1.543920 228ym >I10
benzyl alcohol
t338 Trimethoxyborane (CH,O)SB 103.91 1, 287 0.92q3 1.356820 - 34 67-68 - 13 hyd aq; misc alc, eth
t339 Trimethoxyboroxine [-OB(OCHJ-l, 173.53 1.195 1.3996,O 10 130 10
040 l,l,2-Trimethoxy- CH,OCH,CH(OCH,), 120.15 13, 3183 0.932 1.392lZ0 5956- 23
ethane
041 1,1,3-Trimethoxy- CH,OCH,CH,CH(OCH,), 134.18 1, 820 0.942 1.400420 46""" 40
propane
t342 1,1,3-Trimethoxy- CH,OCH,CH,CH,Si(OCH,), 164.28 0.932 1.390ffo 142 40
propylsilane
043 Trimethoxysilane (CH,O),SiH 122.20 12, 274 0.960 1.3579,O -115 81 -4
044 3-(Trimethoxysilyl)- H,N(CH,),Si(OCH,), 179.29 1.027 1,42402 9215- 83
propylamine
045 N-[3-(Trimethylsilyl)- C,H,~H(CH,),Si(OCH,), 255.39 1.070 1,555020 310 >llO
propyllaniline
046 N-[3-(Trimethoxysilyl)- (CH,O),Si(CH,),NHCH,CH,NH, 224.36 1.019 1.44502'' 14615- >110
propyllethylene-
diamine
t347 3-(Trimethoxysily1)- 248.35 1.045;'' 1.43102'' 190 92
propyl methacrylate
t348 [3-(Trimethoxysilyl)- 222.32 1.150 1.46001'' 217-250 98
propyll~a
049 Trimethylacetic acid 102.13 2,319 0.889 33-35 163-164 63
050 Trimethylacetic- 186.25 2,320 0.918 1.40902O 193 57
anhydride
051 Trimethylacetyl 120.58 2,320 0.979 1.41202O 105-106 8
chloride
052 Trimethylaluminum 72.09 I 4, 643 0.75220 ' 1.43212 15 125-126 - 18 s alk; v sl s alc
t354 Trimethylamine 59.11 4, 43 0.656 1.3631O -117 2.9 -7 41 aq; misc alc; s bz,
chl, eth
t355 2,4,6-Trimethylaniline 135.21 12, 1160 0.963 1.551OZ0 233 96
t356 1,3,3-Trimethyl-6-aza- 153.27 0.902 1.4716,O 194 75
bicyclo[3.2. lloctane
t357 1,2,3-Trimethyl- 120.20 5,399 0.8944:O 1.513920 - 25.4 176.1 48 i aq; s alc, eth
benzene
t358 1,2,4-Trirnethyl- 120.20 5,400 0.8756:O 1.504820 -43.9 169 48 s alc, bz, eth
benzene
t359 1,3,5-Trimethyl- 120.20 5,406 0.8637:O 1.499420 -44.7 165 44 misc alc, bz, eth
benzene
t360 Trimethyl 1,2,4- 252.22 9', 429 1.261 1.5214,O 38-40 194'2"" > 110
benzenebi-carbox-
ylate
t361 2,2,3-Trimethylbutane 100.20 12, 121 0.69011° 1.389OZo - 24.9 80.9 -6 s alc, eth
t362 2,3,3-Trimethyl-2- 116.20 12, 447 0.8380i5 1.423322 15-17 130.5 misc alc, eth
butanol
t363 1,2,4-Trimethylcyclo- 126.24 5, 42 0.786 1.433020 141-143 18
hexane
t364 3,5,5-Trimethylcyclo- 138.2 7, 65 0.918 1.472Oz0 -8.1 215 80 1.2 aq
hex-2-ene-1-one
t365 2,6,6-Trimethyl-2- 152.19 74, 2032 1.49102" 26-28 9411"" 96
cyclohexene-l,4-
dione
t366 Tnmethyl-l,6-diiso- OCKCH,CH2C(CH3)CH2. 210.28 1.012 1.462020 149 >I10
cyanatohexane C(CH3)CH2CN0
t367 2,2,6-Trimethyl-4H- 142.16 19', 1604 1.088 I .462020 12-13 671xnm 86
1,3-dioxin-4-one
t368 4,4'-Trimethylenebis- 238.42 0.896 1.482OZo 13 21Sh' >I10
(1methylpipendine)
069 4,4'-Trimethylene- 210.37 65-58
dipiperidine
t370 3.5.5-Trimethylhexanal (CH3),CCH,CH(CH,jCH,CH0 142.24 l', 2894 0.817 1.4215'O 682 L m n 46
t370a 3.5,5-Tnmethylhexane (CH,),CHCH,CH(CH,jCH(CH,), 128.26 0.721820 1.405l2O - 128 131
t371 3.5,5-Tnmethyl- 1- (CH,),CCH,CH(CH3)- 144.25 I?, 1755 0.8236:O 1.43oNs < -70 193-194 80 s alc, eth
hexanol CH,CH,OH
t372 3,5,5-Trimethyl- (CH,),CCH,CH(CH,)- 176.89 2', 834 0.930 1.436OZo 188-190 140
hexanoyl chloride CH,COCl
(Continued)
2.247
2.248
TABLE
TABLE 2.20
2.20 Physical
Physical Constants
Constants of
of Organic
Organic Compounds
Compounds (Continued)
(Continued)
Formula
Formula Beilstein
Density, Refractive Melting
Melting Boiling
Boiling Flash
Flash Solubility in 100
Solubility in
No.
No. Name
Name Formula weight
weight reference
reference €m-
g/mL index
index point. °C
point, OC parts
parts solvent
solvent
074 Trimethylhydro- 152.19 6,931 172-174 s aq; v s alc, bz, eth
quinone
075 1,3,3-Trimethyl-2- 154.25 6, 70 0.9641:'' 39-45 20 1 73 s alc, eth
norbomanol
t376 1,3,3-Trimethyl-2- 152.24 7, 96 0.94818 1.463518 5 192-194 52 v s alc, eth
norbomanone
t377 Trimethyl orthoacetate 120.15 Z2, 128 0.9428Z5 1.385925 107-109 16 v s alc, eth
t378 Trimethyl 106.12 2, 19 0.9676:'' 1.37902" 100.6 15
orthoformate
t379 2,4,4-Trimethyl-2- 113.16 0.887 1.421320 112-113 12
oxazoline
t380 2,2,3-Trimethylpentane 114.23 l', 62 0.7 160:' 1.4O3Oi0 - 112.3 110 <21 s eth, sl s alc
t381 2,2,4-Trimethylpentane 114.23 12, 127 0.6919:'' 1.3915," - 107.4 99.2 - 12 s bz, chl, eth
t382 2,3,4-Trimethylpentane 114.23 13,500 0.7 190:" 1.4O4Z2O - 109.2 113-114 5 s alc, org solv
t383 2,2,4-Trimethyl-1,3- 146.22 13,2225 0.928:: 1.451315 52-56 232 113 1.8 aq; 75 alc; 22 bz;
pentanediol 25 acet
t384 2,4,4-Trimethyl-1- 112.22 13,849 0.7150:'' 1.411ZZo - 93 101-102 -6
pentene
t385 2,3,5-Trimethylphenol 136.19 6,518 92-95 230-231
t386 2,3,6-Trirnethylphenol 136.19 62-64
t387 2,4,6-Trimethylphenol 136.19 6,518 71-74 220
t388 2,4,6-Trimethyl-1,3- 152.23 13'. 190 88-91
phenylenediamine
t389 Trimethyl phosphate 140.08 1,286 1.1972n 1.39672n - 46 197 107 100 aq; s alc
t390 Trimethyl phosphite 124.08 1,285 1.046;" 1.40802n - 78 111-112 27 dec aq; misc alc, acet,
bz, PE
t391 Trimethyl phosphono- 182.11 1.125 1.437020 lls(J85- >110
acetate
t392 1,2,4-Trimethyl- 128.22 0.851:: 1.448025 - 50 1517&- s aq, alc, acet, bz
piperazine
t393 2,4,6-Trimethylpyridine 121.18 20,250 0.9 166?2 1.495925 - 46 171 57 3.5 aq; misc eth; s alc,
bz, chl
t394 N-(Trimethylsily1)- 131.25 46-49 186 57
t395 Trimethylsilyl acetate CH,CO,Si(CH,), 132.24 43, 1857 0.882 1.38802" -32 108 4
t396 N-(Trimethylsily1)- 140.26 0.956 1.475120 9414mm 5
imidazole
097 Trimetbylsily1 H2C=C(CH,)C0,Si(CH3)3 158.28 0.890 1.41502'' 512- 32
metbacrylate
t398 Trimetbylsilyl hi- CF,SO,Si(CH,), 222.26 1.228 1.360P0 770- 25
fluoromethane sul-
fonate
t399 Trimethylsulfonium 204.07 2 15-220
iodide sublime
t400 Trimethylsulfoxonium 220.07 169 dec
iodide
t400a 1,7,7-Trimethylhi- 136.24 5, 164 0.86688" 1.42968'' 67.5 152.5
cyclo[2.2.1 . o q
heptane
t401 Trimethylvinylsilane 100.24 0.649 1.39202" 55 < -34
t402 2,4,6-Trinitroaniline 228.12 12, 763 1.76214 188-190 explodes s hot acet; sl s alc
t403 1,2,4-Trinitrobenzene 213.11 5, 271 1.7316 61-62 explodes 5.5 alc; 7.1 eth; i aq
t404 1,3,5-Trinitrobenzene 213.11 5, 271 1.6882" 122.5 explodes 0.035 aq; 1.9 alc; 1.5
eth; 6.2 bz
t405 2,4,6-Trinitrotoluene 227.13 5, 347 1.6542'' 80.1 explodes 1.5 alc; 4 eth, s bz,
acet; 0.01 aq
t406 Trioctylamine 353.68 4, 196 0.809 1.44852u 365-367 >110
t407 1,3,5-Trioxane 90.08 19, 381 1.17065 60.2 115 45 17.2 ad8; v s alc, bz,
eth, EtOAc
t408 4,7,1O-Trioxa-1,13- 220.31 4,4, 1625 1.005 1.46402" 14S4"" >110
hidecanediamine
t409 Tripentaerythritol 372.41 225 dec
t410 Triphenylamine 245.33 12, 181 0.7748 125- 127 347-348

