CHEMISTRY DEPARTMENT KS I REVISION KIT FOR BGCSE CHEMISTRY PAPER I Please do not write on this booklet2 ‘A small crystal of potassium manganate(VTI) is placed at the bottom of a stoppered container full of water. Alter several hours, a uniformly coloured solution is formed. Which processes took place? condensation and dissolving 8 diffusion and evaporation © dissolving and diffusion D dissolving and evaporation The diagram shows a Liebig condenser used to change hot vapour into a liquid with the aid of a stream of cold water, cold water hot vapour The symbol of a fluorine atom is "2 F. What are the numbers of particles contained in a fluoride ton? Protons | neutrons | electrons Als 10 10 Bo 9 | 19 | 10 cw | 9 o | > t0 9 | ou3 4 Which two particles have equal but opposite charges? a neutron and a hydrogen nucleus B a proton and an electron € aproton and a hydrogen ion Da proton anda neutron 5 Which diagram shows the arrangement of electrons in an oxygen molecule, 0,7 A OHO) OO GO © 6 Which description of the properties of magnesium chloride is correct? | meting | electrical conductivity! solubility in water point when molten | jal mon god woke B high poor | insoluble | {c tow good | soluble | | dD low | poor | insoluble TTurr ewer4 7 The diagrams show atoms of four different metais. Which metal is the most reactive? A B c D 8 The elements lithium, sodium and potassium are in Group | of the Periodic Table. Why are they placed in this group? They all have A avvigorous reaction with water. B densities less than thal of water. C metallic properties. D one electron in the outermost shell, 3 When sodium hydroxide pellets are dissolved in water, the beaker feels warm. Which term describes this process? A combustion B endothermic © exothermic D respiration 49 Which particles carry current in electrolytes and in metals? inelectrolytes in metals B ions electrons | | c| molecules ions and electrons | iD protons | ions? 5 11 The graph shows how the total volume of hydrogen produced by the reaction between hydrochloric acid and an excess of zinc varied with time. total volume of hydrogen time Which statement describes the part RS of the curve? All the zinc has reacted, B The rate of production of hydrogen is fastest. © The reaction is continuing at a constant rate. D No more hydrogen is produced. 12. The manufacture of sulphuric acid from sulphur involves the four stages below, S$ —» SO, —» SO, —» H,S,0, —» H,S0, Which diagram shows the oxidation number (oxidation state} of sulphur at each stage of the process? A +6- +8 E +4 vot +2-4 “4 0 4 ransom [Turn over6 43. Inwhich equation is the underlined substance reduced? A Ma+2Ht > Mg? + Hy B OH+H*-+ HO © C+00, 200 D B+ 28r+l, 14 Aqueous copper(II) sulphate is electrolysed using copper electrodes. Which equation shows the reaction taking place at the anode? Cu?t(aq) + 20° + Culs) B Cus) -+ Cut(aq) + 2e" Cc 20%(g) » Onig) + de" D 40H (aq) + 2H,O(!) + O2(g) + de" 15 Which ions does dilute sulphuric acid contain? water fons and sulphate ions B sulphuric acid jons and hydroxide ions C sulphate ions and hydrogen ions D_ water ions and sulphuric acid 16 The table shows the pH of four solutions. Which solution is likely to be ethanoic acid? — B 1 57 18 19 20 2t 7 What colour change is observed when an excess of hydrochloric acid is added to aqueous sodium hydroxide containing methyl orange indicator? A orange to red Bred to orange Cred to yellow D yellow to red Which oxide reacts both with acids and with alkalis? carbon dioxide B copper(I!) oxide € iron(tt) oxide D zinc oxide Sodium carbonate reacts with hydrochloric acid as shown, Na,CO, + yHCI + 2NaC/ + CO, + H,0 What is the value of y in this equation? Ad } c D A 464g sample of hydrated sodium carbonate contains 252 g of water of crystallisation. (M: Na,CO,, 106; 18) What is the formula of hydrated sodium carbonate? A NayCO3.7H,0 B Na,CO3.10H,0 © 2Na,CO,.14H,0 D 2Na,CO,.20H,0 What is the total number of atoms in a methyl amine, Cl A 2 His, molecule? Bo3 25 DO? cara op [Turn ever22 23 24 25 26 8 Which metal is found un-combined in the Earth's crust? A aluminium B calcium Cc gold D zine Which oxide can be reduced by hydrogen? A AlO, B CaO © CuO D Na,O Which equation shows the reaction of sodium with water? A 2Na*+H,0 -+Na,O + 2H B 2Na+H,O -+Na,O +H, © 2Na+2H,O + 2NaOH +2H* D 2Na+2H,O ~+2NaOH +H, Which property makes aluminium suitable for the manufacture of food containers? A tis a very good conductor of electricity. B_Itis of low density. © _Itis resistant to corrosion, D_ tris shiny. Which substance is used in the purification of water? A calcium B chlorine © cobalt(Il) chloride D sodium chloride9 27 Rods of metals W, X and Y are placed in different aqueous solutions of salts of the metals, W, ¥ and Z as shown. rod of —- rod of metal W metal X rod of metal ¥ aqueous metal X salt aqueous metal Y salt aqueous metal Z salt In beaker I, metal X is displaced from the solution. In beaker I metal Y is displaced from the solution. In beaker Ill, metal Z is displaced from the solution. What is the order of reactivity of the metals? most reactive > least reactive A w x Y Zz B x Y w z c w x D z w Y 28 The diagram shows a blast furnace as used in the extraction of iron. At which part is molten iron tapped out? 29 What is the name of different forms of an element in the samo physical state? A. allotropes B alloys isomers B_ isotopes cerovaner [Turn over30 31 32 33 34 10 Which two metals form compounds that dissolve in water tomake it hard? A calcium and sodium B_ magnesium and calcium © _ potassium and calcium D potassium and sodium Coal contains the elements carbon, hydrogen, oxygen, sulphur and nitrogen. Which pollutant from burning coat attacks limestone and marble on buildings? A ammonia B carbon monoxide © sulphur dioxide ° water Which one is a use of ammonia? A asa bleaching agent B__ for making margarine © for making fertilizers D for preserving food Which statement about the properties of members of an homologous series is correct? A They have the same empirical formula B They have the same melting point. © They have the same number of carbon atoms in their molecules. oD They undergo similar reactions. Which term describes the formation of ethanol from ethene? A addition B dehydration © hydrogenation D oxidation35 36 W What are the products of fermentation? ‘A ethanol and carbon dioxide B ethanol and carbon monoxide ethanol and sugar D ethanol and water The diagrams show the structures of two compounds that undergo similar chemical reactions. H H H H ut bel H igi H Which property makes them undergo similar chemical reactions? A functional groups B_ number of carbon atoms © number of hycrogen atoms D relative molecular mass12 37 The diagram shows the refining of crude oil StS -TLIt_ — diesel hot crude oil —== iTIt =~ lubricating oll bitumen, What is the use of fraction X? fuel for aircraft B fuel for tractors making candle waxes D surfacing roads 38 Ahydrocarbon Y, IM, = 42, rapidly decotourises aqueous bromine. Which hydrocarbon is Y likely to be? A H H—c- 4 c D Tha i 3 H- C—C—-C—H H—C—=C—C—H rot | H HOH H13 39 An organic compound ¥ reacts with ethano! to produce a compound Z that has a sweet smell. What types of compounds are Y and Z? ‘compound ¥ compound Z | A acid alkali ! B acid ester | c alkali ester D ester acid 40 Which structure is a polymer? A B i i c=Cc g | | HOH H c BD ii ttt H--C—C-—C c-c—c foi 1 ot | HoH H HOH H2 \What happens to the movement and size of carbon dioxide molecules when the gas is heated? movement of molecules size of molecules A faster decrease B_ faster stays the same Cc slower stays the same D slower decrease Which piece of apparatus is needed to prove that the reaction between dilute sodium hydroxide and dilute hydrochloric acid is exothermic? burette thermometer pipette vou > Universal indicator Which property of the atoms of an element determines the position of the element in the Periodic, Table? A number of protons B total number of protons and electrons © number of neutrons D total number of neutrons and electrons Which diagram is that of an atom in the same period as an element with electronic configuration 2, 6? x ORS ry a | k x key x “se nucleus x electron me on cxf & ° ete Ce5 3 What is the formula of iron(II) chloride and of carbon dioxide? carbon dioxide c,0 i co, 6,0 co, Apart from sodium hydroxide, which two other substances are produced during the electrolysis of concentrated aqueous sodium chloride? A chlorine and sodium B chlorine and hydrogen hydrogen and oxygen D hydrogen and sodium Which statement about the Periodic Table is correct? A. Allelements in the same group have similar properties. B__ Elements on the right are metaltic. © Onascending Group I, the elements become more reactive. D On descending Group VII, the elements become more reactive Which set of atomic numbers is that of halogens? A 18, 36,54 B25, 26,27 Cc 35,53, 85 D 38,56, 201 What happens to a magnesium atom when it combines with an oxygen atom? Magnesium gains two electrons from one oxygen atom. A B__ Magnesium shares two electrons with one oxygen atom. ° Magnesium loses one electron to one oxygen atom 1D Magnesium loses two electrons to one oxygen atom. sr ontee [Turn ayer NN10 n 12 13 14 4 Which substance is produced when ethene reacts with steam under suitable conditions? A. ethane B_ ethanol © hydrogen D methane Which statement about the electrolysis of aluminium oxide (bauxite) is correct? A Aluminium forms at the negative electrode. Negative ions gain an electron to form an atom. ‘Oxygen forms at the negative electrode. ooo The positive electrode is made of aluminium. Which element is found free in nature? A aluminium B calcium © carbon D iron What is the total number of atoms in ammonium phosphate, (NH,),PO,? Ad BT © 12 BD 20 What name is used to descrive the water molecules in the formula CuSO,.5H,0? A anhydrous B hard water © water of crystallisation . water of solution wy5 15. The diagram shows an apparatus to investigate the electrolysis of concentrated aqueous sodium 16 7 chloride. concentrated aqueous sodium chloride Which gas is given off at the positive electrode? A chlorine B hydrogen © oxygen D steam Which element burns