Bulk Viscosity
Bulk Viscosity
Bulk Viscosity
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Abstract - The work is focused on the study of bulk viscosity of liquids. The methodology is based on
non-equilibrium thermodynamics. Using its laws the irreversible stress tensor is derived and two
viscosities depending on the strain rate tensor deviator and spherical strain rate tensor are defined. By
analysis of pressure wave distribution, the bulk viscosity of water is determined.
Keywords: liquid, bulk viscosity, second viscosity, Onsager relations, Curie’s principle.
Nomenclature
F - surface force N
I. Current state of knowledge
Fp -external field force N
Fs - inertial force N The greatest progress in the second viscosity
research was reached in the forties of the last century,
V - volume m3 including works of Tisza [1] and later on Liebermann
liquids.
- macroscopic particles surface m 2 In the work of S. Karim and L. Rosenhead [4] are
c - i-th absolute velocity coordinate ms 1 determined the following values above mentioned ratio
i
/ by measuring the absorption of sound waves:
ij - stress tensor Pa water 2,4; chloroform 24; benzol 107.
- external field potential ms2 The values were measured at frequencies: water
5MHz, chloroform 2MHz, benzol 107MHz.
ij - irreversible stress tensor Pa A newer look at the 2nd viscosity is found in the
p - pressure Pa
works of L. D. Landau [5], but especially R. E. Graves
[6], A. S. Dukhin [7], M. J. Holmes [8], G. Emanuel
- density kgm3 [9].
n - unit normal vector to external surface 1
T - absolute temperature K II. Introduction
Q - heat amount J
S - entropy JK 1 By increasing of fluid machines parameters we
increasingly encounter with the unsteady flow and
- entropy production Jm3 s 1K 1 relatively high frequencies of the pressure and flow
pulsations.
i, j - indices In these cases the fluid must be considered
ij - Kronecker delta compressible and so the dampening effect of bulk
viscosity becomes important.
- dynamic viscosity Pas Using the first and second law of
- bulk viscosity Pas thermodynamics, the Gibbs equation and equilibrium
equations of macroscopic particles we determine the
- heat transfer coefficient Ns 1K 1 constitutive equation of a homogeneous and isotropic
liquid. We rely mainly on the so-called Onsager
Summation convection is used in the paper. relations [10], expressing the relationship between
irreversible thermodynamic flows and generalized
1
thermodynamic forces. The basis for the mentioned IV. The balance of kinetic and potential
equation will be the Curie’s principle [11]. energy sum
In this work we will use the Einstein summation
convention. By multiplying the macroscopic particle
momentum equation (1) by velocity vector, we get the
power of individual components, per unit volume.
III. Equilibrium equation and the Law Thus:
of Conservation of Mass
d
ci ci ij ci ci (5)
2 dt x j xi
and the reversible part - p ij associated with reversible Hence it is clear that on the surface , the
changes. Thus: irreversible stress tensor components perform useful
work.
ij ij ij p , (2) While the second term on the right hand side of
equation (6) can be written in the form:
p – static pressure.
ci c c
Let's consider the macroscopic particles according
to Fig. 1. The law of mass conservation is a conditional V
ij x j
dV ij i dV p i dV
V
x j V
xi
statement:
(8)
m const. from (3) The first term on the right hand side is the input
which should be added to cover energy losses. It
d specifies that part of the mechanical work, which has
divc 0 (4) been irreversibly transformed into heat.
dt
The second term is associated with elastic liquid
deformation due to compressibility and represents the
Equation (4) expresses the mass conservation law
reversible change. In the case of an incompressible
of macroscopic particles and presents the continuity
fluid, this expression is absent.
equation.
2
Now, let's deal with kinetic and potential energy
densities balance per unit volume. Establish its
evolution in time: VI. First law of thermodynamics
By using the momentum and continuity equations
we get: The first law of thermodynamics states that the
amount of heat delivered to the system from the
1 1
c j c j ci
environment is spent for energy E increase of that
c j c j system and mechanical work W performance. Then:
t 2 2 xi
ij dQ dE dW . (14)
ci ci .
x j xi
These so called global amounts should also be
(9) expressed through their respective densities. See (10).
Then:
After editing, it holds:
E e xi , t dV (15)
d 1 c
c j c j ij ci ij i V
dt 2 xi x j
dE de
dV
(10)
dt V dt
V. Equation of state, state of local
thermodynamic equilibrium e ec i dV (16)
V
t xi
State of thermodynamic equilibrium of some J E nd J Ei ni d
variable xi is determined by an equation of state,
3
S E sE dV
dQ J
J q nd J qini d qi dV V
dt xi dS E dS
V
E dV J SE nd
(20) dt V dt
J SEi
Considering now the definition of flows J E (16) dV
xi
J q (20) and J . By analogy with the first law of V
(26)
thermodynamics (14) we can write:
and Si , which characterizes the irreversible
J q J E J J qi J Ei J i (21)
processes inside the system caused by the generalized
thermodynamic forces.