t411 Triphenylantimony 353.07 16, 891 1.4343" 52-54 377 > 110 v s bz, eth; sl s alc
t412 Triphenylarsine 306.24 16, 828 1.222Ya 1.613Y8 60-62 23314"" v s bz, eth; s alc
t413 1,3,5-TriphenyIbenzene 306.41 5 , 737 1.205 172-174 460 v s bz; s abs alc, eth
t414 Triphenylborane 242.13 162,636 145 20315-
t415 Triphenylmetbane 244.34 5.698 1.0134y 92-94 360 v s hot alc, eth; 49 chl;
7 bz; s PE
(Continued)
(Continued)
2.249
2.250
TABLE2.20
TABLE 2.20 Physical
PhysicalConstants
Constantsof
ofOrganic
OrganicCompounds
Compounds(Continued)
(Continued)
Formula
Formula Beilstein
Density, Refractive Melting
Melting Boiling
Boiling Flash
Flash Solubilityinin100
Solubility 100
No.
No. Name
Name Formula weight
weight reference
reference g/mL
g/mL index
index point,O°C
point. C point,O°C
point. C point,O°C
point. C partssolvent
parts solvent
t416 Triphenylmethanol 260.34 6,713 1.199: 160-163 360 v s alc, bz, eth; i aq
t417 Triphenylmethyl 323.24 5, 704 152-154 23015mm
bromide
t418 Triphenylmethyl 278.78 5,700 110-112 235,-
chloride
t419 Triphenyl phosphate 326.29 6, 179 50-52 2441- 223 misc alc; s bz, acet,
chl, eth; i aq
t420 Triphenylphosphine 262.29 16,759 1.075:' 79-81 377 181 v s eth, s bz, chl,
HOAc; sl s alc; i aq
t421 Triphenylphosphine 278.29 16,783 156-158
oxide
t422 Triphenyl phosphite 310.29 6, 177 1.184 1.5903" 22-24 360 218 s alc, bz, chl, eth
t423 Triphenylsilane 260.41 16,. 605 42-44 1522mm 76
t424 Triphenyltin acetate 409.06 1@, 1606 124-126 s eth, sl s alc, bz
t425 Triphenyltin chloride 385.46 16,914 108 dec 24013.5mm
t426 Triphenyltin hydroxide 367.02 16,914 124-126

t427 Tripropoxyhorane 188.08 12,369 0.85763O 1.394g20 175-177 32 v s alc; misc eth
t428 Tripropylaluminum 156.25 4, 643 0.823 - 107 84- - 18
t429 Tripropylamine 143.27 4, 139 0.753 1.416020 - 93.5 155-158 36 s aq, alc, eth
t430 Tripropylene glycol 192.26 1.021 1.44225 273 141 s 89
t43 1 Tripropylene glycol 248.4 0.932 1.4302O 276 135
butyl ether
t432 Tripropylene glycol 206.29 14,2475 0.967 1.42825 - 42 242.4 127 misc aq, alc, eth
monomethyl ether
t433 Tripropyl orthoformate 190.28 2, 21 0.8805y l.407220 108- 72
t434 Tris(2-aminoethy1)- 146.24 4, 256 0.977 1.497020 11415mm >110
amine
t435 Tris(2-butoxyethyl) 398.48 1.006 1.435gZ0 22g4"" 110
phosphate
t436 Tris(2-chloroethy l) 285.49 12,337 1.390 1.472lZ0 330 232
phosphate
t437 Tris(2-chloroethyl) 269.49 1.353f0 1.486320 1152mm 190 misc alc, bz, eth
phosphite
t438 Tris(2-ethylhexyl) 434.65 13, 1734 0.924 1.443720 2ki4""" >110 i aq
phosphate
t439 Tns(hydroxymethy1)- (HOCHz),CW 121.14 4,303 171-172 2201-
aminomethane
t440 l,l,l-Tris(hydroxy- CH,C(CH,OH), 120.15 1,520 200-203
methy1)ethane
t441 N-[Tris(hydroxy- (HOCH2),CNHCH2C02H 179.17 Merck 187 satd aqo is 0.8M
methy1)methyll- 12,9783
glycine
t442 Tris(hydroxymethy1)- (HOCWQ'JOz 151.12 1,520 214 pure 220 aq; v s alc; sl s bz
nitromethane 175 tech
t443 Tris[Z-(Z-methoxy- (CH,0CH2CH20CH2CH2),N 323.43 1.011 >110
ethoxy)ethyl]amine
t444 Tris(2-methoxy- H2C=CHSi(OCH2CH2-OCH,), 280.39 44, 4257 1.034z5 284-286 >110
ethoxy)-
vinylsilane
t445 Tris(2-methoxyethyl) 236.08 1'. 2118 1.010 1.41502O 87
borate
t446 Tris(2-methylally1)- 179.31 4,, 462 0.794 1.457520 53
amine
t447 Tris(2,2,2-t1ifluoro- 328.07 14, 1371 1.487 1.324520 >110
ethyl) phosphite
t448 Tris[3-(trimethoxy- 615.86 1.170 1.461020 102
si1yl)propyI]
isocyanurate
t449 Tris(trimethylsily1) 278.38 4', 1861 0.831 1.386120 186 42
borate
t450 1,3,5-Trithiane 138.27 19,382 216-218 s bz; sl s alc, eth
t45 1 Trithiocarbonic acid 110.21 3,221 1.483f 1 .822520 - 26.9 57.8 dec aq, alc; sl s eth
t452 Tri-o-tolylphosphate 368.37 Merck 1.195520 1,557520 11 410 225 sl s aq, alc; s eth
12,9893
t453 1,2,4-TrivinyIcyclo- 162.28 0.836 1.478OZo 68
hexane
t454 L-( -)-Tryptophan 204.23 22,546 280-285 1.14 aqZ5;s hot alc,
dec alk i eth, chl
t455 L-Tyrosine (HO)C,H4CH2CH(NH2)C02H 181.19 14,605 1.456 342-344 0.045 aq; 0.01 alc: s
alk; i eth
ul Undecanal 170.30 1,712 0.825 1.432220 -4 1155mm 96 i aq;s alc, eth
u2 Undecane 156.31 1, 170 0.74022O 1.41732v - 25.6 196 60 i aq; misc alc, eth
2.251
(Continued)
(Continued)
2.252