in air to form an amphoteric oxide? A. calcium B copper magnesium D zine Which statement describes how iron is formed from iron oxide in the blast furnace? A Iron oxide decomposes at high temperatures. B Iron oxide reacts with the hot limestone. € Iron oxide is oxidised by the blast of hot air. D Iron oxide is reduced by the carbon monoxide. corov wee [Turn over18 19 6 The diagram shows the laboratory preparation of chiorine by the addition of liquid R to a solid S. liquid R Solid water concentrated sulphuric acid heat chlorine What is liquid R and solid $? liquid R solid S A concentrated hydrochloric acid sodium chloride. B aqueous sodium chloride potassium permanganate C concentrated hydrochloric acid manganese(IV) oxide D aqueous sodium chloride manganese(1V) oxide From which substances are polymers made? A allotropes B isotopes © isomers D monomers Which gas is given off when copper(II) carbonate is heated strongly? carbon dioxide hydrogen oxygen DO wb water21 22 23 24 7 The diagram shows hydrogen being passed over a heated oxide of metal X. The only products were a red/brown powder and steam. oxide of metal X unused hydrogen burning a“ hydrogen = ce op 4 “—— heat What is metal X? A aluminium B copper Cc iron D- zine Which gas is given off when ethanoic acid reacts with calcium? ammonia carbon dioxide hydrogen comp oxygen Which gas is formed when a mixture of ammonium chloride and sodium hydroxide is gently heated? A ammonia B chlorine € hydrogen chloride Dhydrogen Which process describes how copper is obtained from aqueous copper(II) sulphate? A crystallisation distiltation electrolysis vog filtration 08 on [Turn ower25 26 27 28 29 What is the percentage of nitrogen in air? A 10 B12 © 20 D 7 An aqueous solution containing ammonium sulphate and sodium hydroxide was boiled. The gas given off was bubbled in a blue-green solution X containing a nitrate. A faint blue precipitate was first formed which then dissolved to give a deep blue solution. Which of the following was present in X? A A B cu* Cc Fe’ D Zn Which statement indicates that copper is a metal? A Itis a good conductor of electricity. B It reacts with water to give off a gas. © It forms coloured compounds. D It does not react with dilute acid, Which property does net change during polymerisation of ethene to form poly(ethene)? A. boiling point B molecular formula © melting point D__ percentage composition A sample of 0.1 mol of a metal X (relative atomic mass 24) is burned in oxygen. The resulting oxide has a mass of 4g. What is the formula of the metal oxide? A xO B XO, c x,0 BD X,0,30 31 32 33 34 9 Silicon, Si, is in Group IV of the Periodic Table. What is the correct formula of a chloride of silicon? A SiCr B SiCi, © si,ci, D Si,Cl, What name is given to Group Il elements? alkali alkali earth halogens coop transition Which molecular formula is that of an alkanol? A GH, BCH, © 6H,O D CH,0, Which catalyst is correctly matched with the process itis used in? catalyst process A. iron decomposition of hydrogen peroxide B__ manganese([V) oxide conversion of ethene to ethanol C nickel hydrogenation of fats D phosphoric acid Haber Hydrogen chloride and sodium hydroxide are soluble in water. Which formula shows the particles of hydrogen chloride and of sodium hydroxide present in water? hydrogen chloride sodium hydroxide | | A HOO! Na* OH" 8 Hoot Nav OH ice Hor | Nat OH” | D Hror | Na OH"10 35 A colourless solution X is poured into a test tube containing aqueous potassium iodide. A yellow precipitate is formed. What is the colourless solution X called? ammonia nitrate sodium hydroxide lead(Il) nitrate comp potassium chloride 36 When two gases X and Y are bubbled through aqueous bromine, X decolourised the aqueous bromine but ¥ has no effect. What are X and Y? x Y A ethane ethene B ethene ethane Cc steam ethene D_ steam ethane 37 Which fraction from the fractional distillation of crude oil has the lowest boiling point? A bitumen B diesel C parattin D petrol 38 Which ions cause hardness in water? ‘A ammonium and magnesium B_ ammonium and sodium © calcium and magnesium D calcium and sodium" 39° Which structural formula represents a saturated hydrocarbon? H H | B H—C~C-O-H 40 Which equation represents polymerisation? nH A nH~G-o I HoH | HH B nH -C-C aa ine D olH HOH H 1 CoH H H u | D aoe H od a os i H HOH H H-C-H H -o —4- wow H HOG KH _ HOA2 The rusting of iron involves two stages, X and ¥. Stage X: Fe —> Fe Stage Y: Fett —> Feet Which terms describe stages X and Y? stage X stage Y A. oxidation oxidation B oxidation reduction © reduction oxidation D_ reduction reduction The diagram shows the electrolysis of concentrated aqueous lithium chloride, using platinum electrodes. anode —-cathode ———~ concentrated aqueous lithium chloride Which substances are produced at the electrodes? anode cathode [A chlorine =| ithium | B chlorine hydrogen Le hydrogen lithium | D hydrogen chlorine Which activity in daily life is an example of an acid-base reaction? A addition of dilute sulphuric acid to a car baitery B__ brushing teeth with a toothpaste © drinking cold water to relieve