MSDS HKR102 23032016

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Safety Data Sheet

Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

SECTION 1. Identification of the substance/mixture and of the company/undertaking

Product identifier
Trade name Polypropylene HKR102

Synonyms Polypropylene, Propylene Polymer, Propene Polymer, 1-Propene,


Homopolymer.

Relevant identified uses of the substance or mixture and uses advised against

Use Applications in the food industry. Polymer for extrusion, injection


moulding, blow moulding & thermoforming applications.
Manufacturer or supplier's details

Company Sasol Chemicals, a division of Sasol South Africa (Pty) Ltd

Address 1 Sturdee Avenue


Rosebank
2196
South Africa
Telephone +27114413111

E-mail address [email protected]

Emergency Phone Number

Emergency telephone +44 (0)1235 239 670 (Europe, Israel, Africa, Americas)
number
+44(0)1235 239 671 (Middle East, Arabic African countries)

+65 3158 1074 (Asia Pacific)

+86 10 5100 3039 (China)

+27 (0)17 610 4444 (South Africa)

+61 (2) 8014 4558 (Australia)

SECTION 2. Hazards identification

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Classification of the substance or mixture

South Africa. GHS Classification and Labelling of Chemicals - SANS 10234

Classification This substance is not classified as hazardous according to


GHS.

Label elements

Pictogram Not applicable

Signal word Not applicable

Hazard statements This substance is not classified as hazardous according to GHS.

Precautionary Statement This substance is not classified as hazardous according to GHS.


- Prevention

Precautionary Statement This substance is not classified as hazardous according to GHS.


- Response

Precautionary Statement This substance is not classified as hazardous according to GHS.


- Storage

Precautionary Statement This substance is not classified as hazardous according to GHS.


- Disposal

Other hazards May form combustible dust concentrations in air (during processing).

SECTION 3. Composition/information on ingredients

Substance

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Polypropylene

Contents: >= 99.00 - <= 100.00 %W/W


CAS-No. 9003-07-0 Index-No. EC-No.

SECTION 4. First aid measures

Description of necessary first-aid measures

Inhalation Product does not release fumes at ambient temperatures. If


exposed to fumes from heated polymer move to fresh air
environment.

Skin contact At room temperature the product is not considered harmful


when in contact with skin. In case of skin contact with molten
polymer immediately submerse the affected area in cold water
to cool down polymer.

Eye contact At room temperature the product is not considered hazardous


in contact with eyes. In case of eye contact with molten
polymer, cool under running water for 3-5 minutes. Do not
attempt to remove molten polymer. Get medical attention
immediately.

Ingestion At room temperature the product is not considered harmful


when swallowed.

Most important symptoms/effects, acute and delayed

Refer to SECTION 11

Indication of any immediate medical attention and special treatment needed

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Refer to SECTION 4.1

SECTION 5. Firefighting measures

Suitable extinguishing Dry chemical. Carbon dioxide (CO2). Water spray.


media

Special hazards arising Substance evolves toxic gases when burned.


from the substance or
mixture

Special protective Wear self-contained breathing apparatus and protective suit.


equipment for firefighters

SECTION 6. Accidental release measures

Environmental precautions No special environmental precautions required.

Methods for cleaning up Shovel into suitable container for disposal.

Reference to other sections Refer to Section 8 and 13

SECTION 7. Handling and storage

Safe handling advice No special handling advice required under normal conditions.
Molten polymer: Wear heat-resistant protective equipment.

Advice on protection Keep away from heat and sources of ignition.


against fire and explosion

Requirements for storage Keep away from direct sunlight.Keep away from heat.
areas and containers

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Advice on common storage Keep in a cool, well-ventilated place.

SECTION 8. Exposure controls/personal protection

Components with workplace control parameters

NATIONAL OCCUPATIONAL EXPOSURE LIMITS

Contains no substances with occupational exposure limit values.

Exposure controls

Engineering measures

If user operations generate dust, fumes or mists, use ventilation to keep exposure to airborne contaminants
below the exposure limit.

Use only in an area equipped with explosion proof exhaust ventilation.


The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits.
Ensure adequate ventilation.

Personal protective equipment

Respiratory protection No personal respiratory protective equipment normally


required. In the case of respirable dust and/or fumes, use self-
contained breathing apparatus.

Hand protection No hand protection required under normal conditions. Molten


polymer: Wear heat-resistant gloves.

Eye protection No eye protection is required under normal conditions. Molten


polymer: Wear safety glasses with side shields.

Skin and body protection No special body protection is required under normal conditions.
Molten polymer: Wear heat-resistant protective clothing.

