Organic Chemistry - Rules

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Organic Chemistry

Classes – Functional groups – General formulas – Naming rules


The name of an organic compound is
made of 2 parts

Number (#) of Carbon Specific ending of the class


1 Meth …ane Alkane
2 Eth …ene Alkene
3 Prop …yne Alkyne
4 But …yle Alkyl
5 Pent …ol Alcohol
6 Hex …oxide Ether
7 Hept …al Aldehyde
8 Oct …one Ketone
9 Non …oic acid Carboxylic acid
10 Dec …yle …oate Ester
…amine Amine
…amide Amide
Branches: -CH3: methyl -C2H5: ethyl -C3H7: propyl
-Cl: chloro -Br: bromo -F: fluoro -I: iodo
Class General formula Functional group Naming rules
1- Alkane CnH2n+2 All the bonds are # of carbon + ane
Simple covalent bond
2- Alkene CnH2n One double covalent X + # of carbon + ene
bond
3- Alkyne CnH2n-2 One triple covalent X + # of carbon + yne
bond
4- Alkyl CnH2n+1 - branched
# of carbon + yle
- All the bonds are
Simple covalent bond

5- Alcohol CnH2n+2O

CnH2n+1OH Hydroxyl:  OH X-alkanol

R  OH
6- Ether CnH2n+2O
Oxide:  O  Alkyl oxide
R1  O  R2

7- Aldehyde CnH2nO
O
O  Alkanal
 Carbonyl:  C  H
RCH
8- ketone CnH2nO
O
O  X-alkanone
 Carbonyl:  C 
R1 C  R2

9- Carboxylic CnH2nO2
acid O
O 
 Carboxyl:  C  OH Alkanoic acid
R  C  OH

R  COOH
10- Ester CnH2nO2
O O
  Alkyl Alkanoate
R1  C  O  R2 Carboxylate:  C  O
R1  COO  R2
11- Acyl
chloride
O O
  Alkanoyl chloride
R  C  Cl  C  Cl
12- Acid
anhydride
O O O O
    Alkanoic anhydride
R1  C  O  C  R2  CO C

13- Amine CnH2n+3N


Amine :  N  X-alkanamine

14- Amide O
 Amide : O
R  C  NH2  Alkanamide
 C  NH2

15- Amino acid O Carboxyl :  COOH



R  CH  C  OH And Related to the structure

NH2 Amine :  NH2

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