Safety Data Sheet

Issue Date: 01-Feb-2018 Revision Date: 01-Feb-2018 Version 1

1. IDENTIFICATION

Product Identifier
Product Name Carbofen 5055

Other means of identification

SDS # PTR-001

UN/ID No UN1824

Recommended use of the chemical and restrictions on use

Recommended Use Concrete air entrainer and asphalt emulsifier.

Details of the supplier of the safety data sheet

Manufacturer Address
Polytrade
Av Republica Argentina 1237
Sala 901 Curtibia-PR Brazil 80620-010
polytrade.com.br

Emergency Telephone Number

Company Phone Number +55(41)4042-8888
Emergency Telephone (24 hr) +55(41)4042-8888

2. HAZARDS IDENTIFICATION

Appearance Reddish brown liquid Physical state Liquid Odor Pine

Classification

Acute toxicity - Oral Category 4

Skin corrosion/irritation Category 1 Sub-category B
Serious eye damage/eye irritation Category 1
Skin sensitization Category 1

Signal Word
Danger

Hazard statements
Harmful if swallowed
May cause an allergic skin reaction
Causes severe skin burns and eye damage

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Precautionary Statements - Prevention

Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Do not breathe dusts or mists
Wear protective gloves/protective clothing/eye protection/face protection
Contaminated work clothing must not be allowed out of the workplace

Precautionary Statements - Response

Immediately call a POISON CENTER or doctor
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a POISON CENTER or doctor
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
Wash contaminated clothing before reuse
If skin irritation or rash occurs: Get medical advice/attention
IF INHALED: Remove person to fresh air and keep comfortable for breathing
Immediately call a POISON CENTER or doctor
IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell
Rinse mouth
Do NOT induce vomiting

Precautionary Statements - Storage

Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Other hazards
Harmful to aquatic life with long lasting effects

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Weight-%
Dark Pinewood Resin 65997-04-8 50-60
Water 7732-18-5 30-40
Sodium hydroxide 1310-73-2 1-10

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret. **

4. FIRST AID MEASURES

First Aid Measures

General Advice Immediately call a poison center or doctor/physician.

Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Immediately call a poison center or doctor/physician.

Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
advice/attention.

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Inhalation Remove person to fresh air and keep comfortable for breathing. Immediately call a poison
center or doctor/physician.

Ingestion Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce
vomiting.

Most important symptoms and effects

Symptoms Harmful if swallowed. May cause an allergic skin reaction. Causes severe skin burns and
eye damage.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media Not determined.

Specific Hazards Arising from the Chemical

Not determined.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal Precautions Use personal protective equipment as required.

Environmental precautions

Environmental precautions Avoid dispersion into municipal water or river courses. See Section 12 for additional
Ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Clean-Up Clean up spills in a manner that does not disperse liquid into ground.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or
smoke when using this product. Do not breathe dusts or mists. Wear protective
gloves/protective clothing and eye/face protection. Contaminated work clothing must not be
allowed out of the workplace.

Conditions for safe storage, including any incompatibilities

Storage Conditions Store locked up.

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Incompatible Materials Acids. Flame, heat and electric discharge.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Sodium hydroxide Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3
1310-73-2 (vacated) Ceiling: 2 mg/m3 Ceiling: 2 mg/m3

Appropriate engineering controls

Engineering Controls Showers. Eyewash stations. Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses.

Skin and Body Protection Plastic gloves.

Respiratory Protection Use respiratory protection.

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Physical state Liquid

Appearance Reddish brown liquid Odor Pine
Color Reddish-brown Odor Threshold Not determined

Property Values Remarks • Method

pH 10.5-11.5
Melting point / freezing point 0 °C / 32 °F
Boiling Point / Boiling Range 100 °C / 212 °F
Flash Point 267 °C / 512.6 °F
Evaporation Rate N/A
Flammability (Solid, Gas) Liquid-Not applicable
Flammability Limit in Air
Upper Flammability Limit N/A
Lower Flammability Limit N/A
Vapor Pressure N/A
Vapor Density N/A
Relative Density 1.10-1.20 g/ml
Water Solubility Yes
Solubility in other solvents Soluble in ethanol
Partition Coefficient Not determined
Autoignition temperature N/A
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined

Other Information
VOC Content 0%

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10. STABILITY AND REACTIVITY

Reactivity
Not reactive under normal conditions.

Chemical Stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Conditions to Avoid
Incompatible Materials.

Incompatible Materials
Acids. Flame, heat and electric discharge.

Hazardous Decomposition Products

Product combustion can release irritating gases, smoke and dioxide.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Eye Contact Avoid contact with eyes.

Skin Contact Avoid contact with skin.

Inhalation Do not inhale.

Ingestion Harmful if swallowed.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Dark Pinewood Resin > 2000 mg/kg (Rat) - -
65997-04-8
Sodium hydroxide 140 - 340 mg/kg (Rat) = 1350 mg/kg (Rabbit) -
1310-73-2

Information on physical, chemical and toxicological effects

Symptoms Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Causes severe skin burns.

Serious eye damage/eye Causes severe eye damage.

irritation

Sensitization May cause an allergic skin reaction.

Carcinogenicity Based on the information provided, this product does not contain any carcinogens or
potential carcinogens as listed by OSHA, IARC or NTP.

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Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document.
ATEmix (oral) 1,182.00 mg/kg
ATEmix (dermal) 7,594.00 mg/kg

12. ECOLOGICAL INFORMATION

Ecotoxicity
Harmful to aquatic life with long lasting effects.

Component Information

Chemical Name Algae/aquatic plants Fish Crustacea

Dark Pinewood Resin 3.0 - 8.0: 48 h Leuciscus idus mg/L
65997-04-8 LC50
Sodium hydroxide 45.4: 96 h Oncorhynchus mykiss
1310-73-2 mg/L LC50 static

Persistence/Degradability
Not determined.

Bioaccumulation
Not determined.

Mobility
Not determined

Other Adverse Effects

Not determined

13. DISPOSAL CONSIDERATIONS

Waste Treatment Methods

Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.

Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.

California Hazardous Waste Status

Chemical Name California Hazardous Waste Status

Sodium hydroxide Toxic
1310-73-2 Corrosive

14. TRANSPORT INFORMATION

Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.

DOT
UN/ID No UN1824
Proper Shipping Name Sodium hydroxide, solution
Hazard Class 8
Packing Group II

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IATA
UN/ID No UN1824
Proper Shipping Name Sodium hydroxide, solution
Hazard Class 8
Packing Group II

IMDG
UN/ID No UN1824
Proper Shipping Name Sodium hydroxide, solution
Hazard Class 8
Packing Group II

15. REGULATORY INFORMATION

International Inventories

Chemical Name TSCA DSL/NDSL EINECS/E ENCS IECSC KECL PICCS AICS
LINCS
Dark Pinewood Resin Present X X X Present X
Sodium hydroxide Present X X Present X Present X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations

CERCLA

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)

Sodium hydroxide 1000 lb RQ 1000 lb final RQ
1310-73-2 RQ 454 kg final RQ

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

CWA (Clean Water Act)

Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Quantities Substances
Sodium hydroxide 1000 lb X

US State Regulations

California Proposition 65
This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania

Sodium hydroxide X X X
1310-73-2

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16. OTHER INFORMATION

NFPA Health Hazards Flammability Instability Special Hazards

Not determined Not determined Not determined Not determined
HMIS Health Hazards Flammability Physical hazards Personal Protection
Not determined Not determined Not determined Not determined

Issue Date: 01-Feb-2018

Revision Date: 01-Feb-2018
Revision Note: New format

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

End of Safety Data Sheet

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