OLED Report
OLED Report
OLED Report
CHAPTER 1
INTRODUCTION
Scientific research in the area of semiconducting organic materials as the active substance in light
emitting diodes (LEDs) has increased immensely during the last four decades. Organic semiconductors
was first reported in the 60s and then the materials were only considered to be merely a scientific
curiosity. (They are named organic because they consist primarily of carbon, hydrogen and oxygen).
However when it was recognized in the eighties that many of them are photoconductive under visible
light, industrial interests were attracted. Many major electronic companies, such as Philips and
Pioneer, are today investing a considerable amount of money in the science of organic electronic and
optoelectronic devices. The major reason for the big attention to these devices is that they possibly
could be much more efficient than today's components when it comes to power consumption and
produced light.
Common light emitters today, Light Emitting Diodes (LEDs) and ordinary light bulbs consume more
power than organic diodes do. And the strive to decrease power consumption is always something of
matter. Other reasons for the industrial attention are ie. that eventually organic full color displays will
replace today's liquid crystal displays (LCDs) used in laptop computers and may even one day replace
our ordinary CRT-screens. Organic light-emitting devices (OLEDs) operate on the principle of
converting electrical energy into light, a phenomenon known as electroluminescence. They exploit the
properties of certain organic materials which emit light when an electric current passes through them.
In its simplest form, an OLED consists of a layer of this luminescent material sandwiched between two
electrodes.
When an electric current is passed between the electrodes, through the organic layer, light is emitted
with a colour that depends on the particular material used. In order to observe the light emitted by an
OLED, at least one of the electrodes must be transparent.
When OLEDs are used as pixels in flat panel displays they have some advantages over backlit active-
matrix LCD displays greater viewing angle, lighter weight, and quicker response. Since only the part
of the display that is actually lit up consumes power, the most efficient OLEDs available today use
less power.
Based on these advantages, OLEDs have been proposed for a wide range of display applications
including magnified micro displays, wearable, head-mounted computers, digital cameras, personal
digital assistants, smart pagers, virtual reality games, and mobile phones as well as medical,
automotive, and other industrial applications.
CHAPTER 2
Conductive materials are substances that can transmit electrical charges. Traditionally, most known
conductive materials have been inorganic. Metals such as copper and aluminum are the most familiar
conductive materials, and have high electrical conductivity due to their abundance of delocalized
electrons that move freely throughout the inter-atomic spaces. Some metallic conductors are alloys of
two or more metal elements, common examples of such alloys include steel, brass, bronze, and
pewter.
In the eighteenth and early nineteenth centuries, people began to study the electrical conduction in
metals. In his experiments with lightning, Benjamin Franklin proved that an electrical charge travels
along a metallic rod. Later, Georg Simon Ohm discovered that the current passing through a
substance is directly proportional to the potential difference, known as Ohm's law. This relationship
between potential difference and current became a widely used measure of the ability of various
materials to conduct electricity. Since the discovery of conductivity, studies have focused primarily
on inorganic conductive materials with only a few exceptions.
Henry Letheby discovered the earliest known organic conductive material in 1862. Using anodic
oxidation of aniline in sulfuric acid, he produced a partly conductive material that was later identified
as polyaniline, In the 1950s, the phenomenon that polycyclic aromatic compounds formed semi-
conducting charge-transfer complex salts with halogens was discovered, showing that some organic
compounds could be conductive as well.
More recent work has expanded the range of known organic conductive materials. A high
conductivity of 1 S/cm (S=Siemens) was reported in 1963 for a derivative of tetraiodopyrrole. In
1972, researchers found metallic conductivity (conductivity comparable to a metal) in the charge-
transfer complex TTF-TCNQ.
ORGANIC ELECTRONICS:
Organic electronics is a field of materials science concerning the design, synthesis, characterization,
and application of organic small molecules or polymers that show desirable electronic properties such
as conductivity. Unlike conventional inorganic conductors and semiconductors, organic electronic
materials are constructed from organic (carbon-based) small molecules or polymers using synthetic
strategies developed in the context of organic and polymer chemistry. One of the benefits of organic
electronics is their low cost compared to traditional inorganic electronics.
