POWDER COATINGS RESINS

Product Guide - Americas

www.allnex.com
About allnex Table of Contents

Introduction.........................................................................................................................................................4
Product index......................................................................................................................................................5
Product Nomenclature................................................................................................................................. 6-7
Polyester Resins for Hybrid Powder Coatings.............................................................................................8
Typical Properties for Hybrid Resins..............................................................................................................9
Polyester Resins for TGIC Powder Coatings..............................................................................................10
Typical Properties for TGIC Resins...............................................................................................................11
Polyester Resins for Hydroxyalkyl Amide Powder Coatings...................................................................12
Typical Properties for Hydroxyalkyl Amide Resins...................................................................................13
Hydroxyl Polyester Resins for Urethane Powder Coatings....................................................................14
Typical Properties for Hydroxyl Resins and Hardeners..........................................................................15
Resins for Low Temperature Cure Powders..............................................................................................16
Typical Properties for Low Temperature Cure Powder Coating Resins..............................................17
Masterbatches and Additives for Powder Coatings.................................................................................18
Typical Properties for Masterbatches and Additives...............................................................................19
FDA Status..........................................................................................................................................................20
Health, Safety and Product Handling..........................................................................................................21
Glossary of Terms.............................................................................................................................................22

Facts & Figures

• Global company with $2.2 bn in sales • 33 manufacturing facilities

• Broad Technology portfolio: liquid coating resins, energy • 23 research and technology centers
curable resins, powder coating resins, crosslinkers and • 5 joint ventures
additives, composites and construction materials • Extensive range of solutions for key coating segments:
• Approximately 4000 employees automotive, industrial, packaging coating and inks,
• Customers in more than 100 countries protective, industrial plastics and specialty architectural

With manufacturing, R&D and technical facilities located throughout Europe, North America, Asia Pacific and Latin America, allnex offers global
and reliable supply of resins and additives combined with local, responsive customer support.

allnex 3
 Introduction

One Source Global Supplier product family is the benchmark name among flow
allnex is a single-source, worldwide supplier of modifiers and powder resins in the coatings industry.
high-quality powder coating resins, hardeners, and
additives. We offer one of the broadest lines of top- Bringing value to the formulation of powder coatings
name polyester resins, coupled with global product are ADDITOL® masterbatch flow modifiers, catalysts
availability, and expert technical support. and related products. Additionally, BECKOPOX™ and
ADDITOL specialty hardeners solve problems related
Leading-edge Technologies to flow, and provide special textures or performance to
allnex continues to pioneer the development of finished coatings.
innovative technologies for a wide range of surfaces:

• Superdurable resins for exterior powder applications

• Resins for clearcoat and matte finishes
• Resins for low bake powder systems
• UV curing powder systems

Our newest resin technologies are designed for

cutting-edge applications where powder paints are
not widely used, including industrial and automotive
finishes:
Product index
• High-performance exterior durable systems
Product Description
• Natural and manufactured wood products
• Plastic and other heat-sensitive substrates Vehicle Binder Resins
CRYLCOAT® Polyester powder coating resins
– Hydroxyl (-OH) resins for polyurethane and glycoluril powder coatings
Wide Selection of Top Products – Carboxyl (-COOH) resins for hybrid, TGIC1, glycidylester2 and ß-HAA powder coatings3
As a leading global supplier of powder coating resins,
UVECOAT® Unsaturated resins for UV curable powder coatings.
hardeners and additives, allnex offers one of the
broadest choices of resins for powder coating finishes.
Curing Hardeners (Powder Crosslinkers)

Proven worldwide, our extensive selection of ADDITOL® Polyanhydride resin for epoxy functional (glycidyl) acrylics and urethane hardeners4 for hydroxy
functional binder resins.
CRYLCOAT® polyester resins include carboxyl
BECKOPOX™ Anhydride-like resin for epoxy or hydroxy functional binder resins.
and hydroxyl functional resins for hybrid, TGIC,
glycidylester, hydroxy alkyl amide, urethane, and
glycoluril powder coating systems. Powder Additives and Modifiers

MODAFLOW® Powder coating flow modifiers on silica carrier.

For new technologies like UV curable powder coatings,
Flow additives, catalysts and tribo masterbatches provided on resin carriers and photoinitiators to
we have one of the widest product ranges available, ADDITOL
accelerate the cure of UV powder coatings.
including UVECOAT® unsaturated resins. SYNTHACRYL® GMA-acrylic matting agent.

allnex’s powder coating resin technologies also include

1
Supplier: Huntsman
SYNTHACRYL® matting agents, specialty hardeners, 2
PT-910: Trademark of Huntsman
and additives which can be supplied on a silica or resin 3
Supplier: EMS-chemie, Evonik, and other suppliers
4
Supplier: Dow, Huntsman and other suppliers
carrier.

