Scribd Logo
Upload

Welcome to Scribd!

  • 7 views

    Haloalkane and Haloarenes DPP 7

    Uploaded by

    Dharmvir Tanty

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Haloalkane and Haloarenes DPP 7

    Uploaded by

    Dharmvir Tanty
    7 views2 pages

    Original Title

    Haloalkane and Haloarenes Dpp 7

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    7 views2 pages

    Haloalkane and Haloarenes DPP 7

    Uploaded by

    Dharmvir Tanty

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    1

    GYANA VIKASH ACADEMY


    Haloalkanes and Haloarenes DPP-07

    Br 4. CH3–CH–CH2 CH3MgCl
    Cl Product
    Mg/THF
    1. P , Product P is: O
     Product is?
    MgBr (1) CH3–CH–CH2OH
    MgCl
    (1) (2) CH3
    (2) CH3–CH–CH2–CH3
    Br
    OH
    MgCl (3) CH3 –CH–CH2
    (3) (4) CH3
    (4) HO–CH2–CH2–CH2–CH2–OH
    Cl
    |
    t − BuO− 5. Elimination reaction generally occurs with the
    2. CH 3 − CH − CH − CH 3 ⎯⎯⎯⎯  →
    Major product is:
    formation of
    |
    CH 3 (1) One sigma bond
    (1) CH3 − C = CH − CH3 (2) one pi bond
    | (3) one sigma and one pi bond
    CH3 (4) None of the above
    (2) CH3 − CH − CH = CH 2
    | 6. Which of the following reaction is an elimination
    CH3 reaction?
    (3) CH 2 = C − CH 2 − CH3 (1) CH3 — CH2 — CH 2 — OH ⎯⎯⎯ PCl5
    →
    |
    CH3 CH3 — CH2 — CH2 — Cl
    OH CH3 — CH — CH3
    | (2) CH3 — CH = CH 2 ⎯⎯⎯
    HCl
    → |
    (4) CH 3 − CH − CH − CH 3 Cl
    | (3) CH3 — CH — CH 3 ⎯⎯⎯⎯
    Alc.KOH
    → CH3 — CH = CH2
    CH3 |
    Cl
    MgCl Cl CH3 — C — OCH3
    CH3 — C — OH ⎯⎯⎯⎯ →
    CH3OH
    (4) ||
    || O
    3. + P O
    7. The reaction:
    RX+2Na+RX ⎯⎯⎯⎯ Dry ether
    → R − R + 2NaX is called:
    (1) (2)
    (1) Sandmeyer's reaction
    (2) Fittig reaction
    (3) (4) (3) Wurtz reaction
    (4) Williamson's synthesis
    2

    8. The reaction given below is known as 10. C6H5COOH + CH3MgI → possible products
    C6H5I + 2Na + ICH3 → C6H5 − CH3 + 2NaI (1) C6H5COOMgI
    (2) CH4
    (1) Wurtz reaction
    (3) Both (1) and (2)
    (2) Fittig reaction (4) C6 H5 — C — CH3
    (3) Wurtz-Fittig reaction ||
    (4) Ullmann reaction O

    9. Major product of the reaction given below is 11. (CH3)3CMgCI on reaction with D2O, produces
    (1) (CH3)3CD (2) (CH3)3COD
    (3) (CD3)3CD (4) (CD3)3COD
    alc. KOH

    (1)

    (2)

    (3)

    (4)

    You might also like