Substituting (19) and (7) into (21), we get:
J ei eci ji ci J qi (22)
Si si dV
V
dSi ds
The energy density e is dependent on the internal i dV dV . (27)
energy u by the equation: dt V dt V
1
e u c j c j , (23) Function characterizes the correlation between
2 the irreversible thermodynamic flows J k and the
k
generalized thermodynamic forces X and is called
where the last two terms represent the sum of the
kinetic and potential energy densities. the entropy production density. It holds by 13]
Note that the internal energy u, heat flow J q and
JkXk (28)
flow J represented by stress tensor ij are yet
unknown. When we put together the final entropy from the
two components mentioned above, we obtain:
4
TdSi 0. (32) Substitute from (35)
du p ci J SEi
ij (37)
This fact will be important for the constitutive T dt T x j xi
relations analysis.
Hence from and from the expressions (27) and
(26), it can be derived: From (23) results:
de du d 1
c j c j .
ds J dt dt dt 2
SEi . (33)
dt xi
Substitute from (10):
de du 1
The entropy density s is given by the Gibbs
ijci 1 ij ci
equation. dt dt xi x j
(38)
.
VIII. Gibbs equation
Energy density change e is determined from (18).
From this implies:
Now let´s consider the state equation for entropy
density assuming local thermodynamic equilibrium:
de J
s s u, v . (34) Ei . (39)
dt xi
The entropy density is dependent on the internal
parameter, internal energy and the external parameter, Comparing (19) and (22) we get:
the specific volume v 1/ .
When we move in (34) to the total differential, we
J Ei J qi ji c j .
obtain:
So
s s J qi
ds
u
v v
du
u
dv ,
de
dt
xi xi
ij ci (40)
s 1 s p
; , After substitution of (40) into (38) we have:
u v T v u T
ds 1 du p dv
du c J qi
(35) ij i (41)
dt T dt T dt dt x j xi
By using the equation (4), it is possible to derive: Considering (2) and after substituting (41) into
(37) we get the equation for entropy production
density:
dv 1 ci
,
dt xi 1 c 1 T J
ij i 2 J qi J SEi qi
ds 1 du p ci T x j T xi xi T
ij (36)
dt T dt T x j (42)
5
where index k specifies the type of force,
ci eventually type of flow.
It is possible to resolve the term using the Since at the beginning we assumed an isotropic
x j and homogeneous environment, the relationship
deformation velocity tensor cij and angular velocity between flows and forces will follow the Curie’s
principle 11].
tensor ij : According to this principle thermodynamic forces
of a certain tensor size effect only flow of the same
ci 1 c c j tensor dimension. Then (49) takes the form:
cij ij ; cij i ;
x j 2 x j xi
J ijk X ijk J lm X lm J n X n (50)
1 c c
ij i j
2 x j xi where X ijk represents the 2nd order tensor force,
(45) X lm - vector X n - scalar.
In terms of further solution it is practical to When we compare (50) and (48) it holds:
distribute the stress tensor to the deviator Dij and
k 1
1
spherical tensor ij kk . 1
3 X ij1 dij J ij1 Dij
Analogically also the deformation velocity tensor
T
is distributed to the deviator d ij that represents the m 1
1 T (51)
1
ij ckk that X l1 J l1 J ql
particle shape change and spherical tensor
3 T 2 xl
represents its volume change. n 1
1 1
So X1 c jj J 1 ii
T 3
1 (46)
ij Dij ij kk The relationship between the generalized
3
thermodynamic forces and flows at the same point in
time is determined by the so-called Onsager relations
1 10, 11, 12] by which the dependence of the flow on
cij dij ij ckk , ckk div c (47)
3 the generalized thermodynamic forces in the sense of
Curie’s principle can be expressed by the generalized
Considering that the product of the symmetric and equation:
anti-symmetric tensor is zero, and also that the product
of the deviator and the Kronecker delta is zero, it is J k t Lku X u t (52)
possible write an expression for from (44) in the
form: ku
where L are the so called phenomenological
1 1 1 T
Dij dij ii c jj J qi 2 . coefficients of generalized thermodynamic force
T 3T T xi transfer and there hold the symmetry conditions for
(48) them Lku Luk . Their values are necessary to be set
experimentally. For our case it holds:
Non-equilibrium thermodynamics states that the
density of entropy production can be expressed L11
according to the generalized thermodynamic forces J ij1 L11
T X ij Dij
1 T
dij (53)
k T
X k and irreversible thermodynamic flows J by
equation (34)
1 1
J 1 L11S X 1 ii L11S c jj (54)
J X k k
(49)
3 T
6
1 T 2
J11 L11
V X 1 J ql LV
1 11
(55) (63)
T 2 xl 3
By indices T, S, V we differentiate the given value is called the second viscosity of liquids.
applicability to the tensor, scalar and vector flow. On this occasion it should be noted that in almost
Expression (53) defines the irreversible stress every hydrodynamics literature and also software
tensor deviator and coefficient packages the second viscosity is determined on the
certain basis [1] 14 for monatomic gas so that it
applies
L11T
2 (56) 1
p ii . (64)
T 3
states dynamic viscosity.