Solubility in 100
100
solvent
u3 Undecanenitrile 167.30 2,358 0.823 1.433OZo 253 >110
u4 Undecanoic acid 186.30 2,358 0.8907 1.42944s 28.5 22816omm >110 s alc, chl, eth; i aq
u5 Undecanoic y-lactone 184.28 17,247 0.949 1.450OZ0 16613- >i10
u6 Undecanoic Glactone 184.28 17,, 4257 0.969 1.459OZ0 15510sm" >110
u7 1-Undecanol CMCHJioOH 172.31 I , 427 0.8324 1.4402" 11 242.8 >110
U8 2-Undecanol CH,(CH,),CH(OH)CH, 172.31 1,427 0.828 1.437OZ0 2-3 13lZn"" 88
u9 2-Undecanone CH,(CH,)&OCH, 170.30 I , 173 0.829 1.430OZ0 11-13 23 1-232 88 (CC) s alc,
i aqbz, chl, eth, acet;
u10 3-Undecanone CH,(CH,),COCH,CH, 170.30 1,713 0.827 1.429lZ0 12-13 225-229 89

ull 6-Undecanone CHdCH~)~CO(CHz)~CH3 170.30 1, 174 0.831 1.428OZo 14.6 228 88 i aq; v s alc, eth
u12 10-Undecenal H,C=CH(CH,),CHO 168.28 1,3, 3029 0.810 1.442720 92
u12a 1-Undecene H,C=CH(CH,),CH, 154.30 1,225 0.750320 1.42612o - 49 193 71
u13 10-Undecenoicacid H,C=CH(CH,),CO,H 184.28 2,458 0.907i4 1.449320 24.5 137zm 148 s alc, chl, eth; i aq
u14 1O-Undecen-1-01 H,C=CH(CH,),OH 170.30 I , 452 O.85OL5 1.450020 -2 245 93
u15 10-Undecenoyl H2C=CH(CH2),COCI 202.73 2,459 0.944 1.45W0 122lhm 93
chloride
u16 Urea (HzN)zCO 60.06 3, 42 1.335 133-135 dec >mp 100 aq; 20 alc
u17 Uric acid 168.11 26,513 1.89320 >300 dec s alk,i aq, alc, eth
u18 Uridine 244.20 31,23 166-167 s aq; hot alc, pyr
vl Valeric anhydride 186.25 2,301 0.942 1.42lozo - 57 11216- 101
v2 y-Valerolactone 100.12 17,235 1.057 1.433020 -31 207-208 81
v3 GValerolactone 100.12 17,235 1.079 1.458OZ0 600.5- 100
v4 L-Valine (CH3),CHCH(NH)C02H 117.15 4,427 1.230 >315 suhl 8.8 aq; v sl s alc, eth
v5 Vinyl acetate H2C=CH0,CCH3 86.09 2'. 63 0.932i0 1.3954," - 93 72-73 -8 2 aq; misc alc, eth
v6 Vinyl benzoate C6H5C0,CH=CH, 148.16 9l, 65 1.070 1.529OZ0 96,- 82
v7 4-Vinylbenzyl chloride H2C=CHCBH,CH2C1 152.62 1.083 1.574020 229 104
V8 Vinylcyclohexane C6H,,CH=CH2 110.20 s,35 0.805 1.446320 126- 127 20
v9 4-Vinyl-1-cyclohexene 108.18 5l, 63 0.803y 1.464020 - 101 127 20
v10 2-Vinyl-I ,3-dioxolane 100.12 1.001 1.43OOz0 115-116 14
vll N-Vinylformamide HCONHCH=CH, 71.08 1.014 1.494OZo - 16 210 102
v12 I-Vinylimidazole 94.12 23,, 569 1.039 1.530820 7913- 81
v13 5-Vinyl-2-norbornene 120.20 0.841 1.480220 - 80 141 27
v14 Vinyl propionate CH,CH,CO,CH=CH, 100.12 Z3, 532 0.919 1.4030" - 80 94-95 6
v15 2-Vinylpyridine (C,H,N)CH=CH, 105.14 20,256 0.975 1.549OZo 158-159 46 v s alc, chl, eth
v16 4-Vinylpyridine (C,H,N)CH=CH, 105.14 202, 170 0.975 1.55002O 6515m 51 sl s hot aq, hot alc
I
v17 N-Vinyl-2- 111.14 1.040 1.512020 9313- 93
pyrrolidinone
v18 Vinyltrimethoxysilane H,C=CHSi(OCH,), 148.24 0.968 1.392020 123 22
XI Xanthene 182.22 17.73 101 310-312 s bz, eth: sl s alc, aq
x2 Xanthen-9-carboxylic 226.23 1S2,279 217 dec s hot alc, eth
acid
x3 9-Xanthenone 196.21 17,354 174-176 35073”m 0.5 alc; v s chl
x4 m-Xylene c&(cH3)2 106.17 5,370 0.864220 1.497220 - 47.9 139 27 misc alc, eth, 0.02 aq
x5 o-Xylene Ce.HdcHd2 106.17 5,362 0.8808$ 1.505420 - 25.2 144-145 32 misc alc, eth; 0.017 aq
x6 p-Xylene ce.H.dCHd, 106.17 5,382 0.8611i0 1.4958” 13 138 27 v s eth, s alc; 0.02 aq
x7 Xylitol HOCH,(CHOH),CH,OH 152.15 1,531 1.52 95-97 64 aq; 1.2 EtOH, 6.0
MeOH
x8 D-( +)-XylOSe 150.13 31.47 1.5350 156-158 117 aq; s hot alc, pyr
x9 rn-Xylylenediamine C6H&H2hW2), 136.20 13, 186 1.032 1.5709” > 110
2.253
TABLE 2.21 Melting Points of Derivatives of Organic Compounds
(a) Derivatives of Alcohols

3,5-Dinitro-benzoate 3,5-Dinitro-benzoate
qC,m/°C qC,m/°C
Methanol 109 2-Methylpropan-2-ol 142
Ethanol 94 Pentan-1-ol 46
Propan-1-ol 75 Hexan-1-ol 61
Propan-2-ol 122 Phenylmethanol 113
Butan-1-ol 64 Cyclohexanol 113
2-Methylpropan-1-ol 88 Ethane-1,2-diol (glycol) 169*
Butan-2-ol 76
(b) Derivatives of Phenols
4-Methyl- 4-Methyl-
3,5-Dinitro benzene- 3,5-Dinitro- benzene
benzoate sulphonate benzoate sulphonate
qC,m/°C qC,m/°C qC,m/°C qC,m/°C
Phenol 146 96 Benzene-1,2-diol 152* —
2-Methylphenol 138 55 Benzene-1,3-diol 201* 81*
3-Methylphenol 165 51 Benzene-1,4-diol 317* 159*
4-Methylphenol 189 70 2-Nitrophenol 155 83
Naphthalen-1-ol 217 88 3-Nitrophenol 159 113
Naphthalen-2-ol 210 125 4-Nitrophenol 188 97
(c) Derivatives of Aldehydes and Ketones
2,4-Dinitro-Phenyl- 2,4-Dinitro-Phenyl-
hydrazone hydrazone
qC,m/°C qC,m/°C
Methanal 166 Propanone 126
Ethanal 168 Butanone 116
Propanal 155 Pentan-3-one 156
Butanal 126 Pentan-2-one 144
Benzaldehyde 237 Heptan-4-one 75
2-Hydroxybenzaldehyde 252 dec. Phenylethanone 250
Ethanedial 327 Diphenylmethanone 239
Trichloroethanal 131 Cyclohexanone 162
(d) Derivatives of Amines

4-Methyl-benzene
Ethanoyl derivative Benzoyl derivative sulphonyl derivative
θC,m /°C θC,m /°C θC,m /°C
Methylamine 28 80 75
Ethylamine 205* 69 62
Propylamine 47 85 52
Butylamine 229‡ 70 65
(Phenylmethyl) amine 60 105 116
Phenylamine 114 163 103
Cyclohexylamine 104 147 87
2-Methylphenylamine 112 143 110
Dimethylamine 116‡ 42 87
Diethylamine 186‡ 42 60
Diphenylamine 103 180 142
* Disubstituted derivative.
‡ Boiling temperature.
2.254
ORGANIC CHEMISTRY 2.255
TABLE 2.22 Melting Points of n-Paraffins
Melting point
Number of carbon atoms °C °F
1 –182 –296
2 –183 –297
3 –188 –306
4 –138 –216
5 –130 –202
6 –95 –139
7 –91 –132
8 –57 –71
9 –54 –65
10 –30 –22
11 –26 –15
12 –10 14
13 –5 23
14 6 43
15 10 50
16 18 64
17 22 72
18 28 82
19 32 90
20 36 97
30 66 151
40 82 180
50 92 198
60 99 210
TABLE 2.23 Boiling Point and Density of Alkyl Halides
Chloride Bromide Iodide

B.p., Density B.p., Density B.p., Density
Name °C at 20°C °C at. 20°C °C at 20°C
Methyl –24 5 43 2.279
Ethyl 12.5 38 1.440 72 1.933
n-Propyl 47 .890 71 1.335 102 1.747
n-Butyl 78.5 .884 102 1.276 130 1.617
n-Pentyl 108 .883 130 1.223 157 1.517
n-Hexyl 134 .882 156 1.173 180 1.441
n-Heptyl 160 .880 180 204 1.401
n-Octyl 185 .879 202 225.5
Isopropyl 36.5 .859 60 1.310 89.5 1.705
Isobutyl 69 .875 91 1.261 120 1.605
see-Butyl 68 .871 91 1.258 119 1.595
tert-Butyl 51 .840 73 1.222 100d
Cyclohexyl 142.5 1.000 165
Vinyl(Haloethene) –14 16 56
Allyl (3-Halopropene) 45 .938 71 1.398 103
Crotyl (1-Halo-2-butene) 84 132
(Continued)
2.256 SECTION TWO
TABLE 2.23 Boiling Point and Density of Alkyl Halides (Continued)
Chloride Bromide Iodide

