2021 11 30 Fy Adv ph3

1-
INTERNAL TEST
IIT - JEE
FIRST YEAR 2021-23
PHASE TEST-3
2021 P2
Time: 3 hours Maximum Marks: 180
INSTRUCTIONS: Dated: 29 NOV 2021
Instructions to the Candidates

GENERAL: Question paper format & Marking Scheme:
I. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part has
3 sections.
II. Section I contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D),
ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
III. Section II contains THREE (03) question stems. There are TWO (02) questions corresponding to
each question stem. The answer to each of the questions is a NUMERICAL VALUE.
If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
Answer to each question will be evaluated according to the following marking scheme.
Full Marks : +2 If only the correct numerical value is entered at the designated place.
Zero Marks : 0 In all other cases.
IV. Section III contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02)
questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE
is correct.
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
V Section IV contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
NAME:
ENROLLMENT NO.:
KUKATPALLY CENTRE: # 22-97, Plot No.1, Opp. Patel Kunta Huda Park, Vijaynagar Colony, Hyderabad - 500 072. Ph.: 040-64601123
MIYAPUR CENTRE: Above Sai Motors Maruthi Showroom, Allwyn X Road, Miyapur, Hyderabad.
2- FIRST YEAR PHASE TEST-3 ADV (2021 P2) EX DT. 29-11-2021
SECTION–1 (Maximum Marks: 24)
1. A uniform ring of mass m and radius R is kept on a horizontal rough surface. A horizontal force acts
on it at a top in the plane of ring. Choose the correct options.
(A) ring will undergo rolling without slipping irrespective of value of F
(B) ring will roll with slipping or without slipping depending on value of F
(C) friction acting on ring will be zero
(D) friction acting on ring will be non-zero
2. A thin and uniform rod of mass M and length L is held vertical on a floor with large friction. The rod is
released from rest so that is falls by rotating about its contact-point with the floor without slipping.
Which of the following statement(s) is/are correct, when the rod makes an angle 60 with vertical?
3g
(A) the radial acceleration of the rod’s center of mass will be
4
3g
(B) the angular speed of the rod will be
2L
2g
(C) the angular acceleration of the rod will be
L
Mg
(D) the normal reaction force from the floor on the rod will be
16

3. 
Consider a body of mass 1.0 kg at rest at the origin at time t  0 . A force F  tiˆ  ˆj is applied on 
the body, where   1.0Ns1 and   1.0N . The torque acting on the body about the origin at time

t  1.0s is  . Which of the following statements is (are) true?
 1
(A)   Nm
3

(B) the torque  is in the direction of the unit vector k̂
 1

(C) the velocity of the body at t  1s is v  ˆi  2ˆj ms1
2

1
(D) the magnitude of displacement of the body at t  1s is m
6
4. Four particles of mass m each and kept at the vertices of

a square of edge a as shown in the figure.
(A) if the particles are released then the square will start
shrinking but not remain a square before particles
(B) if the particles are released then the square will be
shrinking and remain a square at all times before particles
meet
(C) the rate of decrease of area of the shape formed by
the particles will be increasing with time
(D) the rate of decrease of area of the shape formed by
the particles will be decreasing with time
5. Choose the incorrect statements from the following:

(A) it is possible to shield a body from the gravitational field of another body by using a thick shielding
material between them
(B) the escape velocity of a body is independent of the mass of the body and the angle of projection
(C) the acceleration due to gravity increases due to the rotation of the earth
(D) the gravitational force exerted by the earth on a body is greater than that exerted by the body on
the earth
6. Two satellites S1 and S2 are revolving around the earth is coplanar

concentric orbits in the opposite sense. At t  0 , the positions of
satellites are shown in the diagram. The periods of S1 and S2 are 4h
and 24h, respectively. The radius of orbit of S1 is 1.28 10 4 km . For this
situation, mark the correct statement(s)
(A) the angular velocity of S2 as observed by S1 at t  12h is 0.468 rad s1