For improving flow and leveling characteristics in all

types of coatings, the versatile MODAFLOW® powder

4 allnex 5
 Product Nomenclature

Thermoset powder coatings are typically cured in a temperature range of 160-200˚C (object temperature) for The nomenclature of the allnex product line for powder coatings is provided in the table below.
10 minutes. General cure guidelines for products listed in this bulletin are summarized below.
Some of allnex’s newer products are referenced with an “E” designation. These resins have been recently
developed and have only been commercially available for a short time, and do not follow the product
Cure Temperature and Time Definitions
nomenclature system.
Slow 374°F (190°C) or greater for 10 min

Medium ~338 - 356°F (170 - 180°C) for 10 min

Fast ~ 320°F (160°C) for 10 min Digit 1 Digit 2 Digit 3 & 4 Digit 5
Low Temp 302°F (150°C) for 10 - 30 min CRYLCOAT System - 5 Digit System
®

1 = Hybrid 5 = 50/50 Whenever possible equivalent to - 0 = Standard (no additives)

Low temperature cure is used for heat sensitive substrates or thick metallic objects. allnex has products that can 6 = 60/40 last two digits of former product - 1 = Tribo
achieve the desired results through thermoset or UV cure. 7 = 70/30 name - 2 = Overbake
8 = 80/20 - 3 = Tribo & Overbake
- 4 = Clearcoat
2 = Standard Outdoor 4 = TGIC - 5 = Special
The resin selection guide allows formulators to select resins for a given coating effect. The color background
4 = Superdurable Outdoor 5 = PT-910 - 6 = Low bake (< 160°C)
used for each product in the charts helps to delineate special product features, as summarized in the table
8 = Crystalline 6 = Hydroxyalkyl Amide
below. From the wide range of resins available, users can match the desired properties with the required coating
9 = Other 8 = Urethane
performance. 9 = Wrinkle Finish

Resin Selection Guide

CRYLCOAT® polyester resins

CRYLCOAT new generation hybrid polyester resins Masterbatch Type Number

CRYLCOAT polyester resin pair for one-shot matte finishes ADDITOL® System
CRYLCOAT polyester resin pair for matte dry blend finishes Flow Aid P 800 - P 899
CRYLCOAT polyester resins for clearcoats Tribo, Catalysts, Crosslinkers P 900 - P 999

UVECOAT unsaturated resins

®

 DDITOL® masterbatch and additives

A
MODAFLOW® powder flow modifiers
SYNTHACRYL® acrylic resins

Type Number

UVECOAT® System

General Purpose Resins 1000 - 1999

Resins for Metal Substrates 2000 - 2999

Resins for Wood and Plastic Substrates 3000 - 3999

Special (i.e., crystalline) 9000 - 9999

Type Number

SYNTHACRYL® System

Acrylic - All p 700 - p 799

6 allnex 7
 Polyester Resins for Hybrid Powder Coatings Typical Properties for Hybrid Resins

50/50 55/45 to 60/40 70/30 to 80/20 CRYLCOAT® Ratio Acid # Visc.a Tg(Cº) Cure Benefit Flow Chemical Overbake Economics
Acid # ~70 Acid # ~50-60 Acid # ~20-35
200°C 1506-0 50/50 71 8000 62 160ºC Good overbake o ++ + -
CRYLCOAT® 1544-4 CRYLCOAT 1660-0 CRYLCOAT 1702-0
392°F 1510-0 50/50 71 8500b 58 180ºC High loading possible o + - o
CRYLCOAT 1622-0 CRYLCOAT 1783-0
180°C 1514-2 50/50 71 9250b 55 180ºC Excellent overbake + o ++ --
CRYLCOAT 1510-0 CRYLCOAT 1650-2 CRYLCOAT E04143
356°F 1540-0 50/50 71 8700b 58 160ºC Good pigment wetting o + -- o
CRYLCOAT 1514-2 CRYLCOAT 1671-0 CRYLCOAT 1770-0
1544-4 50/50 70 2500 54 200ºC Blend resin + + o +
CRYLCOAT 1557-5 CRYLCOAT 1658-5 CRYLCOAT 1771-0
1557-5 50/50 71 2000 50 170ºC Scratch resistance - + o -
CRYLCOAT 1573-0 CRYLCOAT 1620-0 CRYLCOAT 1725-0
1573-0 50/50 70 3500 56 180ºC Economical formulation o o - ++
CRYLCOAT 1626-0 CRYLCOAT 1781-0
1593-0 50/50 70 3500 54 160ºC Economical formulation - + - ++
CRYLCOAT 1627-0 CRYLCOAT 1721-0
170°C 1620-0 55/45 60 2650 54 170ºC - o o +
338°F 1622-0 55/45 60 2500 54 200ºC + o o +
160°C CRYLCOAT 1540-0 CRYLCOAT 1750-0
320°F 1626-0 60/40 48 3000 52 180ºC Workhorse resin ++ o -- ++
CRYLCOAT 1593-0 CRYLCOAT 1701-0
1627-0 60/40 44 4000 62 180ºC High Tg + o -- ++
CRYLCOAT 1506-0
1650-2 60/40 50 4200 57 200ºC + - o -
150°C
CRYLCOAT 1680-6 1658-5 60/40 53 2500 57 170ºC Scratch resistance - + o -
302°F
≤140°C 1660-0 60/40 48 9400b 50 200ºC High loading possible ++ o o -
CRYLCOAT 1574-6
≤284°F
1671-0 60/40 48 11200b 50 180ºC Outstanding gloss ++ o -- -