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

SECTION 9. Physical and chemical properties

Information on basic physical and chemical properties

Form Solid form

State of matter Solid

Colour Translucent to white

Odour None to slightly waxy

Odour Threshold No data available

pH No data available

Melting point/range 130 - 165 °C

Flash point > 350 °C; Open cup

Evaporation rate No data available

Flammability (solid, gas) No data available

Auto-ignition temperature > 390 °C

Lower explosion limit No data available

Upper explosion limit No data available

Vapour pressure No data available

Vapour density No data available

Density 0.88 - 0.92 g/cm3

Water solubility Insoluble

Partition coefficient: n- No data available


octanol/water

SECTION 10. Stability and reactivity

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Reactivity Stable under normal conditions. Continous heating above 160


ºC will lead to thermal oxidation.

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous Strong oxidizing agents


reactions

Conditions to avoid Heat, flames and sparks.

Materials to avoid Oxidizing agents.

Hazardous decomposition Carbon dioxide (CO2).Carbon monoxide.Acroleinformaldehyde-


products like

SECTION 11. Toxicological information


Information on toxicological effects
Acute toxicity
Acute oral toxicity No data available

Irritation and corrosion


Skin irritation No data available

Eye irritation No data available

Sensitisation No data available

Repeated dose toxicity No data available

Carcinogenicity No data available

Mutagenicity No data available

Toxicity for reproduction No data available

Eye contact No data available

Skin contact Molten polymer can cause severe burns in contact with skin
and eyes.

Inhalation No data available

Ingestion No data available

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

SECTION 12. Ecological information

Ecotoxicity effects

Persistence and degradability No data available

Bioaccumulative potential No data available

Mobility in soil No data available

Results of PBT and vPvB No data available


assessment

Other adverse effects No data available

SECTION 13. Disposal considerations

Product Disposal can be done with normal domestic waste. Can be


recycled. Can be incinerated.

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

SECTION 14. Transport information


Further Information Not classified as dangerous in the meaning of transport

regulations.

SECTION 15. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

Registration, Evaluation and Authorisation of All chemical constituents are listed in: Registration, Evaluation
Chemicals (REACH) and Authorisation of Chemicals (REACH) (See chapter 3)

Inv. of Exist. Chem. Substances in China All chemical constituents are listed in: Inv. of Exist. Chem.
Substances in China (See chapter 3)

USA TSCA Inventory All chemical constituents are listed in: USA TSCA Inventory
(See chapter 3)

Canadian Domestic Substances List (DSL) All chemical constituents are listed in: Canadian Domestic
Substances List (DSL) (See chapter 3)

Australian Inv. of Chem. Substances (AICS) All chemical constituents are listed in: Australian Inv. of Chem.
Substances (AICS) (See chapter 3)

New Zealand Inventory of Chemicals All chemical constituents are listed in: New Zealand Inventory of
(NZIoC) Chemicals (NZIoC) (See chapter 3)

Jap. Inv. of Exist. & New Chemicals (ENCS) All chemical constituents are listed in: Jap. Inv. of Exist. & New
Chemicals (ENCS) (See chapter 3)

Japan. Industrial Safety & Health Law (ISHL) All chemical constituents are listed in: Japan. Industrial Safety &
Health Law (ISHL) (See chapter 3)

Korea. Existing Chemicals Inventory (KECI) All chemical constituents are listed in: Korea. Existing
Chemicals Inventory (KECI) (See chapter 3)

Philippines Inventory of Chemicals and All chemical constituents are listed in: Philippines Inventory of
Chemical Substances (PICCS) Chemicals and Chemical Substances (PICCS) (See chapter 3)

China Inv. Existing Chemical Substances All chemical constituents are listed in: China Inv. Existing
(IECSC) Chemical Substances (IECSC) (See chapter 3)

SECTION 16. Other information

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Safety Data Sheet
Polypropylene HKR102
Version 1.00 Revision Date 23.03.2016

All reasonable efforts were exercised to compile this SDS in accordance with the Globally Harmonized System of
Classification and Labelling of Chemicals (GHS). The SDS only provides information regarding the health, safety
and environmental hazards at the date of issue, to facilitate the safe receipt, use and handling of this product in
the workplace and does not replace any product information or product specifications. Since Sasol and its
subsidiaries cannot anticipate or control all conditions under which this product may be handled, used and
received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this
SDS in the context within which this product will be received, handled or used in the workplace. The user, handler
or receiver must ensure that the necessary mitigating measures are in place with respect to health and safety.
This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further
remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties
that may be involved in the receipt, use or handling of this product.
Although all reasonable efforts were exercised in the compilation of this SDS, Sasol does not expressly warrant
the accuracy of, or assume any liability for incomplete information contained herein or any advice given. When
this product is sold, risk passes to the purchaser in accordance with the specific terms and conditions of sale.

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