s as laalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.

N saaslaa
aad ad a aad a
d a Padasalai
aad a
d a aad a
d a d
aa a
d
ww.P.P ww.P.P ww.P.P ww .P.P ww .P.P
w
ww w ww w w www w ww w w ww ww
Lord i . Venkateshwara
N
i . etet
N i . N
i . eMatric.Hr.Sec.School,
N
tet
i . N
i . etet
N T.Kallupatti i . N
i . etet
N
a saaslaala a saaslaala a saaslaala a saaslaala a saaslaa
ww
aa
.P.P
d d Book
ww.P.P a a Back One.PMark
d d
ww.P
aad d Chemistry ww .P.Paad d
ww
d
aa
.P.P d
w
ww w ww w w w w
1.wwMetallurgy ww w w ww ww
Choose the N tet
ecorrect answer: N etet N etet N etet
a i . i . N a i . i . N a i . i . N a i . i . N
1.da s aslala has the composition
Bauxite
a a saaslala a saaslala a sa aslala a saaslaa
a ad
.P.P .PAl
. adad
P .P.Padad .P.Padad adad
.P.P
www w a) Al 2O3
ww wb)
w 2O3 nH2O c)
ww Fe
w w2O 3 2H2O d)None ww w of
w these www w
ww 2. Roasting of sulphide
ww ore gives the gas w
w(A).(A) is a colourless gas.
ww Aqueous solution of (A)
ww is
acidic..N t t
e egas (A) is e t t e t t e t t
a l a liaiThe.N a l alia.Ni.Ne a l alia.Ni.Ne a l a lia.Ni.Ne aslaa
aa)
sa s a
CO2 b)SO3 as a s a c)SO2 a sa s a d)H2S a sa s a a sa
d d
a3.aWhich d
a ad reaction represents d d
a acalcinations? d
a ad d
a ad
w .P.P
w one of thewfollowing.P.P
w w .P.P
w w w.P.P w w.P.P
w
www a) 2Zn + O2 ww 2ZnO
w w w
wb)ww2ZnS + 3O2 2ZnO
w
www+ 2SO2 www w
c) MgCO3etet MgO + CO2 etet d) Both (a) and (c) etet etet
a i .Ni . Noxide which cannot a i N
.be
i . N a i .Ni . N a i .Ni . N
4. The
d adsaasal l
metala
d a
d
l
saasa l a reduced to metal
d a
d saasal
by l a
carbon is
d a
d saasal l a
d a
d saaslaa
a a a) PbO
.P.P b).PAl
.Pa2aO3 c) ZnO
.P.Paa d) FeO .P.P aa aa
.P.P
w ww
w 5. Which of the w w w
metal
w w w w
w w w w
w w www w
ww w is extracted by Hall-Heroult ww process? ww ww
a) Al b) Ni
i . N . etet
N i . N . etet c) Cu
N i . N . ed)tetZn
N i . N . etet
N
6. Which
aslaala ofi the following statements,
aslaala i about the advantage
aslaala i of roasting of sulphide i
aslaala before
ore
d a sa
reduction
d is not true? d a
d sa d a
d sa d a
d sa d a
d saaslaa
aa
.P.P aa
.P.isP .P.Paa .P.Paa aa
.P.P
w ww
w a) ΔG 0 of sulphide w www greater than those
w wfor
w w CS and H S. w ww
w wwww
ww f ww ww 2 2 ww ww
b) ΔGr0 is negative for roasting of sulphide ore to oxide
c) Roastingi . N . etetof the sulphide toi.its
N N . N
tet is thermodynamically
eoxide i . N . etet feasible.
