Ceran XM 220 - MSDS

SAFETY DATA SHEET
Conforms to Regulation (EC) No. 1907/2006 (REACH)
CERAN XM 220
SDS # : 080100
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : CERAN XM 220
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Formulation additives, lubricants and greases - Industrial
General use of lubricants and greases in vehicles or machinery - Industrial
General use of lubricants and greases in vehicles or machinery - Professional
Use of lubricants and greases in open systems - Industrial
Use of lubricants and greases in open systems - Professional
Lubricating grease
TOTAL
1.3 Details of the supplier of the safety data sheet
TotalEnergies Lubrifiants
562 Avenue du Parc de L'ile
92029 Nanterre Cedex FRANCE
Tél: +33 (0)1 41 35 40 00
Fax: +33 (0)1 41 35 84 71
[email protected]
Contact
H.S.E
1.4 Emergency telephone number

National advisory body/Poison Center
Telephone number : France - ORFILA (INRS) Tél : +33 (0)1 45 42 59 59
In France - Poison centers:
ANGERS : 02 41 48 21 21
BORDEAUX : 05 56 96 40 80
LILLE : 08 00 59 59 59
LYON : 04 72 11 69 11
MARSEILLE : 04 91 75 25 25
NANCY : 03 83 22 50 50
PARIS : 01 40 05 48 48
STRASBOURG : 03 88 37 37 37
TOULOUSE : 05 61 77 74 47
Supplier
Telephone number : Emergency phone: +44 1235 239670
Date of revision : Version : 2.01 France ENGLISH 1/32

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SDS # : 080100
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Eye Irrit. 2, H319
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
Ingredients of unknown : 1.8 percent of the mixture consists of component(s) of unknown acute inhalation
toxicity toxicity
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.
2.2 Label elements

Hazard pictograms :
Signal word : Warning

Hazard statements : H319 - Causes serious eye irritation.
Precautionary statements
Prevention : P280 - Wear eye/face protection.
Response : P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 - If eye irritation persists: Get medical advice/attention.
Storage : Not applicable.
Disposal : Not applicable.
Supplemental label : Contains Benzenesulfonic acid, C10-16-alkyl derivs., calcium salts, Benzenesulfonic
elements acid, mono-C16-24-alkyl derivs., calcium salts and Sulfonic acids, petroleum,
calcium salts. May produce an allergic reaction.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
NO (for visibility)
2.3 Other hazards
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
Other hazards which do : Prolonged or repeated contact may dry skin and cause irritation.
not result in classification
SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture

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SDS # : 080100
Product/ingredient name Identifiers % Regulation (EC) No. Type

1272/2008 [CLP]
Benzenesulfonic acid, REACH #: ≤10 Skin Sens. 1B, H317 [1]
C10-16-alkyl derivs., calcium salts 01-2119492627-25
EC: 271-529-4
CAS: 68584-23-6
Benzenesulfonic acid, mono- REACH #: ≤3 Skin Sens. 1B, H317 [1]
C16-24-alkyl derivs., calcium salts 01-2119492616-28
EC: 274-263-7
CAS: 70024-69-0
Sulfonic acids, petroleum, calcium REACH #: ≤3 Skin Sens. 1, H317 [1]
salts 01-2119488992-18
EC: 263-093-9
CAS: 61789-86-4
Benzenesulfonic acid, REACH #: ≤2.9 Skin Irrit. 2, H315 [1]
C10-13-alkyl derivs., Ca Salt 01-2119560592-37 Eye Dam. 1, H318
EC: 932-231-6 Aquatic Chronic 3,
H412
See Section 16 for
the full text of the H
statements declared
above.
Additional information : Mineral oil of petroleum origin Product containing mineral oil with less than 3%
DMSO extract as measured by IP 346
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.
[GHS EU]_Detergent product :

Indicator
SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser.
Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Wash clothing before reuse. Clean shoes thoroughly before reuse.

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Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air
and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : No specific data.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media
5.2 Special hazards arising from the substance or mixture

Hazards from the : No specific fire or explosion hazard.
substance or mixture
Hazardous combustion : carbon dioxide
products carbon monoxide
metal oxide/oxides
5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training.

