CHEMISTRY-XI

1
CH#04 (P.S#01) BY:-SIR. HARESH KUMAR
1. Cation and Anion in a crystal are hold together by:
(a) Co-ordinate covalent bond (c) Polar covalent bond
(b) Vander wall’s bond (d) Electrostatic force
2. Strongest crystal lattice has:
(a) Ionic bonding (b) H-bonding (c) Covalent bonding (d) N.O.T
3. Which one of the following has ionic bonding:
(a) CaCl2 (b) BeCl2 (c) HCl (d) N.O.T
4. In the chemical combination of Na & H to form NaH:
(a) Sodium atom loss electron (c) H – atom gain electron
(b) H – atom loss electron (d) Both a & c
5. What type of bonding is present in NH4Cl:
(a) Dative (b) Ionic (c) Covalent (d) A.O.T
6. Which of the following is not correct?
(a) Triple bond has greater bond energy than double bond
(b) Sigma bond is stronger than pi bond
(c) Sigma bond has shorter bond length than triple bond
(d) Polar bond has greater bond energy than non – polar bond
7. In which molecule central atom is sp – hybridization
(a) BeCl2 (b) C2H2 (c) CO2 (d) A.O.T
8. Covalent compounds:
(a) Soluble in polar solvent (c) Good conductors of electricity
(b) High melting & boiling point (d) N.O.T
9. Which of the following compounds contain no covalent bond:
(a) PH3 (b) C6H6 (c) H2SO4 (d)KCl
10. Which of the following pair of molecule has no multiple bond:
(a) NH3, N2 (b) C6H6, CO (c) C3H8, CH4 (d) O2, N2
11. How many sigma and pi – bond are present in C2H2:
(a) 4𝜎,1𝜋 (b) 4𝜎,1𝜋 (c) 5𝜎,2𝜋 (d) 3𝜎,2𝜋
12. NCl3 is form but NCl5 is not form because:
(a) Greater size of Cl atom (b) Absence of d – orbital
(c) Smaller size of Cl atom (d) N.O.T
13. Which bond is strongest among the following:
(a) Ionic bond (b) Covalent bond (c) Dative bond (d) N.O.T
14. Co-ordinate covalent compounds are mostly:
(a) Polar (b) Non – polar (c) Ionic (d) N.O.T
15. Which of the following pairs don’t form a dative covalent bond to each other?
(a) NH3, H+ (b) H2O + H+ (c) NH3 + BF3 (d) CH4 + AlCl3
16. Which of the following properties associated with B.M.O:
(a) High energy (b) Low energy (c) Lower stability (d) N.O.T
17. Which one has greatest value of bond energy:
(a) HF (b) HCl (c)HBr (d) HI
18. Concept of Hybrid orbital was introduced by:
(a) Sigwick (b) Powel (c) Linus Pauling (d) Both a & b
19. In C – H bond, longest distance in:
(a) C2H2 (b) C2H6 (c) C4H8 (d) C2H4
20. this lewis dot symbol for which of the following atoms:
(a) Na (b) N (c) Mg (d) F
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CHEMISTRY-XI
1
CH#04 (P.S#01) BY:-SIR. HARESH KUMAR
21. V.S.E.p.R is used to predict:
(a) Direction of reaction (b) Molecular shape (c) Molecular size (d) N.O.T
22. In which of the following is the angle b/w the two covalent bond greatest:
(a) CH4 (b) CS2 (c) NH3 (d) H2O
23. Which of the following has highest dipole moment:
(a) HF (b) CHCl3 (c) NH3 (d) NH3
24. Hybridization in carbon atom of Ethylene is:
(a) sp (b) sp2 (c) sp3 (d) NOT
25. hydrogen bonding is maximum in:
(a) C2H5Cl (b) C2H5 – O – C2H5 (c) C2H5 – OH (d) H2O
26. 6 sigma bond and 1 pi bond are present in:
