(@bohring - Bot) GTA-14 P2 - Q.Paper

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec: Sr.Super60_Elite, Target & LIIT-BTs Paper -2(Adv-2023-P2-Model) Date: 08-02-2024
Time: 02.30Pm to 05.30Pm GTA-14 Max. Marks: 180
08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P2)_GTA-14_Syllabus

MATHEMATICS : TOTAL SYLLABUS

PHYSICS : TOTAL SYLLABUS

CHEMISTRY : TOTAL SYLLABUS

Name of the Student: ___________________ H.T. NO:


Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P-2)_GTA-14_Q.P

JEE‐ADVANCE‐2023‐P2‐Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 1 – 4) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 5 – 7) +4 -2 3 12
with partial mark
Sec – III(Q.N : 8 – 13) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 14 – 17) Paragraph NUMERICAL VALUE 3 0 4 12
Total 17 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 18 – 21) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 22 – 24) +4 -2 3 12
with partial mark
Sec – III(Q.N : 25 – 30) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 31 – 34) Paragraph NUMERICAL VALUE 3 0 4 12
Total 17 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 35 – 37) Questions with Single Correct Choice +3 -1 4 12
Questions with Multiple Correct Choice
Sec – II(Q.N : 38 – 41) +4 -2 3 12
with partial mark
Sec – III(Q.N : 42 – 47) Questions with Integer Answer Type +4 0 6 24
Sec – IV(Q.N : 48 – 51) Paragraph NUMERICAL VALUE 3 0 4 12
Total 17 60

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MATHEMATICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
1. Consider two circles in a plane with radii 5 and 3 respectively. Distance between centres
of these two circles is 10. If R1 is radius of circle passing through 4 points of contact of
direct common tangents of these two circles and R2 is radius of circle passing through 4
R1
points of contact of transverse common tangents then ?
R2
5 3 5 25
A) B) 2 C) D)
5 3 3 9

2. A parabola with latus rectum '4a' slides such that it touches the positive coordinate axes.
The locus of its focus is
1 1 1 1 1 2
A)   , x  0, y  0 B)   , x  0, y  0
x2 y 2 a2 x2 y 2 a2
1 1 1 1 1 4
C)   , x  0, y  0 D)   , x  0, y  0
x2 y2 2a 2 x2 y2 a2
3. The distance between  0,0  and the tangent to the curve y  e2 x  x 2 drawn at x  0 , is -

1 2 1 2
A) B) C) D)
5 3 3 5
dy
4. Let y  f  x  be a solution of the differential equation  4 x  y  2  with
dx
 x x 
f  0   2 and g  x   max. 1     ,sinx, x  1  , h  x   ln x
 2 2 
[Note:  y  denotes greatest integer function less than or equal to y ]

Area enclosed by the curves y  f  x  , y  g  x  and the y -axis, is

A) 1 B) 2 C) 3 D) 4
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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
 +1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

5. A fair dice is rolled four times. Find the probability that each number is not greater than
the preceding number. When it is known that it shows '1' only once and that too in the
fourth round.
7 1 1 35
A) B) less than C) greater than D)
25 3 3 216
6. Given that a1,a 2 ,a 3 is an A.P in that order, a1  a 2  a 3  15;b1, b2 , b3 is a G.P. in that
order, and b1 b2 b3  27 . If a1  b1,a 2  b2 ,a 3  b3 are positive integers and form a G.P.
in that order, then
A) maximum possible value of a3 is 15  a1,a 2 ,a 3 are positive integer and unequal)
B) minimum possible value of a3 is 3 a1,a 2 ,a 3 are positive integer and unequal)
55  7 61
C) maximum possible value of a3 is 9 
2
55  7 61
D) maximum possible value of a3 is 4 
2

   
2
7. Let  a  1 x 2  3x  1   a  1 x 4  x 2  1  0  x  R , then which of the following
is/are correct?
 1 4 
A) a    , 
 3 3
2
B) Largest possible value of a is
3
C) Number of possible integral values of a is 3
D) Sum of all possible integral values of a is '0'
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.