(B) the two satellites are closest to each other for the first time at t  12h and then after every 24 h
they are closest to each other
(C) the orbital velocity of S1 is 0.6410km
(D) the velocity of S1 relative to S2 is continuously changing in magnitude and direction both
Question Stem for Question Nos. 7 and 8

Question Stem
On an inclined plane of inclination 37 different bodies of same mass equal to 2 kg and radius 10m
are rolling without slipping then answer the following questions.
7. The force of friction acting on the body if the body is a ring is ________ N
8. The force of friction acting on the body if it’s a hollow sphere is ________ N
Question Stem
A solid sphere of a uniform density and radius 4 units is

located with its centre at the origin O. Two spheres of equal
radii 1 unit, with their centres at A 2,0,0 and B 2,0,0
respectively, are taken out of the solid leaving behind
spherical cavities as shown in fig. Let ‘m’ be mass of each
sphere removed. Then
9. Find the gravitational force at the point B 2,0,0 is ______N.
16 1 
10. The gravitational potential at all points of the circle y 2  z2  36 is Gm    then find the value
 a b 
of b  a  __________
Question Stem
In a double star system, two stars one of mass M and another of mass 16M respectively, with a
separation of “d” rotate about their common centre of mass. Then
11. The ratio of their kinetic energies will be _________
12. The ratio of their angular momenta about their centre of mass ________
PARAGRAPH 1
Gravitational field is a conservative field. Total mechanical energy of the system remains constant.
Gravitational potential is taken a zero at infinite distance from the source of gravitational field (mass)
13. Assume a particle of mass m is released from point A as shown in the

figure towards thin shell of mass M. Time taken by particle to move
from B to D is
R3 R3
(A)  (B) 2
GM GM
R3 2R3
(C) 2 (D)
GM GM
14. In the above problem time taken by particle to move from C to D is

R3 R3 R3 2R3
(A) (B) 2 (C)  (D) 
GM GM GM GM
PARAGRAPH 2
A long slendor rod of mass 2 kg and length 4m is placed on a smooth

horizontal table. Two particles of masses 2 kg and 1 kg strike the rod
simultaneously and stick to the rod after collision as shown in figure.
15. Velocity of the centre of the rod after collision is

(A) 12 m/s (B) 9 m/s (C) 6 m/s (D) 3 m/s
16. Angular velocity of the rod after collision is

11 10 19 30
(A) rad s (B) rad s1 (C) rad s (D) rad s
7 17 17 17
17. A satellite of mass m is orbiting in an orbit of radius r1 . If it is given an

extra impulse in the direction of motion, it goes to the orbit of radius r2 .
GM  kr2 
 . Find k.
The extra velocity given to the satellite is  1
r1  r1  r2 

18. In the figure, a sphere of radius 2m is rolling

without slipping on a plank. The accelerations of
the sphere and the plank are indicated. Find the

value of  in rad s2 
19. A uniform disc of surface mass density  exists in

space. Its radius is R. A small disc of radius (R/2) is cut
from it as shown in the figure. The moment of inertia (I)
15
about axis AB is R 4 . Find the value of K.
16K
20. Which of the following statements are correct?
(A) the number of stereoisomers obtained by the mono chlorination of 2-methylbutane is 4

(B) the IUPAC name the following compound is
C2H5
2-Bromo-3-chloro-2,3-dimethylpentane
Br CH3
Cl CH3
CH3
(C) the IUPAC name of the following compound is cyclohexanoic acid COOH
(D) the IUPAC name of the following compound is 1-Bromo-4- Br

chloro-3-fluorocyclohexane
F
Cl
21. Which of the following statements are correct?

(A) the full name of the following compound is CH3
(2S, 3R)-3-chloro-2-pentanol
H OH
Cl H
C2 H5
(B) the cis-1,2-dimethyl cyclopropane is a meso compound

(C) the trans-1,2-dimethyl cyclopropane exists as a pair of enantiomers
(D) the following compound is (2S, 3R)-3-chloro-2-pentanol CH3
H OH
Cl H
C2H5
22. Which of the following for the structures is/are correct?