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Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
precautions drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).
6.3 Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Avoid dust generation. Using a vacuum with
HEPA filter will reduce dust dispersal. Place spilled material in a designated,
labeled waste container. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do
not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. Dispose of via a licensed waste disposal
contractor.
6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not
in use. Empty containers retain product residue and can be hazardous. Do not
reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

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7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
Reportable hazardous constituent(s) contained in UVCB and/or multi-constituent substance(s) complying
with the classification criteria and/or with an exposure limit (OEL)
No exposure limit value known.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to monitoring standards, such as
the following: European Standard EN 689 (Workplace atmospheres - Guidance for
the assessment of exposure by inhalation to chemical agents for comparison with
limit values and measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for the assessment
of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures
for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be
required.
Advisory OEL : Mineral oil mist: USA: OSHA (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3,
STEL 10 mg/m3, ACGIH (TLV) TWA 5 mg/m3 (highly refined)
DNELs/DMELs
Product/substance Type Exposure Value Population Effects
Benzenesulfonic acid, C10-16-alkyl DNEL Long term Oral 0.833 mg/ General Systemic
derivs., calcium salts kg bw/day population
DNEL Long term Dermal 1.667 mg/ General Systemic
kg bw/day population
DNEL Long term Dermal 3.33 mg/ Workers Systemic
kg bw/day
DNEL Long term 11.75 mg/ Workers Systemic
Inhalation m³
DNEL Long term 2.9 mg/m³ General Systemic
Inhalation population
DNEL Long term Dermal 1.03 mg/ Workers Local
cm²
DNEL Long term Dermal 0.513 mg/ General Local
cm² population
Benzenesulfonic acid, mono- DNEL Long term Oral 0.8333 mg/ General Systemic
C16-24-alkyl derivs., calcium salts kg bw/day population
kg bw/day
Inhalation m³

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cm²
cm² population
Sulfonic acids, petroleum, calcium DNEL Long term Oral 0.8333 mg/ General Systemic
salts kg bw/day population
kg bw/day
Inhalation m³
cm²
cm² population
Benzenesulfonic acid, C10-13-alkyl DNEL Long term Dermal 1.7 mg/kg Workers Systemic
derivs., Ca Salt bw/day
DNEL Long term Dermal 85 mg/kg General Systemic
bw/day population
PNECs
Product/ingredient name Compartment Detail Name Method Detail
Benzenesulfonic acid, C10-16-alkyl derivs., Fresh water 1 mg/l -
calcium salts
Marine water 1 mg/l -
Fresh water sediment 723500000 mg/ -
kg dwt
Marine water sediment 723500000 mg/ -
kg dwt
Soil 868700000 mg/ -
kg dwt
Sewage Treatment 100 mg/l -
Plant
Benzenesulfonic acid, mono-C16-24-alkyl Fresh water 1 mg/l -
derivs., calcium salts
kg dwt
kg dwt
Soil 868700000 mg/ -
kg dwt
Plant
Sulfonic acids, petroleum, calcium salts Fresh water 1 mg/l -
kg dwt
kg dwt
Soil 271000000 mg/ -
kg wwt
Plant
8.2 Exposure controls

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Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Hydrocarbon-proof gloves
nitrile rubber
Fluorinated rubber
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.
In case of prolonged contact with the product, it is recommended to wear gloves
complying with EN 420 and EN 374 standards, protecting at least for 480 minutes
and having a thickness of 0,38 mm at least. These values are indicative only. The
level of protection is provided by the material of the glove, its technical
characteristics, its resistance to the chemicals to be handled, the appropriateness
of its use and its replacement frequency
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use. Respirator with combination filter for vapor/particulate Type A/P1
Warning ! filters have a limited use duration The use of breathing apparatus must
comply strictly with the manufacturer's instructions and the regulations governing
their choices and uses None under normal use conditions
Environmental exposure : Emissions from ventilation or work process equipment should be checked to
controls ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

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SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Solid.
Color : Light brown.
Odor : Characteristic.
Odor threshold : Not available.
pH : Not applicable.
Melting point/freezing point : Not available.
Initial boiling point and : Not available.
boiling range
Flash point : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Upper/lower flammability or : Not available.
explosive limits
Vapor pressure : Not available.
Vapor pressure 37.8°C (100°F) : Not available.
Vapor density : Not available.
Relative density : 0.9
Solubility(ies) : Insoluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): Not applicable.
Explosive properties : Not available.
Oxidizing properties : Not applicable
9.2 Other information
SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : The product is stable.
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : No specific data.
10.5 Incompatible materials : Strong oxidizing agents
10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