gastric pains D_ washing greasy clothes with a detergent5 10 Which diagram showing the effect of adding dilute hydrochloric acid to four different metals is incorrect? copper zine 11 Which method is used to separate an insoluble solid from a liquid? A chromatography B crystallisation © distillation 2 filtration 42. Which equation is most likely to take place? A 2Ag + 2HCI — 2AgCl +H, B Ca + cusoQ, —> CaSO, + Cu © 3Pb + 2Al(NO,), —3 3Pb(NO,), + 2AL D Fe + ZnSO, -—> FeSO, + Zn xreevgniee Turn ower6 13. In an experiment, each of the metals T, U and V is heated with the oxide of another of the three metals. The results are as shown, 14 15 _oxide of V results: T displaced no reaction no reaction What is the order of the reactivity of the elements? most reactive —) least reactive A T u v B u v T c v T u D u T v Under which conditions does zinc react most rapidly with hydrochloric acid? form of zine | temperature of acid/(' | vA chips 25 | fe] chips 45 c | powder 25 | Do powder 45, What values of X and ¥ would balance the equation shown? C,H, + XO, —> 3CO, + YH,O waa ale7 16 Which statement provides the best evidence that matter exists as tiny particles in random motion? A Gases can be liquefied when compressed and cooled, B__ Most elements conduct electricity in solid form, © Asmall mass of water produces a larger volume of steam. D__ The smell of ammonia from an opened bottle quickly fills the room. 17 The electronic structures of four covalent molecules are shown. Which molecule has a double covalent bond? ( (O' ~ Oo ° (Ok) oe < & © ) b QS expeancia farm over8 2e 18 The diagrams show the arrangement of particles of substance X in three different states of matter. oO O % 8 “Od O 0,8,0¢0q O-O QO Which words describe the movement of particles in the three states? [_ [4 [ow Tw Al tast vibrating slow B | vibrating fast slow | | c slow | vibrating fast po [__ vibrating Lo slow _ | fast 4 19 Which alloy contains carbon? A brass B bronze © solder D steel 20 In which manufacture is chlorine used? A domestic bleaches B tertliser © margarine D nitric acid9 ét 21 Whatis the structural formula of X in the equation shown? 4 H woo +X wt 4 4 AH HO B wttl on Aa c oH HH DOH HH witty wot ton hd badd 22 Which catalyst is needed for the reaction shown? CyHy + Hy > C:Hy Aiton B nickel © manganese(IV) oxide D vanadium(\) oxide 23 The electronic structure of the atom of element X is shown. AN oO What is the formula of the phosphate, PO,*, of element X? AR XPO, B X,PO, & x,PO, X3(PO,)o Frurn ove,10 - 24 The graph shows how the pH of an industrial waste changes when substance X is added at the indicated time. 28 substance X added time/s What is substance X? A o calcium oxide hydrochioric acid magnesium sulphate sodium chloride ‘The diagram shows an outline of the Periodic Table and the position of element X. What is a property of element X? a a ° cotourless gas forms coloured compounds liquid with a low meting point soft metalW 26 Gas X turns aqueous potassium iodide brown. Gas Y gives a dense white smoke when mixed with ammonia. Which element is present both in X and in ¥? A carbon B chiorine © hydrogen D oxygen 27 The equation shows a reaction that takes place in a photographic film. 2AgBr —> 2Ag + Br, Which statement explains why the reaction is endothermic? A Br —~Br covalent bonds are formed. B Electrons are transferred from Br to Ag*. © Light eneray is absorbed during the reaction. D One mole of bromine is formed from two moles of silver bromide. 28 Which substance reacts with calcium oxide to produce slag in the blast furnace? A. calcium oxide B carbon monoxide coke D sand 29° The structure of an addition polymer is shown, Hy CHa F GH, CH, F lt tol —C—C—C—C— Soon HOR OH OA What is the formula of the monomer used to make the polymer? A CH,CHCHF B CH,CH! CH,CH, CH,CFH ° suowas [Turn over12 30. The table shows the meiting points of some Group | elements. 31 32 33 element lithium 180 sodium | 94 potassium { 60 Which is the most likely melting point of rubidium? A 155°C B 405°C Cc 655°C D 1005°C Which fuel would cause the least pollution? coal ethanol hydrogen oom > petrol During the analysis of 15.15 g of chalcopyrite, it was found that 5.27 g is copper, 4.61 gis iron and the rest is sulphur. ‘What is the simplest form of chalcopyrite? A Cures B CuFe,S c Cures, D Cu,Fe,S Which structure is for a protein? i A —C—o— ii B J—N—C °13 34 Which type of reaction is shown by the equation below? C,H, + Cl, —> HCI + C,H,CL A addition B hydration C substitution D polymerisation 35 Which two oxides are classified correctiy? [[snprtwiconte [bene Tal ao, | cu | B cuo Li,0 le t,o Zn0 a) 20 Al,Oy 36 The graph shows the temperature change when steam is reacted with carbon, temperature /°C time/s. ‘Which conclusion can be drawn from the graph? A Carbon is a reducing agent. Carbon contains some impurities. The reaction is endothermic. ooo The reaction is exothermic. Ta on oye ran12 30 The table shows the melting points of some Group | elements. 