SDS Ni (OH) 2 Gredium Material Co., Ltd. - New

Gredium
GREDIUM MATERIAL CO., LTD.

MATERIAL SAFETY DATA SHEET
NICKEL HYDROXIDE 1/5
1. Product and Company Identification

Trade Name: Nickel Ore
Chemical Name: Nickel Hydroxide
Molecular Weight: 92.7
Chemical Formula: Ni(OH)2,
Manufacturer: Gredium Material Co., Ltd.
Emergency Call: 886-2-27193456
Address: 9F, 170 Sec 3 Min Chuan E. Road, Taipei 105
2. Hazards Identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Acute toxicity, Inhalation (Category 4), H332
Skin irritation (Category 2), H315
Germ cell mutagenicity (Category 2), H341
Carcinogenicity, Inhalation (Category 1A), H350i
Reproductive toxicity (Category 1B), H360
Skin sensitisation (Category 1), H317
Respiratory sensitisation (Category 1), H334
Specific target organ toxicity - repeated exposure (Category 1), H372
GHS label elements

Labelling according Regulation (EC) No 1272/2008
Signal word : Danger
Hazard statement(s)
H302:- Harmful if swallowed.
H315:- Causes skin irritation.
H317:- May cause an allergic skin reaction.
H332:- Harmful if inhaled.
H334:- May cause allergy or asthma symptoms or breathing difficulties
if inhaled.
Gredium MATERIAL SAFETY DATA SHEET
H341:- Suspected of causing genetic defects.

H350i:- May cause cancer by inhalation.
H360:- May damage fertility or the unborn child.
H372:- Causes damage to organs through prolonged or repeated
exposure.
Precautionary statement(s)
P201:- Obtain special instructions before use.
P261:- Avoid breathing dust/fumes/gas/mist/vapours/spray.
P273:- Avoid release to the environment.
P280:- Wear protective gloves/protective clothing/eye protection/face
protection.
P308 + P313:- If exposed: Call a POISON CENTER or doctor/
physician. P501:- Dispose of contents/container to an approved waste
disposal plant.
3. Composition/Information on Ingredients
CAS No. Component %

12054-48-7 Nickel hydroxide 75-80
Water 20-25
4. First Aid Measures
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower
and upper eyelids occasionally. Get medical attention immediately.
Skin Contact:
Wipe off excess material from skin then immediately flush skin with plenty of
water. Remove contaminated clothing and shoes. Get medical attention, if
necessary. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give
anything by mouth to an unconscious person. Get medical attention.
5. Fire Fighting Measures
Fire:
Contact with strong oxidizers may cause fire.
Explosion:
Gredium MATERIAL SAFETY DATA SHEET
Not considered to be an explosion hazard.

Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full-face piece operated in the pressure
demand or other positive pressure mode.
6. Accidental Release Measures
Ventilate area of leak or spill. Wear appropriate personal protective equipment as

specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal.
Vacuuming or wet sweeping may be used to avoid dust dispersal.
7. Handling and Storage
Handling:
Wash hands before eating and do not eat, drink, or smoke in workplace. Isolate
from incompatible substances. Containers of this material may be hazardous
when empty since they retain product residues (dust, solids); observe all warnings
and precautions listed for the product.
Storage:
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect
against physical damage.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:

Component ACGIH NIOSH OSHA-PEL
Nickel
As Ni: 0.1 mg/ m3 As Ni: 1 mg/ m3
hydroxide
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant at its
source, preventing dispersion of it into the general work area. Please refer to the
ACGIH document, Industrial Ventilation, A Manual of Recommended Practices,
most recent edition, for details.
Personal Respirators (NIOSH Approved):

If the exposure limit is exceeded, a half-face high efficiency dust/mist respirator
may be worn for up to ten times the exposure limit or the maximum use
concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. A full-face piece high efficiency dust/mist respirator may be
worn up to 50 times the exposure limit, or the maximum use concentration
specified by the appropriate regulatory agency or respirator supplier, whichever is
lowest. For emergencies or instances where the exposure levels are not known,
Gredium MATERIAL SAFETY DATA
SHEET NICKEL HYDROXIDE 4/5
use a full-face piece positive-pressure, air-supplied respirator. WARNING:

Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles and/or full-face shield where dusting or splashing of
solutions is possible. Maintain eye wash fountain and quick-drench facilities in
work area.
Industrial Hygiene:
Safety shower and eye bath should be provided. Do not eat, drink or smoke until
after-work showering and changing clothes.
9. Physical and Chemical Properties
Appearance: Greenish powder.

