I I T - JEE

FULL TEST - 4 (Paper II)

ANSWERS, HINTS & SOLUTIONS

SECTION – A

1. B
g
Sol. g  2
 h
1  R 
 

2. B
Sol. y = A sin (kx) cos (t)
2 
k 
 
  length of sting
U=  dU
x
1  x  m
=  (dm) 2 A 2 sin2   and dm  dx
x 0 2    

3. D
1 1 2
Sol.  
v 10 9

4. A
12375
Sol. min   0.30 Å. Hence wavelength less than 0.30 Å is not possible.
40,000
 2

5. A
r
Sol. Potential energy U = eV = eV0 ln
r0
dU eV0
 Force F   .
dt r
 The force will provide the necessary centripetal force.
mv 2 eV0 eV0
Hence,  v …(i)
r r m
nh
and mvr  …(ii)
2
 nh  m
From equations (i) and (ii), mr    or r  n.
 2  eV0

6. B

Sol. v = 2V cos 30° sin 30° (  ˆi) + V(cos2 30° – sin2 30°) ĵ

7. D
1
Sol. minima  = cosec 
sin 

8. ABD
Sol. By conservation of angular momentum,
I 1  i  I 1  I 2  f
 f  1 / 3
1
Ei  I 1  i2
2
1
E f  I 1  I 2 2f
2
Ei  E f 2
Ratio of the heat produced to initial kinetic energy  
Ei 3

9. ABC
Sol. When t = 3s block just about to move and F=t
t2 B A
acceleration of block given by a  t>3
1 fk = 1N fk = 1N
v 10 fs = 1N fs = 2N

0
dv    t  2 dt
3
10
t2 9 
v   2t   50  20     6 
2 3 2 
 30  1.5  31.5 m/s
 3

10. BD
1
Sol. E  m and r 
m

11. ACD
  dB ×
Sol.   d l  A dt
E × R ×
× × ×
E2 x 2  d2  R 2k O
× × ×
R 2 k ×
E
2 x 2  d2 d
  qR2
Wext   qE  dx  k 
0 4 P
E

12. AC

Sol. v AB   3  a  ˆi   3  b  ˆj
  (10,5)
a AB  o B
vAB
 3  a   2  10 and  3  b  2  5
1 A
a = –2 and b =
2 (0,0)

13. AC
L 2 1
Sol.   
Re q 8 4
at steady state inductor short circuited
Hence i = 0.75

14. AB
1 1 1
Sol.  
v u f

15. C
Sol. 
V   Ex dx  Area under Ex  x graph.

16. C
Sol. 
V   Ex dx  Area under Ex  x graph.

17. C
Po V
Sol. P  5Po 
Vo
1  Po V 2 
T 5P
 o V  
nR  Vo 
 4

dT 1  2Po V 
  5Po   =0
dV nR  Vo 
5V
 V  o at maximum temperature.
2
25
 Tmax  To
16

18. D
dQ P dV
Sol.  Cv  0
ndT n dT
 Po V 
 5Po  
 Vo  nR
CV   0
n  2Po V 
 5Po  
 Vo 
 V 
5  
 Vo  3

 2V  2
5  
 Vo 
25
 V= Vo
8
 5

Chemistry PART – II

SECTION – A

19. C
Sol. It is a linear molecule and contains three lone pairs.

20. A
kw
Sol. pK a   logK a , K b 
ka

21. B
Sol. t½ is inversely proportional to rate constant(k). k increases by increasing temperature.

22. B
Sol. Benzyl halides undergo SN1 and SN2 reactions with equal extent.

23. C
Sol. It forms maximum number of ions.

24. B
Sol. It is called carbylamine reaction.

25. C
Sol. Five coordination isomers are possible because
[Cr(NH3)3(CN)3][Co(NH3)3(CN)3] does not exist.

26. ABCD
Sol. P(V – b) = RT at high pressure.

27. ABD
Sol. Benzylic hydrogen is needed for oxidation of side chain.

28. ABD
Sol. -nitronaphthalene has more stable resonating structure than -nitronaphthalene.

29. ABD
Sol. The products are
(A) H3PO4 + PH3, (B) PH3 + Na2HPO2, (C) C + H2O, (D) H2O + O2

30. AB
Sol. Dehydration reaction is endothermic.
Synthesis reaction may be exothermic or endothermic.

31. BC
Sol. This is due to decrease in lattice energy.

32. C
Sol. In acidic medium, glycine adopts this structure.
 6

33. C
Sol. W = Zit, Cu2+ + 2e  Cu

34. C
Sol. 2H2O  O 2  4H  4e 

35. C
Sol.
R is N =N OH

36. C
Sol. It should be moderately basic.
 7

Mathematics PART – III

SECTION – A
37. B
Sol. z5  1   z  1 z  1  z   2  z   3  z   4 
 
In z5  1  ln  z  1  ln  z  1   ln  z   2   ln  z   3   ln  z   4 
Differentiating
5z4 1 1 1 1 1
5
    