1680-6 60/40 48 10500 b

50 150ºC -- o - --

1701-0 70/30 36 6300 62 170ºC Overbake resistance o - + o

CRYLCOAT polyester resins
CRYLCOAT new generation hybrid polyester resins 1702-0 70/30 36 5300 62 200ºC + - + o

1721-0 70/30 40 5000 55 180ºC - - o +

1725-0 70/30 30 6400 55 180ºC TMA free o o o -

1750-0 70/30 34 4750 54 160ºC Non-blooming - - -- +

1770-0 70/30 34 5400 58 180ºC Economical formulation o - - ++

1771-0 70/30 33 4700 56 180ºC o - - ++

1781-0 70/30 33 5000 60 180ºC High Tg - - o ++

1783-0 70/30 34 5000 58 200ºC o - o +

E04143 80/20 22 10000b 57 200ºC Good balance of properties o -- -- ++

1574-6 50/50 71 5000 50 140ºC Low cure for MDF -- + o o

++ Outstanding + Excellent o Good – Fair – – Poor

a
Viscosity at 200ºC unless otherwise specified
b
Viscosity at 175ºC
** For a detailed description of FDA Status, please refer to page 20

CRYLCOAT polyester resins

CRYLCOAT new generation hybrid polyester resins

8 allnex 9
 Polyester Resins for TGIC Powder Coatings Typical Properties for TGIC Resins

93/7 95/5 90/10 CRYLCOAT® Ratio Acid # Visc.a Tg(Cº) Cure Benefit Flow Weathering Overbake Economics
Superdurable
Acid # ~33 Acid # ~25 Acid # ~50
200°C 2401-2 93/7 33 3500 60 200ºC Flexibility ++ o + o
CRYLCOAT® 2437-0 CRYLCOAT 2695-0 CRYLCOAT 2414-0 CRYLCOAT 4430-0
392°F 2408-0 93/7 33 4500 55 180ºC o o ++ o
CRYLCOAT 2401-2 CRYLCOAT 2432-0 CRYLCOAT 4432-4
2409-0 93/7 33 3900 58 160ºC TMA-free o - o -
CRYLCOAT 2471-4 CRYLCOAT 4659-0
Dry blend semi-matte finish w/
CRYLCOAT 2689-0 CRYLCOAT 4488-0 2414-0 90/10 47 4700 57 200ºC - - - -
2432-0. Gloss from 25-35

CRYLCOAT 2441-2 CRYLCOAT 4420-0 2421-5 93/7 33 4500 63 180ºC For PCM Applications o o ++ --

CRYLCOAT 2488-2 2425-0 93/7 34 6200 70 200ºC + - + ++

CRYLCOAT 2425-0 2430-0 93/7 30 9800 69 200ºC - o + o

CRYLCOAT 2430-0 Dry blend semi-matte finish w/

2432-0 96/4 20 7900 53 200ºC -- o + -
2414-0. Gloss from 25-35
CRYLCOAT 2440-2
2433-2 93/7 33 3000 60 160ºC o o + -
180°C CRYLCOAT 2408-0 2437-0 93/7 33 3200 62 200ºC Non-blooming ++ o + --
356°F
CRYLCOAT 2421-5 2440-2 93/7 33 5100 67 200ºC Workhorse o o + o
CRYLCOAT 2450-2 2441-2 93/7 33 5000 67 200ºC Workhorse + o + o
160°C CRYLCOAT 2409-0 2450-2 93/7 33 5000 67 180ºC o - ++ o
320°F
CRYLCOAT 2494-6 2471-4 93/7 33 3500 58 200ºC Smoothness ++ o + o
CRYLCOAT 2473-4 2473-4 93/7 33 3200 63 160ºC Clarity - o + o
CRYLCOAT 2433-2 2488-2 93/7 34 6000 64 200ºC Suitable for matting o o + ++