Odor: Odorless.
Boiling point: No information found.
Melting Point: No information found.
Flash point: Non-combustible, Non-sublimate solid
Relative vapor density: No information found (air=1).
Vapor pressure: No information found.
Evaporation Rate (BuAc=1): No information found.
Specific gravity: ~4
pH: No information found.
% Volatiles by volume @ 21°C (70°F): 0
Solubility: Insoluble in water.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.

Materials to avoid: Strong oxidizing agents.
Hazardous decomposition: decomposes to oxide at temperature above 250℃.
Hazardous polymerization: Will not occur.
Conditions to Avoid: Moisture and incompatibles.
11. Toxicological Information
Toxicity data (oral, rat):

Ni(OH)2: Oral Rat LD50: 1600 mg/kg.
Harmful if swallowed, inhaled or absorbed through the skin. Skin, eye and
respiratory irritant.
Carcinogen Status:
NTP: Anticipated Human Carcinogen; IARC: Human Sufficient Evidence, Animal
Sufficient Evidence, Group 1 (Nickel and nickel compounds); ACGIH:
A1-Confirmed Human Carcinogen insoluble compounds; EC: Category 1
12. Ecological Information

Environmental Fate: No information found.

Environmental Toxicity: No information found.
13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an
appropriate and approved waste disposal facility. Processing, use or contamination
of this product may change the waste management options. Dispose of container
and unused contents in accordance with state and local requirements.
14. Transport Information
IMO/IMDG Not Classified as Hazardous for Transport
ADR Not Classified as Hazardous for Transport
IATA Not Classified as Hazardous for Transport
CFR Not Classified as Hazardous for Transport
TDG Not Classified as Hazardous for Transport
15. Regulatory Information
Chemical Weapons Convention: No

TSCA 12(b): No
CDTA: No
SARA 311/312: No
Acute: Yes
Chronic: Yes
Fire: No
Pressure: No
Reactivity: No
16. Other Information
NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0

Label Data:
First Aid:
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
Storage & Handling:

Keep container tightly closed. Suitable for any general chemical storage area.
Avoid contact with eyes, skin and clothing.
Use with adequate ventilation and appropriate respirator, if necessary.
Spillage:
Wear suitable protective clothing. Carefully sweep up and remove.
Disclaimer:
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to such
information, and we assume no liability resulting from its use. Users should make
their own investigations to determine the suitability of the information for their
particular purposes. In no way shall Gredium Material Co., Ltd. be liable for any
claims, loses, or damages of any third party or for lost profits, damages, arising,
even if Gredium Material Co., Ltd. has been advised of the possibility of such
damages.
Effective Date: January 02, 2018

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Gredium

GREDIUM MATERIAL CO., LTD.

1. Product and Company Identification

GHS label elements

Signal word : Danger

H341:- Suspected of causing genetic defects.

CAS No. Component %

4. First Aid Measures

5. Fire Fighting Measures

Not considered to be an explosion hazard.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as

7. Handling and Storage

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:

Personal Respirators (NIOSH Approved):

use a full-face piece positive-pressure, air-supplied respirator. WARNING:

9. Physical and Chemical Properties

Appearance: Greenish powder.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.

11. Toxicological Information

Toxicity data (oral, rat):

12. Ecological Information

Environmental Fate: No information found.

13. Disposal Considerations

14. Transport Information

IMO/IMDG Not Classified as Hazardous for Transport

ADR Not Classified as Hazardous for Transport

IATA Not Classified as Hazardous for Transport

CFR Not Classified as Hazardous for Transport

TDG Not Classified as Hazardous for Transport

15. Regulatory Information

Chemical Weapons Convention: No

16. Other Information

NFPA Ratings: Health: 2 Flammability: 0 Reactivity: 0

Storage & Handling:

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