B.p., Density B.p., Density B.p., Density
Name °C at 20°C °C at 20°C °C at 20°C
Methylvinylcarbinyl 64
(3-Halo-1-butene)
Propargyl (3-Halopropyne) 65 90 1.520 115
Benzyl 179 1.102 201 9310
a-Phenylethyl 9215 8510
b-Phenylethyl 9220 9211 12719
Diphenylmethyl 17319 18420
Triphenylmethyl 310 23015
Dihalomethane 40 1.336 99 2.49 180d 3.325
Trihalomethane 61 1.489 151 2.89 subl. 4.008
Tetrahalomethane 77 1.595 189.5 3.42 subl. 4.32
1,1-Dihaloethane 57 1.174 110 2.056 179 2.84
1,2-Dihaloethane 84 1.257 132 2.180 d 2.13
Trihaloethylene 87 164 2.708
Tetrahaloethylene 121 subl.
Benzal halide 205 14020
Benzotrihalide 221 1.38
TABLE 2.24 Properties of Carboxylic Acids
Solub.,
M.p., B.p., g/100 g
Name Formula °C °C H2O
Formic HCOOH 8 100.5 ∞
Acetic CH3COOH 16.6 118 ∞
Propionic CH3CH2COOH –22 141 ∞
Butyric CH3(CH2)2COOH –6 164 ∞
Valeric CH3(CH2)3COOH –34 187 3.7
Caproic CH3(CH2)4COOH –3 205 1.0
Caprylic CH3(CH2)6COOH 16 239 0.7
Capric CH3(CH2)8COOH 31 269 0.2
Lauric CH3(CH2)10COOH 44 225100 i.
Myristic CH3(CH2)12COOH 54 251100 i.
Palmitic CH3(CH2)14COOH 63 269100 i.
Stearic CH3(CH2)16COOH 70 287100 i.
Oleic cis-9-Octadecenoic 16 22310 i.
Linoleic cis,cis-9,12-Octadecadienoic –5 23016 i.
Linolenic cis,cis,cis-9,12,15-Octadecatrienoic –11 23217 i.
Cyclohexanecarboxylic cyclo-C6H11COOH 31 233 0.20
Phenylacetic C6H5CH2COOH 77 266 1.66
Benzoic C6H5COOH 122 250 0.34
o-Toluic o-CH3C6H4COOH 106 359 0.12
m-Toluic m-CH3C6H4COOH 112 263 0.10
p-Toluic p-CH3C6H4COOH 180 275 0.03
o-Chlorobenzoic o-ClC6H4COOH 141 0.22
m-Chlorobenzoic m-ClC6H4COOH 154 0.04
p-Chlorobenzoic p-ClC6H4COOH 242 0.009
o-Bromobenzoic o-BrC6H4COOH 148 0.18
m-Bromobenzoic m-BrC6H4COOH 156 0.04
TABLE 2.24 Properties of Carboxylic Acids (Continued)
Solub.,
M.p., B.p., g/100 g
Name Formula °C °C H2O
p-Bromobenzoic p-BrC6H4COOH 254 0.006
o-Nitrobenzoic o-O2NC6H4COOH 147 0.75
m-Nitrobenzoic m-O2NC6H4COOH 141 0.34
p-Nitrobenzoic p-O2NC6H4COOH 242 0.03
Phthalic o-C6H4(COOH)2 231 0.70
Isophthalic m-C6H4(COOH)2 348 0.01
Terephthalic p-C6H4(COOH)2 300 subl. 0.002
Salicylic o-HOC6H4COOH 159 0.22
p-Hydroxybenzoic p-HOC6H4COOH 213 0.65
Anthranilic o-H2NC6H4COOH 146 0.52
m-Aminobenzoic m-H2NC6H4COOH 179 0.77
p-Aminobenzoic p-H2NC6H4COOH 187 0.3
o-Methoxybenzoic o-CH3OC6H4COOH 101 0.5
m-Methoxybenzoic m-CH3OC6H4COOH 110
p-Methoxybenzoic (Anisic) p-CH3OC6H4COOH 184 0.04
TABLE 2.25 The Structure, Melting Point, and Boiling Points of Polycyclic Aromatic Hydrocarbons
IUPAC Melting Boiling

nomeclature Molecular point point
Structure (synonyms) weight (°C) (°C)760
Indan 118.18 –51 178
Hydrindene
2,3-Dihydroindene
Indene 116.16 –2 183

Indonaphthene
Naphthalene 128.19 81 218

Tar Camphor
White Tar
Moth Flakes
2-Methylnaphthalene 142.20 35 241

b-Methylnaphthalene
1-Methylnaphthalene 142.20 –22 245

a-Methylnaphthalene
Biphenyl 154.21 71 255

Diphenyl
Phenylbenzene
Bibenzene
2-Ethylnaphthalene 156.23 –7 258

b-Ethylnaphthalene
2.258 SECTION TWO
(Continued )

1-Ethylnaphthalene 156.23 –14 259
2,6-Dimethylnaphthalene 156.23 110 262
1,7-Dimethylnaphthalene 156.23 263

Guaiene

a-Dimethylnaphthalene
4-Methylbiphenyl 168.24 50 268

(Continued)

Azulene 128.19 100 270 d
1,2-Dimethylnaphthalene 156.23 –4 271
Acenaphthylene 152.21 93 –270 d
3-Methylbiphenyl 168.24 5 273
3,5-Dimethylbiphenyl 182.27 275
Acenaphthene 154.21 96 279

Naphthyleneethylene
1,3,7-Trimethylnaphthalene 170.25 14 280
Fluorene 166.23 117 294

2,3-Benzindene
Diphenylenemethane
9-Methylfluorene 180.25 47
(Continued)
2.260 SECTION TWO
(Continued)

4-Methylfluorene 180.25
3-Methylfluorene 180.25 85 316
2-Methylfluorene 180.25 104 318
1-Methylfluorene 180.25 –318
1-Phenylnaphthalene 204.28 –45 334

a-Phenylnaphthalene
Phenanthrene 178.24 101 338

o-Diphenyleneethylene
Anthracene 178.24 216 340
3-Methylphenanthrene 192.26 65 352
2-Methylphenanthrene 192.26 355

(Continued)

2-Methylanthracene 192.26 209 359 sub
4,5-Methylenephenanthrene 190.24 116 359

4H-Cyclopenteno[def]phenanthrene
4H-Cyclopenta[def]phenanthrene
4,5-Phenanthrylenemethane
4-Methylphenanthrene 192.26
2-Phenylnaphthalene 204.28 104 360

b-Phenylnaphthalene
1-Methylanthracene 192.26 86 363
3,6-Dimethylphenanthrene 206.29 363
2,7-Dimethylanthracene 206.29 241 –370
(Continued)
2.262 SECTION TWO
(Continued)

2,6-Dimethylanthracene 206.29 250 –370
2,3-Dimethylanthracene 206.29 252
Fluoranthene 202.26 111 383

Idryl
1,2-Benzacenaphthene
Benzo[jk]fluorine
Benz[a]acenaphthylene
9,10-Dimethylanthracene 206.29 183
Pyrene 202.26 156 393

Benzo[def]phenanthrene
2,7-Dimethylpyrene 230.32 396
Benzo[b]fluorene 216.29 209 402

11 H-Benzo[b]fluorene
2,3-Benzofluorene
Isonaphthofluorene
Benzo[c]fluorene 216.29 406

7H-Benzo[c]fluorene
3,4-Benzofluorene
Benzo[a]fluorene 216.29 190 407

11 H-Benzo[a]fluorene
1,2-Benzofluorene
Chrysofluorene
2-Methylpyrene 216.29 410

4-Methylpyren
(Continued)


3-Methylpyren

1-Methylpyren
Benzo[ghi]fluoranthene 226.28 432
Benzo[c]phenanthrene 238.30 68
3,4-Benzophenanthrene
Benz[a]anthracene 228.30 162 435 sub

1,2-Benzanthracene
Tetraphene
Naphthanthracene
Triphenylene 228.30 199 439

lsochrysene
Chrysene 228.30 256 441

Benzo[a]phenanthrene
6-Methylchrysene 242.32
(Continued)
2.264 SECTION TWO
(Continued)

1-Methylchrysene 242.32 257
Naphthacene 228.30 257 450 sub

Benz[b]anthracene
2,3-Benzanthracene
Tetracene
2,2′-Dinaphthyl 254.34 188 452753 sub

2,2′-Binaphthyl
b,b′-Binaphthyl
b,b′-Dinaphthyl
Benzo[b]fluoranthene 252.32 168 481