2494-6 93/7 33 2800 58 160ºC Non-blooming - - o o

2689-0 93/7 34 4000 62 200ºC Also used with HAA o -- o +

CRYLCOAT polyester resins
2695-0 95/5 25 5500 59 200ºC Also used with HAA + -- o +
CRYLCOAT polyester resin pair for matte dry blend finishes
CRYLCOAT polyester resins for clearcoats Dry blend semi-matte finish w/
4420-0 90/10 51 5500 64 200ºC - ++ o --
4430-0. Gloss from 25 -35
4430-0 93/7 35 2000 62 200ºC Superdurable ++ ++ o -

4432-4 93/7 35 2300 62 200ºC Superdurable ++ ++ o --

4488-0 93/7 30 5400 64 200ºC Best Florida data - ++ ++ -

4659-0 93/7 33 3600 59 200ºC Flexibility ++ + o +

++ Outstanding + Excellent o Good – Fair – – Poor

** For a detailed description of FDA Status, please refer to page 20

CRYLCOAT polyester resins

CRYLCOAT polyester resin pair for matte dry blend finishes
CRYLCOAT polyester resins for clearcoats

10 allnex 11
 Polyester Resins for Hydroxyalkyl Amide Powder Coatings Typical Properties for Hydroxyalkyl Amide Resins

96.5/3.5 95/5 92/8 90/10 CRYLCOAT® Ratio Acid # Visc.a Tg(Cº) Cure Benefit Flow Weathering Overbake Economics
Superdurable
Acid # ~25 Acid # ~33 Acid # ~50 Acid # ~70
2617-3 95/5 33 3500 61 180ºC TMA free + o + o
CRYLCOAT® 2695-0 CRYLCOAT 2618-3 CRYLCOAT 2671-3 CRYLCOAT 2621-2 CRYLCOAT 4688-2
2618-3 95/5 35 3100 61 180ºC Gas oven stabilized ++ + + o
CRYLCOAT 2691-2 CRYLCOAT 2617-3 CRYLCOAT 2620-2 CRYLCOAT 2650-3 CRYLCOAT 4642·3
180°C 2620-2 92/8 50 4200 58 180ºC Semi-gloss dry blend o o o -
CRYLCOAT 2689-0 CRYLCOAT 2655-6 CRYLCOAT 2626-2 CRYLCOAT 4659·0
2621-2 90/10 72 4000 62 200ºC Matte dry blend o o o --
CRYLCOAT 2682-1 CRYLCOAT 4626·0
200°F 2622-2 96/4 21 5300 61 200ºC Semi-gloss dry blend + o o -
CRYLCOAT 2670-3 CRYLCOAT 4641·0
2626-2 90/10 71 9600 55 200ºC -- o - --
CRYLCOAT 2698-3 CRYLCOAT 4420·0
2650-3 90/10 70 6200 51 200ºC For very low gloss o o - --
allnex also offers one shot matte powder coatings for hydroxyalkyl amide crosslinkers.
2655-6 93/7 47 5800 58 160ºC Low cure options o o o --

HAA HAA 2670-3 97/3 20 6000 64 200ºC Semi-matte dry blend + + o o

Standard Superdurables
2671-3 93/7 47 4000 62 180ºC Semi-matte dry blend o + - -

Dry Blend Gloss Control Systems 2682-1 95/5 34 6000 64 200ºC o - o o

Semi-Gloss CRYLCOAT
 2622-2 2689-0 95/5 34 4000 62 180ºC Workhorse + - o +
Acid #21
2691-2 97/3 21 7600 62 200ºC Matte dry blend + - + ++
C
 RYLCOAT 2620-2
Acid #50 2695-0 96.5/3.5 25 5500 59 180ºC Workhorse o -- o ++
Gloss 30 - 40 2698-3 95/5 33 3500 56 180ºC High flow ++ o + -
C
 RYLCOAT 2670-3 CRYLCOAT 2650-3 CRYLCOAT 4641-0 4420-0 92/8 51 5500 64 200ºC Matte dry blend superdurable o ++ -- --
Acid #20 Acid #70 Acid #20
C
 RYLCOAT 2671-3 CRYLCOAT 2670-3 CRYLCOAT 4420-0 4626-0 92/8 50 4300b 64 180ºC Storage stability + ++ -- --
Semi-Matte
Acid #47 Acid #20 Acid #51 4641-0 97/3 20 4200 60 200ºC Matte dry blend superdurable + ++ o o
Gloss 32 - 36 Gloss 25 - 35 Gloss 25 - 35
4642-3 95/5 35 1900 62 180ºC ++ ++ - -
C
 RYLCOAT 2691-2
Acid #21 4659-0 95/5 33 3600 59 190ºC + ++ - +