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Sri Chaitanya IIT Academy 08-02-2024_Sr.Super60_Elite, Target & LIIT-BTs_Jee-Adv(2023-P-2)_GTA-14_Q.P
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
• Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
100 100
1 r
8. Let t100   and S100   , then the value of
   
5 5
r 1 100 Cr r 0 100 Cr

  S  50  
sec  cos 1  100   equals
 150t
  100  
9. The quadratic polynomial P  x  satisfy the equation P  x   P  x  1  2 x  1 x  R . If
the greatest value of P  x  in   ,0 is 2, then value of P  1  P 1 is equal to
6
10. Six points  xi , yi  , i  1,2,.,6 are taken on the circle x  y  4 such that 2 2
 xi  12
i 1
6
and  yi  8 . The line segment joining orthocentre of a triangle made by any three points
i 1
and the centroid of the triangle made by other three points passes through a fixed
points  h, k  , then h  k is __________

11. Let N be the number of arrangements of the letters of the word "LOVEISLIFE" in which
no two alike letters are together and containing the word LOVE. Then N is
12. Let P is a point on the plane ax  by  cz  d . A point Q  ,  ,   is taken on the line OP

2d  a  b  c 
such that OP.OQ  d 2 , then is equal to (where O is origin)
2  2  2
 x3  1 x5 3x  2
 
2
13. Let A   y  1 6 x  2 z  1  and A  3
 
 2 3 9 x  6
 

If f ( x )  tr(B 1) and B  adj A , then global minimum value of f  x  in x   0,6 is p

and it is achieved at ' n ' number of value(s) of x then n  p is equal to

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SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
Paragraph – I
Let A, B, C be 3 sets such that

A   x, y  : x  2cos , y  2sin ,  R

 x 1 y 
B   x, y  :   r, r  R 
 cos2205 sin2205 

C  x, y  : ( x  3) 2  ( y  1) 2 a 2 ; a  R 
Let C1, C2 be the curves represented by A and B respectively while R be the region
represented by C.
14. Points P  x1, y1  and Q  x2 , y2  be such that P, Q  A  B , then point of intersection of

tangents drawn to C1 at P and Q is (    , then find   


15. If minimum value of ' a ' for which A  C  A is  , then length of curve C2 lying in R
corresponding to a   , is
Paragraph – II

 
Let f  x  and g  x  be two functions satisfying f x 4  g  2  x   3 x 2 and

g 2  x  g  x  0 .
1
16. The value of  g 1  x  dx is equal to
1
2
17. The value of   
f x 4 dx is equal to
2
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PHYSICS Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases

18. The electric field of a light wave at a point is E  100


N
C
  
sin 3  1015 t sin 6  1015 t 
where t is time in seconds. This light falls on a metal surface having work function
of 2eV , then maximum possible kinetic energy of photoelectrons is about
A) 16eV B) 7eV C) 6eV D) 4eV
19. In the figure shown the switch S is closed at t  0 . QA , QB and QC are charges on the
capacitor A, capacitor B and capacitor C in the steady state respectively. Choose the
correct statement

A) QA  QB  QC B) QA  QC  QB
C) QC  QA  QB D) QC  QB  QA
20. The space has electromagnetic field which varies with time whose variation is given as
  m
B0 k if 0t 
 qB0
  m 2 m
B   B0 j if t 
 qB0 qB0
 2 m
 0 if  t 
 qB0

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 2 m
0 if 0t 
  qB0
and E  
E k 2 m
if  t 
 0 qB0
A charge particle having mass m and positive charge q is given velocity v0 i at origin at
t  0 sec. The coordinate of point on xy plane when it is passing through plane again is
 2mv0 v0 2mv0   2mv0 v0 mv0 
A)  , ,0  B)  , ,0 
 q E B qB   q E B qB 
 0 0 0   0 0 0 
 mv0 v0 2mv0   mv v0 mv0 
C)  , ,0  D)  0 , ,0 
 q E B qB   q E B qB 
 0 0 0   0 0 0 
21. The refractive index of space changes with y , whose function is given as


 1 if y0

  y   ky 2 if 0  y  y0
 
 if y0  y  2 y0
 y 2
where k and  are positive constant. A light ray is incident at point A as shown in figure.
When the ray reaches to point B, it becomes parallel to xz-plane. Choose the correct
statement.
A)  is independent of k B)  is independent of 
C)  is independent of both k and  D) none of these

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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
+1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.
22. Two coaxial thin pipes (hollow cylinder) of radius R and 2R are having a common
horizontal axis. A thin uniform hollow spherical ball of diameter R is fitted inside them as
shown. The inner surfaces are sufficiently rough so that there is no slipping at contact
surfaces anywhere. The outer pipe is held fixed but inner pipe is free to rotate about its
axis. On slight displacement, the ball starts moving along the gap shown in the downward
direction. All the 3 bodies (both pipes & ball) have same mass of 1 kg each. When ball

reaches the bottom of the pipe [Take g  10 m / s 2 ]

A) Angular speeds of inner pipe and ball about their respective axes is same.
B) Ratio of angular speeds of the inner pipe and sphere about their respective axes is 4:3
C) Ratio of KE of inner pipe to ball is12 : 5
D) Net force on the ball at bottom most position is approximately 7.06 N
23. Two bulbs 25 watt- 100 volt (bulb E) and 100 watt- 200 volt (bulb F) are connected in the
circuit as shown in figure. Choose the correct answer (s).