2,3-Benzofluoranthene
Benz[e]acephenanthrylene
Benzo[j]fluoranthene 252.32 166 ∼480

Benzo[k]fluoranthene 252.32 217 481

8,9-benzofluoranthene
Benzo[e]pyrene 252.32 179 493

4,5-Benzpyrene
1,2-Benzopyrene
Benzo[a]pyrene 252.32 177 496

1,2-Benzpyrene
3,4-Benzopyrene
Benzo[def]chrysene
(Continued)

Perylene 252.32 278

peri-Dinaphthalene
3-Methylcholanthrene 268.38 180

20-Methylcholanthrene
Indeno[1,2,3-cd]pyrene 276.34
o-Phenylenepyrene
Dibenz[a,c]anthracene 278.36 205

1,2:3,4-Dibenzanthracene
Naphtho-2′,3′,:9,10-phenanthrene
Dibenz[a,h]anthracene 278.36 270

Dibenz[a,i]anthracene 278.36 264

1,2-Benzonaphthacene
Isopentaphene
Dibenz[a,j]anthracene 278.36 198

a,a′-Dibenzanthracene
Dinaphthanthracene
(Continued)
2.266 SECTION TWO
(Continued)

Benzo[b]chrysene 278.36 294

1,2:6,7-Dibenzophenanthrene
3,4-Benzotetraphene
Naphtho-2′,1′:1,2-anthracene
Picene 278.36 368 519

Dibenzo[a;i]phenanthrene
3,4-Benzochrysene
1,2:7,8-Dibenzophenanthrene
Benzo[ghi]perylene 276.34 278

1,12-Benzoperylene
Anthanthrene 276.34
Dibenzo[def, mno]chrysene
Coronene 300.36 439 cor 525?

Hexabenzobenzene
Dibenzo[a,e]pyrene 302.38 234
*Key: d = decomposes; sub = sublimes.

TABLE 2.26 Properties of Naturally Occurring Amino Acids
Three- One-
letter letter Side chains (–R) Mol ∆Hion Volume ASAmc ASAnpl
sc ASApol
sc
Name code code R-CH(NH2)COOH weight pKa kJ ⋅ mol–1 Å3 Å2 Å2 Å2
Alanine Ala A -CH3 71.08 88.6 46 67
Arginine Arg R -(CH2)3-CNH(˙NH)NH3 156.20 12 44.9 173.4 45 89 107
Asparagine Asn N -CH2-CONH2 114.11 117.7 45 44 69
Aspartic acid Asp D -CH2-COOH 115.09 4.5 4.6 111.1 45 48 58
Cystein Cys C -CH2-SH 103.14 9.1–9.5 36.0 108.5 36 35 69
Glutamine Gln Q -(CH2)2-CONH2 128.14 143.9 45 53 91
Glutamic acid Glu E -(CH2)2-COOH 129.12 4.6 1.6 138.4 45 61 77
Glycine Gly G -H 57.06 60.1 85
N
Histidine His H CH2 137.15 6.2 43.6 153.2 43 102 49
N
Isoleucine Ile I -CH(CH3)-C2H5 113.17 166.7 42 140
Leucine Leu L -CH(CH3)2-CH2 113.17 166.7 43 137
Lysine Lys K -(CH2)4-NH2 128.18 10.4 53.6 168.6 44 119 48
Methionine Met M -(CH2)2-S-CH3 131.21 162.9 44 117 43
Phenylalanine Phe F CH2 147.18 189.9 43 175
Proline Pro P * 97.12 122.7 38 105

Serine Ser S -CH2-OH 87.08 89.0 42 44 36
Threonine Thr T -CH2-(CH3)-OH 101.11 116.1 44 74 28
Tryptophane Trp W CH2 186.21 277.8 42 190 27
Tyrosine Tyr Y 163.18 9.7 25.1 193.6 42 144 43

CH2 OH
Valine Val V -CH-(CH3)2 99.14 140 43 117

α-amino 6.8–7.9
α-carboxyl 3.5–4.3
a
Enthalpies of ionization of side chains at 25°C, ∆Hion, are from [20]; van der Waals volume from [21]; ASAmc, surface area of the backbone,
ASAnpl pol
sc , nonpolar surface area of the side chains, and ASAsc , polar surface area of the side chains are taken [17].
2.268 SECTION TWO
TABLE 2.27 Hildebrand Solubility Parameters of Organic Liquids
Solvent d (Mpa1/2) H-bonding tendencyb Solvent d (Mpa1/2) H-bonding tendencyb

Acetaldehyde 21.1 m Ethyl chloride 18.8 m
Acetic acid 20.7 s Ethylenediamine 25.2 s
Acetone 20.2 m Ethylene dichloride 20.0 p
Acetonitrile 24.3 p Ethylene glycol 29.9 s
Acetyl chloride 19.4 m Ethylene glycol 17.6 m
N-Acetylpiperidine 22.9 s dimethylether
Acrylic acid 24.5 s Ethylene oxide 22.7 m
Allyl acetate 18.8 m Ethyl formate 19.2 m
Allyl alcohol 24.1 s Ethyl methacrylate 17.0 m
Ammonia 33.3 s Formic acid 24.7 s
Benzene 18.8 p Furan 19.2 m
Bromobenzene 20.2 p Heptane 15.1 p
1,3-Butadiene 14.5 p Hexane 14.9 p
Butane 13.9 p 1-Hexene 15.1 p
1,3-Butanediol 23.7 s Hydrazine 37.0 s
1-Butanol 23.3 s Hydrogen 6.1 p
2-Butanol 22.1 s Isobutanol 21.5 s
tert-Butanol 21.7 s Isobutyl acetate 17.0 m
Butyl acetate 17.4 m Isobutylene 13.7 p
Butyl amine 17.8 s Isoprene 15.1 p
Butyl ether 16.0 m Isopropanol 23.5 s
Butyl lactate 19.2 m Isopropyl acetate 17.2 m
Carbon disulfide 20.4 p Methane 11.0 p
Chloroacetonitrile 25.8 p Methanol 29.6 s
Chlorobenzene 19.4 p Methyl acetate 19.6 m
Chloroethane 18.8 m Methyl acrylate 18.2 m
Chloromethane 19.8 m Methyl butyl ketone 17.0 m
Cyclohexane 16.8 p Methyl ethyl ketone 19.0 m
Cyclohexanol 23.3 s Methyl formate 20.9 m
Cyclopentane 17.8 p Methyl isopropyl ketone 17.4 m
Decalin 18.0 p Methyl methacrylate 18.0 m
Decane 13.5 p Nitrobenzene 20.5 p
Diamyl ether 14.9 m Nitroethane 22.7 p
Dibenzyl ether 19.2 m Octane 15.6 p
Dibutyl amine 16.6 s Pentane 14.3 p
Dibutyl fumarate 18.4 m Propane 13.1 p
Dibutyl phenyl phosphate 17.8 m 1-Propanol 24.3 s
Dibutyl phthalate 19.0 m 2-Propanol 23.5 s
Diethylamine 16.4 s Pyridine 21.9 s
Diethlene glycol 24.8 s Quinoline 22.1 s
Diethyl ether 15.1 m Silicon tetrachloride 15.1 p
Diisopropyl ether 14.1 m Styrene 19.0 p
Diisopropyl ketone 16.4 m Succinic anhydride 31.5 s
N,N-Dimethylformamide 24.8 m Tetra chloromethane 17.6 p
Dimethyl sulfone 29.7 m Tetrahydrofuran 18.6 m
Dimethylsulfoxide 24.5 m Toluene 18.2 p
1,4-Dioxane 20.5 m 1,1,2-Trichloroethane 19.6 p
Ethane 12.3 p Trichloromethane 19.0 p
Ethanol 26.0 s Water 47.9 s
Ethyl acetate 18.6 m Xylene 18.0 p
Ethylamine 20.5 s
Ethylbenzene 18.0 p
b
p denotes poor; m, moderate; s, strong.
TABLE 2.28 Hansen Solubility Parameters of Organic Liquids
Solubility parameter (MPa1/2)