CH3 OH CH=CH2 H
H OH H CH3 H3C OH HO CH=CH2
CH=CH2 CH=CH2 H CH3
(A) (B) (C) (D)
(A) the structures A and B are enantiomers (B) the structures A and C are identical
(C) the structures A and D are enantiomers (D) the structures B and D are identical
23. Which of the following is/are correct?

H OH
(A) C C has ‘Z’ configuration
H3C COOH
H3C C CH
(B) C C has ‘Z’ configuration
F C(CH3)3
H3C CH2 OH
(C) C C has ‘E’ configuration
Cl C N
OHC CH2 Cl
(D) C C has ‘E’ configuration
H2N CF 3

(A) the ratio of hybrid orbitals to pure orbitals in acetylene is 2:3
(B) the number of atoms in the same plane in the structure CH3  CH  CH  CH  CH  CH3 is 10
(C) C2H5 4 C IUPAC name is 2, 2 – diethylpentane
(D) CH2  CH  CH2  CH  CH  C  CH IUPAC name is Hepta-3,6-dien-1-yne

(A) n-propyl alcohol and isopropyl alcohol are position isomers
(B) n-butyl alcohol and isobutyl alcohol are chain isomers
(C) isobutyl alcohol and tertiarybutyl alcohol are position isomers
(D) H2C CH3 CH3 are chain isomers
CH3
&
Question Stem
Any substance which rotate plane polarized light is an optically active substance and if it rotate light to
left is known as laevo rotatory and to right is known as dextro rotatory
p
q C assymmetric (or) chiral centre
s
r
26. A mixture of   2  phenyl propionic acid shows optical activity 12 . The specific rotation of
 2  phenyl propionic acid is +30. Calculate the percentage of enantiomeric excess?
27. The observed specific rotation for enantiomeric mixture of 2-butanol 6.75 and the percentage of
enantiomeric excess is 50. Find the specific rotation of enantiomerically pure  2  bu tanol .

Question Stem
The possible hybridizations in organic molecules are sp, sp2 , sp3 as there is no availability of d-orbital
in carbon.
28. Find the percentage of P-character of third carbon in

CH3  CH2  O  C CH2  CH  CH  CH2  CH2  CH2  COOH
||
O
10 - FIRST YEAR PHASE TEST-3 ADV (2021 P2) EX DT. 29-11-2021
29. The degree of unsaturation is x and the sum of s-character of all sp3 hybridized carbons is y in
following compound. Find y x .

Question Stem
The isomers which are having same molecular formula but differ in their structure are known as
structural isomers. These can be of various types such as chain, positional, functional, metamers and
tautomers.
30. The no. of possible structural isomers can be written for C6H14
31. The sum of principle quantum numbers of two orbitals of atoms which involved in   bond in
functional isomer of propanal
PARAGRAPH 1
Different spatial arrangements of the atoms that result from restricted rotation about a single bond are
conformers. N-Butane has four conformers eclipsed, fully eclipsed, gauch and anti. The stability order of these
conformers are as follows
anti > gauch > eclipsed > fully eclipsed
32. Which one of the following is most stable conformer?

CH3 CH3
CH3 H H CH3
(B)
(A)
H H H H
H H
CH3 H
H H H
(C) (D)
H H
H CH3
CH3 H CH3
33. Which one of the following is the most stable conformer?

