Scribd Logo
Upload

Welcome to Scribd!

  • 13 views

    PH Su Hoto Ulfate Ometr Eina Ric D Aque Eterm Eous Mina Solu Ation Ution Nof Ns

    Uploaded by

    sheilla
    This document describes a photometric method for determining sulfate concentration in aqueous solutions by titrating with barium chloride and back-titrating the excess barium with EDTA. The method involves precipitating sulfate from a sample solution with barium chloride, then back-titrating the unreacted barium with EDTA using a titrator and measuring absorbance with an optical sensor.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    PH Su Hoto Ulfate Ometr Eina Ric D Aque Eterm Eous Mina Solu Ation Ution Nof Ns

    Uploaded by

    sheilla
    13 views2 pages
    This document describes a photometric method for determining sulfate concentration in aqueous solutions by titrating with barium chloride and back-titrating the excess barium with EDTA. The method involves precipitating sulfate from a sample solution with barium chloride, then back-titrating the unreacted barium with EDTA using a titrator and measuring absorbance with an optical sensor.

    Original Title

    926256_963116_AN-t077

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document describes a photometric method for determining sulfate concentration in aqueous solutions by titrating with barium chloride and back-titrating the excess barium with EDTA. The method involves precipitating sulfate from a sample solution with barium chloride, then back-titrating the unreacted barium with EDTA using a titrator and measuring absorbance with an optical sensor.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    13 views2 pages

    PH Su Hoto Ulfate Ometr Eina Ric D Aque Eterm Eous Mina Solu Ation Ution Nof Ns

    Uploaded by

    sheilla
    This document describes a photometric method for determining sulfate concentration in aqueous solutions by titrating with barium chloride and back-titrating the excess barium with EDTA. The method involves precipitating sulfate from a sample solution with barium chloride, then back-titrating the unreacted barium with EDTA using a titrator and measuring absorbance with an optical sensor.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 2

    Titrration Applica

    A tion No
    ote T–77
    Ph
    hotoometrric determ
    mina
    ation
    n of
    su
    ulfate
    e in aque
    a eous soluution
    ns

    This Applicatioon Note describes


    d tthe photometric detterminationn of sulfate in
    aqueeous solutions by usin
    ng the Opttrode (520 0 nm). Sulfaate is preci pitated witth an
    um chloride solution . Back-titraation of the unreacteed barium with
    exceess of bariu
    EDTAA provides the sulfatee content.
    Method description

    Sample Parameters
    Sulfuric acid Titration mode DET U
    Measurement drift 50 mV/min
    Sample preparation Min. waiting time 0s

    No sample preparation required Max. waiting time 26 s


    Min. increment 10 μL
    EP criterion 5
    Configuration
    EP recognition greatest
    907 Titrando 1 x 2.907.0010 Stirring speed 8
    800 Dosino 5 x 2.800.0010
    Dosing unit 2 mL 1 x 6.3032.120 Calculations
    Dosing unit 10 mL 3 x 6.3032.210 mol/L SO42–= ((C01 × C02) – (EP1 × C03)) × C04/C00
    Dosing unit 50 mL 1 x 6.3032.250
    802 Rod Stirrer 1 x 2.802.0020 EP1 = titrant consumption in mL
    815 Robotic USB SP 1 x 2.815.0110 C00 = sample volume in mL
    C01 = volume of the BaCl2 solution in mL
    Sample beaker 1 x 6.1432.320
    250 mL C02 = conc. of the BaCl2 solution in mol/L (0.1)
    C03 = conc. of Na2EDTA solution in mol/L (0.025)
    Sample rack 1 x 6.2041.820 C04 = titer Na2EDTA (dimensionless unit)
    28 × 250 mL
    Optrode (at 520 nm) 1 x 6.1115.000
    Results

    Solutions c(SO42–) in mol/L


    0.0516 ± 0.0002
    Titrant Dissolve 9.855 g
    (n = 6)
    c(Na2EDTA) = Na2EDTA•2H2O in dist.
    0.025 mol/L water, add 10 mL c(NaOH)
    = 1 mol/L, and make up to
    1 L with dist. water.
    Indicator /buffer Dissolve 12.8 g MgEDTA
    solution (calmagite) (CAS 14402-88-1) and
    0.150 g calmagite (CAS
    3147-14-6) indicator in
    dist. water. Add 400 mL of
    25% ammonia and make up
    to 1 L with dist. water.
    Auxiliary solution CAS 7647-01-0
    c(HCl) = 1 mol/L
    Barium chloride Dissolve 24.428 g
    solution BaCl2•2H2O (CAS 10326-
    c(BaCl2) = 0.1 mol/L 27-9) in dist. water and
    make up to 1 L.

    Analysis
    To x mL sample solution add 100 mL dist. water, 2 mL
    hydrochloric acid, and 5 mL barium chloride solution.
    Titration Application Note T–77

    After a precipitation time of about 120 s, add 5 mL of


    buffer solution. Then titrate with c(Na2EDTA) = 0.025
    mol/L using the DET mode and the Optrode (520 nm).
    Version 1

    You might also like