31 32 33 [element melting point/°C | lithium 16 sodium | o4 | “potassium | 60 Which is the most likely melting point of rubidium? A 155°C B 405°C © 655°C Which fuel would cause the least pollution? coal ethanol ° hydrogen 0 petrol D 100.5°C During the analysis of 15.184 of chalcopyrite, it was found that 5.274 is copper, 4.61 gis iron and the rest is sulphur. What is the simplest form of chalcopyrite? A CuFes B CuFe,S © Cures, D Cu,Fe,s Which structure is for a protein? i i i A —c—o—| |—C—F — I—C—o— HO HO HO » it (Il —N—C— —N—C c¢ —o— ——O—| —o— —o— a H 4 Do jy |—N—4 wo 37. The diagrams show beakers containing different liquids, ilute hydrochloric paraffin aqueous water acid sodium chloride ' " wv Which liquids turn cobalt chloride paper pink? A tonly Blandi © |Iland Iv D_ IVonly 38 The equation shows the oxidation of sulphur dioxide. 280, + 0; —> 280, How many moles of oxygen molecules are needed to oxidise four moles of sulphur dioxide to sulphur trioxide? A 05 B 1.0 c 20 DB 40 39 Why is graphite used as a lubricant? A Each atom has one electron that conducts electricity. B Its atoms form a spherical structure. © The layers of atoms can slide over each other. The atoms form very long molecular structures.15 40 The equation represents the decomposition of hydrogen peroxide. 2H,0 — 2H,0 + 0, The tabie shows two experiments X — experiment total volume of oxyger collected /cm* and Y carried out to measure the rate of oxygen production. nt concentration of hydrogen | peroxide / mol/dm? 200 1.0 300 0.8 Which graph shows the rate of oxygen produced from experiments X and Y? A volume of oxygen/ em? concentration of hydrogen peroxide/mol/ dma ° volume of oxygen/ m3 concentration of hydrogen peroxide/mol/cim? volume of oxygen/| om? te concentration of hydrogen peroxide /mol/dm? D volume of oxygen/ cm? concentration of hydrogen peroxide/mol/dms2 4. Which diagram represents the structure of an atom? 2 Anore of iron which contains 80% pure iron(II) oxide by mass is used to extract iron as shown by the equation below. Fe,0, + 3CO —> 2Fe + 3CO, What is the mass of iron that can be extracted from 200kg of the ore? 56 70 12 160 ooo, 3. Which substance is diamond an allotrope of? A coal B graphite C limestone Dd silica © BEC 2004 mHORVON3 4 Transition elements are metals with variable valencies. ‘What is the meaning of the underlined words? The compounds of the elements are often used as catalysts. The elements form cations of different charges: The elements form different coloured compounds. voap The elements have high melting points. 5 Dilute hydrochloric acid is added to marble chips as shown in the diagram below. cotton wool. dilute hydrochloric / acid marble chips balance What happens to the balance reading as the reaction continues? A decreases o increases € decreases then increases D increases then decreases 6 The diagrams show the atomic structures of elements V, W, X, ¥ and Z. (2x\ (\ [(F a ©G©OO © v Ww x Y z @ Which two elements combine to form an ionic chioride? A Vand W B Wandz © Xandy DB Yandz BEC 2004 9570101008 [Tum ove7 Which two elements are present in bronze? carbon and iton copper and zine copper and tin gomn> lead and tin 8 The diagram shows the electrolysis of concentrated aqueous sodium chloride using platinum electrodes anode — platinum electrodes Which equation represents the anode reaction? A 2cl > Cl, + 2e Bo 2Ht + 26 > H, © Nat +e —> Na D 40H > 2H,0 + 0, +407 2 BEC 200 asraiDLOmM05 t 9 Which substance is correctly matched with its use? —] substance ust | A aluminium making dril bits BY diamond | making cooking pots ie polythene | making electrodes Db zine | making galvanized iron | 10. The equation shows the fermentation of glucose. yeast » 2C,H,OH (ag) + 2CO, (g) CaH,,.0, (aq) Why is the temperature of this reaction carefully controlled? A to keep the enzymes active B to slowly drive away carbon dioxide © to prevent the formation of ethanoic acid D to hydrolyse the glucose 11 What is the order of increasing reactivity in Group and Group VII? j Group | Group Vil | least most st most | “reactive "reactive | reactive reactive (cs ett ee ee a a a BEC 200 sro vostwo4 [Turn over6 412. Which apparatus in the electrolysis diagram is the electrolyte? ooaP oprov 13 Which pair of compounds decompose on heating? A ALO, and CulOH), B Cu(OH), and Mg(OH), © Mg(Oh), and Na,CO, D Na,CO, and ALO, 14 How many hydrogen molecules are formed when 6 atoms of aluminium react completely with dilute hydrochloric as shown by the equation below? 2AL + GHC! — 2AICI, + SH, A 3 B6 eg D 12 15 Which process does net involve combination with oxygen? A combustion B photosynthesis © respiration Dusting EC 2004 os70i0vonu08uf 7 16 The graph shows the total volume of hydrogen produced by the reaction between dilute hydrochloric acid and magnesium at different times. At which point on the graph is the reaction rate highest? total . volume of “e 2 gas/em 17. The equation shows the decomposition of calcium carbonate. CaCO, (s) > CaO (s) + CO, (g) Which statement about the reaction is correct? Both products are acidic. Both products are ionic. The reaction requires strong heating. oom D> The reaction is a redox reaction. 