CH3 CH3
OH H H CH3
(B)
(A)
H OH H OH
CH3 OH
CH3 OH
H OH H CH3
(C) (D)
H OH H CH3
CH3 OH
PARAGRAPH 2
Isomers which are nonsuperimposable mirror images of each other are called enantiomers. All optically active
compounds exhibit enantiomerism. The stereoisomers which are not mirror images of each other are called
diastereomers. Enantiomers are always chiral molecules whereas diastereomers may or may not be chiral
configuration of the compound having no element of symmetry is always chiral. Chiral molecule may or may
not contain chiral carbon.
34. Which of the following compounds are not chiral?
Br
CHO H3C C2H5 CH3 H3C CH3
H OH C C C C C C C
CH2OH H H H H3C H
Cl
(A) (B) (C) (D)
35. Which of the following pairs are diastereomers?
COOH COOH
CHO CHO
H C Br and Br C H
(A) H C OH and HO C H (B)
Br C H H C Br
CH3 CH3
C6H5 C6H5
H3C CH3 H3C H OH

HO H H
(C) C C and C C (D) and
H H H3C COOH H3C COOH
H CH3
36. The sum of locants of the substituents in the IUPAC name of the CH3
following compound is _______.
H3C
3 2
37. No. of sp hybridized atoms are ‘x’, no. of sp hybridized atoms are ‘y’. Then (x – y) is ?
OH
38. How many functional groups are present in the following compounds
NH2 O
H OH
NH
O
O O O
O O
 
n  
For any positive integer n, let Sn : 0,   defined by Sn  x :  tan1 
4x
39. 
k 1  2

 4  4k  1 x 
2

  
where for any x   , tan1  x   ,  and cot1  x  0,  . Then which of the following is (are)
 2 2 
TRUE?
  20x 
(A) S5  x   cot1   , for all x  0
2  4  11x 2 
(B) lim tan Sn  x  

2
, for all x  0
n x

(C) The equation S1  x   has no real roots in 0,
4
(D) lim 7x tan S3  x   4
x
40. Let f  x  sin1 e x   sin1 ex  , where . denotes ‘Greatest Integer Function’. Then which of the
   
following is/are TRUE?
(A) Domain of f  x is  loge 2, loge 2
 
 
(B) Range of f  x is 
 , 


2 
 

(C) f  x is continuous at x  0
(D) The equation cos1 x  max range of f  x has only one solution
41. Let f  x and g x be two function such that f g x is one-one function, then which of the following
is/are TRUE?
(A) g x must be one-one (B) f  x must be one-one
(C) f  x need not be one-one (D) g x need not be one-one
  x  1 
42. If lim 4x   tan1    y  3y  4 , then y can be equal to
2
x  4  x  2 
(A) 1 (B) –1 (C) 2 (D) –2
 sin x 
43. For a fixed integer m, lim m  is equal
x0  x 
(A) m  1 if m  0 (B) m  1 if m  0 (C) m if m  0 (D) m if m  0
   
x  1   1 if  1  x  2, x  0
44. The function f  x      2   2  is

 1 if x  0
(where t denotes the fractional part of t)
1
(A) continuous at x  1 (B) discontinuous at x 
2
3
(C) continuous at x  (D) discontinuous at x  0
2
Question Stem
5x
Let the function f : 0,1   be defined by f  x   for all x  0,1 . Then,
5x  5
1 2 3  19 

45. The value of f    f    f    ......  f    f 1 is
10  10  10   20 
1  r  
f    f  2n  r  is equal to

2n

46. The value of lim 
n  n   n   n 
r 1 
Question Stem
a sin x  bx  cx 2  x 3
If lim exists finitely and equals to L, then
x0 2x 2 log
e 1  x  2x3  x 4
47. The value of 40L is equal to
48. The value of 2a  b  c is equal to
Question Stem
Consider the functions
 x  x  if 0  x  2
f  x    ,
 x  1 x  if 2  x  3

 x 1
 if x  Q
where . denotes the ‘Greatest Integer Function’ and g x  
 2

x  x  2 if x  Q

Then,
49. The number of points of discontinuity of f  x is
50. The sum of all possible values of x for which g x is continuous is
PARAGRAPH-1
 ab  1  bc  1  ca  1

Let G  cot1   cot1   cot1 
 a  b   b  c   c  a 
, where a,b,c are distinct positive real numbers.
Then,
51. If a  b  c , the value of G equals to


(A) 0 (B)  (C) (D) 2
2
52. If a  b  c , the value of G equals to

 3
(A) (B)  (C) (D) 2
2 2
PARAGRAPH-2
Let f :    and g :   B be two functions such that f  x   2f 1 x  2  x 2 for all x   and
g x  tan1 3f  x    for all x   .
  