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A) Heat lost per second in the circuit will be 80 J .


B) Ratio of heat produced per second in bulb E and bulb F will be1:1 .
C) Ratio of heat produced in branch to Branch CD will be 2 :1
D) current drawn from the cell is 0.4 amp .
24. In the shown figure a triangular wedge and a cylinder each having equal mass 'm' are
released from rest. The vertical wall and horizontal surface are frictionless and between
the wedge and the cylinder friction is sufficient to allow cylinder to roll over it. Choose

the correct option(s), just after system is released from rest: [Take : g 10 m /s 2 ]

A) Acceleration of wedge is g/3


B) Minimum value of coefficient of friction between wedge and cylinder for rolling
without slipping is 1/3
C) Minimum value of coefficient of friction between wedge and cylinder for rolling
without slipping is 1/2
D) If m  3 20 kg , the contact force between cylinder and wedge is100 N .

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SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..

25. A dumbbell consists of two balls A and B each of mass m  1 kg and connected by a
spring. The whole system is placed on a smooth horizontal surface as shown in the figure.
8
Initially the spring is at its natural length, the ball B is imparted a velocity v0  m/s
7
in the direction shown. The spring constant of the spring is adjusted so that the length of
the spring at maximum elongation is twice that of the natural length (= 1 meter) of the
spring. Find the spring constant (in N/m) of spring.

26. An LCR series circuit with 100Ω resistance is connected to an a.c. source of r.m.s.
voltage 200 V and angular frequency 300 rad / sec . When only the capacitance is

removed, the current lags behind the voltage by 60 . When only the inductance is

removed, the current leads the voltage by 60 . Calculate the r. m. s. current (in ampere) in
the LCR series circuit.
27. ABC is a triangular frame made out of a metallic wire. BD is a median of the triangular
frame joining the vertex B to the side AC, (also made of the same metallic wire). It is
known that AB  6 cm , BC  8 cm and AC  10 cm . The cross sectional area of the wire

is and its resistivity is 24  10-9 Ωm . The triangle ABC lies in a cylindrical


region of magnetic field such that the intersection of the surface of the cylinder with the
plane containing the frame forms the circumcircle of triangle ABC . The magnetic field in
the region varies at the rate of 0.263 T / s . What is the magnitude of the induced current in
mA in the median BD of the frame?

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28. In the shown figure, a particle of mass  M / 10  strikes the block of mass M (which was
hanging in rest as shown in figure) with velocity v0 and gets attached to it. For what
velocity v0 (in ms 1) , the block B just able to leave the ground?
(Given: M  100gm,K  880 N/m , g  10 m /s 2 )

29. In the arrangement shown, the rod is freely pivoted at point O and is in contact with the
equilateral triangular block (whose front view is shown in figure) which can move on the
horizontal frictionless ground. As the block is given a speed v forward, the rod rotates

about point O . Find the angular velocity of rod in rad / s at the instant when   30 ,
v  20 m/s, a  1 meter.

30. In a typical Young's double silt experiment a point source of monochromatic light is kept
as shown in the figure. If the source is given an instantaneous velocity v  1 mm per
second towards the screen as shown, then the magnitude of instantaneous velocity of

central maxima is n 106 m/s . Find the value of n.


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SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
Paragraph - 1
A container contains three immiscible liquids as shown in the figure. The specific gravity
of liquid 1 and liquid 2 are 0.8 and 1.2 respectively. There is a small hole having area
106 m2 at point P as shown in the figure. Initially hole is closed. The cross-sectional
area of container is 50 cm2 . Assume all liquids to be ideal and neglect any type of
friction between liquid and container. Read the paragraph carefully and answer the
following questions (given that g  9.8 m / s 2 and h  28 cm )

31. The value of h1 / h2 is ……… .


32. At some instant, hole is open, the speed of water coming out from hole just after the
opening of hole is………….. m/s

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Paragraph - 2
A charge Q is distributed in a spherical volume of radius R   2.2 m  , such that the

volume charge density is    / r  where  is a constant and r is the distance of point

from the centre of the sphere. Two point charges Q each are released from rest from
points equidistant from centre inside the sphere as shown in the figure Assume point
charges can easily move inside the dielectric charged sphere without any obstacle.
Relative permittivity of the medium in which charge is distributed (bounded) is unity.
1
[Given  9  109 S.I. unit, Q  4.84  109 C, 2  1.4, In solving use 2  1.4
4 0

when 2 is in numerator. If in denominator then rationalise it then use 2  1.4 in


numerator.]

