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    Chlorine MSDS

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    DuraiMurugan

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    © All Rights Reserved
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    Chlorine MSDS

    Uploaded by

    DuraiMurugan
    9 views4 pages

    Original Title

    CHLORINE MSDS

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    9 views4 pages

    Chlorine MSDS

    Uploaded by

    DuraiMurugan

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    © All Rights Reserved
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    of 4

    MATERIAL

    Linde Gas LLC


    AGA GAS, INC. (216) 642-6600 SAFETY
    P.O.
    6055Box 94737 WOODS BLVD
    ROCKSIDE DATA SHEET
    Cleveland, Ohio 44101
    P.O. BOX 94737
    www.us.lindegas.com
    CLEVELAND, OH 44101-4737 EMERGENCY CONTACT NUMBER: 1-800-424-9300
    PRODUCT NAME CAS #
    7782-50-5
    Chlorine
    DOT I.D. No.:
    TRADE NAME AND SYNONYMS UN 1017 RQ 10(4.54)
    Chlorine DOT Hazard Class:
    CHEMICAL NAME AND SYNONYMS
    Division 2.3

    Chlorine
    Formula
    Cl2
    ISSUE DATES AND REVISIONS Chemical Family:
    Halogen
    Revised:April
    Revised September
    1998 27, 2010

    HEALTH HAZARD DATA


    TIME WEIGHTED AVERAGE EXPOSURE LIMIT
    0.5 Molar PPM with an A4 (Not Classifiable as a Human Carcinogent) carcinogen rating. STEL = 1 Molar
    PPM and an A4 carcinoqen ratinq (ACGIH 1997). (Continued on Page 4).
    SYMPTOMS OF EXPOSURE

    Corrosive and irritating to the upper and lower respiratory tract, all mucosal tissue, skin and eyes.
    Inhalation: Initial symptoms are irritation of the eyes, nose and throat becoming steadily worse, suffocating
    and painful. (Continued on Page 4)

    TOXICOLOGICAL PROPERTIES

    Irritating and corrosive to all living tissue. Toxic level exposure to dermal tissues causes acid-like burns and
    skin lesions resulting in early necrosis and scarring. Chemical pneumonitis and pulmonary edema result
    from exposure to the lower respiratory tract and deep lung. Burns to the eye result in lesions and possible
    loss of vision.
    Chlorine is not listed in the IARC, NTP or by OSHA as a carcinogen or potential carcinogen.
    Persons in ill health where such illness would be aggravated by exposure to chlorine should not be allowed
    to work with or handle this product.

    RECOMMENDED FIRST AID TREATMENT

    PROMPT MEDICAL ATTENTION IS REQUIRED IN ALL CASES OF OVEREXPOSURE TO CHLORINE.


    RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS.
    Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air.
    Unconscious persons should be moved to an uncontaminated area and given assisted respiration and
    supplemental oxygen. Keep the victim warm and quiet. Assure that mucus or vomited material does not
    obstruct the airway by positional drainage. Further treatment should be symptomatic and supportive.
    Eye Contact: PERSONS WITH POTENTIAL EXPOSURE TO CHLORINE SHOULD NOT WEAR
    CONTACT
    LENSES. (Continued on Page 4)

    Information contained in this material safety data sheet is offered without charge for use by technically qualified personnel at their discretion and
    risk. All statements, technical information and recommendations contained herein are based on tests and data which we believe to be reliable, but
    the accuracy or completeness thereof is not guaranteed and no warranty of any kind is made with respect thereto. This information is not intended
    as a license to operate under or a recommendation to practice or infringe any patent of this Company or others covering any process, composition
    of matter or use.
    Since the Company shall have no control of the use of the product described herein, the Company assumes no liability for loss or damage incurred
    from the proper or improper use of such product.
    CHLORıNE
    HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES
    High reactivity with organic and inorganic compounds may cause explosions and can cause or aggravate
    fires. Most hazardous reactions are with OF2, O2F2, F2, NH3, phosphorus and arsenic.

    PHYSICAL DATA
    BOILING POINT LIQUID DENSITY AT BOILING POINT
    -29.3°F (-34.1°C) 97.4 lb/ft3 (1560 kg/m3)
    VAPOR PRESSURE GAS DENSITY AT 70°F. 1 atm
    @ 70°F (21.1°C) = 100.2 psia (691 kPa) .185 lb/ft3 (2.96 kg/m3)
    SOLUBILITY IN WATER FREEZING POINT
    Very soluble -149.8°F (-101°C)
    EVAPORATION RATE SPECIFIC GRAVITY (AIR=1)
    N/A, (Gas) 70°F (21.1°C) = 2.47
    APPEARANCE AND ODOR
    Liquid is amber colored. Gas is greenish-yellow with a sharp, suffocatinq odor.

    FIRE AND EXPLOSION HAZARD DATA


    FLASH POINT (Method used) AUTO IGNITION TEMPERATURE FLAMMABLE LIMITS % BY VOLUME (See Page 4)
    N/A N/A LEL N/A UEL N/A
    EXTINGUISHING MEDIA ELECTRICAL CLASSIFICATION
    Nonflammable gas Nonhazardous
    SPECIAL FIRE FIGHTING PROCEDURES

    If cylinders are involved in a fire, safely relocate or keep cool with water spray.