CONDUCTIVE MATERIALS:
Conductive small molecules are usually used in the construction of organic semiconductors, which
exhibit degrees of electrical conductivity between those of insulators and metals. Semiconducting small
molecules include polycyclic aromatic compounds such as pentacene, anthracene and rubrene.
Conductive polymers are typically intrinsically conductive. Their conductivity can be comparable to
metals or semiconductors. Most conductive polymers are not thermo formable, during production.
However they can provide very high electrical conductivity without showing similar mechanical
properties to other commercially available polymers. Both organic synthesis and advanced dispersion
techniques can be used to tune the electrical properties of conductive polymers, unlike typical inorganic
conductors. The well-studied class of conductive polymers is the so-called linear-backbone "polymer
blacks" inchading polyacetylene, polypyrrole, polyaniline, and their copolymers.
Poly (p-phenylene vinylene) and its derivatives are used for electroluminescent semiconducting
polymers. Poly (3-alkythiophenes) are also a typical material for use in solar cells and transistors.
There are four major application areas, displays, lighting, photovoltaics and integrated smart systems.
While OLAE technology is currently used in many manufacturing processes, new applications are
entering the marketplace rapidly.
While organic light emitting diodes (OLEDs) are already used commercially in displays of mobile
devices and significant progress has been made in applying organic photovoltaic cells to light-weight
flexible fabrics to generate low-cost solar energy, a brand new range of applications is possible such as
biomedical implants and disposable biodegradable RFID packaging tags.
In addition, low cost organic solar cells have the potential to drive down the cost of photovoltaics to
levels, which are not achievable with mono or poly-crystalline solar cells. Similarly, organic light
emitting diodes will revolutionize current lighting applications, significantly reducing CO2 impact.
Also, smart devices incorporating organic and printed circuits, sensors and energy sources will enable
new approaches in logistics and consumer packaging, and new flexible displays with exceptionally
low energy consumption will be used anywhere and anytime.
The possibilities are limitless as the technology is evolving at such a rapid pace. Industrial
designers across all sectors and markets should be aware of the technology and looking at ways of
harnessing its power and benefits into new product design.
Possible applications could include:
1. Memory or logic devices
2. Detectors, lasers and light emitters
3. Information displays advertising billboards and other media
4. Micro lenses
5. Batteries
6. Power or light sources
7. Subsystem packaging
8. Image patterning
9. Electrical or optical fibers
10. Transistors
11. Photoconductors
ORGANIC LED:
1. Easy to process
4. They can possess to low-cost substrates (ie., plastic, paper even cloth)
The components in an OLED differ according to the number of layers of the organic material.
There is a basic single layer OLED, two layer and also three layer OLED's. As the number of layers
increase the efficiency of the device also increases. The increase in layers also helps in injecting
charges at the electrodes and thus helps in blocking a charge from being dumped after reaching the
opposite electrode. Any type of OLED consists of the following components.
1. An emissive layer
2. A conducting layer
3. A substrate
CHAPTER 3
As previously mentioned, OLEDs are an emissive technology, which means they emits light
instead of diffusing or reflecting a secondary source, as LCDs and LEDs currently do. Below is a
graphic explanation of how the technology works,
3.2 WORKING:
The organic light emitting diode (OLED) is a p-n diode, in which charge-carriers (e-h pairs)
recombine to emit photons in an organic layer. The thickness of this layer is approximately 100 mm
(experiments have shown that 70 nm is an optimal thickness). When an electron and a hole
recombine, an excited state called an exciton is formed. Depending on the spin of the e-h pair, the
excitation is either a singlet or a triplet. An electron can have two different spins, spin up and spin
down. When the spin of two particles is the same, they are said to be in a spin- paired, or a triplet
state, and when the spin is opposite they are in a spin-paired singlet state.