(a) CH4 (b) CH3NO2 (c) C2H4 (d) C2H6
27. Pi – bond is found in structure of:
(a) O2 (b) CH4 (c) NH3 (d) NOT
0
28. Which one of the following molecule has an angle of 104.5 ?
(a) NH3 (b) CH4 (c) BeCl2 (d) H2O
29. The maximum repulsion in:
(a) L.p – L.p electrons (b) B.p – B.p electrons (c) B.p – L.p electrons (d) Both a & c
30. The hybridization of SO2 is:
(a) sp2 (b)sp (c) sp3 (d) NOT
31. Which of the following liquid is miscible with H2O?
(a) CCl4 (b) CH4 (c) C2H6 (d) C2H5 – OH
32. Which of the following molecule does not have sp2 hybridization?
(a) CCl4 (b) C2H4 (c) BF3 (d) SO2
33. The E.N difference of pure bond is:
(a) Less than 1.7 (b) Greater than 1.7 (c) Zero (d) NOT
34. Energy is _____ when two atoms form a bond:
(a) Absorbed (b) Remains same (c) Released (d) Both a & b
35. Generally shorter bond length has _____ bond energy?
(a) Equal (b) Greater (c) Remain same (d) NOT
36. Which of the following has maximum overlapping:
(a) s – s (b) p – p (c) s – p (d) NOT
37. S.I unit of dipole momentum is:
(a) c.m (b) N.m (c) Kg.m (d) NOT
38. Which statement indicates the nature of bonding in CBr4 and NaCl?
(a) Ionic in both (c) Ionic in CBr4 and covalent in NaCl
(b) Covalent in both (d) NOT
39. Which of the following species has four pair of e–?
(a) F (b) O– (c) N (d) Cl–
40. Formation of NH4OH is an example of ___
(a) Covalent bond (b) Ionic bond (c) Co-ordinate covalent bond (d) A.O.T
41. Tetravalency of carbon is best explained by the concept of:
(a) Electron detocalization (b) Resonance
(c) Hybridization (d) VSEPR rule
42. Acc: to M.O.T what the bond order in the O2?
(a) 3 (b) 6 (c) 2 (d) 4

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CHEMISTRY-XI
1
CH#04 (P.S#01) BY:-SIR. HARESH KUMAR
43. The valence of Mg in ground state is:
(a) 2 (b) 0 (c) 1 (d) 3
44. Which molecules has triple covalent bond?
(a) O2 (b) H2 (c) PH3 (d) HCN
45. Shape of molecules is decided by _______
(a) Sigma bond (b) π –bond
(c) Both a & b (d) Neither 𝜎 - bond nor π bonds
o o
46. Bond angle in H2O is 104.5 and 109.28 because of _______
(a) L.p – L.p repulsion (b) B.p – B.p repulsion
(c) L.p – B.p repulsion (d) High E.N in oxygen
47. The compounds which do not consist of molecules are:
(a) Ionic compound (b) Co-ordinate compounds
(c) Covalent Compound (d) NOT
−𝟐
48. The structure of 𝑪𝒓𝑶𝟒 is:
(a) Tetrahedral (b) Octahedral (c) Cubic (d) Linear
+
49. The shape of H3O is:
(a) Tetrahedral (b) Angular (c) Trigonal planer (d) pyramidal
50. A hetrodiatomic molecule has dipole moment
(a) Less than zero (b) greater than zero (c) equal to zero (d) N.O.T
51. Carbon on acetylene contains _______ un hybrid orbitals:
(a) One (b) two (c) three (d) four
52. Acetylene molecules contains:
(a) 4 sigma, 1 pi (b) 5 sigma, 1 pi (c) 3 sigma, 2 pi (d) NOT
53. According to V.(B)T bonding electron is:
(a) Monocentric (b) polycentric (c)dicentric (d) NOT
54. Anti bonding molecular orbital have __ energy than that of parent atomic orbitals:
(a) Lower (b) higher (c) moderate (d) NOT
55. Which of the following bond is formed by physical interaction of positive pole of one molecule and
negative pole of other molecule:
(a) Hydrogen bond (b) co-ordinate covalent bond
(c) non polar (d) polar bond
56. CO2 and CS2 has no dipole moment due to:
(a) Linear structure (b) pyramidal structural (c) angular structure (d) both A & C