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SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Not available.
Product/substance Result Species Dose Exposure Test
Benzenesulfonic acid, LC50 Inhalation Dusts Rat - Male, >1.9 mg/l 4 hours EPA OPP
C10-16-alkyl derivs., and mists Female 81-3 Acute
calcium salts Inhalation
Toxicity
LD50 Dermal Rabbit - >4000 mg/kg - OECD
Male, Female
LD50 Oral Rat - Male, >5000 mg/kg - OECD 401
Female Read across
Benzenesulfonic acid, mono- LC50 Inhalation Dusts Rat - Male, >1.9 mg/l 4 hours EPA OPP
C16-24-alkyl derivs., and mists Female 81-3 Acute
calcium salts Inhalation
Toxicity
Read across
LD50 Dermal Rabbit - >5000 mg/kg - OECD 402
Male, Female
LD50 Oral Rat - Male, >5000 mg/kg - OECD 401
Female
Sulfonic acids, petroleum, LC50 Inhalation Dusts Rat - Male >1.9 mg/l 4 hours EPA OPP
calcium salts and mists 81-3 Acute
Inhalation
Toxicity
LD50 Dermal Rabbit - >4000 mg/kg - -
Male, Female
LD50 Oral Rat - Male >16000 mg/ - Section 772 .
kg 112-21 CFR
40
Benzenesulfonic acid, LD50 Dermal Rat - Male, >2000 mg/kg - OECD 402
C10-13-alkyl derivs., Ca Salt Female
LD50 Oral Rat - Female 4445 mg/kg - -
Conclusion/Summary : Based on available data, the classification criteria are not met.
Acute toxicity estimates
Product/substance Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
Benzenesulfonic acid, C10-13-alkyl derivs., Ca Salt 4445 N/A N/A N/A N/A
Irritation/Corrosion Not available. Not available. Not available.
Product/substance Result Species Score Exposure Test
Benzenesulfonic acid, Skin - Edema Rabbit 0.3 4 hours EPA OPPTS
C10-16-alkyl derivs., 870.2500
calcium salts Acute Dermal
Irritation
Skin - Primary dermal irritation Rabbit 0.5 4 hours OECD
index (PDII)
Eyes - Cornea opacity Rabbit 0 - EPA
Benzenesulfonic acid, Skin - Erythema/Eschar Rabbit 2.7 4 hours OECD 404
C10-13-alkyl derivs., Ca Salt
Eyes - Irritant Rabbit 1 - OECD 405
Conclusion/Summary

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Skin : Based on available data, the classification criteria are not met.
Eyes : Based on available data, the classification criteria are met.
Respiratory : Based on available data, the classification criteria are not met.
Sensitization Not available. Not available.
Product/substance Route of Species Result
exposure
Benzenesulfonic acid, skin Human Sensitizing
C10-16-alkyl derivs.,
calcium salts
Benzenesulfonic acid, mono- skin Mouse Sensitizing
calcium salts
Sulfonic acids, petroleum, skin Guinea pig Sensitizing
calcium salts
Benzenesulfonic acid, skin Guinea pig Not sensitizing
C10-13-alkyl derivs., Ca Salt
Conclusion/Summary :
Skin : The supplier of one or more of the components contained within this formulation has
indicated that he has data on the components and/or similar mixtures, which
confirms that at the concentration used, classification is not required
Respiratory : Based on available data, the classification criteria are not met.
Mutagenicity Not available.
Product/substance Test Experiment Result
Benzenesulfonic acid, OECD 471 Experiment: In vitro Negative
C10-16-alkyl derivs., Subject: Bacteria
calcium salts
OECD 471 Experiment: In vitro Negative
Subject: Bacteria
OECD 476 Experiment: In vitro Negative
Subject: Mammalian-Animal
OECD 474 Experiment: In vivo Negative
Cell: Somatic
- Experiment: In vivo Negative
Carcinogenicity Not available.
Reproductive toxicity Not available.
Product/substance Maternal Fertility Development Species Dose Exposure
toxicity toxin
Benzenesulfonic acid, Negative Negative Negative Rat - Male, Female Oral -
calcium salts
Teratogenicity Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)

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Not available.
Aspiration hazard
Not available.
Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Defatting to the skin. May cause skin dryness and irritation.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
dryness
cracking
Ingestion : No specific data.
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Product/substance Result Species Dose Exposure
Benzenesulfonic acid, Sub-acute NOAEL Oral Rat - Male, 500 mg/kg -
C10-16-alkyl derivs., Female
calcium salts
Sub-acute NOAEL Dermal Rat - Male, >1000 mg/kg -
Female
Sub-acute NOAEL Inhalation Rat - Male, 50 mg/m³ 28 days
Vapor Female
Conclusion/Summary : Not available.
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.