18 The pHi values of four aqueous solutions P, Q, R and § are shown, [ lemon | potassium | sodium | sulphuric | | juice chloride | hydroxide acid | A a P — Q | R - s |B | a R | 8 P | c R s | Pp a | Oo; os Pp | 8 R | 066 2008 osraovornvos8 19 Which statement is correct for all exothermic reactions? They are oxidation reactions. They are reduction reactions. They absorb heat energy from the surroundings. vom They give out heat energy to the surroundings, 20 Which reaction takes place at room temperature? A Cus) + 2HCilaq) => CuCi,(s) + Hy (a) B 2Ag(s) + CuSO, (aa) —> Ag,SO, (aq) + Cu(s) © 2KBr(aq) + Cl, ig) > 2KCl(aq) + Br, (l) D 30,(g) + 4Au(s) > 2AU0, (s) 21. The diagram shows the arrangement of electrons in an ion of element X. + What is the atomic number of clement X? A 16 BOT c 18 D 19 22 Which method is used to prepare barium sulphate, BaSO,, from the reaction shown by the ‘equation below? Ba(NO,), (aq) + H3SO, (aq) —> BaSO, (s) + 2HNO, (aq) A. crystallisation B filtration C neutralisation D precipitation @ BEC 2004 57010 V09 23 The diagram shows an experiment in which lmewater turns milky when dilute nitric acid reacts with solid ¥. / \ sie a E -limewater Cages) solid ¥ What is solid Y? calcium hydroxide A B copper({l) carbonate © iron(iIl) oxide D zine sulphate 24 What is the purpose of cryolite in the extraction of aluminium from aluminium oxide? to increase the aluminium content of the aluminium oxide to lower the electrical conductivity of the aluminium oxide to lower the melting point of aluminium oxide coaE to remove the sand impurity from aluminium oxide 25 How many atoms of calcium, Ca, phosphorus, P, and oxygen, O, are there in a molecule of calcium phosphate, Ca,(PO,),? | ca pr | o jae Dos | 4 ve! 2 | 3 | 8B ix | 4 i) los BEC 2004 osraoronwoa [Turn owa 10 26 Deuterium, 70, is an isotope of hydrogen. What is the chemical formula of water formed from this isotope? A DO B 0,0 Cc D,0, D bo, 27 Solid X sublimes on heating but solid ¥ does not, Which set-up is used to obtain X from a mixture of solids X and ¥? 28 Why is magnesium oxide used for lining a blast furnace? A Itis.a solid at room temperature and pressure. B It forms a giant molecular structure. C_ Ithasa very high metting point. D Itis an alloy of magnesium and oxygen. 29 Which source of eneray is used for generating electricity without causing pollution? A biogas B coal C natural gas o tidal power BEC 2008 57001011008GS, " 30 When zinc turnings are added to a solution of a metal nitrate, metal P is deposited and a solution of zinc nitrate is produced. What is metal P? A aluminium B calcium citron D sodium 31 Which fuel does not contain alkanes? charcoal fossil fuels natural gas vomp petroleum 32. The diagram shows an apparatus used to measure the percentage of oxygen in the air. 90cm! of ait copper(li) oxide 4 —_| H 100]80 60 40 20b=e—O Safe 40 60 80 100 A t t B heat The copper turnings are heated and 90 cm? of air are passed over them. What is the final volume of air in the syringe? A 20cm B 720m? © 79¢m? 9 80cm? © BEC 2004 asroonvonos (Turn over€e 12 33 Which material cannot be recycled? A aluminium can, B glass C paper D petroleum 34 The relative molecular mass of an organic compound X that decolourises aqueous bromine is between 10 and 36. What is X? A CH, BCA, CCH, D CH,OH 38 Which polymer is correctly matched with its use? | | polymer use | aA | fats production of clothes | B nylon making floor ceramic tiles Cc. polythene making lubricating oll D protein body building | © BEC 2008 os yD uo MOG13 36. The table shows the melting and boiling points of some Group 1 elements, | element melting point | boiling point ig point | c | ne sodium | 98 | 890 1 | | | potassium, an i caesium | wubidim |__matting point a4 700 64 | 774 a3. 1007 120 817 37 The diagram shows the preparation of dry chlorine in the laboratory concentrated hydrochloric fl acid potassium mangnate( VII) chlorine water concentrated sulphuric acid What is the purpose of the water and of the concentrated sulphutic acid? ‘ater concentrated sulphuric acid to absorb hydrogen chloride to absorb water to ansorb wet chlorine to oxidise hydrogen chloride to hydrolyse manganese(It) chloride to absorb excess chlorine {o oxidise potassium chloride to reduce hydrogen chloride eee 2008 No: [Turn over4 38. The diagram shows a chromatogram obtained after the analysis of four different proteins, P,Q, R and S, by using a protein digestion enzyme solvent. ; FJ e ee} e e e e e e e e oe e+ — Pa sR S$ ~ starting fine How many different components do the four proteins contain? A 4 B7 c 8 DoW 38 Which organic substance is obtained by cracking decane, C igtts.? How to A peo B HOH HOH Ho L_ | 1 oii c § § b a HOH 4 @ PEC 2008 asrow ons15 40 Which property of solid $ is measured by using the set-up shown? stirring rod \}] | __—-0°C - 150°C thermometer glass tube rubber band — ~ solid S _-—---water in a beaker gentle heating boiling point conductivity melting point com > solubility Conprgte nekromiadgerens Eenry reason tot has been maa o ace 8 copy hola, The publehers woud be pss o Near liom anyone whose sighs we have uneitingly veinge, ‘rivet of