57. In multiple bonds combining atoms posses bond length:
(a) 1.340 (b) 1.200 (c) both A & B (d) NOT
58. Which of the following molecules has more bond energy:
(a) C2H2 (b) CH4 (c) C2H6 (d) C2H4
59. Which one of the following is ionic substance:
(a) CCl4 (b) CSF (c) HBr (d) C6H6
60. Bond energy is inversely proportional to:
(a) Ionic character (b) polarity (c) bond distance (d) AOT
61. Total number of electrons that part in forming bonds in N2 is:
(a) 2 (b) 3 (c) 6 (d) 10
62. Which of the following is a polar molecule?
(a) NH3 (b) CCl4 (c) C6H6 (d) C2H4
63. HCl involves
(a) s – s overlapping (b) s – p overlapping
(c) p – p overlapping (d) p𝜋 – p𝜋 overlapping
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CHEMISTRY-XI
1
CH#04 (P.S#01) BY:-SIR. HARESH KUMAR
64. In which compound carbon is Sp3 hybridized _______
(a) HCOOH (b) C3H6 (c) C2H4 (d) (CH3)3C–OH
65. The theory which states that electron pairs are arranged around the central atom of a molecule with
maximum separation is:
(a) VSEPR theory (b) V.B theory (c) M.O theory (d) NOT
66. Which of the following pairs have similar geometry?
(a) SO2,BeCl2 (b) NH3, PH3 (c) C2H4, C2H6 (d) NOT
67. How many covalent bonds are present in CO2 molecule?
(a) 4 (b) 2 (c) 1 (d) 0
68. Al becomes ISO electric with Ne By:
(a) Losing two electrons (b) By losing three electrons
(c) By gaining two electrons (d) By gaining three electrons
69. The central atom in the following compound is Sp3 hybridized:
(a) pH3 (b) H2SO4 (c) pOCl3 (d) A.O.T
70. Lattice energy of NaCl is – K.j/mole
(a) –348 (b) –495 (c) –788 (d) –475
71. Strongest H – bonding occur in:
(a) HI (b) HF (c)HCl (d)HBr
–
72. The spinning of e in single covalent bond is _______
(a) Unpaired (b) paired (c) Both a & b (d) N.O.T
73. Bond formed b/w two atoms of same element is:
(a) 100% pure covalent (b) Ionic (c) 50% covalent (d) N.O.T
74. The decreasing order of Ionic character in the Hx molecule is:
(a) HF >HCl>HBr> HI (b) HI >HBr>HCl> HF
(c) HCl> HI > HF >HBr (d) Hbr>HCl> HI > HF
75. The non polar compound is:
(a) H2O (b) CH3Cl (c) CO2 (d) N.O.T
76. Sp3 hybridization with two lone pairs in the central atom gives the shapes of molecule___
(a) Trigonal (b) pyramidal (c) Bentor angular (d) A.O.T
77. The octet rule is not valid for ______.
(a) CO2 (b) O2 (c) H2 (d) N2
78. The molecules which contain more no: of Pi–bonds:
(a) O2 (b) Cl2 (c) HCl (d) N2
79. The angle is minimum between:
(a) Sp3 (b) H2O molecule (c) Px and Py orbital (d) A.O.T
80. The bond energy For H – H is 436K.J/mole. The amount of energy released when 6.02 × 1022 atoms of
H combine to form H2 molecule is:
(a) 43.6K.J/mole (b) 28.6K.J/mole (c) 21.8K.J/mole (d) N.O.T

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