Nanotechnology and Nanotech Materials in
Nanotechnology and Nanotech Materials in
Nanotechnology and Nanotech Materials in
Natural
Nanomaterials Carbon Based
Nanomaterials
Matal Based
Artificial
Nanomaterials
Dendrimers
Composites
Now, let’s discuss each nanomaterial briefly unique electrical properties, and thermal conductivity. They
are also durable mechanically and have crack preventing
1.6.1 Carbon Nanotubes (CNTs) ability that’s why it can be used in concrete. Their
Carbon nanotubes are in the shape of hollow enhanced mechanical and thermal properties can be used in
cylinder made up of carbon atoms having two dimensional ceramics. They are five times stronger than Young’s
hexagonal lattices. As they structurally belong to fullerene modulus and eight times stronger than steel.
family therefore they show the extraordinary strength,
Fig. 6(a) Structure of Aluminium Oxide Nanoparticles Fig. 6(b) Aluminium Oxide Nanopowder
Fig. 7(a) Structure of Zinc Oxide Nanoparticles Fig. 7(b) Zinc Oxide Nanopowder
Fig. 8(a) Structure of Zirconium Oxide Nanoparticles Fig. 8(b) Zirconium Oxide Nanopowder
Fig. 9(a) Structure of Silicon Dioxide Nanoparticles Fig. 9(b) Silicon Dioxide Nanopowder
Fig. 10(a) Structure of Titanium Dioxide Nanoparticles Fig. 6(b) Titanium Dioxide Nanopowder
Fig. 11(a) Structure of Wolfram Trioxide Nanoparticles Fig. 6(b) Wolfram Trioxide Nanopowder
2. INTRODUCTION OF NANOTECHNOLOGY IN which hardens with time. Concrete have some major
CIVIL ENGINEERING properties like Mechanical Strength, Compressive Strength,
Civil Engineering does not only mean Durability, Porosity, Density, Thermal and acoustic
construction of residential buildings, it have to deal with a insulation. These properties can be improved by
lots of fields such as construction of Roadways, Bridges, nanotechnology and nanomaterials.
Canals, Tunnels, Traffic Systems, Public transportations Nano-silica (SiO2) densifies the micro and
and other structures that operate on large scale. These fields nanostructure of Concrete. This results in improvement of
require special treatment from Earthquake, Winds, Massive mechanical properties of concrete. Nano-silica has the
Public Movement and even Military strikes. By using property to control degradation of fundamental Calcium-
nanotechnology, these structures can be strengthened. Silicate-Hydrate (C-S-H) reaction of concrete caused by
Nanotechnology can be applied to build lighter but stronger calcium leaching in water penetration, therefore leads to
structural composites. Nanotechnology have the property improve durability. Nano-silica can also be used for pre-
of Low maintenance coating, Improved pipe joining existing concrete structures. Fiber sheet (also known as
materials and techniques, Better properties of cementitious Matrix) containing nano-silica along with hardeners,
materials, Reduced thermal transfer rate of fire retardant penetrate in small cracks and fills them. Fiber Sheet forms
and insulation, Increased sound absorption of acoustic very good bond between surfaces of concrete and fiber
absorber, Increased reflectivity of glass, water repellents, reinforcement, resulting in improvement of particle
nano-clay filled polymers, self-disinfecting surfaces, UV packing in concrete and gives very good strength.
light protector, air cleaners, nano-sized sensors, and solar Titanium Dioxide (TiO2) is also a nanomaterial
cells. These reasons are strong enough for nanotechnology used for improved performance of concrete owing to its
to be beneficial for construction industry. property to break down the organic pollutants, volatile
2.1 Improvement of Construction Materials using organic compounds and bacterial membrane via catalytic
Nanotechnology reactions. It can therefore reduce airborne pollutants. In
Civil Engineers have to deal with many like manner, TiO2 have self-cleaning property, for this
construction materials such as cement, concrete, steel, reason they attract and make sheet of rainwater to the
wood, glass etc. They also have to go through different concrete surface and then this sheet collect the pollutants as
construction processes like structural monitoring, painting, well as dirt particles and washes them off. This result the
coating, thermal insulation, fire protection etc. these concrete surfaces clean and good aesthetically as they
materials and techniques require some standard time to remain the concrete surface white.