Teratogenicity : No known significant effects or critical hazards.

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Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.
Other information : Not available.
SECTION 12: Ecological information

12.1 Toxicity
Product/substance Result Species Exposure Test
Benzenesulfonic acid, Acute EC50 >1000 mg/l Algae - 72 hours -
C10-16-alkyl derivs., calcium Pseudokirchneriella
salts subcapitata
Acute EC50 >1000 mg/l Daphnia - Daphnia magna 48 hours -
Benzenesulfonic acid, mono- Acute EC50 >1000 mg/l Algae - 72 hours -
C16-24-alkyl derivs., calcium Pseudokirchnerella
salts subcapitata
Acute EC50 >1000 mg/l Daphnia - Daphnia magna 48 hours -
Sulfonic acids, petroleum, Acute EC50 >1000 mg/l Algae - 72 hours -
calcium salts Pseudokirchnerella
subcapitata
Acute EC50 >1000 mg/l Daphnia - Daphnia magna 48 hours OECD 202
Benzenesulfonic acid, Acute EC50 29 mg/l Algae - 72 hours -
C10-13-alkyl derivs., Ca Salt Pseudokirchneriella
subcapitata
Acute EC50 2.9 mg/l Daphnia - Daphnia magna 48 hours OECD 202
Acute NOEC 0.5 mg/l Algae 96 hours -
Acute NOEC 0.23 mg/l Fish 72 hours -
Chronic NOEC 1.18 mg/l Daphnia - Daphnia magna 21 days -
12.2 Persistence and degradability

Conclusion/Summary : Not available.
Product/substance Aquatic half-life Photolysis Biodegradability
Benzenesulfonic acid, - - Not readily
calcium salts
Benzenesulfonic acid, mono- - - Not readily
calcium salts
Sulfonic acids, petroleum, - - Not readily
calcium salts
12.3 Bioaccumulative potential

Not available.
12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
Mobility in soil : Given its physical and chemical characteristics, the product has no soil mobility.
The product is insoluble and floats on water Loss by evaporation is limited
12.5 Results of PBT and vPvB assessment

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This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
12.6 Other adverse effects : No known significant effects or critical hazards.
SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction.
Hazardous waste : Yes.
According to the European Waste Catalogue, Waste Codes are not product specific,
but application specific Waste codes should be assigned by the user based on the
application for which the product was used The following Waste Codes are only
suggestions: 12 01 12*
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.
SECTION 14: Transport information

ADR/RID ADN IMDG ICAO/IATA
14.1 UN number Not regulated. Not regulated. Not regulated. Not regulated.
14.2 UN proper - - - -
shipping name
14.3 Transport - - - -
hazard class(es)
14.4 Packing - - - -
group
14.5 No. No. No. No.
Environmental
hazards
14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

2021/09/01
CERAN XM 220
SDS # : 080100
14.7 Transport in bulk : Not available.

according to Annex II of
MARPOL and the IBC Code
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Other EU regulations
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Air
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Water
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product is not controlled under the Seveso Directive.
National regulations
Social Security Code, : CERAN XM 220 RG 36
Articles L 461-1 to L 461-7
Reinforced medical : Act of July 11, 1977 determining the list of activities which require reinforced
surveillance medical surveillance: not applicable
Art. R. 4624-18 to 4624-19 of the labour code (Special medical surveillance).
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

2021/09/01
CERAN XM 220
SDS # : 080100
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)

Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : Not determined.
Canada : Not determined.
China : Not determined.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
New Zealand : Not determined.
Philippines : Not determined.
Republic of Korea : Not determined.
Taiwan : Not determined.
Thailand : Not determined.
Turkey : Not determined.
United States : Not determined.
Viet Nam : Not determined.
15.2 Chemical Safety : This product contains substances for which Chemical Safety Assessments are still
Assessment required.
SECTION 16: Other information