N i . N . etet
N
a
lala
asCarbon i ala i
aslasuitable a i
aslalafor metal sulphides. a
aslala i aslaa
a s
d)a and hydrogen a sare
a reducing a s
agents
a a sa a sa
adad
.P.P .P.P adad .P.Padad adad
.P.the
P adad
.P.P
www w 7. Match items in
ww w
column
w - I with the items
ww w of
w column – II and w
assign
ww w correct code. www w
ww ww ww ww ww
i . N . eteColumn-I
N t
i . N . etet Column-II
N i . N . etet
N i . N . etet
N
l
asal a a i l
asala a i l
asal a a i A B l
asala a Ci D aslaa
d a sa d a sa d a sa d a sa d a sa
a ad A Cyanide process
.P.P .P.P a ad (i) Ultrapure
.P.P d
a aGe (a) ww
a ad(ii) (iii) (iv) .P.P
P.P
.(i) a ad
w w w w w w w w w w w w w
www B
Froth w
wwfloatation (ii) w ww of ZnS
Dressing www www
process (b) (iii) (iv) (ii) (i)
N e te t N e te t N e t
e t N e t
e t
s as laaClia. i.Electrolytic
N
reduction s as
i.N Extraction of Al
laalia. (iii) s as laalia. i.N (c) (iv) (ii) s as a. i.N (i)
laali(iii) saaslaa
aad ad a aad a
d a aad a
d a aad a
d a d
aa a
d
ww.P.P D Zone refining ww.P.P (iv) Extractionww.P.P of Au (d) ww P.P
.(ii) (iii) (i) (iv) ww .P.P
w
ww w ww w w www w ww w w ww ww
(v) Purification of Ni
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
8.da saaslaala ore is separated
Wolframite
d d a
d
aala tinstone by theaprocess
saaslfrom d d saaslaala of d a
d saaslaala d a
d saaslaa
aa
.P.P .P.P aa aa
.P.c)P .P.Paa aa
.P.P
w ww
w a) Smelting ww ww b) Calcination ww ww Roasting d) Electromagnetic w ww
w separation wwww
ww ww
9. Which one of the following is not feasible
ww ww ww
a) Zn(s) N +N tet 2+ (aq)
eCu Cu(s).+N.Zn ete(aq)
t 2+ b) Cu(s) .+N.Zn ete2+t (aq) Zn(s) +.N Cu et(aq)
et 2+
a i . i . a i i N a i i N a i i . N
ac)
sa
lala + 2Ag+ (aq)
asCu(s) a sa slala + Cu(aq) 2+
aAg(s) saaslala+ Cu2+ (aq)
d)aFe(s) a sCu
a asla(s)la+ Fe(aq) 2+ a saaslaa
dad
a10. adad is used to extract.P.P adad adad adad
w .P.P
w Electrochemicalwprocess .P.P
w w w w w.P.P w w.P.P
ww
ww a) Iron ww ww b) Lead wwww c) Sodium ww ww d) silver ww ww
11. Flux is aesubstance
N tet which is used
N etetot convert N etet N etet
a i . i . N a i . i . N a i . i . N a i . i . N
aa)
sa
lal
asMinerala into silicate sa
a a slal a b) Infusible
a sa
l a
asal impurities to soluble a sa
l a
asalimpurities a saaslaa
d
a adc) Soluble impurities d
adinfusible impurities
ato d
a ad d) All of these .P.P d
a ad d
a ad
w .P.P
w w .P.P
w w .P.P
w w w w w.P.P
w
www 12. Which one of w
wwthew following ores is best w
www concentrated by froth ww w
–w floatation method? www w
a) Magnetite b) Hematite
i . N . etet
N i . N . etet c) Galena
N i . N . ed)tetCassiterite
N i .N . etet
N
13. Inathe a i
extraction of aluminium a i from alumina by i
electrolysis,
a cryolite is added a i
to
d ad
a)
la
sasLower l a
the melting d a
d
point
l l a
saasofa alumina d a
d
l l a
saasb)a Remove impurities d a
d a
l
asa
sfrom l a
alumina d a
d saaslaa
aa
.P.P .P.P aa .P.Paa .P.Paa aa
.P.P
w ww
w c) Decrease thew ww w
electrical conductivity w ww
w d) Increase w
theww
w rate of reduction www
w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N i . . Netet
Matric.Hr.Sec.School,
N T.Kallupatti
i . N . etet Page 1
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
aad a
d a aa d a
d a Padasalai
aa d ad a aad a
d a d
aa a
d
ww.P.P ww.P.P ww.P.P ww .P.P ww .P.P
w
ww w ww w w www w ww w w wwww
14. Zinc is obtained etet from ZnO by etet etet etet
i . N
i . N
laala reduction i . Ni . N i . N
i . N i . N
i . N
d a
d
a)
saasCarbon d a
d saaslaala d adsaasb)laalReduction
a using silver
d a
d saaslaala d a
d saaslaa
a a c) Electrochemical.Pprocess
.P.P aa