V
Solvent (cm3/mol) dd dp dh dt
Acetic acid 57.1 14.5 8.0 13.5 21.3
Acetone 74.0 15.5 10.4 7.0 20.1
Acetonitrile 52.6 15.3 18.0 6.1 24.6
Acetyl chloride 71.0 15.8 10.6 3.9 19.4
Benzene 29.4 18.4 0.0 2.0 18.6
Benzaldehyde 101.5 19.4 7.4 5.3 21.5
Benzyl chloride 115.0 18.8 7.2 2.7 20.3
Bromoform 87.5 21.5 4.1 6.1 22.7
N-Butane 101.4 14.1 0.0 0.0 14.1
Butyronitrile 27.0 15.3 12.5 5.1 20.5
Carbon tetrachloride 97.1 17.8 0.0 0.6 17.8
Carbon disulfide 60.0 20.5 0.0 0.6 20.5
Chlorobenzene 102.1 19.0 4.3 2.0 19.6
Chloroform 80.7 17.8 3.1 5.7 19.0
Cyclohexanol 106.0 17.4 4.1 13.5 22.5
Cyclohexylamine 115.2 17.4 3.1 6.5 18.8
N-Decane 195.9 15.8 0.0 0.0 15.8
Diacetone alcohol 124.2 15.8 8.2 4.8 20.9
o-Dichlorobenzene 112.8 19.2 6.3 3.3 20.5
Diethyl carbonate 121.0 16.6 3.1 6.1 18.0
Diethyl ketone 106.4 15.8 7.6 4.7 18.2
Dimethyl phthalate 163.0 18.6 4.8 4.9 22.1
Dimethyl sulfoxide 71.3 18.4 16.4 10.2 26.6
Ethanol 58.5 15.8 8.8 19.4 26.6
Ethyl acetate 98.5 15.8 5.3 7.2 18.2
Ethyl bromide 76.9 16.6 8.0 5.1 19.0
Ethyl formate 80.2 15.5 8.4 8.4 19.6
Ethylene carbonate 66.0 19.4 21.7 5.1 29.5
Ethylene dichloride 79.4 19.0 7.4 4.1 20.9
Formic acid 37.8 14.3 11.9 16.6 25.0
Furan 72.5 17.8 1.8 5.3 18.6
Methanol 40.7 15.1 12.3 22.3 29.7
Methyl acetate 79.7 15.5 7.2 7.6 18.8
Methyl chloride 55.4 15.3 6.1 3.9 17.0
Methylene dichloride 63.9 18.2 6.3 6.1 20.3
Nitrobenzene 102.7 20.1 8.6 4.1 22.1
Nitroethane 71.5 16.0 15.5 4.5 22.7
Nitromethane 54.3 15.8 18.8 5.1 25.0
1-Octanol 157.7 17.0 3.3 11.9 20.9
2-Octanol 159.1 16.2 4.9 11.0 20.3
Phenol 87.5 18.0 5.9 14.9 24.1
1-Propanol 75.2 16.0 6.8 17.4 24.6
2-Propanol 76.8 15.8 6.1 16.4 23.5
Quinoline 118.0 19.4 7.0 7.6 22.1
Styrene 115.6 18.6 1.0 4.1 19.0
Tetrahydrofuran 81.7 16.8 5.7 8.0 19.4
Toluene 106.8 18.0 1.4 2.0 18.2
Trimethyl phosphate 99.9 16.8 16.0 10.2 25.4
Water 18.0 15.5 16.0 42.4 47.9
2.270 SECTION TWO
TABLE 2.29 Group Contributions to the Solubility Parameter
Fi Fi
Group (1) (2) (3) Group (1) (2) (3)
[Br 340 258 300 [CæN 410 355 480
[Cl 250–270 205 230 O
;
[F … 41 80 [C[NH2 … … 600
O
[H 80–100 … … ;
[I 425 … … NH2[C[O[ … … 725
[NO2 440 … … —CO— 275 263 335
[ONO2 440 … … —COO— 310 327 250
[O[ 70 115 125 —COOH … … 319
[OH … 226 369 —CO3— … … 375
[PO4 500 … … —CæC— 222 … …
[S— 225 209 225 CHæC— 285 … …
[SH 315 … … O O
; ;
C –93 32 0 [C[O[C[ … 567 375
[CH˙ 19 84 40 [C˙C[C˙C[20–30 23 …
[CF2[ 150 115 …
[CF3 274 156 … 105–115 21 …
CH 28 86 68 [C6H4 658 705 673
[CH˙ 111 122 109 [C6H5 735 683 741

[CH2— 133 131 137
7
CH28 190 127 … 95–105 –23 …
[CH3 214 148 205 [C10H7 1146 … …

a
Adapted from D. W. Van Krevelen, Properties of Polymers, 2nd ed. (Elsevier, Amsterdam, 1976), p. 134. The references
referred to for the Fi values are (1) P.A. Small, J. Appl. Chem. 3, 71 (1953); (2) K. L. Hoy, J. Paint Technol. 42, 76 (1970); (3) D. W.
Van Krevelen, Properties of Polymers, 2nd ed. (Elsevier, Amsterdam, 1976), p. 134.
2.3 VISCOSITY AND SURFACE TENSION
The dynamic viscosity, or coefficient of viscosity, h of a Newtonian fluid is defined as the force per
unit area necessary to maintain a unit velocity gradient at right angles to the direction of flow
between two parallel planes a unit distance apart. The SI unit is pascal-second or netwon-second per
meter squared [N ⋅ s ⋅ m−2]. The c.g.s. unit of viscosity is the poise [P]; 1 cPæ1 mN ⋅ s ⋅ m−2.
Kinematic viscosity v is the ratio of the dynamic viscosity to the density of a fluid. The SI unit is
meter squared per second [m2 ⋅ s−1]. The c.g.s. units are called stokes [cm2 ⋅ s−1]; poises = stokes ×
density.
Fluidity f is the reciprocal of the dynamic viscosity.

The primary reference liquid for viscosity measurements is water. The absolute viscosity of water
at 20°C is 1.0019 (±0.0003) mN ⋅ s ⋅ m−2 (or centipoise), as determined by Swindells, Coe, and
Godfrey, J. Research Natl. Bur. Standards 48:1 (1952). The relative viscosity of water, h/h20°, is
0.8885 at 25°C, 0.7960 at 30°C, and 0.6518 at 40°C. Values at temperatures between 15 and 60°C are
best represented by Cragoe’s equation:
η 1.2348(20 − t ) − 0.001 467(t − 20)2

log =
η20o t + 96
The Reynolds number for flow in a tube is defined by dnr/h,− where d is the diameter of the tube,
n− is the average velocity of the fluid along the tube, r is the density of the fluid, and h is its dynamic
viscosity. At flow velocities corresponding with values of the Reynolds number of greater than 2000,
turbulence is encountered.
The surface tension of a liquid, g, is the force per unit length on the surface that opposes the
expansion of the surface area. In the literature the surface tensions are expressed in dyn ⋅ cm−1; 1 dyn ⋅
cm−1 = 1 mN ⋅ m−1 in the SI system. For the large majority of compounds the dependence of the
surface tension on the temperature can be given as
g = a − bt
where a and b are constants and t is the temperature in degrees Celsius. The values of a and b
given in Tables 2.30 can be used to calculate the values of surface tension for the particular com-
pound within its liquid range. For example, the least-squares constants for acetic anhydride
(liquid from −73 to 140°C) are 35.52 and 0.1436, respectively. At 20°C, g = 35.52 − 0.1436(20) =
32.64 dyn ⋅ cm−1.
2.272 SECTION TWO
TABLE 2.30
2.30 Viscosity and Surface
Surface Tension of Organic Compounds
For the majority of substances

substances the dependence surface tension gyon
dependence of the surface on the temperature can be given as:
gy == a -−bbt
t
where a and b are constants and t is the temperature in degrees Celsius.

Celsius. In the SI system the surface tensions are
expressed in mN ⋅ m (= dyn ⋅ cm
m-'−1 (= −1
).
cm-').
A compilation
compilation of some 2200 liquid compounds has been prepared by J. J. Jasper,Jasper. J. Phys.
Phjs. Chem.
Clzeni. Reference
Data 1:841 (1972).
Dara (1972).
The SI unit of viscosity is pascal-second (Pa ⋅ s) or Newton-second
Newton-second per meter squared (N ⋅. s ⋅. m −2
). Values
m-*).
tabulated are mN ⋅ s ⋅ m m-'−2 (=
(= centipoise,
centipoise. cP). The temperature in degrees Celsius at which the viscosity of a
substance value..
substance was measured is shown in parentheses after the value
Surface tension,
mN. m-I
Substance a b Liquid range, "C Viscosity, mN . s . m-2
Acetaldehyde 23.90 0.1360 - 123 to 21 0.2797(0), 0.2557(10), 0.22(20)