Matte C
 RYLCOAT 2621-2 4688-2 95/5 30 5500 54 180ºC Flexible superdurable ++ ++ - --
Acid #72
Gloss 20 - 30
++ Outstanding + Excellent o Good – Fair – – Poor
a
Viscosity at 200ºC unless otherwise specified
b
Viscosity at 175ºC
CRYLCOAT polyester resins ** For a detailed description of FDA Status, please refer to page 20
CRYLCOAT polyester resin pair for matte dry blend finishes

CRYLCOAT Acid # OH # Visc.a Tg(Cº) Description

One-Shot Gloss Control System

2611-0 25 3 5500 58
Polyester-HAA durable system that achieves a gloss range from 8-12%.
2687-2 90 5 3500 58
2635-2 85 5 3000 57
Polyester-HAA durable system that achieves a gloss range from 25-40%.
2638-2 33 1 5500 62
4693-2 90 5 3500 58
Polyester-HAA superdurable system that achieves a gloss range from 8-12%.
4651-0 21 1 4000 59
4629-0 30 2 3500 57
Polyester-HAA superdurable system that achieves a gloss range from 25-40%.
4645-2 90 5 2000 55

CRYLCOAT polyester resins

CRYLCOAT polyester resin pair for matte dry blend finishes

12 allnex 13
 Hydroxil Polyester Resins for Urethane Powder Coatings Typical Properties for Hydroxyl Resins and Hardeners

OH # 30-40 OH # ~50 OH # 80-100 OH # >200 Superdurable CRYLCOAT® OH # Visc.a Tg(Cº) Cure Benefit Flow Weathering Overbake Economics

CRYLCOAT® 2890-0 CRYLCOAT 2883-0 CRYLCOAT 2818-0 CRYLCOAT E04176 CRYLCOAT 4890-0 2818-0 100 3200 58 200ºC Chemcial resistance -- o + --

CRYLCOAT 2845-0 CRYLCOAT 2839-0 CRYLCOAT 4874-0 2839-0 50 5500 57 200ºC Workhorse - - - +

CRYLCOAT 2872-0 CRYLCOAT 2860 CRYLCOAT E04290 2845-0 35 7100 57 200ºC Workhorse - - - ++

2872-0 40 3700 55 200ºC Chemical resistance o o o +

2883-0 47 4000 61 200ºC Excellent hardness + o + -

Urethane Standard Urethane Superdurable 2890-0 30 6700 60 200ºC Workhorse + o + o

2920-0 33 12700 67 200ºC Wrinkle -- o o -

One Shot Gloss Control Systems
4890-0 30 5000 58 200ºC ++ ++ + ++
 RYLCOAT E04176
C CRYLCOAT 4874-0
OH #290 OH #290 2860-0 50 3500 52 200ºC One shot matte o o o -

 RYLCOAT 2860-0
C CRYLCOAT E04290 E04176 290 4500 58 200ºC One shot matte -- o o --
OH #50 OH #30
E04290 30 5500 56 200ºC One shot matte w/ 4874-0 ++ ++ 0 --
Gloss from 8 - 30 Gloss from 8 - 30
4874-0 290 3000 52 200ºC Anti-graffiti -- ++ -- --

ADDITOL® OH # NCO % Tg(Cº) Benefit Flow Weathering Overbake Economics

Wrinkle System NCO Hardeners
P
 920 42 N/A 58 Wrinkle -- o o o

Specialty Hydroxyl Polyester Resins and Hardeners P

 932 N/A 9-10 62 Canada only + o o -

CRYLCOAT 2920-0 ADDITOL P 932 P

 965 N/A 16-17 62 Aromatic urethane - -- + -

ADDITOL® P 920 ADDITOL P 965

BECKOPOX™ EH 694 BECKOPOX™ Acid # MP(Cº) Cure Benefit Flow Weathering Overbake Economics
ANHYDRIDE HARDENER
E
 H 694 31 50-60 N/A Chemical resistance o o – o

CRYLCOAT polyester resins

CRYLCOAT polyester resin pair for one-shot matte finishes ++ Outstanding + Excellent o Good – Fair – – Poor
ADDITOL masterbatch and additives a
Viscosity at 200ºC
MODAFLOW® powder flow modifiers ** For a detailed description of FDA Status, please refer to page 20.
SYNTHACRYL® acrylic resins
CRYLCOAT polyester resins
CRYLCOAT polyester resin pair for one-shot matte finishes
A
 DDITOL masterbatch and additives
MODAFLOW® powder flow modifiers
SYNTHACRYL® acrylic resins

