Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)

2015/830

SAFETY DATA SHEET

Harpic Power Plus Lemon Active Tablets

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Product name : Harpic Power Plus Lemon Active Tablets
SDS # : D8378521 v2.0
Formulation # : FF3138808 v1.0
Product type : Solid. (Tablets)

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Toilet Bowl Cleaner ( Removes 100% Limescale; Deep clean without scrubbing)Consumer use

1.3 Details of the supplier of the safety data sheet

Supplier
To be filled by local business.

Manufacturer
Copacker-MDG

ORAPI - Parc Industriel de la Plaine de l'Ain - 225 allée des Cèdres - 01150 SAINT-VULBAS – France
e-mail address of person : To be filled by local business.
responsible for this SDS
National contact
To be filled by local business.

1.4 Emergency telephone number

National advisory body/Poison Center
Telephone number : To be filled by local business.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

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SECTION 2: Hazards identification

Hazard pictograms :

Signal word : Warning

Hazard statements : Causes serious eye irritation.
Causes skin irritation.
Harmful to aquatic life with long lasting effects.
Precautionary statements
General : Keep out of reach of children.
Prevention : Wash hands thoroughly after handling. Wear protective gloves.
Response : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a doctor. IF ON SKIN:
Wash with plenty of soap and water. If skin irritation occurs, get medical advice/
attention.
Storage : Not applicable.
Disposal : Dispose of contents/container in accordance with local regulations
Hazardous ingredients : SODIUM CARBONATE PEROXIDE
Supplemental label : Contains Limonene. May produce an allergic reaction.
elements
Ingredient Declaration:
Contains 5% or less anionic surfactants
Contains 5% or less non-ionic surfactants
Perfume
Contains Citral, Limonene.
Annex XVII - Restrictions : None
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture
Product/ingredient name Identifiers % Regulation (EC) No. Type
1272/2008 [CLP]

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SECTION 3: Composition/information on ingredients

sulphamidic acid REACH #: ≥50 - ≤75 Skin Irrit. 2, H315 [1]
01-2120756701-55 Eye Irrit. 2, H319
EC: 226-218-8 Aquatic Chronic 3,
CAS: 5329-14-6 H412
Index: 016-026-00-0
SODIUM CARBONATE REACH #: ≥10 - ≤25 Eye Irrit. 2, H319 [1]
01-2119485498-19
EC: 207-838-8
CAS: 497-19-8
Index: 011-005-00-2
SODIUM CARBONATE PEROXIDE REACH #: ≤10 Ox. Sol. 3, H272 [1]
01-2119457268-30 Acute Tox. 4, H302
EC: 239-707-6 Eye Dam. 1, H318
CAS: 15630-89-4
Limonene REACH #: ≤0.3 Flam. Liq. 3, H226 [1]
01-2119529223-47 Skin Irrit. 2, H315
EC: 227-813-5 Skin Sens. 1, H317
CAS: 5989-27-5 Aquatic Acute 1, H400
Index: 601-029-00-7 (M=1)
Aquatic Chronic 1,
H410 (M=1)
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent
concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse
health effects persist or are severe. If unconscious, place in recovery position and
get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash
clothing before reuse. Clean shoes thoroughly before reuse.

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SECTION 4: First aid measures

Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed
and the exposed person is conscious, give small quantities of water to drink. Stop if
the exposed person feels sick as vomiting may be dangerous. Do not induce
vomiting unless directed to do so by medical personnel. If vomiting occurs, the head
should be kept low so that vomit does not enter the lungs. Get medical attention if
adverse health effects persist or are severe. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media

Unsuitable extinguishing : None known.

media

5.2 Special hazards arising from the substance or mixture

Hazards from the : This material is harmful to aquatic life with long lasting effects. Fire water
substance or mixture contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.

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SECTION 5: Firefighting measures

Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves)
conforming to European standard EN 469 will provide a basic level of protection for
chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Provide adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Put on appropriate
personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities.

6.3 Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Avoid dust generation. Using a vacuum with HEPA
filter will reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. Dispose of via a licensed waste disposal contractor.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid release to the environment. Keep
in the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Empty containers retain product residue and can
be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section 8 for additional information on
hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and
well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright
to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

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SECTION 7: Handling and storage

7.3 Specific end use(s)
Recommendations : Toilet Bowl Cleaner ( Removes 100% Limescale; Deep clean without scrubbing)
Consumer use
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