Indicates information that has changed from previously issued version.
Value : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Eye Irrit. 2, H319 Calculation method
Full text of abbreviated H statements

2021/09/01
CERAN XM 220
SDS # : 080100
H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Aquatic Chronic 3, H412 AQUATIC HAZARD (LONG-TERM) - Category 3
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Skin Sens. 1B, H317 SKIN SENSITIZATION - Category 1B
Additionnal details on the supplier of the product
TOTAL Réunion
3 rue Jacques Prévert
BP286 – 97827 LE PORT
tél : +262 (0) 262 55 20 20
fax : +262 (0) 262 55 20 31
TOTAL Mayotte
Immeuble Jacaranda 1, Lotissement Les 3 vallées Majicavo Lamir
BP 867 kawéni
97600 MAMOUDZOU
tél : +262 (0) 269 60 12 94
fax : +262 (0) 269 60 17 30
TOTAL Caraïbes
ZI. Californie
97232 Le Lamentin
Martinique France
Tel : +596 596 504 957
Date of revision : 9/1/2021
Date of previous revision : 3/26/2021
Version : 2.01
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may
present unknown hazards and should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards that exist.

2021/09/01
Annex to the extended Safety Data Sheet (eSDS)
Industrial
Identification of the substance or mixture
Code : 080100
Section 1 - Title
Short title of the exposure : Formulation additives, lubricants and greases - Industrial
scenario
List of use descriptors : Identified use name: Formulation additives, lubricants and greases - Industrial
Process Category: PROC01, PROC02, PROC03, PROC04, PROC05, PROC08a,
PROC08b, PROC09, PROC15
Sector of end use: SU03, SU10
Subsequent service life relevant for that use: No.
Environmental Release Category: ERC02
Environmental :
contributing scenarios
Health Contributing : General measures applicable to all activities
scenarios General exposures Use in contained systems Elevated temperature - PROC02
Mixing operations Closed systems Batch processes at elevated temperatures -
PROC03
Mixing operations Open systems Batch processes at elevated temperatures -
PROC04, PROC05
Mixing operations (open systems) - PROC04, PROC05
Process sampling - PROC04, PROC08b
Bulk transfers Dedicated facility - PROC08b
Drum/batch transfers Dedicated facility - PROC08b
Drum/batch transfers Non-dedicated facility - PROC08a
Equipment cleaning and maintenance - PROC08a, PROC08b
Drum and small package filling - PROC09
Laboratory activities - PROC15
Storage - PROC01, PROC02
Processes and activities : Industrial formulation of lubricant additives, lubricants and greases. Includes material
covered by the exposure transfers, mixing, large and small scale packing, sampling, maintenance.
scenario
Section 2 - Exposure controls

Contributing scenario controlling environmental exposure for 1:
No exposure scenario required
Contributing scenario controlling worker exposure for 2: General measures applicable to all activities
Concentration of : Covers percentage substance in the product up to 100 %. (unless stated differently)
substance in mixture or
article
Physical state : Liquid, vapor pressure < 0.5 kPa at Standard Temperature and Pressure
Amounts used : Not applicable.
Frequency and duration of : Covers daily exposures up to 8 hours (unless stated differently)
use/exposure
Human factors not : Not applicable.
influenced by risk
management
Other conditions affecting : Covers percentage substance in the product up to 100% (unless stated differently)
workers exposure
Date of issue/Date of revision : 7/2/2020 18/32

CERAN XM 220 Formulation additives, lubricants and greases -
Industrial
Conditions and measures related to personal protection, hygiene and health evaluation
Advice on general : Avoid direct skin contact with product. Identify potential areas for indirect skin
occupational hygiene contact. Wear gloves (tested to EN 374) if hand contact with substance likely. Clean
up contamination/spills as soon as they occur. Wash off any skin contamination
immediately. Provide basic employee training to prevent/minimise exposures and to
report any skin problems that may develop. Avoid direct eye contact with product,
also via contamination on hands.
Personal protection : Use suitable eye protection.
Contributing scenario controlling worker exposure for 3: General exposures Use in contained systems
Elevated temperature
No other specific measures identified.
Contributing scenario controlling worker exposure for 4: Mixing operations Closed systems Batch processes
at elevated temperatures
Ventilation control : Provide extract ventilation to points where emissions occur.
measures
Contributing scenario controlling worker exposure for 5: Mixing operations Open systems Batch processes at
elevated temperatures
Frequency and duration of : Avoid carrying out activities involving exposure for more than 4 hours per day.
use/exposure
measures
Contributing scenario controlling worker exposure for 6: Mixing operations (open systems)
measures
Contributing scenario controlling worker exposure for 7: Process sampling