.P a a d) Acid leaching.P.P
.P.P aa aa
.P.P
w ww
w 15. Cupellation isw w
a
wprocess
w used for the w www
refining of w ww
w wwww
ww ww ww ww ww
a) Silver t t b) Lead c) Copper d) iron
i . N . ee
N i . N . etet
N i . N . etet
N i . N . etet
N
16. Extraction
a
aslala i of gold and silver a
aslala i
involves leaching with
aslalaa i
cyanide ion. silver is latera
aslala i
recovered by
aslaa
a sa a sa a sa a sa a sa
adad(NEET-2017)
.P.P .P.Padad adad
.P.c)P adad
.P.P adad
.P.P
www w a) Distillation ww ww b) Zone refining ww w w Displacement with
www w
zinc d) w
liquation
ww w
ww ww ww ww ww
17. Considering Ellingham diagram, which of the following metals can be used to reduce
alumina? i . N . et(NEET-2018)
N et i . N . etet
N i . N . etet
N i . N . etet
N
l a
asFeal a i aCul a
al a i l
asal a a i l a a
asal d) Zni aslaa
d a s
a)a d a s
b)a s c) dMg
a sa d a sa d a sa
a ad
.P.P .P.Pa ad a ad
.P.P a ad
.P.P a ad
.P.P
w w w w ww w w w w w w w w w
www 18. The following wwsetw
of reactions are used
www in refining Zirconium w
wZrw(impure) + 2I2 523Kwww ZrI4
e t t e t t e t t e t t
a ia.N Ne
i.1800K a ia.N i.Ne a ia.Ni.Ne a ia.Ni.Ne
d a
d
a
ZrI
sas4 la l Zr (pure)
d a
d
a
sas 2l
+a l
2I This method is
d a a
known
dsas la l as
d a
d sasa la l
d a
d saaslaa
a a a) Liquation
.P.P .P.Pa a b) van Arkel process a a c) Zone refining.P.P
.P.P aa aa
.P.P
w ww
w w www w www w ww d) Mond’s process
w wwww
ww 19. Which of the wwfollowing is used for concentrating ww ore in metallurgy? ww ww
a) Leaching
i . N . etet
N
b) Roasting
i . N . etet
N
c) Froth
i . N . etefloatation
N t d) Both (a)eand
i . N . N
tet (c)
i i i i
d d saaslaaincorrect
20. The
a
la statementsamong
d a
d aaslaala the following isasaaslaala
d d d a
d saaslaala d a
d saaslaa
a a a) Nickel is refined.Pby
.P.P a aMond’s process .P.b)
.P a aTitanium is refined .by
P aVan
P.P a Arkel’s process .P.P aa
w ww
w c) Zinc blende w www w ww w w w
w w www w
ww wwis concentrated by froth wwfloatation ww ww
d) In the metallurgy of gold, the metal is leached with dilute sodium chloride solution
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
21. In the a
aslala i
electrolytic refining ofa
aslala i
copper, which one of the
aslalaa i
following is used as anode?
a
aslala i aslaa
a sa a sa a sa a sa a sa
adada) Pure copper .P.P
.P.P adadb) Impure copper .P.c)P adaCarbon
d rod adad electrode .P.P
d) Platinum
.P.P adad
www w 22. Which of the ww
following
ww plot gives Ellingham
ww w w diagram www w www w
ww ww ww ww ww
a) ΔS Vs T b) Δ G0 Vs T c) ΔG0 Vs 1/T d) ΔG0 Vs T2
23. In the i . N . etet
Ellingham
N diagram, for i . N
the. eteformation
N t of carbon i . N . etet
monoxide
N i . N . etet
N
l
asΔS a a i
al0/T is negative ab) l
asΔG a a i
al 0/ΔT is positive asaasc)aΔG l a a
l 0 i l
asala a i aslaa
d a s
a)a d sa d /ΔT is negatived a sa d a sa
a ad
.P.P a ad
.P0.P a ad 0
.P.0,
P a ad
.P.P a ad
.P.P
w w w d) initially ΔT/ w w
ΔG0
w is positive, after w w
700C w ΔG /ΔTis negativew w w w w w
www 24. Which of theww w www
following reduction is not thermodynamically feasible?
www www
a) Cr2O 3+
tet 2
e2Al Al2O3 +.N 2Cretetb) Al O + 2Cr Cr O +N tet 2 3 2 3 ___
e2Al etet
a i .Ni . N a i i . N a i .Ni . a i .Ni . N
d a
d
c) l
saas3TiO l a
a + 4Al 2 Al O + 3Ti
d a
d
l l a
saas2a2 3 ___ d) none ofdthese adsaasal l a
d a
d saasal l a
d a
d saaslaa
a25.
.P.P a Which of the following .P.Pa ais not true with respect a a to Ellingham diagram?
.P.P aa
.P.P aa
.P.P
w ww
w w www w www w ww
w wwww
ww a) Free energy wwchanges follow a straight ww line. Deviation occurs wwwhen there is a phaseww
change.