On the average, one singlet and three triplets are formed for every four electron-hole pairs, and this
is a big inefficiency in the operation of the diodes. A singlet state decays very quickly, within a few
nanoseconds, and thereby emits a photon in a process called fluorescence. A triplet state, however,
is much more long-lived , and generally just produce heat. One method of improving the
performance is to add a phosphorescent material to one of the layers in the OLED. This is done by
adding a heavy metal such as iridium or platinum. The excitation can then transfer its energy to a
phosphorescent molecule which in turn emits a photon. It is however a problem that few
phosphorescent materials are efficient emitters at room temperature.
There have been devices manufactured which transforms both singlet and tripletstates in a host to a
singlet state in the fluorescent dye. This is done by using a phosphorescent compound which both the
singlets and triplets transfer their energy to, after which the compound transfer its energy to a
fluorescent material which then emits light.
Using one organic layer has some problems associated with it. The electrodes energy levels have to
be matched very closely, otherwise the electron and hole currents will not be properly balanced. This
leads to a waste in energy since charges can then pass the entire structure without recombining, and
this lowers the efficiency of the device. With two organic layers, the situation improves dramatically.
Now the different layers can be optimized for the electrons and holes respectively. The charges are
blocked at the interface of the materials, and "waits" there for a "partner".
Laboratory set up of a high-precision inkjet printer for making polymer OLED displays
The biggest part of manufacturing OLEDs is applying the organic layers to the substrate. This can be
done in three ways
1. Vacuum deposition or vacuum thermal evaporation (VTE) - In a vacuum chamber, the organic
molecules are gently heated (evaporated) and allowed to condense as thin films onto cooled
substrates. This process is expensive and inefficient.
3. Inkjet printing-With inkjet technology, OLEDs are sprayed onto substrates just like inks are
sprayed onto paper during printing. Inkjet technology greatly reduces the cost of OLED
manufacturing and allows OLEDs to be printed onto very large films for large displays like 80-
inch TV screens or electronic billboards.
1. Passive-matrix OLED.
2. Active-matrix OLED.
3. Transparent OLED.
4. Top-emitting OLED.
5. Foldable OLED.
6. White OLED.
1. PASSIVE-MATRIX OLED (PMOLED):
PMOLEDs have strips of cathode, organic layers and strips of anode. The anode strips are
arranged perpendicular to the cathode strips. The intersections of the cathode and anode make up
the pixels where light is emitted. External circuitry apples current to selected strips of anode and
cathode, determining which pixels get turned on and which pixels remain off. Again, the
brightness of each pixel is proportional to the amount of applied current.
PMOLEDs are easy to make, but they consume more power than other types of OLED, mainly
due to the power needed for the external circuitry, PMOLEDs are most efficient for text and
icons and are best suited for small screens (2- to 3-inch diagonal) such as those you find in CELL
PHONES, PDA's and MP3 Players. Even with the external circuitry, passive-matrix OLEDs
consume less battery power than the LCDs that currently power these devices.
AMOLEDs have full layers of cathode, organic molecules and anode, but the anode layer overlays a
thin film transistor (TFT) array that forms a matrix. The TFT array itself is the circuitry that
determines which pixels get turned on to form an image.
AMOLEDs consume less power than PMOLEDs because the TFT array requires less power than
external circuitry, so they are efficient for large displays. AMOLEDs also have faster refresh rates
suitable for video. The best uses for AMOLEDs are computer monitors, large-screen TVs and
electronic signs or billboards.
1. Self-Emissive Pixels: Each pixel in an AMOLED display emits its own light when a current
passes through it, eliminating the need for a backlight and resulting in true black colors and
high contrast ratios.
2. Flexible Designs: AMOLED displays can be made on flexible substrates, making them
suitable for curved and foldable screens.
3. Thin and Lightweight: AMOLED displays are typically thin and lightweight, which is
beneficial for portable devices such as smartphones and smartwatches.
3. TRANSPARENT OLED:
Transparent OLEDs have only transparent components (substrate, cathode and anode) and, when
turned off, are up to 85 percent as transparent as their substrate. When a transparent OLED display
is turned on, it allows light to pass in both directions. A transparent OLED display can be either
active or passive-matrix. This technology can be used for heads-up displays.