14 allnex 15
 Resins for Low Temperature Cure Powder Coatings Typical Properties for Low Temperature Cure Powder Coating Resins

allnex is dedicated to finding new applications for This portfolio represents low temperature cure Product Viscosity (temp.) Tg(Cº) Product use
powder coating resins. Since many materials are offerings across three product lines: CRYLCOAT®
sensitive to heat, standard thermoset powder coatings polyester resins for thermoset powder coatings, Thermal Cure
cannot be used. allnex has products that can be UVECOAT® resins for UV powder coatings, and ADDITOL® P963 3400 (200ºC) N/A Catalyst for use in pigmented hybrid and TGIC coatings.
used in low temperature thermoset coatings as well ADDITOL® catalyst masterbatches that can lower the
ADDITOL P964 3200 (200ºC) N/A Catalyst for use in pigmented hybrid and TGIC coatings.
as UV powder coatings. These technologies offer the cure time and temperature of thermoset powder
following advantages compared to standard thermoset coatings. ADDITOL P966 1900 (200ºC) N/A Catalyst for use in superdurable pigmented TGIC coatings.

coatings: CRYLCOAT® 1680-6 10500 (175ºC) 50 60/40 hybrid resin that can cure down to 150ºC.

CRYLCOAT 2409-0 3900 (200ºC) N/A Smoothest TGIC resin for cure at 160ºC and lower.
• Cost savings during application by using less energy
CRYLCOAT 2494-6 2800 (200ºC) 60 Non-blooming TGIC resin for cure at 160ºC and lower.
• The most environmentally friendly coatings on the
CRYLCOAT 2473-4 3200 (200ºC) 49 160ºC TGIC resin for use in clear powder coatings.
market
• Expanding the reach of powder into temperature CRYLCOAT 2433-2 3000 (200ºC) 57 Workhorse resin that can cure at 160ºC.

sensitive substrates such as wood, plastic, and paper CRYLCOAT 1574-6 5000 (200ºC) 50 50/50 hybrid that can cure as low as 120ºC.

UV Cure

UVECOAT® 2100 5500 (200ºC) 57 Exterior durable UV powder resin for use in clear and pigmented coatings.

UVECOAT 2200 4500 (200ºC) 54 Superdurable UV powder resin that can achieve 1000+ hours corrosion resistance.
Metal MDF/Wood PVC Toner For MDF and wood substrates. Can be used for clear and pigmented systems. Excellent
Additives UVECOAT 3002 4500 (175ºC) 49
Applications Applications Applications Applications chemical resistance and improved UV resistance.
CRYLCOAT 1680-6 CRYLCOAT 1574-6 UVECOAT 3003 UVECOAT T37621 ADDITOL P 964 UVECOAT 3003 3200 (175ºC) 49 Improved chemical and abrasion resistance with good flexibility for indoor PVC applications.
CRYLCOAT 2409-0 UVECOAT 3002 ADDITOL P 963 UVECOAT 3005 4000 (200ºC) 48 General purpose grade for MDF and wood applications. Good chemical resistance.
CRYLCOAT 2494-6 UVECOAT 3005 ADDITOL P 966 UVECOAT 9010 350 (100ºC) 85 Semi-crystalline unsaturated additive to improve smoothness and flexibility.
CRYLCOAT 2473-4 UVECOAT 9010 UVECOAT 9539 4000 (200ºC) 44 For use with Uvecoat 2100 to provide excellent adhesion to various metal substrates.
CRYLCOAT 2433-2 UVECOAT 9539 UVECOAT T37621 5200 (200ºC) 51 Unsaturated resin that combines high reactivity and high Tg for toners.
UVECOAT 2100

UVECOAT 2200
CRYLCOAT polyester resins
CRYLCOAT polyester resins for clearcoats
UVECOAT unsaturated resins
CRYLCOAT polyester resins
A
 DDITOL masterbatch and additives
CRYLCOAT polyester resins for clearcoats
MODAFLOW® powder flow modifiers
UVECOAT unsaturated resins
SYNTHACRYL® acrylic resins
ADDITOL masterbatch and additives
MODAFLOW® powder flow modifiers
SYNTHACRYL® acrylic resins

16 allnex 17
 Masterbatches and Additives for Powder Coatings Typical Properties for Masterbatches and Additives