Frequency and duration of : Avoid carrying out activities involving exposure for more than 1 hour per day.
use/exposure
Personal protection : Wear chemical-resistant gloves (tested to EN374) in combination with specific
activity training.
Contributing scenario controlling worker exposure for 8: Bulk transfers Dedicated facility
use/exposure
Personal protection : Wear chemical-resistant gloves (tested to EN374) in combination with intensive
management supervision controls.
Contributing scenario controlling worker exposure for 9: Drum/batch transfers Dedicated facility
measures

Industrial
Contributing scenario controlling worker exposure for 10: Drum/batch transfers Non-dedicated facility
use/exposure
Ventilation control : Provide a good standard of general or controlled ventilation (10 to 15 air changes
measures per hour).
Contributing scenario controlling worker exposure for 11: Equipment cleaning and maintenance
Technical conditions and : Retain drain-downs in sealed storage pending disposal or for subsequent recycle.
measures to control
dispersion from source
towards the worker
Engineering controls : Drain down and flush system prior to equipment break-in or maintenance.
Advice on general : Clear spills immediately.
occupational hygiene
Contributing scenario controlling worker exposure for 12: Drum and small package filling
measures per hour).
activity training.
Contributing scenario controlling worker exposure for 13: Laboratory activities

use/exposure
Contributing scenario controlling worker exposure for 14: Storage

Engineering controls : Store substance within a closed system.
Section 3 - Exposure estimation and reference to its source

Website: : Not applicable.
Exposure estimation and reference to its source - Environment: 1:

Exposure assessment : Used ECETOC TRA model.
(environment):
Exposure estimation and : Not available.
reference to its source
Exposure estimation and reference to its source - Workers: 2:

Exposure assessment : The risk Management Mesures/Operational Conditions that are identified in the
(human): Exposure Scenario are the outcome of a quantitative and qualitative assessment
that covers this product.
Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES

Industrial
Environment : Guidance is based on assumed operating conditions which may not be applicable to
all sites; thus, scaling may be necessary to define appropriate site-specific risk
management measures. Further details on scaling and control technologies are
provided in SPERC factsheet. If scaling reveals a condition of unsafe use (i.e.,
RCRs > 1), additional RMMs or a site-specific chemical safety assessment is
required. For further information see www.atiel.org/reach/introduction.
Health : Where other risk management measures/operational conditions are adopted, then
users should ensure that risks are managed to at least equivalent levels. For further
information see www.atiel.org/reach/introduction.
Additional good practice advice beyond the REACH CSA

Environment : Not available.
Health : Not available.

Industrial
Code : 080100
Section 1 - Title
Short title of the exposure : General use of lubricants and greases in vehicles or machinery - Industrial
scenario
List of use descriptors : Identified use name: General use of lubricants and greases in vehicles or
machinery - Industrial
Process Category: PROC01, PROC02, PROC08b, PROC09
Sector of end use: SU03
Environmental Release Category: ERC04, ERC07
Environmental :
scenarios General exposures (closed systems) - PROC01
Initial factory fill of equipment Use in contained systems - PROC02, PROC09
Initial factory fill of equipment Open systems - PROC08b
Operation of equipment containing engine oils and similar Use in contained
systems - PROC01
Equipment cleaning and maintenance - PROC08b
Equipment cleaning and maintenance Operation is carried out at elevated
temperature (> 20°C above ambient temperature) - PROC08b
Processes and activities : Covers general use of lubricants and greases in vehiculs or machinery in closed
covered by the exposure systems. Includes filling and draining of containers and operation of enclosed
scenario machinery (including engines) and associated maintenance and storage activities.

Concentration of : Covers percentage substance in the product up to 100% (unless stated differently).
article
Physical state : Liquid, vapor pressure < 0.5 kPa at Standard Temperature and Pressure.
Frequency and duration of : Covers daily exposures up to 8 hours (unless stated differently).
use/exposure
Other conditions affecting : Assumes use at not more than 20°C above ambient temperature. unless stated
workers exposure differently.
Assumes a good basic standard of occupational hygiene has been implemented.