Acetaldoxime 34.23 0.1134 12(p) or 46.5((~)to
114.5
Acetamide 47.66 0.1021 81 to 222 1.63(94), 1.32(105), 1.06(120)
Acetanilide 46.21 0.0912 I14 to 304 2.22(120), l.YO(130)
Acetic acid 29.58 0.0994 16.7 to 118 1.056(25), 0.786(50), 0.424(110)
Acetic anhydride 35.52 0.1436 -73 to 139 1.241(0), 0.907(20), 0.699(40)
Acetone 26.26 0.112 - 94 to 56 0.395(0), 0.306(25), 0.256(50)
Acetonitrile 29.58 0.1178 -44 to 81.6 0.397(10), 0.329(30), 0.2753(50)
Acetophenone 41.92 0.1154 20 to 202 1.511(30), 1.192(45), 0.634(100)
Acetyl chloride 26.7(15) - 113 to 51 0.368(25), 0.294(50)
Acrylic acid 28.1(30) 14 to 141
Acrylonitrile 29.58 0.1178 -83.5 to 77.3
Allyl acetate 28.73 0.1186 up to 104
Allyl alcohol 27.53 0.0902 - 129 to 97 1.218(25), 0.759(50), 0.553(70)
Allylamine 27.49 0.1287 -88 to 55
Allyl isothiocyanate 36.76 0.1074 -80 to 152
2-Aminoethanol 51.11 0.1117 10.3 to 171
Aniline 44.83 0.1085 -6 to 186 3.847(25), 2.029(50), 1.247(75)
Benzaldehyde 40.72 0.1090 -26 to 179
Benzamide 47.26 0.0705 129 to 290
Benzene 28.88(20) 27.56(30) 5.5 to 80 0.649(20), 0.566(30), 0.395(60)
Benzenesulfonyl chloride 45.48 0.1117 14.5 to 251
Benzenethiol 41.41 0.1202 - 14.9 to 169
Benzonitrile 41.69 0.1159 - 12.7 to 191 1.447(15), l.lIl(30), 0.883(50)
Benzophenone 46.31 0.1128 48 to 305
Benzoyl bromide 45.85 0.1397 -24 to 219
Benzoyl chloride 41.34 0.1084 - 1 to 197
Benzyl alcohol 38.25 0.1381 - 15.2 to 205 5.474(25), 2.760(50), 1.618(75)
Benzylamine 42.33 0.1213 10 to 180 1.624(25), 1.080(50), 0.769(75)
Benzyl benzoate 48.07 0.1065 21 to 323 8.454(25)
Benzyl chloride 39.92 0.1227 -43 to 179
ORGANICCHEMISTRY
2.273
TABLE2.30
TABLE 2.30 Viscosity
Viscosity and
andSurface
SurfaceTension
TensionofofOrganic
OrganicCompounds (Continued)
Compounds(Continued)
Surface tension,
mN . m-'

Benzyl ethyl ether 32.82(20) 29.97(40) up to 186
Biphenyl 41.52 0.0931 69 to 256
Bis(2-ethoxyethyl) ether 29.74 0.1176 -45 to 188
Bis(2-hydroxyethyl) ether 46.97 0.0880 - 10.4 to 246
Bis(Zmethoxyethy1) ether 32.47 0.1164 -68 to 162
Bromobenzene 38.14 0.1160 - 30.6 to 156 1.196(15), 0.985(30), 0.385(1423)
1-Bromobutane 28.71 0.1126 - 112.4 to 101.6 0.633(20), 0.606(25), 0.471(50)
(?)-2-Bromobutane 27.48 0.1 107 - 112.7 to 91.4
Bromochloromethane 33.32(20) - 88 to 68
Bromocyclohexane 36.13 0.1117 up to 165.8
1Bromodecane 31.26 0.0856 - 30 to 240
Bromodichloromethane 35.11 0.1294 -55 to 87
1Bromododecane 32.58 0.0882 - 11 to bp
Bromoethane 26.52 0.1159 - 119 to 38.2 0.477(10), 0.374(25)
Bromoform 48.14 0.1308 8 to 149
1-Bromoheptane 30.74 0.0982 -58 to 180
1-Bromohexadecane 33.37 0.0861 17.8 to 336
1Bromohexane 29.81 0.0967 -85 to 158
Bromomethane 26.52 0.1159 - 94 to 3.56
1-Bromo-3-methylbutane 28.10 0.0996 - 112 to 119.7
1-Bromo-2-methylpropane 26.96 0.1059 - 119 to 91.5
1-Bromonaphthalene 46.44 0.1018 - 1.8 to 281
1-Bromononane 31.36 0.0894 ca. -55 to 201
1-Bromooctane 3 1.OO 0.0928 -55 to 201
1-Bromopentane 29.5 1 0.1049 - 88 to 129.6
p-Bromophenol 48.88 0.1070 64 to 238
1-Bromopropane 28.30 0.1218 - 110.1 to 71 0.539(15), 0.459(30), 0.338(70)
2-Bromopropane 26.21 0.1183 - 89 to 59.5 0.536(15), 0.437(30), 0.359(50)
3-Bromopropene 29.45 0.1257 - 119 to 70 0.620(0), 0.471(25), 0.373(50)
1-Bromotetradecane 32.93 0.0878 6 to > 178
o-Bromotoluene 36.62 0.0998 -26 to 181
p-Bromotoluene 36.40 0.0997 28.5 to 184
1-Bromoundecane 31.94 0.0861 -9 to >138
Butanal 26.67 0.0925 - 99 to 74.8
Butane 14.87 0.1206 - 138.3 to -0.5
1.3-Butanediol 37.8(25) < - 50 to 207.5
2,3-Butanediol 36(25) 25 to 182
Butanenitrile - 112 to 117.6 0.553(25), 0.418(50), 0.330(75)
Butanesulfonyl chloride 37.33 0.0977
1-Butanethiol 28.07 0.1 142 - 116 to 98.5
Butanoic acid 28.35 0.0920 -6 to 163.5 1.540(20), 0.980(40), 0.323(60)
Butanoic anhydride 28.93(20) 28.44(25) -66 to 199.5
1-Butanol 27.18 0.0898 -89.5 to 117.7 5.185(0),'2.948(20), 1.782(40)
(+)-2-Butanol 23.47(20) 22.62(30) - 114.7 to 99.5 3.907(20), 1.332(50), 0.698(75)
2-Butanone 26.77 0.1122 - 86.7 to 79.6 0.428(20), 0.349(40), 0.249(75)
1-Butene 15.19 0.1323 - 185 to - 6.5
2-Butene 16.11 0.1289 - 106 to 0.9
3-Butenenitrile 3 1.40 0.1085 -87 to 119
2-Butoxyethanol 28.18 0.0816 -75 to 168
(Continued)
(Conrinued)
2.274 SECTION TWO
TABLE 2.30
2.30 Viscosity and Surface Tension of Organic
O g a riic Compounds (Continued)
(Continued)
Surface tension,
mN. m-I
2-(2-Butoxyethoxy)ethanol 30.0(25) -68.1 to 230.4

Butyl acetate 27.55 0.1068 -77 to 126 0.734(20), 0.688(25), 0.500(50)
(2)-sec-Butyl acetate 23.33(22) 21.24(42) -99 to 112 0.676(25), 0.493(50), 0.370(75)
rerr-Butyl acetate 24.69 0.1 102 up to 98
Butylamine 26.24 0.1122 - 50 to 77 0.830(0), 0.574(25), 0.409(50)
sec-Butylamine 23.75 0.1057 - 104 to 63 0.770(0), 0.571(25), 0.367(50)
ferr-Butylamine 19.44 0.1028 -66 to 44
Butylbenzene 31.28 0.1025 -88 to 183 1.035(20), 0.683(50),0.515(75)
sec-Butylbenzene 30.48 0.0979 -82.7 to 173
tert-Butylbenzene 30.10 0.0985 -58.1 to 168.5
Butyl butanoate 27.65 0.0965 -91.5 to 166
Butyl ethyl ether 22.75 0.1049 - 124 to 92
Butyl formate 27.08 0.1026 -91.5 to 106 0.940(0), 0.691(20), 0.472(50)
Butyl methyl ether 22.17 0.1057 -115.5t070
Butyl nitrate 30.35 0.1126 up to 133
Butyl propanoate 27.37 0.0993 - 89 to 146.8
4-terf-Butylpyridine 35.48 0.0951 ca. -44 to 197
Butyl stearate 33.0(25) 32.7(30) 26 to 343
Butyl vinyl ether 21.99(20) - 92 to 94.2
Carbon disulfide 35.29 0.1484 -111.6t046.5 0.429(0), 0.363(20), 0.352(25)
Carbon tetrachloride 29.49 0.1224 - 23 to 76.7 1.321(0), 0.908(25), 0.656(50)
D-( +)-Carvone 36.54 0.0920 < 15 to 230
Chloroacetic acid 43.27 0.1117 61 to 189 3.15(50), 1.92(75)
o-Chlproaniline 43.41 0.0904 - 14 to 208.8 3.316(25), 1.913(50), 1.248(75)
p-Chloroaniline 48.69 0.1099 72.5 to 232
Chlorobenzene 35.97 0.1191 -45.3 to 131.7 0.799(20), 0.63 1(40), 0.512(60)
1-Chlorobutane 25.97 0.1117 - 123.1 to 78.4 0.556(0), 0.422(25), 0.329(50)
2-Chlorobutane 24.40 0.1118 - 131.3 to 68.2 0.439( 15)
Chlorocyclohexane 33.90 0.1101 -44 to 142
1-Chlorododecane 31.56 0.0904 -9 to 116
1-Chloro-2,3-epoxypropane 39.76 0.1360 -57.2 to 116.1 I .03(25)
Chloroethane 21.18(5) 20.58(10) - 139 to 12.3 0.416(-252 0.319(0), 0.279(10)
2-Chloroethanol 38.9(20) -67.5 to 128.6 3.913(15)
Chloroform 29.91 0.1295 -63.6 t061.1 0.706(0), 0.596(15), 0.514(30)
1-Chloroheptane 28.94 0.0961 -69 to 161
1-Chlorohexane 28.32 0.1038
1-Chloro-3-methylhutane 25.51 0.1076 - 104 to 99
1-Chloro-2-methylpropane 24.40 0.1099 - 130.3 to 68.9 0.462(20), 0.373(40)
2-Chloro-2-methyl propane 20.06( 15) 18.35(30) - 26 to 50.8 0.543( 15)
1-Chloronaphthalene 44.12 0.1035 - 2.3 to 259 2.940(25)
o-Chloronitrohenzene 48.10 0.1171 33 to 246
m-Chloronitrohenzene 49.71 0.1417 44 to 236
p-Chloronitrohenzene 4.5.84 0.1046 84 to 242
1-Chlorooctane 29.64 0.0961 -58 to 182
1 -Chloropentane 27.09 0.1076 - 99 to 108 0.580(20)
o-Chlorophenol 42.5 0.1122 9.8 to 175 3.589(25), 1.835(50),1.131(75)
m-Chlorophenol 43.7 0.1009 33 to 214 1 I .55(25), 4.725(45),4.041(50)
p-Chlorophenol 46.0 0.1049 43 to 220 4.99(50)
1-Chloropropane 24.41 0.1246 - 122.8 to 47 0.436(0), 0.372(15), 0.3 18(30)
Next Page
TABLE 2.30
2.30 Viscosity and Surface
Surface Tension of Organic Compounds (Continued)
(Continued)
Surface tension,
m N . m-
Substance a b Liquid range, "C Viscosity, mN s m-z
2-Chloropropane 21.37 0.0883 -117t036 0.401(0), 0.335(15), 0.299(30)