53. If B   ,  and g is a surjection then  is equal to
 4 2 
(A) –1 (B) 1 (C) 2 (D) 3
  
54. If   0 and B   ,  then the function g x is
 2 2 
(A) one-one but not onto (B) onto but not one-one
(C) bijection (D) neither one-one nor onto
55. The number of real roots of the equation 2x 2  x 2  1  x  1  0 is _____
56. Let the functions f : 1,1   and g : 1,1  1,1 be defined by

f  x  3x  1  3x  1 and g x  x   x  ,
where  x  denotes the greatest integer less than or equal to x. Let fog : 1,1   be the composite
function defined by fog x  f g x .
Suppose c is the number of points of discontinuity of fog x in the interval 1,1 . Then, the value of
8c is
1 x  x
57. For some     0,1 , if lim exists and equals to L, where  t  denotes greatest integer
x 0   x   x
less than or equal x, then L is equal to

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Instructions to the Candidates

SECTION–1 (Maximum Marks: 24)

4. Four particles of mass m each and kept at the vertices of

5. Choose the incorrect statements from the following:

6. Two satellites S1 and S2 are revolving around the earth is coplanar

(A) the angular velocity of S2 as observed by S1 at t  12h is 0.468 rad s1

SECTION–2 (Maximum Marks: 12)

Question Stem for Question Nos. 7 and 8

Question Stem for Question Nos. 9 and 10

A solid sphere of a uniform density and radius 4 units is

9. Find the gravitational force at the point B 2,0,0 is ______N.

Question Stem for Question Nos. 11 and 12

11. The ratio of their kinetic energies will be _________

SECTION–3 (Maximum Marks: 12)

13. Assume a particle of mass m is released from point A as shown in the

14. In the above problem time taken by particle to move from C to D is

A long slendor rod of mass 2 kg and length 4m is placed on a smooth

15. Velocity of the centre of the rod after collision is

16. Angular velocity of the rod after collision is

SECTION–4 (Maximum Marks: 12)

17. A satellite of mass m is orbiting in an orbit of radius r1 . If it is given an

18. In the figure, a sphere of radius 2m is rolling

19. A uniform disc of surface mass density  exists in

SECTION–1 (Maximum Marks: 24)

20. Which of the following statements are correct?

(A) the number of stereoisomers obtained by the mono chlorination of 2-methylbutane is 4

(D) the IUPAC name of the following compound is 1-Bromo-4- Br

21. Which of the following statements are correct?

(B) the cis-1,2-dimethyl cyclopropane is a meso compound

22. Which of the following for the structures is/are correct?

H OH H CH3 H3C OH HO CH=CH2

CH=CH2 CH=CH2 H CH3

(A) (B) (C) (D)

23. Which of the following is/are correct?

24. Which of the following is/are correct?

25. Which of the following is/are correct?

SECTION–2 (Maximum Marks: 12)

Question Stem for Question Nos. 26 and 27

Question Stem for Question Nos. 28 and 29

28. Find the percentage of P-character of third carbon in

Question Stem for Question Nos. 30 and 31

SECTION–3 (Maximum Marks: 12)

32. Which one of the following is most stable conformer?

33. Which one of the following is the most stable conformer?

34. Which of the following compounds are not chiral?

35. Which of the following pairs are diastereomers?

H3C CH3 H3C H OH

SECTION–4 (Maximum Marks: 12)

SECTION–1 (Maximum Marks: 24)

(B) lim tan Sn  x  

SECTION–2 (Maximum Marks: 12)

Question Stem for Question Nos. 45 and 46

1 2 3  19 

Question Stem for Question Nos. 47 and 48

47. The value of 40L is equal to

48. The value of 2a  b  c is equal to

Question Stem for Question Nos. 49 and 50

49. The number of points of discontinuity of f  x is