CERAN XM 220 General use of lubricants and greases in vehicles or
Contributing scenario controlling worker exposure for 3: General exposures (closed systems)
Contributing scenario controlling worker exposure for 4: Initial factory fill of equipment Use in contained
systems
Contributing scenario controlling worker exposure for 5: Initial factory fill of equipment Open systems
use/exposure
measures per hour)
Contributing scenario controlling worker exposure for 6: Operation of equipment containing engine oils and
similar Use in contained systems
measures at process level
(source) to prevent release
Engineering controls : Drain down system prior to equipment break-in or maintenance.
Ventilation control : Provide a good standard of general ventilation (not less than 3 to 5 air changes per
measures hour).
activity training.
Contributing scenario controlling worker exposure for 8: Equipment cleaning and maintenance Operation is
carried out at elevated temperature (> 20°C above ambient temperature)
measures to control
dispersion from source
towards the worker
Ventilation control : Provide extract ventilation to emission points when contact with warm (>50°C)
measures lubricant is likely.



(environment):



Professional
Code : 080100
Section 1 - Title
Short title of the exposure : General use of lubricants and greases in vehicles or machinery - Professional
scenario
List of use descriptors : Identified use name: General use of lubricants and greases in vehicles or
machinery - Professional
Process Category: PROC01, PROC02, PROC08a, PROC08b, PROC20
Environmental Release Category: ERC09a, ERC09b
Environmental :
scenarios Operation of equipment containing engine oils and similar Use in contained
systems - PROC01
Material transfers Non-dedicated facility - PROC08a
Equipment cleaning and maintenance Dedicated facility - PROC08b, PROC20
Processes and activities : Covers general use of lubricants and greases in vehiculs or machinery in closed
covered by the exposure systems. Includes filling and draining of containers and operation of enclosed
scenario machinery (including engines) and associated maintenance and storage activities.

article
use/exposure

machinery - Professional
Contributing scenario controlling worker exposure for 3: Operation of equipment containing engine oils and
similar Use in contained systems
Contributing scenario controlling worker exposure for 4: Material transfers Non-dedicated facility
use/exposure
activity training.
Contributing scenario controlling worker exposure for 5: Equipment cleaning and maintenance Dedicated
facility



(environment):



Industrial
Code : 080100
Section 1 - Title
Short title of the exposure : Use of lubricants and greases in open systems - Industrial
scenario
List of use descriptors : Identified use name: Use of lubricants and greases in open systems - Industrial
Process Category: PROC01, PROC02, PROC07, PROC08b, PROC09, PROC10,
PROC13
Environmental Release Category: ERC04
Environmental :
scenarios Material transfers Manual - PROC08b
Material transfers Automated process with (semi) closed systems - PROC08b,
PROC09
Roller, spreader, flow application - PROC10
Spraying - PROC07
Treatment of articles by dipping and pouring - PROC13
Equipment cleaning and maintenance - PROC08b
Processes and activities : Covers use of lubricants and greases in open systems, including application of
covered by the exposure lubricant to work pieces or equipment by dipping, brushing or spraying (without
scenario exposure to heat), e.g. mold releases, corrosion protection, slideways. Includes
associated product storage, material transfers, sampling and maintenance activities

article
use/exposure
report any skin problems that may develop. Other skin protection measures such as
impervious suits and face shields may be required during high dispersion activities
which are likely to lead to substantial aerosol release, e.g. spraying. Avoid direct eye
contact with product, also via contamination on hands.

CERAN XM 220 Use of lubricants and greases in open systems -
Industrial
Contributing scenario controlling worker exposure for 3: Material transfers Manual

use/exposure
Contributing scenario controlling worker exposure for 4: Material transfers Automated process with (semi)
closed systems
Ventilation control : Ensure material transfers are under containment or extract ventilation.
measures
Contributing scenario controlling worker exposure for 5: Roller, spreader, flow application
measures
Contributing scenario controlling worker exposure for 6: Spraying

Ventilation control : Carry out in a vented booth or extracted enclosure.
measures
activity training.
Contributing scenario controlling worker exposure for 7: Treatment of articles by dipping and pouring
measures per hour)
Ventilation control : Provide a good standard of general ventilation (not less than 3 to 5 air changes per
measures hour).
activity training.