The information in this section contains generic advice and guidance. Information is provided based on typical
anticipated uses of the product. Additional measures might be required for bulk handling or other uses that could
significantly increase worker exposure or environmental releases.
8.1 Control parameters
Occupational exposure limits
No exposure limit value known.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
SODIUM CARBONATE DNEL Long term 10 mg/m³ Workers Local
Inhalation
DNEL Short term 10 mg/m³ General Local
Inhalation population
[Consumers]
SODIUM CARBONATE PEROXIDE DNEL Short term Dermal 6.4 mg/cm² General Local
population
[Consumers]
DNEL Short term Dermal 12.8 mg/ Workers Local
cm²
DNEL Short term 5 mg/m³ Workers Local
Inhalation
Limonene DNEL Long term 66.7 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 9.5 mg/kg Workers Systemic
bw/day
DNEL Long term 16.6 mg/m³ General Systemic
Inhalation population
[Consumers]
DNEL Long term Dermal 4.8 mg/kg General Systemic
bw/day population
[Consumers]
DNEL Long term Oral 4.8 mg/kg General Systemic
bw/day population
[Consumers]
PNECs
Product/ingredient name Compartment Detail Value Method Detail
SODIUM CARBONATE PEROXIDE Sewage Treatment 16.24 mg/l Assessment Factors
Plant
Fresh water 0.035 mg/l Assessment Factors
Marine water 0.035 mg/l Assessment Factors
Limonene Fresh water 14 µg/l Assessment Factors
Marine water 1.4 µg/l Assessment Factors
Sewage Treatment 1.8 mg/l Assessment Factors
Plant
Fresh water sediment 3.85 mg/kg dwt Equilibrium Partitioning
Marine water sediment 0.385 mg/kg dwt Equilibrium Partitioning
Soil 0.763 mg/kg Equilibrium Partitioning

8.2 Exposure controls

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne
controls contaminants.

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SECTION 8: Exposure controls/personal protection

Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Skin protection
Hand protection : EN 16523-1:2015
Tested for protection against chemical permeation.
Low chemical resistant or waterproof gloves.
(EN 16523-1:2015 supersedes EN 374-3:2003)
EN 374-2:2003
Tested for protection against liquid penetration and micro-organisms.
EN 388:2003
Tested for protection against mechanical risks (abrasion, blade cut resistance, tear
resistance and puncture resistance).
ISO 374-1:2016/Type A
Protective glove with permeation resistance of at least 30 minutes each for at least 6
test chemicals.
ISO 374-1:2016/Type B
Protective glove with permeation resistance of at least 30 minutes each for at least 3
test chemicals.
ISO 374-1:2016/Type C
Protective glove with permeation resistance of at least 10 minutes for at least 1 test
chemical.
Considering the parameters specified by the glove manufacturer, check during use
that the gloves are still retaining their protective properties. It should be noted that
the time to breakthrough for any glove material may be different for different glove
manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state : Solid. [Block (Tablet)]
Color : Pale Blue
Odor : Mild lemon scent
Odor threshold : Not determined
pH : 1.2 to 2.2 [Conc. (% w/w): 1%]
Melting point/freezing point : Not determined
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SECTION 9: Physical and chemical properties

Initial boiling point and boiling : Not determined
range
Flash point : Not determined
Evaporation rate : Not determined
Flammability (solid, gas) : Not determined
Upper/lower flammability or : Not determined
explosive limits
Vapor pressure : Not determined
Vapor density : Not determined
Relative density : Not determined
Solubility(ies) : Easily soluble in the following materials: cold water and hot water.
Partition coefficient: n-octanol/ : Not determined
water
Decomposition temperature : Not determined
Viscosity : Not determined.
Explosive properties : Not determined
Oxidizing properties : Not determined

9.2 Other information

Auto-ignition temperature : Not available.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability : The product is stable.

10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions

10.4 Conditions to avoid : No specific data.

10.5 Incompatible materials : No specific data.

10.6 Hazardous : Under normal conditions of storage and use, hazardous decomposition products
decomposition products should not be produced.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
sulphamidic acid LD50 Oral Rat 3160 mg/kg -
SODIUM CARBONATE LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat 2800 mg/kg -
SODIUM CARBONATE LD50 Oral Rat 1034 mg/kg -
PEROXIDE
Limonene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 4400 mg/kg -
Conclusion/Summary : Based on available data, the classification criteria are not met.
Acute toxicity estimates

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SECTION 11: Toxicological information

Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts
(ppm) (mg/l) and mists)
(mg/l)
sulphamidic acid 3160 N/A N/A N/A N/A
sodium carbonate 2800 N/A N/A N/A N/A
disodium carbonate, compound with hydrogen 1034 N/A N/A N/A N/A
peroxide (2:3)
Limonene 4400 N/A N/A N/A N/A
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
sulphamidic acid Eyes - Moderate irritant Rabbit - 20 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 250 -
Micrograms
Skin - Mild irritant Human - 120 hours 4 -
Percent
Intermittent
Skin - Severe irritant Rabbit - 24 hours 500 -
milligrams
SODIUM CARBONATE Eyes - Mild irritant Rabbit - 0.5 minutes -
100
milligrams
Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Limonene Skin - Mild irritant Rabbit - 24 hours 10 -
Percent
Conclusion/Summary
Skin : Based on Calculation Method: Causes skin irritation.
Eyes : Based on Calculation Method: Causes serious eye damage.
Respiratory : Based on available data, the classification criteria are not met.
Sensitization
Product/ingredient name Route of Species Result
exposure
Not applicable.