1. Self-Emissive Pixels: Each pixel in an AMOLED display emits its own light when a current
passes through it, eliminating the need for a backlight and resulting in true black colors and
high contrast ratios.
2. Flexible Designs: AMOLED displays can be made on flexible substrates, making them
suitable for curved and foldable screens.
3. Energy Efficiency: TOLEDs are energy-efficient because they do not require a backlight,
relying instead on self-emissive pixels.
4. Design Flexibility: Transparent OLED displays can be made in various shapes and sizes,
making them suitable for creative and novel applications in retail, architecture, automotive, and
more.
4. TOP-EMITTING OLED:
Top-emitting OLEDs have a substrate that is either opaque or reflective. They are best suited to
active-matrix design. Manufacturers may use top-emitting OLED displays in SMART CARDS.
1. Improved Light Efficiency: Top-emitting OLEDs can be designed to maximize light efficiency,
as the emitted light does not pass through the substrate or TFT layer. This can lead to brighter
displays and improved power efficiency.
2. Compatibility with Different Substrates: TEOLEDs can be used with a variety of substrates,
including opaque ones, such as silicon, which are often used in integrated circuits. This allows
for the integration of OLED displays with other electronic components.
3. High Pixel Density: TEOLEDs allow for high pixel density, which can result in higher
resolution displays, particularly when used with active-matrix driving techniques.
5. FOLDABLE OLED:
Foldable OLEDs have substrates made of very flexible metallic foils or plastics. Foldable OLEDs
are very lightweight and durable. Their use in devices such as cell phones and PDAs can reduce
breakage, a major cause for return or repair. Potentially, foldable OLED displays can be attached
to fabrics to create "smart" clothing, such as outdoor survival clothing with an integrated computer
chip, cell phone, GPS receiver into it.
1. Flexibility: Foldable OLEDs are built on flexible substrates such as plastic or metal foil, which
allows the display to bend or fold. This flexibility opens up possibilities for new form factors in
devices.
2. Innovative Designs: Foldable OLEDs enable the development of novel devices with unique
designs, such as folding smartphones, tablets that can be compacted for easier transport, or even
wearable devices that can conform to the user's body.
3. Vibrant Colors and High Contrast: Like traditional OLEDs, foldable OLEDs offer vibrant
colors, deep blacks, and high contrast ratios, resulting in excellent display quality.
4. Energy Efficiency: Foldable OLEDs do not require a backlight because the pixels themselves
emit light, which helps in saving power.
6. WHITE OLED:
White OLEDs emit white light that is brighter, more uniform and more energy efficient than that
emitted by fluorescent lights. White OLEDs also have the true-color qualities of incandescent
lighting. Because OLEDs can be made in large sheets, they can replace fluorescent lights that are
currently used in homes and buildings. Their use could potentially reduce energy costs for lighting.
2. Wide Color Gamut: By filtering the white light through RGB color filters, WOLED displays can
achieve a wide color gamut and good color accuracy, producing vivid and realistic colors.
3. Simplified Manufacturing: The use of a single white light-emitting layer can simplify the
manufacturing process compared to using multiple layers for different colors.
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than 1 gm more than the liquid telephone. 10 gm weak degree.
crystal panel in the case of one
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Answer time Several us Several ns
A wide use of temperature range 86 °C~ -40 °C ~-10 °C
CHAPTER 4
4.1 ADVANTAGES
1. The different manufacturing process of OLEDs lends itself to several advantages over flat-panel
displays made with LCD technology.
2. Lower cost in the future: OLEDs can be printed onto any suitable substrate by an inkjet printer
or even by screen printing, theoretically making them cheaper to produce than LCD or plasma
display. However, fabrication of the OLED substrate is more costly than that of a TFT LCD,
until mass production methods lower cost through scalability.