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i
laalagraph for the formation i i i
d a
d
b)
saasThe d a
d saaslaalaof CO2 is a straight d ad
aala almost parallel atosaa
saaslline d d
freea
slalaenergy axis. dadsaasla
a
a a c) Negative slope of.P.CO
.P.P a a shows that it becomes
P a amore stable with increase
.P.P a a in temperature. .P.P
.P.P aa
w ww
w d) Positive slope w www w ww w w w
w w www w
ww ww of metal oxides shows wwthat their stabilities decrease ww with increase in ww
temperature.
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i asla2.
a i
la P – Block elements aslala - I
a i a
aslala i aslaa
a sa a sa a sa a sa a sa
a1.daAn
.P.P d aqueous solution .P.Paofdaborax
d is adad
.P.P adad
.P.P adad
.P.P
www w w ww w w
ww c) basic www w www w
ww a) neutral www b) acidic ww ww d) amphoteric ww
2. Boric acideis tetan acid because itsNmolecule etet (NEET) etet etet
a i . N
i . N a i . i . N a i . N
i . N a i . N
i . N
a sa s lal
a)acontainsa replaceable H+
a sa
l
asaion l a b) gives
a sa
l
asaup a
l a proton
a sa
l
asal a
a saaslaa
d
a adc) combines with .proton d
a ad to form water molecule d
a ad d
a ad d
a ad
w .P.P
w ww P.P w .P.P
w w .P.P
w w w.P.P
w
www d) accepts OH- w
wwwfrom water ,releasingww w w
proton. www w w
www
3. Which among
i . N . etet the following is inot
N . N . eateborane?
N t .N . etet
N .N . etet
N
a)Bla H i b)B H
3ala i c)B4H10 lalia i d) none of these a i i
saaslaa
2 la 6 l 6 l l a
d
4. a saasa of the following dmetals
Which
d a
d saasa has the largest abundance d adsaasa in the earth’sdcrust? adsaasa d a
d
aa
.P.P .P.Paa aa
.P.P aa
.Psodium
.P aa
.P.P
w ww
w a) Aluminium w www b) calcium w www c) Magnesium w wd)w
w wwww
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t Chemistry., Lord Venkateshwara
i . N . etet
N Matric.Hr.Sec.School,
i . N. Netet T.Kallupatti
i . N . etet Page 2
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s aslaalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
aa d a
d a aad a
d a Padasalai
aa d ad a aad a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww.P.P ww.P.P
w
ww w www w ww w w ww w w www w
5. In diborane, etetthe number of electrons etet that accounts fori.N banana
etet bonds is etet
i
laala . N
i . N a i. Ni . N i . N i . N
i . N
d a
d sa)
aassix
d a
d
b)sa
a slala
two c) four
d adsaaslaala d) three sala
d a
d a s la
a
d a
d saaslaa
a6.aThe element that does
.P.P a anot show catenation.Pamong
.P.P a a the following p-block .P.Pa a elements is aa
.P.P
w ww
w a) Carbon w www b) silicon w ww.c)P Lead
w w w
w
d)w germanium w ww
w
ww ww ww ww ww
7. Carbon atoms in fullerene with formula C60 have
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a) sp3a
aslala ihybridised a
aslala i
b) sp hybridised a
aslala i aslalaa i aslaa
a sa a sa a sa a sa a sa
adadc) sp2 hybridised.P.P
.P.P adad d) partially sp2 adaand
.P.P d partially sp3 hybridised .P.Padad adad
.P.P
www w 8. Oxidation stateww w
of w
carbon in its hydrides www w www w www w
ww ww ww ww ww
a) +4 b) -4 c) +3 d) +2
9. The basic N tet
estructural unit of silicates N etetis (NEET) N etet N etet
a i . i . N a i . i . N a i . i . N a i . i . N
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d d d d d
a ada) (SiO3) a adb) (SiO4) d . (.SiO4
a ad ) a ad
−4
.P.c)P
a a(SiO)− d) P
− 2 − 2
w .P.P
w w w.P.P w w w w P w .P.P
w
w
www 10. The repeating w w in silicone is v www
wwunit w wwww w
www
a) SiO2 t t b)
i . N . ee
N i . N . etet c)
N i . N . ed)tet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d a
d saasal l a
d adsaasal l a
d a
d saasal l a
d a
d saaslaa
aa
.P.P aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w w www w ww
w w ww
w w ww
w
ww ww ww ww ww
N tet
ethese N etefort a high moleculari.Nmass etet silicone polymer?i.N.N etet
11. Which i
laala . i .