    UNUSUAL FIRE AND EXPLOSION HAZARDS

    Most combustible materials burn in chlorine as they do in oxygen.

    REACTIVITY DATA
    STABILITY CONDITIONS TO AVOID
    Unstable None
    Stable X
    INCOMPATIBILITY (Materials to avoid)
    Hydrocarbons, ammonia, ether

    HAZARDOUS DECOMPOSITION PRODUCTS


    None

    HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID

    May Occur
    None
    Will Not Occur X

    SPILL OR LEAK PROCEDURES


    STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

    Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user’s
    equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is in container or
    container valve, contact your closest suppiler location or call the emergency telephone number listed herein.

    WASTE DISPOSAL METHOD


    Do not attempt to dispose of waste or unused quantities. Return in the shipping container properly labeled,
    with any valve outlet plugs or caps secured and valve protection cap in place to your supplier. For
    emergency disposal assistance, contact- your closest supplier location or call the emergency telephone
    number listed herein.
    2
    CHLORINE
    SPECIAL PROTECTION INFORMATION
    RESPIRATORY PROTECTION
    (Specify type)
    Positive pressure air line with mask or self-contained breathing apparatus should be
    available for emergency use.
    VENTILATION LOCAL EXHAUST SPECIAL
    To prevent accumulation above the TWA N/A
    Hood with forced ventilation MECHANICAL (Gen.) OTHER
    N/A N/A
    PROTECTIVE GLOVES
    PVC, Teflon® or Kel-F®. Natural rubber has poor resistance to chlorine as does Neoprene® and Nylon®
    EYE PROTECTION
    Safety goggles or glasses
    OTHER PROTECTIVE EQUIPMENT
    Safety shoes, safety shower, eyewash “fountain”

    SPECIAL PRECAUTIONS*
    SPECIAL LABELING INFORMATION

    DOT Shipping Name: Chlorine DOT Hazard Class: Division 2.3


    DOT Shipping Label: Toxic Gas; Corrosive I.D. No.: UN 1017 (RQ 10/4.54)
    SPECIAL HANDLING RECOMMENDATIONS

    Use only in well-ventilated areas. Valve protection caps must remain in place unless container is secured
    with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder
    movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<250 psig)
    piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the
    cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder.
    For additional handling recommendations, consult Compressed Gas Association’s Pamphlet P-1.

    SPECIAL STORAGE RECOMMENDATIONS

    Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked
    areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 125F (52C).
    Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and
    empty cylinders should be segregated. Use a “first in - first out” inventory system to prevent full cylinders
    being stored for excessive periods of time.
    For additiona1 storage recommendations, consult Compressed Gas Association’s Pamphlet P-1.

    SPECIAL PACKAGING RECOMMENDATIONS


    Most metals are corroded by chlorine at ambient temperatures if moisture is present. Systems must be kept
    scrupulously dry. Lead, gold, tantalum and Hasteloy® offer the best corrosion resistance to moist chlorine.

    OTHER RECOMMENDATIONS OR PRECAUTIONS


    Compressed gas cylinders should not be refilled except by qualified producers of compressed gases.
    Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent
    is a violation of Federal Law (49CFR). (Continued on Page 4)

    *Various Government Agencies (i.e. Department of Transportation, Occupational Safety and Health Administration, Food and Drug Administration
    and others) may have specific regulations concerning the transportation, handling, storage or use of this product which will not be reflected in this
    data sheet. The customer should review these regulations to ensure that he is in full compliance.
    3
    CHLORINE
    HEALTH HAZARD DATA
    TIME WEIGHTED AVERAGE EXPOSURE LIMIT: (Continued)
    OSHA 1995 lists a 1 Molar PPM Ceiling Limit.

    SYMPTOMS OF EXPOSURE: (Continued)


    The irritation extends to the chest causing a cough reflex which may be violent and painful and may include
    the discharge of blood or vomiting with eventual collapse. Other symptoms may include headache, general
    discomfort and anxiety.
    Skin and Eye Contact: Contact with the liquid or vapor causes painful burns and ulcerations.

    RECOMMENDED FIRST AID TREATMENT: (Continued)


    Flush contaminated eye(s) with copious quantities of water. Part eyelids to assure complete flushing. Continue
    for a minimum of 15 minutes.
    Skin Contact: Flush affected area with copious quantities of water. Remove contaminated clothing as rapidly
    as possible.

    SPECIAL PRECAUTIONS
    OTHER RECOMMENDATIONS OR PRECAUTIONS: (Continued)
    Always secure cylinders in an upright position before transporting them. NEVER transport cylinders in trunks
    of vehicles, enclosed vans, truck cabs or in passenger compartments. Transport cylinders secured in open
    flatbed or in open pick-up type vehicles.
    Chlorine is a toxic chemical and subject to the reporting requirements of SARA, Title III, Section 313.
    NFPA 704 No. for chlorine = 3 O O OX

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