33. Find the distance 'd' (in metre) between the two charges (  Q) each so that the
configuration is in the static equilibrium.

34. Find the magnitude of electric field in NC1 at a point distance R / 2 from the centre of
the sphere on perpendicular bisector of the line joining the charges (-Q) each.

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CHEMISTRY Max Marks: 60
SECTION–I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
 Negative Marks : −1 In all other cases

35.

Compound A, B and C are respectively :


A) BiCl3 , Bi(OH)3 and BiOCl B) Bi(OH)3 , BiCl3 and BiOCl
C) Bi(OH)3 , BiOCl and Bi(OH)3 D) BiCl3 , BiOCl and BiOCl

36. The main ore of lead is galena  PbS . Lead is extracted from galena ore either by  P 

or  Q  .

Auto-reduction process is:


A) only P B) only Q C) both P and Q D) none of these

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The IR stretching frequencies of free CO , and CO in  V(CO)6  , Cr(CO)6  and
0
37.

 Mn(CO)6  are 2143 cm1,1860 cm1,2000 cm1 and 2090 cm1 , respectively. Then
correct statement about metal carbonyls is : greater the cfse values
A) ' C  O ' bond is strongest in the cation and weakest in the anion.
B) ' C  O ' bond is weakest in the cation and strongest in the anion.
C) ' C  O ' bond is longer in the cation than in the anion.
D) ' M  C ' pi bonding is higher in the cation.
38. Which of the following is true for O 2 and C2 molecules according to M.O.T.?
A) Both are having 1. and 1 bond B) Both have same bond length
C) Both are having same bond order D) Both are having two  bonds
SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get
 +1 mark; choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

39. True statement(s) about the following compound is/are:

A) It shows geometrical isomerism


B) It shows optical isomerism
C) Its configuration is E
D) It is having three stereocentres
 P   V   V 
40. For one mole of an ideal gas       
 T V  T P  P T

R2 R2
A) 1 B)  C) 1 D)
P2 P2
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41. Which of the following is false?

A)

Product of this reaction is a lactam

B)

Major product of this reaction is having R configuration.

C)

Gives two molecules of iodoform per molecule when treated with NaOH  I2 .
D) Isopropanol gives yellow precipitate with I 2 in NaOH .
SECTION-III
(NON-NEGATIVE INTEGER)
• This section contains SIX (06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER..
• For each question, enter the correct integer corresponding to the answer using the mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.

42. A mixture of H 2C 2O 4 and K 2C 2O 4 required 0.2 N, 25 mL KMnO 4 solution for


complete oxidation same mixture needs 0.2M , 20 mL NaOH solution for its complete
neutralization. Calculate mole percentage of H 2C 2O 4 in the given mixture.
43. Infinite number of flask are connected to one another as shown.

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The volumes and pressure in each flask vary as shown above. The stop-cocks are initially
closed. Then find the common pressure in atm when all the stop-cocks are opened if
 P  30 atm 
44. How many monobromo alkenes (including stereoisomers) are produced during the
reaction?

45. If electrode potential of following cell:

   2 
Pt( s ) Fe(2aq )
, Fe(3aq )
MnO4( aq ) , Mn( aq ) , H ( aq ) Pt( s )
1M 1M 1M 1M pH 5

is X V then calculate value of 20X.


2.303RT
[Given: E   1.51V , E   0.78V ,  0.06 ]
MnO4 |Mn 2 3
Fe |Fe 2
F
46. Find the number of geometrical isomer of Ma2bcde which have identical ligands at
maximum distance. (a, b, c, d and e are monodentate ligands)
47. The maximum number of moles of Grignard's reagent will be consumed per mole of
following compound?

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SECTION-IV
(PARAGRAPH QUESTIONS)
 This section contains TWO (02) questions stems.
 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme:
 Full Marks: +3 If ONLY the correct numerical value is entered at the designated place;
 Zero Marks:0 in all other cases
Paragraph - 1
100 ml of 0.1M H3PO4 is titrated with 0.05M NaOH solution till 2nd equivalence point.
Then, resultant solution was mixed with 10ml of 0.5M HCl solution
K1  103 M
K 2  108 M
K3  1013 M
48 pH after HCl was added will be :
49. Solubility of compound A(OH)2 in final solution will be x  1018 M then find the value
of x
[Given: K sp A(OH)2  4  1030 M 3 ]
Paragraph - 2
For a given compound

There are 3 benzenoid isomer of ‘X’ P, Q and R for which following observation are
made:
(a) P is a monosubstituted benzene derivative which can give aldol reaction.
(b) Q give positive iodoform test.
(c) R gives silver mirror with Tollen’s reagent.
50. Number of possible P:
51. Number of possible R:
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