Conclusion/Summary
Skin : Based on available data, the classification criteria are not met.
Respiratory : Based on available data, the classification criteria are not met.
Mutagenicity
Product/ingredient name Test Experiment Result
Not applicable.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Carcinogenicity
Product/ingredient name Result Species Dose Exposure
Not applicable.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Reproductive toxicity
Product/ingredient name Maternal Fertility Development Species Dose Exposure
toxicity toxin
Not applicable.

Conclusion/Summary : Based on available data, the classification criteria are not met.
Teratogenicity

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SECTION 11: Toxicological information

Product/ingredient name Result Species Dose Exposure
Not applicable.
Conclusion/Summary : Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
Not applicable.
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
Not applicable.

Aspiration hazard
Product/ingredient name Result
Not applicable.

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Conclusion/Summary : Based on available data, the classification criteria are not met.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.

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SECTION 11: Toxicological information

Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Other information : Not available.

SECTION 12: Ecological information

12.1 Toxicity
Product/ingredient name Result Species Exposure
sulphamidic acid Acute LC50 14200 µg/l Fresh water Fish - Pimephales promelas 96 hours
SODIUM CARBONATE Acute EC50 242000 µg/l Fresh water Algae - Navicula seminulum 96 hours
Acute LC50 176000 µg/l Fresh water Crustaceans - Amphipoda 48 hours
Acute LC50 265000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 300000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
SODIUM CARBONATE Acute EC50 70 mg/l Algae - Chlorella emersonii 240 hours
PEROXIDE
Acute EC50 4.9 mg/l Daphnia - Daphnia Pulex 48 hours
Acute LC50 70.7 mg/l Fish - Pimephales promelas 48 hours
Limonene Acute EC50 421 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute EC50 688 µg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Conclusion/Summary : Based on Calculation Method: Harmful to aquatic life with long lasting effects.

12.2 Persistence and degradability

Conclusion/Summary : The surfactant(s) contained in this preparation complies (comply) with the
biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
Data to support this assertion are held at the disposal of the competent authorities of
the Member States and will be made available to them, at their direct request or at
the request of a detergent manufacturer.

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
sulphamidic acid 0.101 - low
Limonene 4.38 - high

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product

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SECTION 13: Disposal considerations

Methods of disposal : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal : The generation of waste should be avoided or minimized wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

For long distance transport of bulk material or shrunk pallet take into consideration sections 7 and 10.
ADR/RID ADN IMDG IATA
14.1 UN number UN2967 UN2967 UN2967 UN2967

14.2 UN proper SULPHAMIC ACID SULPHAMIC ACID SULPHAMIC ACID Sulphamic acid
shipping name
14.3 Transport 8 8 8 8
hazard class(es)

14.4 Packing group III III III III

14.5 No. Yes. No. No.
Environmental
hazards
Additional information
ADR/RID : Hazard identification number 80
Limited quantity 5 kg
Tunnel code (E)
ADN : The product is only regulated as an environmentally hazardous substance when
transported in tank vessels.
IMDG : Emergency schedules F-A, S-B
IATA : Quantity limitation Passenger and Cargo Aircraft: 25 kg. Packaging instructions:
860. Cargo Aircraft Only: 100 kg. Packaging instructions: 864. Limited Quantities -
Passenger Aircraft: 5 kg. Packaging instructions: Y845.
Special provisions A803

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not available.

according to Annex II of
MARPOL and the IBC Code

Date of issue/Date of revision : 26/08/2020 Date of previous issue : 11/08/2020 Version : 2.0 12/14
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830
D8378521 v2.0

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorization
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions : None
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Other EU regulations
Ozone depleting substances (1005/2009/EU)
Not listed.

Prior Informed Consent (PIC) (649/2012/EU)

Not listed.

Seveso Directive
This product is not controlled under the Seveso Directive.

15.2 Chemical Safety : No Chemical Safety Assessment has been carried out.
Assessment

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method
Aquatic Chronic 3, H412 Calculation method
Full text of abbreviated H statements
H226 Flammable liquid and vapor.
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]

Date of issue/Date of revision : 26/08/2020 Date of previous issue : 11/08/2020 Version : 2.0 13/14
Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Commission Regulation (EU)
2015/830
D8378521 v2.0

SECTION 16: Other information

Acute Tox. 4, H302 ACUTE TOXICITY (oral) - Category 4
Aquatic Acute 1, H400 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1, H410 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 3, H412 AQUATIC HAZARD (LONG-TERM) - Category 3
Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Ox. Sol. 3, H272 OXIDIZING SOLIDS - Category 3
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1
Date of printing : 26/08/2020
Date of issue/ Date of : 26/08/2020
revision
Date of previous issue : 11/08/2020
Version : 2.0
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

Date of issue/Date of revision : 26/08/2020 Date of previous issue : 11/08/2020 Version : 2.0 14/14