z  1 z  1 z  1 z   2 z   3 z   4
4
1 80 49
Setting z  2,   1
r 1 2   r 31 31

38. B
Sol.   6
      5
  1
  2  2   2  26
 22  2  2   2  2  13
39. B
Sol. x 3  2x 2  1  0 or  3  1  2 2
11 11 11 8 8 8
T11  T8             
 
T10 10  10  10


  
8 3  1  8 3  1   8  3  1     2 10
 10  10  2
10  10  10 10  10  10
40. D
k/n 1/n
 n
 n 
Sol. l   lim  1   
 n k 1  k  
 
x k /n
  1 k  n 
Given f  x   1   and f    1   
  x n  k 
Taking log,
k /n
1 n  n
lnl  lim .  ln  1  
n n k
k 1 
 
1 n k  1
 lim .  ln  1  
n n
k 1 n  k

 n
1
 1
  x ln  1   dx
0 II    x

I
 8

1 1
 1  x2  1 1  x2
 ln 1   .      . dx
 x  2  0 0  x x  1  2
1 1 1
 ln 2   x  ln  x  1  0
2 2
1 1 1
 ln 2  1  ln 2   0 
2 2 2
l e

41. C
Sol.  
g  x   f ex
g'  x   f '  e  e
x x

g'  x   0  f '  e   0 x

2 x  2 x 22x  1
    1, 1
2x  2 x 22x  1
 1  e x  1
 x   , 0 

42. C
Sol.  
On (1, 2, 3) satisfies the plane x  2y  z  0 and also ˆi  2ˆj  3kˆ . ˆi  2ˆj  kˆ  0 
  a
x 1 y  2 z  3
Since the lines   both satisfy t  1,2t  2 and 3t  3
1 2 3
Hence both are same   b  .
Given lines is obviously  to the plane x  2y  z  6   d 

43. A
Sol. E1 “No card is king from removed cards”
E 2 “1 card is king from removed cards”
E3 “2 card is king from removed cards”
E 4 “3 card is king from removed cards”
E5 “4 card is king from removed cards”
F = 3 cards are drawn from pack those are kings.
S
 F  48 C 4
C 48
C . 4C1 3 C3
P F    P Ei  .P    52 26 . 26 3  5225 . 26 000
i 1  Ei  C26 C3 C26 C3
4 4  49C26 1
 52
C26 . 26 C3
 48

C26  48C25  52 26

C26 . C3 13 17  25 

44. ABCD
k 1 1 k 1  1 1 
Sol. Put k  log x  t, then bk   dt      dt
k t  t  1 k
 t t  1
 9

2
 k  1
 log   log
k2
 log
 k  1
 k k  2 
 k  k 1
n n
 k 1 k  2
an   bk   log  log
k 1 k 1  k k  1 
n2 2n  2
 log2  log  log
n 1 n2
lim an  log2  1
n 

45. CD
Sol. (a) In a triangle ABC, A  B  C   , so tan A  tanB  tan C  tan A tanB tan C . Since
none of tan A,tanB,tan C can be zero, a triangle given in (a) is not possible.

(b)
 sin A   sinB   sin C  , so that by the laws of sines
a b c
  
ab 5

 
2 3 7 2 3 7 c 7
which is not possible, as the sum of two sides of a triangle is greater than the third.
2 a2  b2  c 2 1
(c) We have  a  b   c 2  ab, so that 
2ab 2
1
 cos C    C  120o and 2  sin A  cos A   3
2
1 1 3
 sin A  cos A 
2 2 2
  3  
 sin  A     A 
 4 2 4 3

