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CHEMISTRY 9701/22
Paper 2 Structured Questions AS Core May/June 2014
1 hour 15 minutes
Candidates answer on the Question Paper.
Additional Materials: Data Booklet
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The number of marks is given in brackets [ ] at the end of each question or part question.
IB14 06_9701_22/3RP
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(b) Bromine exists naturally as a mixture of two stable isotopes, 79Br and 81Br, with relative isotopic
masses of 78.92 and 80.92 respectively.
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(ii) Using the relative atomic mass of bromine, 79.90, calculate the relative isotopic abundances
of 79Br and 81Br.
[3]
(c) Bromine reacts with the element A to form a compound with empirical formula ABr3. The
percentage composition by mass of ABr3 is A, 4.31; Br, 95.69.
Ar of A = ....................... [3]
(d) The elements in Period 3 of the Periodic Table show different behaviours in their reactions with
oxygen.
(i) Describe what you would see when separate samples of magnesium and sulfur are
reacted with oxygen.
magnesium
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sulfur
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[4]
(ii) Write equations for the reactions of aluminium oxide, Al 2O3, with
sodium hydroxide,
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hydrochloric acid.
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[2]
State the shape of and two different bond angles in a molecule of PCl 5.
[Total: 17]
2 A 6.30 g sample of hydrated ethanedioic acid, H2C2O4.xH2O, was dissolved in water and the
solution made up to 250 cm3.
A 25.0 cm3 sample of this solution was acidified and titrated with 0.100 mol dm–3 potassium
manganate(VII) solution. 20.0 cm3 of this potassium manganate(VII) solution was required to
react fully with the ethanedioate ions, C2O42–, present in the sample.
(a) The MnO4– ions in the potassium manganate(VII) oxidise the ethanedioate ions.
(i) Explain, in terms of electron transfer, the meaning of the term oxidise in the sentence
above.
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(ii) Complete and balance the ionic equation for the reaction between the manganate(VII)
ions and the ethanedioate ions.
(b) (i) Calculate the number of moles of manganate(VII) used in the titration.
[1]
(ii) Use the equation in (a)(ii) and your answer to (b)(i) to calculate the number of moles of
C2O42– present in the 25.0 cm3 sample of solution used.
[1]
[1]
[1]
(v) The relative formula mass of anhydrous ethanedioic acid, H2C2O4, is 90.
[1]
[Total: 9]
3 The elements in Period 3 of the Periodic Table show variations in their behaviour across the period.
(a) The bar chart below shows the variation of melting points of the elements across Period 3.
1800
1600
1400
1200
melting 1000
point / K 800
600
400
200
0
Na Mg Al Si P S Cl Ar
In each of the following parts of this question you should clearly identify the interactions involved
and, where appropriate, explain their relative magnitudes.
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(iii) Explain why Si has a much higher melting point than any of the other elements in the
period.
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(b) The graph below shows the variation of the first ionisation energies across Period 3.
1600
1400
1200
1000
first ionisation
800
energy / kJ mol–1
600
400
200
0
Na Mg Al Si P S Cl Ar
(i) Explain why the first ionisation energy of Ar is greater than that of Cl.
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(ii) Explain why the first ionisation energy of Al is less than that of Mg.
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(iii) Explain why the first ionisation energy of S is less than that of P.
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[Total: 10]
(a) Give the names of one physical process and one chemical process carried out during the
processing of crude oil.
(b) Alkanes and alkenes can both be obtained from crude oil.
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ethane, ................................................................................................................................
ethene. ................................................................................................................................
[1]
(iii) State the shape of each molecule in terms of the arrangement of the atoms bonded to
each carbon atom.
(iv) Explain why these molecules have different shapes in terms of the carbon-carbon bonds
present.
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(c) (i) Use a series of equations to describe the mechanism of the reaction of ethane with chlorine
to form chloroethane. Name the steps in this reaction.
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(ii) Write an equation to show how butane could be produced as a by-product of this reaction.
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[Total: 13]
On reaction with hot, concentrated, acidified potassium manganate(VII) solution a single organic
product, Q, is obtained.
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name of P ...........................................................................................................................
[2]
name of Q ...........................................................................................................................
[2]
(b) There are several structural isomers of P that also decolourise bromine, but only four of these
structural isomers exhibit geometrical (cis-trans) isomerism.
Give the structures of any three structural isomers of P that exhibit geometrical (cis-trans)
isomerism.
[3]
[Total: 11]
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