of N is not a monomer a i . i . N i . N i
d a
d saasMe
a) SiCl d a
db) slala 3
saaPhSiCl c) d a saaslaal3a
MeSiCl
d d) Me d a saas2laala
SiCl
d d a
d saaslaa
aa
.P.P 3 aa
.P.P aa
.P.P .P.Paa2 aa
.P.P
w ww
w 12. Which of the w ww
following
w is not sp2 w ww
hybridised?
w w ww
w w ww
w
ww ww ww ww ww
a) Graphite b) graphene c) Fullerene d) dry ice
13. Theageometry
i . N . etet at which carbon
N i . N etet in diamond are bonded
N
atom
. i . N . etet to each other is i.N.N
N etet
lala i
asTetrahedral a
lala
ahexagonal i a
aslala i a
lala
asthese i aslaa
a s
a)a a s
b)a s c) a s
Octahedral
a d) none a s
ofa a sa
adad
.P.P adad
.P.P adad
.P.P .P.Padad adad
.P.P
www w 14. Which of the ww w
following
w statements is w
not
ww correct?
w www w www w
ww ww
a) Beryl is a cyclic silicate
ww ww
b) Mg2SiO4 is an orthosilicate
ww
c) SiOi4.N 4− e
. istethe
N t basic structural.Nunit
i . etet of silicates d) Feldspar
N i . N . etet is not aluminosilicate
N i . N . etet
N
l a a i
asal is soluble in HF only l a a i
al the presence of KF. l a a i
asaisl due to the formation l a a i aslaa
15.aAlF3
sa a sa asin a saIt a saasa ofl (NEET) a sa
d
a ada) K [AlF3H3] d
a adb) K3[AlF6] d
a aAlHd d
ad 3]
a[AlFH d
a ad
w .P.P
w w w.P.P w .P.c)P
w 3 w .PK.P
d)
w w .P.P
w
w
www 16 w
www wwww wwww w
www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i Column-I a i Column-II a i a i
d a
d saasal l a
d a
d saasal l a
d adsaasal l a A
d
B
a
d saasal lCa D
d a
d saaslaa
aa
.P.P A Borazole .P.P a a 1 B(OH)3 .P.P aa (a) w2 .P.Paa1 4 3 w.P.P aa
w ww
w w www w ww
w w w w w w w
ww B Boric wwacid 2 B3N3H w6w w
(b) w 1 2 4
w
3w
Ci.N . etet
Quartz
N 3 i.N Na. e2te[Bt4O5(OH)4]8H2O i.N.N
N ete(c)
t 1 2 i3.N . ete4t
N
i i i i
d a
d saaslaaD
la
Borax d a
d saas4laalaSiO2 d adsaaslaala (d) d
Nonea
d saasoflaathese
la
d a
d saaslaa
aa
.P.P aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w w www w ww
w  w w
w w w w
w w
ww ww ww ww ww
17. Duralumin
i . N . etetis an alloy of
N i . N . etet
N i . N . etet
N i . N . etet
N
a
lala
asCu,Mn i a
aslala i a
aslald) a i aslalaa i aslaa
aa)
sa b) Cu,Al,Mg
a sa c) Al,Mn
a sa Al,Cu,Mn,Mg
a sa a sa
adad
.P.P adad
.P.P adad
P.P
.of .P.Padad adad
.P.P
www w 18. Thermodynamically ww w w the most stable form
www w carbon is www w www w
ww ww ww ww ww
a) Diamond b) graphite c) Fullerene d) none of these
19. Thelacompound
i . N . etet that is used ini.Nnuclear
N . etet reactors as protective
N i . N . etet shields and control
N i . N . N
tet
erods is
a a l a i a laa l a i a laa l a i a l aal a i aslaa
d a sa s d a sa s d a sa s d a sa s d a sa
a ada) Metal borides b)
.P.P a ad oxides
.P.metal
P .P.c)P d carbonates .PP
a aMetal .a a
d d) metal a ad
.P.P
w w w carbide w w w w w w w w w w w w
www www www www www
20. The stability of +1 oxidation state increases in the sequence
ia.N .Netet i N
.In . etet
N i .N . etet
N i N
.In . etet
N
a i a i a i a i
d a
d
a) aAl
sasa l <
l Ga < In < Tl
d a
d
b) Tl
saasal <l a < Ga < Al
d
c)
ad
In <
saasal Tl
l a < Ga < Al
d
d)
a
d saasa < Al < Tl
Ga<l l a
d a
d saaslaa
a a
.P.P aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w w www w ww
w w ww
w w ww
w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N i . . Netet
Matric.Hr.Sec.School,
N T.Kallupatti
i . N . etet Page 3
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s aslaalia. i.N s aslaalia. i.N saaslaa
aad a
d a aad a
d a Padasalaiaad ad a aad a
d a d
aa a
d
ww.P.P ww.P.P ww.P.P ww .P.P ww.P.P
w
ww w ww w w ww w w www w wwww

i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaala d a
d saas3.