That is, A   15o and B  45o . Such a triangle is possible.
12
3 
(d) Since cos A cosB  sin A sinB  , we get cos  A  B   0 , i.e. A  B  . Also,
4 2
3   
from cos  A  B   , we get A  B  , so that A  ,B  and
2 6 3 6
3 1 3 1
sin A  sinB   
2 2 2
Hence, such a triangle is also possible.
46. AC
   1
Sol. We have p
 q r     
a b c 
 
  
Therefore, p q r   0
 
  
   p q r 
 a  x  0, x a b c     2 (Using AM  GM )
x
(b) similarly, use AM  GM

47. ABD
 10

dx
Sol. Rewriting the given equation, we have  x 2 y3  xy
dy
dx
 x 2  x 1y  y 3 , which is reducible to linear form.
dy
du
Putting x 1  u, we have  yu   y3
dy
2
This I.F. of this equation e y /2
. So the solution is
ue y
2
/2 2
   y3 e y /2dy  C   y 2e y  2
/2
 2e y
2
/2
C
1 2 2

x
 
 2  y 2  C e  y /2 or 1  2x  / x   y 2  C e y /2

48. BCD
2 n
Sol. Solving f  x   2x  x and g  x   x
We have 2x  x 2  x n  x  0 and x  1
1 1
x 3 xn 1 
A  2 n
2x  x  x dx  x    2

3 n  1 0

0

g(x) = xn

f(x) = 2x – x2

x
O

1 1 2 1
 1   
3 n 1 3 n 1
2 1 1 2 1 1
Hence,     
3 n1 2 3 2 n 1
43 1
   n 1 6  n  5
6 n 1
Hence n is a divisor of 15, 20, 30

49. ABCD

Sol.  Sr  r  r   ...  r  sr
 S r 2  Sr  r  0
 11

1 1  4r 
 Sr  r  0 
2
Alternate (a) S2 ,S6 ,S12 ,S20 i.e. 2, 3, 4, 5 are in AP.
1  17 1  37 1  65
Alternate (b) S4 ,S9 ,S16 i.e. , , are irrational
2 2 2
2 2 2
Alternate (c)  2S4  1 ,  2S5  1 ,  2S6  1 i.e. 17, 21, 25 are in A.P.
Alternate (d) S2 ,S12 ,S56 i.e. 2, 4, 8 are in G.P.

50. ACD
1
Sol.
10!
 20
C1  2. 10C3  10C5 
10
C1  10C3  10C5  10C7  10C9

10!
9 3
2 8 8n
    a  3, b  4, c  5
10!  2.5 !  2.c !

51. B
 x
3x, x  0  , x0
Sol. We have f  x    and g  x    3
 x, x  0  x, x  0

Clearly f and g are inverse of each other
 x
3  x, x  0
Now, h  x   f  g  x      3 
 x, x0

As, h  x   x x  R
1
 k  x  1


cos1 x  cot 1 x 
Domain of k  x    1, 1 and k  x  is decreasing function on  1, 1
As k  x  is continuous function on  1, 1
1
Now, k min  x  1  1 


cos1 1  cot 1 1 
1  1 5
 1  0    1 
 4 4 4
1

k max.  x  1  1  cos1  1  cot 1  1


1 3  7 11  5 11
 1      1   Range of k  x    , 
 4 4 4 4 4 

52. D
1
Sol. We have f  x   g  x    2x  x    2x  x 
3
 12

8
4x 4  x; x0
  x  3
3 3  0 ; x  0
8x
 For domain of function, 0  1
3
 3
 Domain of l  x    , 
 8
 
(Note : Range of function l  x   0,  )
 2

53. B
54. A
Sol. (Q. 53 – 54)
It is given that one of the diagonals of the square is parallel to the line y  x .
Also, the length of the diagonal of the square is 4 2 .
x3 y4
Hence, the equation of one of the diagonal is   r  2 2
1 1
2 2
Hence, x  3  y  4  2
 x  5,1 and y  6,2
Hence, two vertices are (1, 2) and (5, 6).
The other diagonal is parallel to the line y   x, so that its equation is
x3 y4
  r  2 2
1 1

2 2
Hence, the two vertices on this diagonal are (1, 6) and (5, 2).
D D F
A A

G
r F F
(i) (ii)
E E

C B C B
AB  4, AC  4 2  AE  2 2
In figure (i) EF  FA  AE
2 2
 r  2r  2 2  r
2 1
2 2  2 1 
In figure (ii), EG + GF = EF
2
 2r  r  2  r
2 1
2  2 1 