3-Chloro-1-propene 25.50 0.0946 - 134.5 to 45 0.347(15)
o-Chlorotoluene - 35.6 to 159 1.267(25), 0.883(50), 0.662(75)
m-Chlorotoluene -47.8 to 161.8 0.964(25), 0.710(50),0.547(75)
p-Chlorotoluene 34.93 0.1082 7.5 to 162.4 0.837(25), 0.621(50),0.483(75)
Chlorotrimethylsilane 19.51 0.0875 -40 to 57
o-Cresol 39.43 0.1011 30 to 191 3.035(50), 1.562(75), 0.961(100)
m-Cresol 38.00 0.0924 12 to 202 12.9(25),4.417(50), 2.093(75)
p-Cresol 38.58 0.0962 34.8 to 202 5.607(45)
Cycloheptanol 35.02 0.0923 2 to 185
Cyclohexane 27.62 0.1188 6.6 to 80.7 0.980(20), 0.912(25),0.650(50)
Cyclohexanol 35.33 0.0966 25.4 to 161 57.5(25), 41.07(30), 12.3(50)
Cyclohexanone 37.67 0.1242 -31 to 155.7 2.453(15), 1.803(30), 1.321(50)
Cyclohexene 29.23 0. I223 - 103.5 to 83 0.882(0),0.625(25), 0.467(50)
Cyclohexylamine 34.19 0.1188 18 to 134
- 1.079(25), 0.692(50), 0.485(75)
Cyclooctane 32.02 0.1090 14.8 to 151.1
Cyclopentane 25.53 0.1462 - 94 to 50 0.555(0), 0.413(25), 0.321(50)
Cyclopentanol 35.04 0.1011 19 to 140
- 0.439(20)
Cyclopentanone 35.55 0.1100 -51 to 130.6
Cyclopentene 25.94 0.1495 - 135.1 to 44.2
cis-Decahydronaphthalene 32.18(20) 31.01(30) -43 to 195.8 3.042(25), 1.875(50), 1.271(75)
trans-Decahydronaphthalene 29.89(20) 28.87(30) - 30.4 to 187.3 1.948(25), 1.289(50),0.917(75)
Decamethylcyclopentasiloxane 19.56 0.0565 -38 to >I01
Decamethyltetrasiloxane 86.20(25) -68 to 194 1.28(20)
Decane 25.67 0.0920 -29.7 to 174.1 1.277(0),0.838(25), 0.598(50)
I-Decanol 30.34 0.0732 6.9 to 232 10.9(25), 4.590(50)
I-Decene 25.84 0.0919 - 66 to 170.6 0.805(20)
Dibenzylamine 43.27 0.1086 - 26 to 300
Dibenzyl ether 38.2(35) 2 to 298 3.7 1l(25)
p-Dibromobenzene 41.84 0.1007 87.3 to 220
1,4-Dibromobutane 48.24 0.1190 -20 to 198
1,Z-Dibromoethane 42.85 0.1320 10 to 131.7 1.721(20), 1.286(40), 0.648(100)
1,Z-Dibromopropane 36.81 0.1155 -55.5 to 142 1.5(25)
Dibromotetrafluoroethane 18.9(20) 18.1(25) - 110.5 to 47 0.72(25)
Dibutylamine 26.50 0.0952 -62 to 159.6 0.918(25), 0.619(50), 0.449(75)
Dibutyl decanedioate - 10 to 345 9.03(25)
Dibutyl ether 24.78 0.0934 -95 to 140 0.637(25), 0.466(50), 0.356(75)
Dibutyl maleate 32.46 0.0865 < -80t0281 5.62(20), 4.76(25)
Dihutyl o-phthalate 33.40(20) - 35 to 340 19.91(20), 11.17(35), 7.85(45)
Dichloroacetic acid 37.8 0.0927 9 to 194 3.23(50), 1.92(75)
o-Dichlorobenzene 35.55(30) - 17 to 180.4 1.324(25),0.962(50), 0.739(75)
m-Dichlorobenzene 38.30 0.1147 -24.8 to 173.1 1.044(25), 0.783(50), 0.628(75)
p-Dichlorobenzene 34.66 0.0879 53 to 174.1 0.839(55), 0.668(79)
1.4-Dichlorohutane 37.79 0.1174 -38 to 163
1.1-Dichloroethane 27.03 0.1186 -97 to 57.3 0.505(15),0.464(25), 0.362(50)
1,2-Dichloroethane 35.43 0.1428 -35.7 to 83.5 1.125(0), 0.779(25),0.576(50)
I, 1-Dichloroethylene - 122.6 to 31.6 0.442(0), 0.358(20)
cis-1.2-Dichloroethylene 28(20) -80.1 to 60 0.785( - 25), 0.575(0), 0.444(25)
trans- 1,2-Dichloroethylene 25(20) -49.8 to 48.7 0.522(-25), 0.398(0), 0.317(25)
2,2'-Dichloroethyl ether 40.57 0.1306 up to 178.5 2.41(20), 2.065(25)
(Continued)
(Continued)

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TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants

Formula Beilstein Density, Refractive Melting- Boiling Flash Solubility

TABLE 2.20 Physical Constants

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

TABLE 2.20 Physical Constants

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants of Organic

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

n8 l&Naphthalic 198.18 17,521 268 sl s HOAc

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

TABLE 2.20 Physical Constants

Formula Beilstein Density,

TABLE 2.20 Physical Constants

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

p135 2-Phenylphenol 170.21 623

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

TABLE 2.20 Physical Constants

Formula Beilstein Density,

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

s9 trans-Stilbene 180.25 5,630 0.970 122-124 307 v s bz, eth

s12 Styrene oxide H$-CHC6HS 120.15 17,49 1.054 1.533820 - 37 194 19

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

TABLE 2.20 Physical Constants

Formula Beilstein Density,

TABLE 2.20 Physical Constants

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants

Formula Beilstein Density,

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density,

TABLE 2.20 Physical Constants of Organic

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

TABLE 2.20 Physical Constants of Organic Compounds (Continued)

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

t410 Triphenylamine 245.33 12, 181 0.7748 125- 127 347-348

t426 Triphenyltin hydroxide 367.02 16,914 124-126

TABLE 2.20 Physical Constants of Organic

Formula Beilstein Density, Refractive Melting Boiling Flash Solubility

u10 3-Undecanone CH,(CH,),COCH,CH, 170.30 1,713 0.827 1.429lZ0 12-13 225-229 89

(a) Derivatives of Alcohols

(d) Derivatives of Amines

TABLE 2.22 Melting Points of n-Paraffins

TABLE 2.23 Boiling Point and Density of Alkyl Halides

Chloride Bromide Iodide

TABLE 2.23 Boiling Point and Density of Alkyl Halides (Continued)