Cambridge Carbon Cam202029
Cambridge Carbon Cam202029
Cambridge Carbon Cam202029
CAM202029
Cambridge Carbon Capture Ltd, Allia Future Business Centre, Kings Hedges Road, Cambridge. CB4 2HY.
TABLE OF CONTENTS
Cambridge Carbon Capture’s Patented CO2LOC technology greatly accelerates this natural
process by first digesting these abundant Magnesium Silicate minerals. The CO2LOC
process has been developed to selectively capture CO2, NOx and SOx from industrial
emissions and converts them to commercially useful Magnesium Carbonate minerals. These
gases exist in relatively high concentrations in the industrial emissions and this drives the
reactions in the process. However, CO2 in air is at a very low concentration and as a result
the driving ‘pressure’ is low resulting in very slow reactions. In this project the CO2LOC
process has been adapted to capture CO2 directly from air.
The digestion is not restricted to any one mineral. Talc has been chosen, but every
Magnesium Silicate mineral studied so far has been digested by our process.
DISPOSAL OF WASTE
The philosophy behind the CO2LOC process is that all the by-products of the process have
value and are sold into existing or future markets generating revenues, the 50kt plant will
therefore have no waste outputs. One of the purposes of the Pilot plant is to help develop
local markets for the by-products by providing materials for trials with future customers for
the by-products for the 50kt plant.
The CO2 that is captured is locked away as Magnesium Carbonate and it is planned that this
will be used as a construction material when at a commercial stage. CCC is working with
Holcim, Saint Gobain, CRH and others to develop construction materials using our captured
CO2 and the plan with the pilot project is to provide the magnesium carbonate produced to
these partners to enable them to develop and test materials. The Magnesium Carbonate
produced is therefore removed from site free of charge by our construction materials
development partners.
The pilot project will support the development of construction materials with partners so that,
by the time the 50kt plant is being commissioned, there will be a local market demand for the
magnesium carbonate produced, this market being of a sufficient size to take all the material
produced at the site and at a gate price which helps support the venture as a going concern
without the need for further UK Government support.
Another by-product will be the silica. At the pilot stage, the silica will also contain trace
metals contained in the magnesium silicate feedstock and will be in a form which will depend
greatly on the process conditions selected. It is the intention of the pilot project to explore the
properties of the produced silica at differing process conditions and determine further
process steps needed to extract the various metals contained within. These investigations
will be carried out as part of the pilot trials. As there is currently not a customer for this by-
product output from the pilot trials, this material will be collected and removed from site as a
waste product. A budget will be allocated for this activity within the pilot project. However, the
intention of the pilot trial is to establish a local market for the silica and metals produced. To
this end, CCC have been working with an industrial expert in silicas and magnesium
carbonates, and his contacts at PQ Corporation, (https://www.pqcorp.com/), to bring them in
as partners in the pilot trial to explore properties achievable and develop markets for these
materials and explore their use in existing target markets such as uses in high quality cement
and a filler in tyres and other wear resistant rubber and plastic products. This will lead to the
development of a market for the silica produced in time to offtake the silica produced by the
50kt Plant and generate further revenue for the plant.
A detailed TEA and LCA of the proposed 50kt Capture Plant was carried out as one of the
key deliverables of this project. In this analysis the process was split into a number of stages
and the energy and fuel requirements and subsequent CO2e emissions have been calculated
and presented in the following Table 1.
Heat input for Energy Input CO2 from heat Heat recovered
digestion agent needed to run from digestion
recovery process evaporator step
Renewables 181.14
Used
Table 1 lists the emissions produced by the process normalised to a tonne of captured CO 2.
The conclusion is that for every tonne captured 495 KgCO2eq is released giving a NET
benefit of 505 KgCO2eq for every tonne removed from the air.
OTHER CONTAMINENTS
The mineral feedstock contains trace amounts of various metals but the build-up of these
metals in the recirculated/recovered water will not be an issue as, in the 50kt plant we will
have a metal recovery step within the process so these metals would only be present below
the limits that the metal recovery process can economically extract them. These remaining
metal contaminants will end up in the magnesium carbonate mineral at the end of the
process. As this material is to be used as a construction material, purity of the magnesium
carbonate is not a big issue so there is likely to be a wide tolerance on acceptable
contamination of the product. There may however be some issues around the possible
leaching out of these materials and possible interactions with other construction materials in
the built environment. One of the outputs of the collaboration with Holcim and other
construction materials companies such as Forterra over the pilot project will be to explore the
use of the magnesium carbonate produced and the assessment of the material properties
tolerances necessary regarding compatibility issues and possible aging effects such as
leaching of contaminants over time.