2
Expression (54) defines the scalar flow of an Here is based , which means that
average irreversible stress flow in the so called bulk 3
L11S 0. The above derivation shows that the
viscosity dependence . Expression (55) ku
T phenomenological coefficients L , see (52), do not
defines the known Fourier’s law of heat convection, depend on time. The experiments show that the
1 phenomena in nature are more complex. In a more
where L11
V is heat conduction coefficient. general approach the flow function of generalized
T2 thermodynamic forces need not be instantaneous, as is
Substituting the formulas (53), (54) and (55) to assumed in expression (52). If the flows deem on the
formula for entropy production entropy (48), we get: whole changes history of generalized thermodynamic
forces, then it can be assumed, see. (52), that
2 T T
dij dij cii ckk
t
Taking into account (27) and (32), it is clear that In mentioned meaning are changing the
it must hold: expressions (53), (54), then it holds:
dV 0.
t
(58) Dij 2 t dij d (66)
V
0
t
ii t cii d
Because according to the Curie’s principle the 1
(67)
individual flows are independent, must be applied [3]: 3 0
0; 0; 0 (59)
In special case of:
2
ij 2 cij ij ckk . (62) X. Experiment
3
The second viscosity was determined on the
where experimental basis using a modal analysis of the water
7
pressure pulsations in a tube of circular cross section
[15, 16].
Figure 2 shows the device where the pressure
pulsations in the pipe were caused by an ultrasonic
generator.
The experiment resulted in its frequency
dependence.
It is a hyperbolic dependence, so it is possible to
establish a second kinematic viscosity from the
following equation (70).
; f r 1000 Hz (70)
fr
while for water holds the second viscosity
coefficient =9800 m2.s2 .
The fact that the second viscosity depends on the
frequency, is essential. A mathematical model of
irreversible stress tensor, defined by equation (62), (63)
can only be used for solving forced vibration excited
by harmonic functions. It cannot be used for solving
transient fluid vibrations. To this end, it is necessary to
find a formula for the second viscosity in the time
domain, in the form of convolution integrals.
Fig.3: Ultrasonic generator of pressure pulsations in the
circular cross section pipe [20]
XI. Conclusion
Summing up the results so far, it is necessary to
state the following:
1. Based on the methods of non-equilibrium
thermodynamics there is evidence of bulk and therefore
the second viscosity.
2. Bulk viscosity varies depending on frequency,
see (70).
3. In technical practice is not usually a pure
liquid. Real liquids contain minerals, dissolved gases in
them, and so on. It is therefore necessary to seek
second viscosity formulation depending on the
concentration of these substances and pressure.
4. From the mentioned references, especially [7],
it is obvious that the second viscosity values were
researched just in the ultrasonic area. The introduced
paper diffuses the knowledge also into the subsonic
area. That allows the more precise simulation of the
pressure pulsations of the compressible liquid in the
technical applications.
Acknowledgement
Fig.2: Ultrasonic generator of pressure pulsations in the This work was gratefully acknowledged by grant
circular cross section pipe – sketch [20] projects: GA101/09/1716, P101/10/0209
8
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9
35 H. Soufi, D. Nehari, L Adjlout, O. Imine, A Two- Simona Fialová was born in Brno, Czech
Republic 16th November 1977.
dimensional Numerical Simulation of Oscillating 1996-2001 study at the Department of
Flow Using a Pseudo Spectral Method. The hydraulic machines, Brno University of
International of Review of Mechanical Technology, 2001-2004 postgraduate study,
Engineering (IREME), Vol. 1.n. 6, pp. 595 – 602, Department of Fluids Engineering, Brno
University of Technology, 2002 passed
2007. examination FCE, 2004 passed examination
36 N. Bekka, R. Bessaih, M. Sellam, Numerical CAE, 2005 graduate Ph.D.
Study of Transonic Flow Using Various Publication activities: 16 research reports, 25 articles, presentations
Turbulence Models. The International of Review at domestic and international conferences, 8 utility models, 2
research projects
of Mechanical Engineering (IREME), Vol. 2. n. 4,
pp. 599 – 607, 2008.
Authors’ information
1
František Pochylý, Czech Republic
2
Vladimír Habán, Czech Republic
3
Simona Fialová, Czech Republic
10