achieve their particular strengths. By adaptation of Carbon Nanotubes (CNTs) can also be used for
nanotechnology these processes can be enhanced by means health monitoring and damage detection of concrete as they
of strength and performance. improve compressive strength. Adding CNT in cement can
2.1.1 Improvement of Cement using Nanotechnology give better void filling thus better concrete can be casted.
(Nano Cement)
2.1.3 Improvement of Steel using Nanotechnology (Nano
Cement is a basic and must material for
Steel)
construction. As civil engineer we all know that the cement
Steel plays an important role in construction. Steel
is a binding material commonly used to cast concrete.
can be used as reinforcement in concrete or fully steel
Portland cement is most commonly used cement. Lime
structure can also be constructed. Fully steel structure faces
stone, shells and chalk or marl combined with shale, clay,
fatigue problem. This leads the structure failure if steel is
slate, blast furnace slag, silica sand and iron ore are the
loaded in cycle loading manner. Fatigue problem occurs in
common materials to manufacture cement. Although
case of bridges, towers and off-shore platforms where the
particles of cement are very small but they are not at nano
stresses are lower than the yield stress. This problem can be
level that is why we can not get 100% result. Studying
covered using copper nanoparticles as they make the
cement at nano level, best results can be achieved.
surface of steel flat by reducing unevenness. Copper
There are two ways from which performance of
nanoparticles limit the number of stress risers which causes
cement can be improved. Particles of cement either can be
reduction in fatigue.
reduced to nano-level or some nanomaterials like carbon
Steel structural members are often joined by bolts.
fiber, carbon nanotubes can be added to cement. Latest
Steel bolts may fail when the tensile strength of tempered
researches found that Carbon Nanotubes give better results
martensite steel increases above 1200MPa. After this much
than Carbon Fiber. As discussed in 1.5.1, CNT have
tensile strength, very small amount of hydrogen embrittles
various properties like extraordinary strength, thermal
the gain boundaries. This phenomenon is known as delayed
resistivity, durability and crack prevention, therefore it is
fracture and it can cause the steel failure during use. High
very beneficial to use CNTs as an additive in cement. Also
strength bolts usually falls under this phenomenon. It can
dimension of CNT varies from 0.25 to 25nm hence their
be limited by use of Vanadium and Molybdenum
particles will fill the voids between large sized cement
nanoparticles. These nanoparticles are reduces the
particles and will provide better strength.
embrittlement of hydrogen which directly is responsible for
2.1.2 Improvement of Concrete using Nanotechnology steel bolt strengthening. They limit their strength in
(Nano-Crete) between 1000 to 1200MPa.
As we all know, Concrete is a mixture of cement, Another problem faced by steel structure is
fine aggregate (sand), course aggregate mixed with water corrosion. There are two nanomaterials available in market
named Sandvik Nanoflex and MMFX2 steel. These two nanometer scale so that they can increase its durability and
nanomaterials have the ability to resist corrosion. By reduce heat of friction.
addition of these two nanomaterials, corrosion-less
structure can be constructed. 2.2 Nanotechnology in Construction processes
2.1.4 Improvement of Wood using Nanotechnology (Nano Public safety is preferred over any factor in
Wood) construction. To build safe structure, Civil Engineer must
Wood is also an important material for have to follow some construction processes. Using
construction. Wood can be fully used for construction of nanotechnology in the process may aid to build better
houses in villages specially. Woods are mainly preferred in structures. By the use of some nanoparticles, problems like
construction of doors and windows. Wood is a major thermal insulation can be reduced. Also there will be more
construction material in case of Timber Dams. Although safety from fire and bacterial attacks on structures.