Cambri Insert Examinations pt of he Uren of Carnage Leal Examations Synakate (UCLES), which soll a doparment ofthe Unversty of Cambridge BEC 2004 osTaovonves2 1 The diagram shows the change in particle arrangement when steam undergoes Process x. oO process X ° C2 Qq0, °° 5388 What is process X? $2 A condensation B freezing Cc melting D__suiblimation 2. How many protons are there in a sodium ion, Nat? A 10 Bo c i2 D 23 3. Which graph represents the cooling curve af a pure substance changing from its gaseous state to its solid state? { N | NN temperature / temperature \ c temperature) \ | t oy ime ie out 057010 1011053 4 The electronic structures of Xand Y are as shown X= 2,882 V=2,8,7 What are the formula and bonding in the compound they form? formula | bonding XY | covalent x ionic | XY, | covalent X¥ | _ionie | 5 Asalt, AT, is prepared by the reaction shown RCO, + 2HT — 2AT + CO, + H,0 This reaction can be carried out by the method of titration. What are the solubilties of the carbonate A,CO,, the acid HT and the sat RT? | carbonate of a _ acid H T _ T salt RT | insoluble | insoluble insoluble insoluble soluble: | soluble soluble | insoluble insoluble | souble | —_ soluble soluble | @ What happens to the movement and size of molecules of water if its temperature Is decreased from 60°C to 25°C? movement of molecules size of molecules | faster decreases | | B faster remains thesame | co) slower | decreases | D | slower | stays the same | BEC 2005, 570011005 (Turn ovs4 7 Which organic compound is correctly matched with its property? | _erganiecompound “propery VA i ethane | polymerises to form poly(ethane} | By ethanol | decolourises aqueous bromine c ) ethanoic acid reacts with magnesium to form hydrogen ' jo) undergoes substitution reaction with chlorine | ethene . _t 8 Which diagram shows the structure of an ester? H B | con H— | H ° D —c—oH H- 9 Chlorine is bubbled into four different liquids as shown In which diagram does an orange colour form? B chlorine bromine c D chlorine chlorine chlorine, ce tf re ii universal i aqueous F} ‘indeater iH potassium solution Ce bromide © BEC 2005 psraavomnes5 10 Which substance in the table is a liquid at 25°C? boiling point/°C A) 165 92 | a | 7 | 559 | x 25 2 | lp | 650 | 1300 | 11 What type of oxide is calcium oxide? A acidic B amphoteric C basic D neutral 12 What is the mass of 2 moles of ethane, C,H,? [A: CG, 12;H, 1] A 18g B 30g © 36g 609 13° The diagram shows the structure of a molecule carbon | ; 5 carbon | hydrogen carbon | yyorog oxygen carbon BEC 2005 057010 WoNI05 flurn6 44. The diagram shows the electrolysis of aqueous copper(I) sulphate using copper electrodes. copper anode ~~ | — copper cathode aqueous copper(II) sulphate What is observed at the anode? A Bubbles are formed The anode becomes thicker. oo The anode becomes thinner. o The solution becomes colourless. 45. The electronic structure of X is 2,8,6 and that of ¥ is 2. Which is the most likely property of the compound formed between % and ¥? A conducts electricity when motten dissolves in water B C exists as a hard crystalline solic D has low molting point @SEC 2005 0570/0:/01N0S7 16 The diagram shows part of the Periodic Table with some elements represented by letters P, Q, P. 7 SandT. Which two elements combine to form an ionic compound? A Panda B QandR Cc Rands D SandT Dissolving concentrated sulphuric acid in water is an exothermic process. Which graph describes the temperature change when sulphuric acid is added to water and lett io stand until there is no change in temperature? A 8 4 ‘ wcon / : toon temperature [~~ ~~ = > © rere a time * 8g ime c uD 4 4 room | co ----- ~- ~~ temperature temperature perature8 18 What are the approximate relative masses of an electron, a neutron and a proton? 7 7 electron neutron | _proton A 1 1/1840 1/1840 Bo 11840 1/1840 | jc 1 wre4o | 1 | i) St 19 What ere the products of the complete combustion of methane? A. carbon dioxide and hydro. B carbon monoxide and hydrogen C carbon dioxide and water D carbon monoxide and water 20 Which gas is present in the exhaust of a car engine in much greater amount than any other gas? A. carbon dioxide B carbon monoxide © nitrogen D steam 21 Carbon-12 and carbon: 4 are two isotopes of carbon. How many neutrons are present in an atom of each of those isotopes? TAD ee | B 6 | 8 fe) 8 6 BD 14 REC 2005, omni ve22 23 24 BEC 2005 9 ‘Which equation shows the reaction between ammonium sulphate and sodium hydroxide? A INH,},80, + 2NaOH —> 2NH, + Na,SO, + 2H,0 B (NH,),SO, + NaOH — NH, + Na,S0, + H,0 C (NH,),SO, + 2NaH > 2NH, + Na,SO, + 2H,0 D_ (NH,},SO, + NaOH > N, + Na,SO, + H0 Which element in Group Vil is the most powerful oxidising agent? A bromine B chlorine © fivorine D iodine The table shows the reaction 5 of metals X, Y and Z with cold water and dilute hydrochloric acid, reaction with dilute hydrochloric acid metal | reaction with cold no reaction slow reaction violent reaction x Y fast reaction Zz no reaction I What is the reactivity of the metals starting with the most reactive? most reactive — t reactive A x Y Zz 8 Y x Zz c Y z x D z