Arc Anachem Questions

Download as docx, pdf, or txt
Download as docx, pdf, or txt
You are on page 1of 4

ANALYTICAL CHEMISTRY

1. What volume of water must be added to concentrated HNO3 solution to prepare 50


mL 2.50 M HNO3 solution?
a. 7.91 mL b. 36.78 mL c. 42.09 mL d. 68.83 mL

2. A 15% wt/wt aqueous solution of CaCl2 (110.98) at 25°C has a density of 2.15 g/mL.
Express the amount of CaCl2 in this solution as follows:
i. % wt/vol
a. 15.74% b. 32.25% c. 55.36% d. 3.74%
ii. molarity (M)
a. 2.9 M b. 3.8 M c. 4.3 M d. 5.6 M
iii. molality (m)
a. 0.8 m b. 1.6 m c. 2.1 m d. 3.1 m

3. A sample of a CaCO3 of mass 1.233 g was dissolved in an acidic solution. The calcium
was precipitated as CaC2O4.H2O (146.11) and the ignited precipitate was found to
weigh 0.735 g. What is the percentage of CaO (56.08) in the sample?
a. 12.23% b. 15.67% c. 18.19% d. 22.9%

4. A mixture weighing 802.750 mg contains AlCl3 (133.33) and FeCl3 (162.20).


Ammonia was used to precipitate the chlorides followed by ignition forming
mixture of Al2O3 (101.96) and Fe2O3 (159.69) weighing 379.850 mg. Calculate the Al
(26.98) in the sample in % wt/wt.
a. 1.23% b. 2.34% c. 2.98% d. 3.51%

5. Determine the mass of a manganese ore so that the % wt/wt of MnO2 from it would
be thrice the mass of precipitate containing Mn3O4 in mg.
a. 37.99mg b. 31.22 mg c. 15.62 mg d. 10.08 mg

6. In order to obtain a pH of 9.00, determine the volume of 0.150 M HCl that must be
added to 12.760 mL of 0.100 M NH3. Ka = 5.5 x 10-10
a. 2.3 mL b. 5.5 mL c. 6.3 mL d. 7.7 mL

7. In order to reduce the original value of hydroxide ions concentration into one-
hundredth, determine the mass of NH4Cl (53.45) to be added in 570 mL of 0.050 F
NH3. Kb = 1.8 x 10-5
a. 2.9 g b. 3.1 g c. 3.3 g d. 3.5 g

8. A 15.66 mL of NaOH was needed to titrate 0.209 g of primary standard KHP (204.2).
Determine the molarity of NaOH.
a. 0.055 M b. 0.065 M c. 0.075 M d. 0.085 M
9. A 40.50 mL of NaOH (40.0) was used to neutralize 1.520 g of KHP (204.2). The
excess alkali was titrated with 9.00 mL acid (10.75 mg NaOH: 1 mL acid). Determine
the molarity of NaOH solution.
a. 0.04 M b. 0.14 M c. 0.24 M d. 0.34 M

10. A 25.150 mL of 0.082 N HCl was used to titrate 0.235 g calcite sample which
contains impure CaCO3(100). The excess acid was back titrated with 5.750 mL of
0.093 N NaOH. Determine the % wt/wt CaCO3 as percentage purity of the sample.
a. 32.50% b. 42.00% c. 45.50% c. 52.00%

11. A 1-g sample of each mixture was analyzed for its alkaline content using 0.132 M
HCl through double indicator method.
Mixture 1 2 3 4 5
V0-Ph (mL) 8.51 0.02 10.25 12.74 11.26
V0-MR (mL) 20.20 12.25 20.50 12.75 18.10

i. Which of the following mixtures contain NaHCO3?


a. Mixture 1 & 5 b. Mixture 2 & 4 c. Mixture 1 & 2 d. Mixture 3 & 4
ii. Calculate the purity of the sample containing NaHCO3 (84) only.
a. 11.5 % b. 12.5 % c. 13.5 % d. 14.5 %
iii. What is the % wt NaOH (40) for the sample containing a mixture of NaOH-
Na2CO3?
a. 0.3 % b. 1.3% c. 2.3 % d. 3.3%

12. Kjeldahl method was used to analyzed the nitrogen content of a 8.450 g of meat
sample. During digestion, the evolved ammonia was collected using 65 mL of 0.820
M HCl. A 20.30 mL of 0.52 M NaOH was used to titrate the mixture employing mixed
indicator method. Determine the % protein in the meat sample. Use 6.30 as factor
for meat products.
a. 2.0% b. 2.4% c. 2.8% d. 3.2%