laalaP – Block elements
d ad saaslaala – II d a
d saaslaala d a
d saaslaa
a1.aIn which of the following
.P.P .P.Pa a , NH3 is not used?.P.P aa .P.P aa aa
.P.P
w ww
w w ww
w w ww
w w ww
w wwww
ww a) Nessler’s reagent ww wb)wReagent for the analysis ww of IV group basic radical ww
c) Reagent
i . N . etefor
N t the analysis of III
i . N . etet basic radical i.N.N
group
N ed)tetTollen’s reagent i.N.N etet
2. Which a i
aslalais true regarding anitrogen? a
aslala i a
aslala i a
aslala i aslaa
a sa sa a sa a sa a sa
adada) least electronegative
.P.P .P.Padadelement .P.b)adahas
P d low ionisation enthalpy .P.P adad than oxygen .P.P adad
www w ww w w w w
ww d) ability to formwp𝜋- w w
wwp𝜋 bonds with itselfww www w
ww c) d- orbitalswavailable w ww w
3. An elementt belongs to group 15 and
i . N . e et
N i . N . etet3 rd period of thei.periodic
N N . etet table, its electronic
N i . N . etet
N
configuration
l a a
asa2l 2 4 i would be l
asal3a a i l a
asal2 2a i l a a
asa6l 2 3 i aslaa
d a sa d a sa d a sa d a sa d a sa
a ada) 1s 2s 2p
.P.P b)P1s
. .P
2 d 2p
a a2s 2 c) 1s P2s
2
. .P a a2p
2 d 3s 3p
6 d) P
. 1s
.P
2 d 2p 3s 3p
a a2s 2
a ad
.P.P
w w w 4. Solid (A) reacts w w w
with strong aqueous w
NaOH w w liberating a foul w w w
smelling gas(B) which w w w
www www www www www
spontaneously burn in air giving smoky rings. A and B are respectively
tet
eand eteandt PH etetH2S eteand
t HS
a) P4a(red)i .Ni . N PH3 b) P4a i .N
(white)
i . N c)aSia .8Ni N
and
. d) P4(white)
a i .Ni . N
saaslaa
3 2
s as la l a s as la l a s asla l s asla l a
5.
aad a
In
d athe brown ring test,aad a
brown
d a colour of the ring
aad ais
d adue to aad a
d a d
aa a
d
ww.P.P a) a mixture ofwNo ww.P.P
and NO2 b) Nitroso .P.P
wferrous
w sulphate .PFerrous
wc)w .P nitrate d)ww ww.P.P
w
ww w ww w ww w w www w ww
Ferric nitrate
6. On hydrolysis,
i . N . etet PCl3 gives
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saasHlaa3PO
a) la 3
d b)s
a
d aaPH a
slal3a c) Ha3s
d d PO
a asla
4
ala d) POCla3s
d d a aslaala
d a
d saaslaa
a7.aP4O6 reacts with cold
.P.P .P.Paa water to give .P.P aa .P.P aa aa
.P.P
w ww
w w ww
w w ww
w w ww
w wwww
ww a) H3PO3 ww b) H4P2O7 ww c) HPO3 ww d) H3PO4 ww
8. The basicity
i . N . etetof pyrophosphorous
N i . N . N
tet ( H4P2O5) is
eacid i . N . etet
N i . N . etet
N
a) a
as4lala i b)sa 2 a
lala i c) 3 sa a
lala i d) 5 a
aslala i aslaa
a sa a a s a a s a sa a sa
a9.daThe
.P.P d molarity of given .P.P
dad
aorthophosphoric acid.P adad is 2M. its normality
solution
. P .P.P adadis adad
.P.P
www w ww w w w w
ww c) 2N w w
wwd) none of these ww www w
ww a) 6N ww b) 4N ww ww
10. Assertion t: tbond dissociation energy
i . N . ee
N i . N . etet of fluorine is greater
N i . N . etethan
N t chlorine gas .NN
i . etet
Reason:
l
asal a a i chlorine has more l
asal a i
electronic
a repulsion than l
asala i
fluorine
a l
asala a i aslaa
d a sa d a sa d a sa d a sa d a sa
a ada) Both assertion .and
.P.P P.P d
a areason are true and P a ad is the correct explanation
. reason
.P .P.P a ad of assertion. .P.P a ad
w w w b) Both assertionw w w
and reason are true w w
but wreason is not the w w w
correct explanation of w w w
www www www www www
assertion.