Y x10 25 The diagram shows a blast furnace used for the extraction of iron. Pp L — raw materials firebrick lining | exhaust gases. molten iron | A | Pp i a | B P R c | a | R | D RD | o | | alloy elements } My brenze tT per and zine | is brass | capper andtin | c mild steel iron and carbon iD | stainless stee! | iron and aluminium | GEC 2005 som WOIRvS9 22 Which equation shows the reaction between ammonium sulphate and sodium hydroxide? A (NH,),80, + 2NaOH —» 2NH, + Na,SO, + 2,0 B iwny,s0, + NaOH > NH, + Na,SO, + H,0 © INH,),S0, + 2NeH 5 2NH, + Na,SO, + 2H,0 D_ (NH,),80, + NaOH 5 N, + Na,S0, + H,0 23° Which element in Group VI is the most powerful oxidising agent? A bromine B chlorine © fluorine D iodine 24 The table shi ws the reactions of metals X, ¥ and Z with cold water and dilute hydrochloric acid. | metal | reaction with cold water | teaction with dilute | - _|__ hydrochloric acid | x no reaction | slow reaction | Y fast reaction | violent reaction | L2 no reaction no reaction | What is the reactivity of the metals starting with the most reactive? most reactive —» least reactive A x Y z 8 Y x Zz c Y z x D Zz Y x osroroinvos {Turn overn 27 Which ion is present in the greatest concentration in dilute sulphuric acid? A HY B OF © On D so? 28 The ionic equation for the reaction between iron( Ii) sulphate and potassium iodide is given. 2Fe+(aq) + 2I-(aq) — 2Fe**(aq) + L(s) Which statement about this reaction is correct? A fodine atoms are oxidised. B Iodide ions are reduced. C _Iron(Ifl) ions are reduced. D Iron{Ili) ions are oxidised. 29° Why are alkali metals stored in paraffin? A. They have low melting points. ‘They readily react with oxygen in air. ‘They decompose when exposed to air. oo They have low densities compared with other metals. y 30 Why are alkanes used as fuels? They are made of hydrogen and carbon atoms. They are produced from the distillation of oil. They have single bonds between all their atoms. sooD They release useful heat energy when burnt. 31 Which methods are used to soften temporary hardness and permanent hardness in water? | temporary permanent boiling ion exchange | B distillation boiling | oc ionexchange boiling @ BEC 2005 osra10 vores (Turn esse ay32 33 34 12 Which process uses sodium carbonate? A. extracting iron making fertilisers making glass vo preserving food The equation shows the reaction between aqueous silver nitrate and aqueous sodium chloride: AgNO,(aq) + NaCi(aq) —> AgCl(p} + NaNO,(q) What state symbols do p and q represent in the equation? A colourless solution X reacts with aquecus sodium hydroxide to form a white precipitate which dissolves in excess sodium hydroxide. Which ion is present in X? A Catt B c D Zn’?" 27° Which ion is present in the greatest concentration in dilute sulphuric acid? A Ht B OF Cc OW D so, 28. The ionic equation for the reaction between iron(III) sulphate and potassium iodide is given. 2Fe"+(aq) + 2I-(aq) —> 2Fe?*(aq) + L(s) Which statement about this reaction is correct? A Iodine atoms are oxidised B Iodide ions are reduced. C _tron(IIl) ions are reduced, D ron(II}) ions are oxidised 29° Why are alkali metals stored in paraffin? A They have low melting points. B_ They readily react with oxygen in air. © They decompose when exposed to air. D They have low densities compared with other metals, Y 30 Why are alkanes used as fuels? Thoy are made of hydrogen and carbon atoms. , They are produced from the distillation of oil They have single bonds between all their atoms. goa» They release useful heat energy when burnt, 31 Which methods are used to soften temporary hardness and permanent hardness in water? 7. ee | temporary permanent | al boiling ion exchange | distillation boiling | B © ion exchange boiling D | precipitation crystallisation BBEC 2005, 0570: uOANWOScor 12 32 Which process uses sodium carbonate? A extracting iron B_ making fertilisers making glass D preserving food 33 The equation shows the reaction between aqueous silver nitrate and aqueous sodium chloride. AgNO,{aq) + NaCliaq) —> AgClip) + NaNO,(q) What state symbols do p and q represent in the equation? 34 A colourless solution X reacts with aqueous sodium hydroxide to form a white precipitate which dissolves in excess sodium hydroxide, Which ion is present in X? A Ca’* BONH,* Cc s0,? Do znt* @BEC sro womnvos13 35. Equal masses of magnesium powder are added to four different concentrations of dilute hydrochloric acid. In each case, the acid is in excess. The total volumes of hydrogen given off are measured at room temperature and pressure. Which graph is obtained for the acid of lowest concentration? volume of hydrogen 3 36 Which of the following is an ore of zinc? A bauxite B biende € cryolite B haematite 37. Why is oxygen blown into molten pig iron during A to make iron oxide B to make the steel brittle © to remove excess carbon D to solidity the iron 38 Why do copper(I!) sulphate crystals turn white when heated? Copperill) oxide powder is formed, Sulphur dioxide gas is given off a 8 Copperili) sulphate is reduced to copper(!} sulphate. c D Water of crystallisation is lost. BEC 2005