3. Light weight & flexible plastic substrates: OLED displays can be fabricated on flexible plastic
substrates leading to the possibility of flexible organic light-emitting diodes being fabricated or
other new applications such as roll-up displays embedded in fabrics or clothing.
4. Wider viewing angles & improved brightness: OLEDs can enable a greater artificial contrast
ratio (both dynamic range and static, measured in purely dark conditions) and viewing angle
compared to LCDs because OLED pixels directly emit light.
5. Better power efficiency: LCDs filter the light emitted from a back light.
6. Response time: OLEDs can also have a faster response time than standard LCD screens.
4.2 DISADVANTAGES
1. OLED seem to be the perfect technology for all types of displays; however, they do have some
problems, including:
3. Power consumption: While an OLED will consume around 40% of the power of an LCD
displaying an image
4. Screen burn-in: Unlike displays with a common light source, the brightness of each OLED pixel
fades depending on the content displayed. The varied lifespan of the organic dyes can cause a
discrepancy between red, green, and blue intensity. This leads to image persistence, also known
as burn in.
5. UV sensitivity: OLED displays can be damaged by prolonged exposure to UV light. The most
pronounced example of this can be seen with a near UV laser (such as a Bluray pointer) and can
damage the display almost instantly with more than 20mW leading to dim or dead spots where
the beam is focused.
6. Color balance issues: Additionally, as the OLED material used to produce blue light degrades
significantly more rapidly than the materials that produce other colors, blue light output will
decrease relative to the other colors of light. This differential color output change will change the
color balance of the display and is much more noticeable than a decrease in overall luminance.
7. Water damage: Water can damage the organic materials of the displays. Therefore, improved
sealing processes are important for practical manufacturing. Water damage may especially limit
the longevity of more flexible displays.
4.3 APPLICATIONS:
1. Mobile Phones Mobile phones were the first to adopt AMOLED displays and is the largest market
for OLEDs today.
2. OLED TVS-OLED TVs had begun shipping in 2013 but their prices are still very high.
3. Digital Cameras- Several compact and high-end cameras use AMOLED displays that offer rich
colors and high contrast and brightness. Kodak was the first to release a digital camera with an
OLED display in March 2003, the Easy Share LS633.
4. OLED Lamps- OLED lamps are currently very expensive, but already several companies are
offering these in the premium lighting category.
2. Scroll Laptop:
CONCLUSION
Performance of organic LEDs depend upon many parameters such as electron and hole mobility,
magnitude of applied field, nature of hole and electron transport layers and excited life-times. Organic
materials are poised as never before to transform the world IF circuit and display technology. Major
electronics firms are betting that the future hokis tremendous opportunity for the low cost and sometimes
surprisingly high performance offered by organic electronic and optoelectronic devices.
Organic Light Emitting Diodes are evolving as the next generation of light sources. Presently researchers
have been going on to develop a 1.5 emitting device. This wavelength is of special interest for
telecommunications as it is the low-loss wavelength for optical fiber communications. Organic full-colour
displays may eventually replace liquid crystal displays for use with lap top and even desktop computers.
Researches are going on this subject and it is sure that OLED will emerge as future solid state light source.
BIBLIOGRAPHY
TEXT BOOKS:
1. "Organic Light Emitting Diodes (OLEDs): Materials, Devices and Applications" by Alastair
Buckley, 2nd Edition, 2013.
2. "Organic Light Emitting Diodes (OLEDs): Materials, Devices and Applications" by Franky So,
1st Edition, 2006.
4. "Organic Light Emitting Diodes: Principles, Characteristics & Processes" by Jan Kalinowski, 1st
Edition, 2014.
5. "OLED Display Fundamentals and Applications" by Takatoshi Tsujimura, 1st Edition, 2017.
WEBSITES:
6. http://jalopnik.com/5154953/samsung-transparent-oled-display-pitched-as-automotive-hud.
7. http://www.pocket-lint.com/news/news.phtml/23150/24174/samsung-say-oled-not.
8. http://www.voidspace.org.uk/technology/top_ten_phone_techs.shtml#keep-your-eye-on.
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