13. A 47.65 mL of 0.110 M AgNO3 was use to titrate 1.75 g impure aluminum chloride
dissolved in water employing indicator K2CrO4. Find % AlCl3 (133.33).
a. 13.3% b. 24.4% c. 35.5% d. 46.6%

14. A 55.50 mL of 0.200 M AgNO3 was used to titrate a 760 mg mixture of BaBr2
(297.22) and LiBr (86.845). The excess AgNO3 solution was back titrated using 8.52
mL of 0.332 M KSCN employing ferric alum indicator. Determine % BaBr2 in the
sample.
a. 11.2% b. 14.2% c. 19.7% d. 22.5%
15. A 22.750 mL of 0.152 M AgNO3 was used to titrate a 450 mg NaCN-containing
sample, until permanently faint turbidity. Determine % CN (26).
a. 30% b. 35% c. 40% d. 45%

16. A 75 mL of 0.123 M KCN was used to titrate ammoniacal solution from 699 mg
nickel alloy. The excess cyanide was back titrated with 2.77 mL of 0.010 M AgNO 3.
What is the % Ni (58.69) in the alloy?
a. 19.2% b. 21.3% c. 32.7% d. 35.8%

17. A 29.01 mL of EDTA solution was used to titrate 0.521 g of primary standard CaCO 3.
A 40.00 mL of EDTA solution was used to find the hardness of 1.5 L sample of
mineral water through titration. Find the hardness of the mineral water in ppm
CaCO3 (100).
a. 359 ppm b. 367 ppm c. 402 ppm d. 431 ppm

18. A 33.33 mL of 0.121 M BaCl2 was used to precipitate sulfate from a 400 mg sample
of impure raw Na2SO4 (142.04) which was dissolved in water. A 7.00 mL of 0.25 M
EDTA solution was used to titrate the precipitate to Calmagite endpoint. Determine
the purity of sample.
a. 61% b. 71% c. 81% d. 91%

19. Determine the potential of the half reaction, 2H+(aq) + 2e-  H2(g) at 1.2 bar, 298.15
K and pH=7.
a. 0.1 V b. 0.4 V c. 0.7 V d. 1.1 V

20. A 22.72 mL of KMnO4 solution was used to standardized against 1.130 g Na2C2O4
(134) in acidic medium. Find the molarity of the KMnO4 solution?
a. 0.05 M b. 0.10 M c. 0.15 M d. 0.20 M

21. A 55.5 mL of 0.015 M K2Cr2O7 was used to titrate solution from 392.01 mg iron ore
dissolved in acid employing diphenylamine sulfonic acid indicator. What is the %
Fe3O4 (231.55) in the iron ore?
a. 95 % b. 92% c. 98% d. 90%

22. A 45.25 mL of 0.121 M Na2S2O3 solution was used to titrate the iodine liberated from
0.300 g of pyrolusite sample treated with KI. Determine the % MnO2 (86.94) in the
pyrolusite.
a. 79.3% b. 74.2% c. 70.5% d. 67.8%

23. A 27.73 mL of 0.006 M KMnO4 was used to titrate solution from water-pureed,
filtered and acidified 10.5 g cooked ham sample. The excess KMnO4 was back
titrated with 15.00 mL 0f 0.015 M FeSO4. Determine the ppm nitrite (46.01) in the
sample.
a. 800.8 ppm b. 900.8 ppm c. 457.5 ppm d. 237.6 ppm

24. A 8.10 mL of 0.01 M Na2S2O3 was used to titrate 90 mL of water in order to


determine its dissolved oxygen via Winkler Method. What is the ppm O 2 in the water
sample?
a. 5.3 ppm b. 7.2 ppm c. 9.5 ppm d. 11.1 ppm

25. A 250 mg sample of a solution which contains nickel (58.69) and cobalt (58.93) was
dissolved and diluted to 27 mL. A 15 mL aliquot was treated with a complexing
agent to produce a colored complex and the volume was adjusted to 28 mL. The
following data were obtained for the simultaneous determination in a 1.00 cm cell:
Wavelenth (nm) Molar absorptivity, ε [M-1-cm-1] Absorbance of
solution, A
Co Ni
510 18100 2770 0.408
656 630 8800 0.157

Calculate the ppm Co in the solution.


a. 800.8 ppm b. 900.8 ppm c. 457.5 ppm d. 237.6 ppm

You might also like