NOISE
As the 50kt Plant will be drawing a huge volume of air through the system to capture the low
concentration CO2 there is a requirement to force this air through using fans. The fans used
will be highly efficient and therefore low noise. However, these fans will produce some noise,
and this will have an impact of the local communities and wildlife. Suitable guarding around
the fans and the relatively slow air speed will prevent injury to birds. The proposed site for
the plant is in a heavily industrialised area and away from any residential areas so noise will
have a minimal impact to the local community.
EMISSIONS
The only emissions from the site will be the processed air. As the air that passes through the
system will pick up moisture from the scrubber, in certain weather conditions there is likely to
be a plume of steam coming from the site. Again, this is an industrialised zone, and the
region has many cooling stacks emitting steam including the cooling fans at the Ineos power
plant in Runcorn and process steam from the Stanlow Oil Refinery, so this is unlikely to raise
any concerns by the local community or adjacent industrial facilities.
For the 50kt plant, the magnesium silicate materials will be transported to site from Norway
by ship. The site will have access to the canal berth on the Manchester Ship Canal, with
some materials storage space nearby, so there will be a requirement for some material
movement on site. The majority of transport from the quayside to the plant will be via
conveyors. The plant will be producing 190kt of magnesium carbonate per annum which will
need to be transferred to the construction material manufacturers facility. This equates to
approx. 18 x 40 tonne tipper trucks movements per day, (assuming a 5-day week). As the
region is well served by rail infrastructure with a number of rail heads available on the
Stanlow oil refinery site and at the nearby CF Fertilisers plant, there is the opportunity for this
material to be transported away from the site by rail or by barge using the Manchester Ship
Canal.
Other materials outputs include silica and valuable non-ferrous metals. The metals are
relatively small quantities and would result in a small number of road truck movements to
metal smelting customers. The silica production however will be in significant quantities,
circa 52kt per annum, approx. 5 truck movements per day off site and some internal
materials transport within the plant.
A programme of work has been developed for the next phases of design through to
handover for pilot plant operations along with a proposed project structure that would
become the basis for a detailed project execution plan. A capital cost estimate has also been
prepared, with an assessment of an appropriate contingency level to apply.
The proposed site for the pilot plant has been reviewed and is seen to be a suitable choice.
The Pilot Plant will focus on demonstrating and proving the major key components and unit
operations of the process consisting of the following:
• The Digester.
• The Direct Air Contactor/Stage 2 scrubber.
The Pilot Plant will be used to prove and optimise the ability to capture carbon dioxide from
the air, conversion step to capture the CO2 from air and Magnesium Hydroxide to use to
sequester the CO2 as Magnesium Carbonate for scale up to a larger scale plant. The pilot
trials and supporting research would focus on the development of techniques for:
The by-products from the process will be used to develop and test markets for their use with
commercial partners including PQ Corporation for the silica and Holcim for construction
materials.
Although much further work will be required in the future design stages the fundamental
feasibility of these items for the duties defined by the Flow Sheet have been established. An
early task for the detailed design phase in the Phase 2 project will be to re-visit these
designs, taking into account any new information uncovered by any further chemical testing.
DIGESTER
The function of the digester is to create materials to be used in the CO2 Capture Scrubber
and there are various technologies available that could achieve this.
• Digester
• Heated centreless screw
• Multi-hearth furnace
• Batch kiln (as typically used in the ceramics industry).
From these the current selection is for a Digester but a more comprehensive review of the
options, once more information has been obtained from the supply chain, will be undertaken
in the early stages of detailed design in Phase 2. Results from further material testing should
also be brought to bear in this decision if and when it becomes available.
The scrubber operates at ambient temperature which simplifies material selection and
scrubber design. Polypropylene (PP) is the likely choice. Appendix A shows an air contactor
unit similar to the one designed for the Phase 2 project.
Project partners/sub-contracts to this project include University of Chester, providing the pilot
site and access to research facilities, Otto-Simon Ltd, providing engineering design and pilot
3 PROJECT PLAN
The selected site is adjacent to Chester University facilities giving access to labs, expertise
and scientific analytical equipment needed to assess the performance of the pilot. The plan
is to have the University of Chester as a sub-contract to the project to give us access to their
facilities and expertise. This will enable students to access the technology and could support
research projects looking at various aspects of the technology to further develop the
technology.
The site is also adjacent to Protos, the proposed site for the 50kt plant and the HyNET
project, (see Appendix B). Proximity to the proposed deployment site and industrial partners
such as Peel Environmental Ltd (owners of the Protos site) would help develop the
commercial relationships and confidence in the technology needed to successfully develop
the subsequent plans for the 50kt DAC facility.
The risk in using this site is that there is currently a change of management company
managing the site. This is making it difficult to establish a firm price for the hosting of the pilot
plant as this situation may lead to delays in securing leases for the site. However, the
University of Chester is very supportive of this project and new innovative technologies,
especially in technologies addressing the climate emergency. This support is echoed by the
new site management company who will be keen to exploit the publicity and kudos that this
project will generate for the site.