Catalysts Flow Promoters Flow Aids Tribo ADDITOL® Acid/OH # Visc.a Tg (Cº) % Active Used for Flow Catalyst Tribo Acrylic
MODAFLOW ®
P 791 Acid #317 N/A N/A N/A Coatings with Synthacryl 716
ADDITOL® P 964 ADDITOL P 896 ADDITOL P 950
POWDER III
P 810 OH #30 4500 N/A 5 Clear coatings
MODAFLOW
ADDITOL P 963 ADDITOL P 824
POWDER 6000 P 820 Acid #34 3000 60 10 Pigmented coatings
ADDITOL P 966 ADDITOL P 820 P 824 OH #45 1400 49 15 Pigmented coatings
ADDITOL P 891 P 891 Acid #35 2300 56 5 Clear coatings
ADDITOL P 810 P 896 OH #35 1700 57 15 Durable coatings

P 950 OH #28 8000 N/A 5 All coatings

P 963 Acid #33 3400 N/A 5 Hybrid and TGIC systems

Acrylic Hardener P 964 Acid #33 3200 N/A 5 Hybrid and TGIC systems

ADDITOL P 791 P 966 Acid #35 1900 N/A 5 Superdurable coatings

B
 ECKOPOX™ EH 694
ANHYDRIDE HARDENER
S
 YNTHACRYL® 700
MATTING AGENT Volatile
MODAFLOW® Activity % Density (g/cm2) Description
loss %

ADDITOL masterbatch and additives

Powder III Min. 65 Max. 4 0.58 - 0.64 Addition of 0.6-1.5% of the total formulation. FDA listed monomers.
MODAFLOW powder flow modifiers Powder Addition of 0.6-1.5% of the total formulation. Excellent flow and gloss.
SYNTHACRYL acrylic resins Min. 65 Max. 4 0.58 - 0.64
6000 Lessens cross-contamination issues.

SYNTHACRYL® Epoxy EEW Visc.a Tg (Cº) Description

700 714 40000 80 Glycidyl poly acrylic for use as a matting hardener. Only available in Latin America.

BECKOPOX™ Acid # MP(Cº) Cure Benefit Flow Weathering Overbake Economics

EH 694 31 50-60 N/A Chemical resistance o o – o

++ Outstanding + Excellent o Good – Fair – – Poor

a
Viscosity at 200ºC

A
 DDITOL masterbatch and additives
MODAFLOW powder flow modifiers
SYNTHACRYL acrylic resins

18 allnex 19
 FDA Status Health, Safety and Product Handling

Regarding the use of allnex polyester resins and This provision holds true if the coatings are not used in Toxicity
additives in FDA applications: contact with alcoholic foods and beverages and these CRYLCOAT® polyester products are solid, non-flamma-
coatings meet applicable end tests identified in 21 ble resins with minimal toxicity. MODAFLOW® products
The allnex Product Stewardship and Regulatory Affairs Code of Federal Regulations (CFR) § 175.300 (c). Other have been subjected to acute toxicity and mutageni-
department can provide a certification letter verifying provisions may apply. For full compliance statement, city studies. Details on specific coverage of individual
which CRYLCOAT® resins may be used in contact with please contact us at PSRA-Customer-requests@allnex. studies are available upon request.
food. The certificate for CRYLCOAT resins is limited com. The following table lists CRYLCOAT resins that
for applications to articles used in repeated-use may be used in the type of repeated-use applications Resin containers may contain polymer dust that could
applications such as: kitchen appliances, refrigerator described here in full compliance with the Federal be irritating. Prevent dusty conditions and avoid
shelving, commercial food processing equipment, Food, Drug, and Cosmetic Act and all applicable breathing dust. Also, avoid contact with eyes and
potable water tanks and food-preparation surfaces. regulations regarding food contact coatings, including prolonged or repeated contact with skin. Use only with
21 CFR § 175.300 (“Resinous and polymeric coatings”). adequate ventilation. Equipment should be ground
to prevent electrical sparking. For more information
on each product, please consult the current material
safety data sheet (MSDS) which will be provided by
allnex. Take into account the potential risk resulting
50/50 Hybrids 60/40 Hybrids 70/30 Hybrids TGIC Resins HAA Resins OH Resins
in formulation with other materials such as catalysts,
CRYLCOAT Polyester Resins that Qualify under 21 CFR 175.300
hardeners, pigments, and fillers.