(environment):

Industrial


Professional
Code : 080100
Section 1 - Title
Short title of the exposure : Use of lubricants and greases in open systems - Professional
scenario
List of use descriptors : Identified use name: Use of lubricants and greases in open systems - Professional
Process Category: PROC01, PROC02, PROC08a, PROC10, PROC11, PROC13
Environmental Release Category: ERC08a, ERC08d
Environmental :
scenarios Material transfers Manual - PROC08a
Roller, spreader, flow application - PROC10
Spraying - PROC11
Treatment of articles by dipping and pouring - PROC13
Equipment cleaning and maintenance - PROC08a
Processes and activities : Covers use of lubricants and greases in open systems, including application of
covered by the exposure lubricant to work pieces or equipment by dipping, brushing or spraying (without
scenario exposure to heat), e.g. mold releases, corrosion protection, slideways. Includes
associated product storage, material transfers, sampling and maintenance activities.

article
use/exposure
report any skin problems that may develop. Other skin protection measures such as
impervious suits and face shields may be required during high dispersion activities
which are likely to lead to substantial aerosol release, e.g. spraying. Avoid direct eye
contact with product, also via contamination on hands.

Professional
Contributing scenario controlling worker exposure for 3: Material transfers Manual
use/exposure
Contributing scenario controlling worker exposure for 4: Roller, spreader, flow application
use/exposure
Ventilation control : Provide a good standard of general or controlled ventilation (5 to 15 air changes per
measures hour) Natural ventilation is from doors, windows etc. Controlled ventilation means air
is supplied or removed by a powered fan.
activity training.
Contributing scenario controlling worker exposure for 5: Spraying

use/exposure
Personal protection : Wear suitable coveralls to prevent exposure to the skin. Wear chemical-resistant
gloves (tested to EN374) in combination with specific activity training.
Respiratory protection : Wear a respirator conforming to EN140 with type A/P2 filter or better.
Contributing scenario controlling worker exposure for 6: Treatment of articles by dipping and pouring
use/exposure



(environment):

Professional


Ceran XM 220 - MSDS

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SAFETY DATA SHEET

Conforms to Regulation (EC) No. 1907/2006 (REACH)

SECTION 1: Identification of the substance/mixture and of the company/

1.4 Emergency telephone number

Date of revision : Version : 2.01 France ENGLISH 1/32

SECTION 2: Hazards identification

2.2 Label elements

Signal word : Warning

SECTION 3: Composition/information on ingredients

Date of revision : Version : 2.01 France ENGLISH 2/32

Product/ingredient name Identifiers % Regulation (EC) No. Type

[GHS EU]_Detergent product :

SECTION 4: First aid measures

Date of revision : Version : 2.01 France ENGLISH 3/32

SECTION 5: Firefighting measures

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Date of revision : Version : 2.01 France ENGLISH 4/32

SECTION 6: Accidental release measures

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other : See Section 1 for emergency contact information.

SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities

Date of revision : Version : 2.01 France ENGLISH 5/32

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

Date of revision : Version : 2.01 France ENGLISH 6/32

DNEL Long term Dermal 1.03 mg/ Workers Local

8.2 Exposure controls

Date of revision : Version : 2.01 France ENGLISH 7/32

Date of revision : Version : 2.01 France ENGLISH 8/32

SECTION 9: Physical and chemical properties

9.2 Other information

SECTION 10: Stability and reactivity

10.2 Chemical stability : The product is stable.

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : Strong oxidizing agents

Date of revision : Version : 2.01 France ENGLISH 9/32

SECTION 11: Toxicological information

Date of revision : Version : 2.01 France ENGLISH 10/32

Date of revision : Version : 2.01 France ENGLISH 11/32

Information on the likely : Not available.

Symptoms related to the physical, chemical and toxicological characteristics

Mutagenicity : No known significant effects or critical hazards.

Date of revision : Version : 2.01 France ENGLISH 12/32

Developmental effects : No known significant effects or critical hazards.

Other information : Not available.

SECTION 12: Ecological information

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

Date of revision : Version : 2.01 France ENGLISH 13/32

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

SECTION 14: Transport information

Date of revision : Version : 2.01 France ENGLISH 14/32

14.7 Transport in bulk : Not available.

SECTION 15: Regulatory information