The project will run over 2 years and 1 month (25 months) from the start of the project.
BUDGET
The total budget is £2,999,876.00. This budget is split across 9 Work Packages as described
below:
A more detailed breakdown of project cost and milestones can be found in Appendix C: The Project
Delivery Plan.
Over the course of the Phase 1 project, it became apparent that the concept developed did
not benefit from the available waste heat at SizewellC and being located near a nuclear
power station created a great deal of complexity to any future project and nuclear power
stations. Also, nuclear power stations are generally located away from areas of high
population and other industries so therefore markets for by-products produced. This added
further cost and increased the carbon intensity of the concept. As a result, the project team
found an alternative location at the Protos site and SizewellC will no longer be part of the
consortium going forward. Local supply chain partners have been located on or near the
Protos site to support the business opportunity presented by the 50kt plant at that location.
Partners identified include:
Figure 1: Potential future consortium members located on or near the proposed Protos site
The table below is a summary of the TEA outputs taken from that report.
This TEA suggests that NET revenues from capturing a tonne of CO2 from the air using
CO2LOC technology is £286/tCO2eq. The Life-Cycle Analysis LCA is presented in section 1.2
of this report.
As the CAPEX for the plant will be a total of £139m this gives a healthy Internal Rate of
Return (IRR) for the project. Table 2 shows the result of IRR analysis of the project at various
future carbon prices and amortisation periods, a discount rate of 10% was assumed.
For a plant of this size, a 20-year investment window would be considered reasonable and
carbon prices are likely to track up past £50 per tonne. This suggests an IRR of 9% which
compares favourably with expected IRRs of below 4% on a typical offshore wind project.
(Grant Thornton - https://www.grantthornton.co.uk/insights/valuing-renewable-energy-assets-
does-capm-work/)
In parallel, the pilot project will enable CCC and potential customers for the by-products to
assess the quality and properties of the by-products of the process and develop plans and
commercial relationships to exploit the outputs of the 50kt plant. This will lead to the
development of a business plan to support the securing of the £140m needed to build the
50kt plant from a combination of investors, partner companies, grants and loans/bonds.
The CCC team are also entering the X-Prize Carbon Removal Prize. The results of this
Phase 1 project being used to support the application in the first round. Success in the first
round will result in $1m USD investment in CCC which will be used to enhance R&D
activities which in turn will benefit the Phase 2 project. Success of the Phase 2 project will
then put CCC in the running for the subsequent $50m USD prize which, if won, will be used
to part fund the planned 50kt DAC Plant.
The pilot plant is planned to be located at Thornton Science Park which is in close proximity
to the Protos site, owned by The Peel Group. The Peel Group are keen to follow the
progress of the Pilot with the possibility of their future involvement and the siting of the 50kt
DAC Plant on the Protos site. The Peel Group own a significant proportion of the land on
which the HyNET project will be based and are a key contributor to that project. Through our
relationship with Peel Group CCC hope to be integrated into the HyNET project as our
technology nears commercialisation.
Secondary research questions addressed by research activities running in parallel with the
pilot operations will include:
Materials produced by the pilot will also enable CCC to work with partners in the construction
sector to develop and test construction materials to create a market for the materials
produced by a future 50kt plant. Similarly, with the silica and metals market to maximise
revenues from both the silica and metals produced.
Results from this work will enable the detailed design of the 50kt Plant and validate the
economics of the process. It will also help develop the commercial relationships necessary to
enable a 50kt Plant project to be developed and provide the evidence needed to support
efforts to raise funding required to deliver the project.
The commercial viability of the technology at a 50kt scale is highly dependent on the future
prices of silica, metals and magnesium carbonate and the local market demand for these
materials. In our analysis in this Phase 1 project, 5-year average prices have been used for
the various by-products and recent average UK energy prices assumed. However, there has
been an upward trend in commodity prices and as our by-products will be effectively NET
Zero emissions, a premium may well be possible offering higher revenues than anticipated in
our financial model.
To a lesser extent the business model supporting the 50kt Plant is also dependent on the
prevailing carbon price. This is also likely to increase in price over the coming years as more
companies are starting to engage with the carbon market, generating more demand and
greater liquidity in the market.