1510-0 1620-0 1701-0 2414-0 2620-2 2818-0

Storage
1514-2 1622-0 1702-0 2425-0 2621-2 2839-0 CRYLCOAT, UVECOAT®, SYNTHACRYL®, and ADDITOL®
1540-0 1626-0 1721-0 2432-0 2689-0 2883-0 resins should be stored in a dry location at room
1544-4 1627-0 1750-0 2437-0 2691-2 2890-0 temperature. Keep away from heat sources and direct
sunlight. Do not stack more than two pallets high.
1573-0 1660-0 1770-0 2440-2 2689-0 2920-0
MODAFLOW powder products should not be stored
1671-0 1771-0 2441-2 2695-0 4890-0
in environments of high heat or humidity. The ideal
1783-0 2450-2 4659-0 storage temperature is between 40˚F (4˚C) and 100˚F
2471-4 (38˚C). Keep away from sparks and flame.
2494-6
Shelf Stability
4430-0
CRYLCOAT, UVECOAT, SYNTHACRYL, and ADDITOL res-
4488-0
ins have a minimum shelf life of one year when stored
in a dry location at room temperature. The shelf life of
MODAFLOW powder products is typically at least four
allnex Powder Coating Additives that Qualify For CFR Title 21 years, when stored in the recommended environment.

MODAFLOW® and ADDITOL® powder products may Product 175.105 175.300 177.1010 Packaging Information
be used in certain indirect food applications. These CRYLCOAT, UVECOAT, SYNTHACRYL, and ADDITOL
MODAFLOW
applications are regulated by the U.S. Food and Drug Yes Yes Yes
Powder III resins are typically provided in 25 kg (55.1 lb) polyethy-
Administration (FDA), under Title 21 of the Code of MODAFLOW lene bags. Supersack containers of 500 or 1,000 kg are
Yes Yes Yes
Regulations, CFR sections listed here: Powder 6000
available upon request. MODAFLOW powder products
Not Not
ADDITOL P 896
determined
Yes
determined
are typically provided in 150 lb (68 kg) fiber drums.
Upon special request, 1,000 lb (454 kg) polypropylene
bulk bags are available.

20 allnex 21
 Glossary of Terms

Key Word Description

The amount of KOH, reported in mg, necessary to neutralize the acid functional groups in 1 gram of
Acid Value
polyester.
A hazy appearance on the surface of the coating brought on by migration of low molecular weight
Blooming
material during low temperature cure or extended exposure to heat.
Curing Temperature The metal or object temperature required to fully cure the powder coating system in 10 minutes.
Standard outdoor exposure test to approximate the natural weathering performance of a coating
Florida Exposure
under severe conditions. The test panels are exposed in south Florida.
The characteristic temperature in °C of an amorphous polymer corresponding to the change from a
Glass Transition Temperature (Tg)
solid to liquid state as measured by DSC.
Gloss Degree to which a surface reflects light.

Hydroxyl Value The amount of KOH, reported in mg, equivalent to the hydroxyl content of 1 gram of polyester.

Hardener Powder coating raw material that reacts with polyester resin to create cured coating.
A coating surface that inconsistently reflects light to the eye. This causes coating to have non-glossy
Matte
appearance.
Overbake Resistance Ability of powder coating to withstand high or extended heating with minimal change.

Polyester: Hardener Ratio Weight ratio between the polyester resin and the hardener recommended for optimal properties.

Semi Crystalline Amorphous resins with crystalline functionality to allow for coatings with better flow.
The ability of powder coatings to maintain uniform powder flow properties after being subjected to a
Storage Stability
specified storage condition.
A polyester resin that exhibits extended outdoor weathering characteristics, typically maintaining
Superdurable
>50% gloss after 5 years.
The melt viscosity of the polymer, measured with a Brookfield5 viscometer in mPa.s at a specified
Viscosity
temperature.
The ability of a raw material to incorporate into the finished powder coating during processing. Can
Wetting
also refer to the ability of the coating to flow out the substrate.
Wrinkle A unique, special effect finish characterized by closely associated ridge-like structures.

Disclaimer: Allnex Belgium SA/NV including its affiliates (“allnex”) decline any liability with respect to any use of the information contained
herein (“Information”). This Information represents allnex's best knowledge without constituting any express or implied guarantee or warranty
including the accuracy, the completeness or relevance of the Information. Nothing contained herein shall be construed as conferring any
license or right under any patent or other intellectual property of allnex or of any third party. No guarantee or warranty is provided that the
product or Information is adapted for any specific use, performance or result and that product or Information does not infringe any allnex or
third party intellectual property rights. The user should perform its own tests to determine suitability for a particular purpose and remains
solely responsible for any use of a product or the Information. Notice: Trademarks indicated with ®, ™ or * as well as the allnex name and logo
are registered, unregistered or pending trademarks of Allnex IP S.à r.l. or its directly or indirectly affiliated companies.

© 2017 allnex Group. All Rights Reserved.

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