c) Assertion
i .N . etetis true but reasoni.N
N is. N
tet
efalse. i .N . etet
N i .N . etet
N
a i a i a i a i
d a
dd)
l
saasBoth l a
a assertion and reason
d a
d
l l a
saasa are false. d ad saasal l a
d a
d saasal l a
d a
d saaslaa
aa
.P.P .P.Paa .P.P aa .P.P aa aa
.P.P
w ww
w 11. Among the following, w ww
w which is the strongest w ww
w oxidizing agent? ww ww wwww
ww ww ww ww ww
a) Cl2 b) F2 c) Br2 d) I2
12. The correct i . N . etetorder of the thermal
N i . N . N
tet
estability of hydrogeni.halide N . etet is
N i . N . etet
N
i
laal>a HBr > HCl > HF saslaala i i
aala > HI i
d a
d saasHI
a)
d a
d a b) HF > HCl
d ad sa>aslHBr d a
d saaslaala d a
d saaslaa
a a c) HCl > HF > HBr.P>.P
.P.P aa .P>.P
aHCl
a > HF > HBr .P.P aa aa
.P.P
w ww
w w ww HI
w
d) HI
w ww
w w ww
w wwww
ww 13. Which one of wwthe following compounds ww is not formed? ww ww
a) XeOF 4etet b) XeO3Netet c) XeF2 etet d) NeF2 etet
a i . N
i . N a i . i . N a i . Ni . N a i . N
i . N
14. Most
a saaslalaeasily liquefiable agas sa ala
aslis a sa aslala a sa aslala a saaslaa
adada) Ar
.P.P .P.Padadb) Ne adaHe
.P.c)P d d).P Kr
.Padad adad
.P.P
w w
ww 15. XeF6 on complete w w
ww hydrolysis produces ww w w www w www w
ww ww ww ww ww
a) XeOF4et t b) XeO2F2et t c) XeO3 etet d) XeO2 etet
i . N
i . N e i . N
i . N e i . Ni . N i . N
i . N
16. On
s l
asal aoxidation
a with iodine,
s l
asal a
sulphite
a ion is transformed
s l
asala a to
s l
asala a s aslaa
d a a
a ada) S4O6 d a a
a adb) S2O6 d ad4 a d
a3ada a d a
a ad a
.P.c)P
a aSO d) P
. SO
2− 2− 2− 2−
w .P.P
w 17. Which of the w .P.P
w
following is strongest acid w w
among all? w w .P w .P.P
w
w
www wwww wwww w
www w
www
a) HI b) HF c) HBr d) HCl
18. Which i .N one
. etetof the following orders
N i .N . eteist correct for the bond
N i .N . N
tet
edissociation enthalpy i .N of
. ethalogen
N et
a i a i a i a i
d a
d saasal
molecules?
l a
(NEET) da d saasal l a
d ad saasal l a
d a
d saasal l a
d a
d saaslaa
aa
.P.P .PP aa aa
.P.c)P .P .Paa aa
.P.P
w ww a) Br2>I2>F2>Cl w 2ww. b) F2>Cl2>Br2>Iw2w ww I2>Br2>Cl2>F2 ww d)w
w Cl 2>Br2>F2>I2 www
ww w ww w ww ww ww w
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N Matric.Hr.Sec.School,
i . N . Netet T.Kallupatti
i . N . etet Page 4
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s aslaalia. i.N s aslaalia. i.N saaslaa
d
aa ad a d
aa a
d a Padasalaiaad ad a aa d a
d a d
aa a
d
ww.P.P ww .P.P ww .P.P ww .P.P ww.P.P
w
ww w ww w w ww w w www w www w

i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d dsaaslaala the following the
19. Among
a d a
d
aslaala order of acidityasa
sacorrect d d
a
slala
isa(NEET)
d a
d saaslaala d a
d saaslaa
a a a) HClO2 < HClO <.PHClO
.P.P a a 3 < HClO4
.P a aHClO4 < HClO2 < HClO
.P.b)
P .P.P a a< HClO3 aa
.P.P
w ww
w c) HClO < HClO w w
w w< HClO < HClO w w
w w d) HClO < HClO w
<
w
w w
HClO < HClO w w
w w
ww 3 ww 4 2 ww 2ww 3 4 ww
20. When copper is heated with conc HNO3 it produces
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a) Cu(NO a
aslala i 3) 2 , NO and NO 2 a
aslala i b) Cu(NO 3 ) 2 and a