Stack
Elevation On A-A Showing Typical General Arrangement Of 2 Stage Absorption Scrubber System
Figure 3: Scrubber GA
Stage 2 Scrubber Pump Pump Stage 1 Scrubber
Inlet Ductwork To Scrubber
By Client UNO
Stack
General Arrangement Of
Two Stage Absorption System
S.D.Hodges 14/12/21
@ A0
Q20292/CLT/0001
1:40
Figure 5: Selected site for the pilot at Chester University’s Thornton Science Park Campus
1. Project management
2. Detailed design of the pilot
3. Equipment procurement
4. Pilot build
4.1. Site preparation
4.2. Installation
4.3. Commissioning
4.4. Pilot handover
5. Pilot Trials
6. Supporting research activities
7. 50kt Plant planning
8. Business and commercial planning
9. Decommissioning
• To ensure the smooth running of the project, manage time against project plans ensuring
timely delivery of milestones and planned deliverables.
Description of work
• Project management, chairing of project review meetings and quarterly meetings with
assigned monitoring officer.
• Maintenance of risk register and coordinator of risk mitigation strategy planning and
execution.
Dependencies
Start date : M1
End date : M10
Work Package Leader: OSL
Contributing Partners: CCC
Work Package Objectives:
• Detailed design and construction planning of the pilot based on detailed site information and available
budgets
Description of work
Detailed design of the plant and review of construction planning. Negotiation of contracts with key delivery
partner, service providers and subcontractors.
Milestones:
Dependencies
Description of work
Milestones:
Summary of Deliverables: Detail the planned external (E) and internal (I) deliverables
Del. Title External /Internal Responsibility Due Date Comments / Notes
Ref (E/I)
D3.1 Purchase Orders available I CCC M2
Dependencies
Description of work
Milestones:
Summary of Deliverables: Detail the planned external (E) and internal (I) deliverables
Del. Title External /Internal Responsibility Due Date Comments / Notes
Ref (E/I)
D4.1.1 Site cleared I OSL M3
Dependencies
Description of work
Milestones:
Summary of Deliverables : Detail the planned external (E) and internal (I) deliverables
Del. Title External /Internal Responsibility Due Date Comments / Notes
Ref (E/I)
D5.1 Trial experimental plan I CCC M17
Dependencies
Start date : M1
End date : M22
Work Package Leader: CCC
Contributing Partners: UoC/OSL
Work Package Objectives:
• Confirmation of key reaction rates and temperatures in support of detailed design phase
• By-product analysis and optimisation of process parameters during pilot trials in support of
WP5
Description of work
Task 1: Confirmation of key process parameters and other reactor design input in detailed design phase
(WP2)
Task 2: Scientific support for the trial
Task 3: Process development and innovation
Task 4: Capture of new IP
Task 5: Preparation of materials and planning of dissemination of project outcomes
Milestones:
MS6.1 – Conclusion of DAC pilot research activity and research summary report and dissemination materials
and plan available
Summary of Deliverables: Detail the planned external (E) and internal (I) deliverables
Del. Title External /Internal Responsibility Due Date Comments / Notes
Ref (E/I)
Dependencies
Start date : M5
End date : M24
Work Package Leader: CCC
Contributing Partners: OSL
Work Package Objectives:
• More detailed design of a future 50kt CO2LOC DAC plant based on learning from the pilot plant
• Construction plan and costing it support business planning and consortium building (WP8)
Milestones:
Dependencies
• Development of a business plan to attract investment and partners to deliver the 50kt DAC plant
• Bring together interested parties to form a consortium to deliver the 50kt DAC project
• Secure seed investment to support the business team focused on the development of the 50kt DAC
plant and delivery of the business plan
• Management of PR about the pilot project and future plans
Description of work
Dependencies
Description of work
Milestones:
Milestones
WP.MS Milestone Deliverable Date
1.1 Project Start Kick-off meeting report M1
1.2 Project Completed Close Out meeting report M25
2.1 Pilot design completed Full design documentation available M4
3.1 Long lead-time equipment Delivery schedule, purchase orders M2
procured
3.2 Equipment delivered to site Equipment delivered to site M10
4.1.1 Site work started Work schedule available M3
4.1.2 Site ready for pilot build Site ready for pilot build M6
4.2.1 Plant installation started Work schedule available M4
4.2.2 Plant Installed on site Pilot plant on site M13
4.3 Pilot commissioned Operational pilot plant M16
4.4 Pilot handed over to demo team Demo team on site M17
Project Management
Regular technical review meetings with the CCC team and quarterly meetings with our Monitoring
Officer during the 25-month project will provide the backbone for project progress monitoring and
reporting. Measurable, significant and timed key milestones have been included in our plan for each
work package task. This structure is also intended to help manage technical risk, as it provides
frequent opportunities to identify and correct any shortcomings in pilot equipment or methodology and
any timeline slippage.
As a further risk management strategy, the process of stakeholder consultation and experimental
review through the project provides the opportunity and time to make changes to the detail of
experiments & data collection if feedback from stakeholders warrants it.
Despite CCC having management of the overall project, management of the pilot design and
construction will be under the direct control of Otto-Simon Ltd, this will leverage their experience and
expertise, ensuring successful delivery of the pilot plant.