they are temporary dams but the required strength to hold Many processes can be upgraded using
the water is must. As we all know that wood is much nanoparticles are discussed as below:
weaker material than concrete and steel. It can be
strengthen by addition of nanoparticles. As discussed in 2.2.1 Process of Thermal Insulation using Nanotechnology
1.5.5 about Al2O3 and in 1.5.8 about SiO2. These two Bodies having different temperature exchange
nanoparticles are water repellant therefore can be used as their temperature with each other. Reduction in heat
coating in wooden work. Water makes wood weak when it transfer between two or more objects is nothing but thermal
gets penetrated. By coating of Al2O3 and SiO2, woods insulation. In Civil Engineering many construction
become water repellant so water will not get a chance to be materials like concrete, steel, clay etc have the property to
penetrated resulting the structure more strong and durable. absorb heat. They absorb sunlight and transfer heat to the
room. This causes rise of room temperature which is not
2.1.5 Improvement of Glass using Nanotechnology (Nano good for human health. With nanotechnology, thermal
Glasses) insulation can be achieved by the help of some specially
Using glasses in construction is increasing day to engineered nanomaterials.
day. In last two decades, glasses were used in windows and There is a nanomaterial named Nanoporous Silica
doors but nowadays construction of fully glassed structure Aerogel has the property of low thermal conductivity, good
are getting popular. From this point it can be concluded compressive strength, light weight, fire protection anti-
that there should be improvement in glasses as they are fungal, low shrinkage ability, sound proof, non-toxicity,
brittle material. Improvement can be done through non-corrosive and eco-friendly. Owing to thermal
nanotechnology. insulation they can be used in construction so that
Glasses are generally used in exterior of a building reduction in heat transfer can be achieved.
which makes it look good. Using glass, in exterior, has to
face light and heat majorly. Sometimes heat can break the 2.2.2 Process of Fire Resistance using Nanotechnology
glasses. This is why fire-protective glasses are needed. It Fire is another problem for construction safety.
can be made using SiO2 nanoparticles. Fumed Silica is Structures should be constructed in such a way that it
sandwiched between two glass panels. This will make the should resist fire. In that way accidents caused by fire can
glass fire protective. As far as light is concerned, it can be be avoided.
controlled using Tungsten Trioxide nanoparticles. (Refer Researches conclude that nano-cement (refer
section 1.6.10) section 2.1.1) have some properties including thermal
resistance so it can be used as fire resistance material as
2.1.6 Improvement of Coatings using Nanotechnology well as coating on steel structure as steel absorbs more
(Nano Coatings) heat. Nano-cement is made by mixing CNTs therefore it is
Coating is nothing but a covering applied on the durable, fire protective as well as crack preventing. Other
surface of any object for decorative or functional or both than CNTs, there is nanomaterial called Polypropylene
the purposes. Coating is mainly done to reduce corrosion, which can also be used as fire resistive material because
as protective barriers against abrasion, ingress of harmful they also have property to prevent structures from fire.
chemical attack, hydro-thermal variations, to change the Also it is cheaper process than conventional materials used
electrical properties of metals and for good aesthetics. for fire resistivity.
The process of coating can also be improved
through nanotechnology. One of the nanomaterial 2.2.3 Process of reducing Bacterial Attack using
discussed in 1.5.9 i.e. TiO2, have the some properties to Nanotechnology
improve the coating work. They can enable the self Bacteria and fungi are one of the main reasons for
cleaning property and can enhance the abrasion resistance. degradation of construction materials. Their growth can
TiO2 coatings are used in roadways. By capturing organic also affect on human health. For these reasons Civil
and inorganic air pollutants, TiO2 may help in putting roads Engineers must take strict action on it.
to good environment. With the help of TiO2 powder, the bacterial attack
Furthermore, many new materials along with can be minimized because TiO2 powder has the property to
techniques are being developed to improve coatings at destroy bacteria and termites. Within 1 to 2 hours it
destroys all the bacteria. This will lead to healthy