aslala N i2 O a
aslala i aslaa
a sa a sa a sa a sa a sa
adadc) Cu(NO3)2 and NO
.P.P adad
.P.2P
d) Cu(NO
.P.Pada3)d2 and NO .P.P adad adad
.P.P
www w w w
wwTransition And w
wInner
w w w w
wElements
w www w
ww w4.w ww Transition ww ww
1. Sc( Z=21)
i . N . eisteat transition element
N i . N . e tet Zinc (z=30) is not N
but
N i . . etet
because
N i . N . etet
N
l a a i
al Sc3+ and Zn2+ ions
asboth l a a i
al colourless and form
asare l a a i
al compounds. asaasal
aswhite l a a i aslaa
aa)
sa a sa a sa a sa
d
a adb) in case of Sc, 3d.P.orbital d
a ad are partially filled dad in Zn these are completely
abut d
a ad filled d
a ad
w .P.P
w w w P w .P.P
w w w.P.P w .P.P
w
w
www c) last electron
w
wwas w assumed to be added w
wwwto 4s level in case ofwzinc w
ww w
www
d) both Sc
i .ofN . eteand
N t Zn do not exhibit
i N . N
.element
tet
evariable oxidation states
i .N . etet
N i .N . etet
N
a i a i a i i
2. Which
d adsaasa l l a the following
d
d
a
d
block
saasa l l a has half
d ad
filled
saasal l a
penultimate d sub
d a
d
l
shell a
saasa well as half dadsaaslaa
l aas
a a filled valence sub .shell?
.P.P P.Paa .P.Paa .P.P aa aa
.P.P
w ww
w a) Cr w w
w w b) Pd w w
w w c) Pt w w
w w d) none of these w w
w w
ww ww ww ww ww
3. Among thettransition metals of 3d series, the one that has highest negative (M /M 2+)

i . N . e et
N i . N . etet
N i . N . etet
N i . N . etet
N
standard i electrode potential is i i i
d a saasTilaala
a)
d d a
d saaCu
b)
a
slala d ad saasc)laaMn
la
d a
dd)
a
slala
saaZn d a
d saaslaa
aa
.P.P .P.Paa .P.Paa P.P aa
.electrons aa
.P.P
w ww
w 4. Which one of the
w wfollowing
w w ions has the w ww
same
w number of unpaired w ww
w as present w ww
in
w
ww ww ww ww ww
V3+?
a) Tia 3+ NN
i . . etet b) Fe 3+NN
i . . etet c)aNi i . N
2+N
. etet d) Cr3+ i . N . etet
N
ala
aslmagnetic i a i
asla2+laion is aslala i a
aslala i aslaa
5.da s
Thea moment a
of sMn
a a sa a sa a sa
a ad
.P.P .P.Padad .P.Padad .P.P adad adad
.P.P
www w a) 5.92BM ww w w b) 2.80BM ww w w c) 8.95BM ww w w d) 3.90BM www w
ww ww
6. Which of the following compounds is colourless?
ww ww ww
a) Fe3+.NN
i . etet b) Ti4+ .NN
i . etet c) Co
i . N2+etet
. N d) Ni2+ .NN
i . etet
l a
al a
ascatalytic i l
asal a a i l a a i
asalcompounds is ascribed l al a
asamainly i aslaa
7. a
the
sa behaviour of a satransition metals andatheir sa a sa due to a sa
d
a ada) their magnetic behaviour d
a ad d
a ad d
a ad d orbitals d
a ad
w .P.P
w w .P.P
w w .P.P
w w.P.P
b) theirwunfilled w .P.P
w
w
www c) their ability
w
wwtowadopt variable oxidation w
www states w
wwwchemical reactivitywww
d) their
w
8. The correct
i .+N . eteorder
N t of increasing oxidizing
i .N . etet power in the iseries
N .<N . etet
N i .N . etet
N
a i a i a i a i
d aa)
d
l
VO
saasa 2 l a < Cr O
2 7
2- < MnO
d a
d
−
4 aa
sas l l a b)
d
Cr
ad
O l
2 a7a
sa s l
2- a VO 2
+ < MnO 4
−
d a
d
l
saasa l a
d a
d saaslaa
a a c) Cr2O72-< MnO4−.<P.VO
.P.P a a2+
P a aMnO4− < Cr2O72-< VO
.P.d)
P aa
.P2.+P aa
.P.P
w ww
w 9. The alloy of copper w w
w w w w
w w w w
w w w w
w w
ww ww that contain Zincwisw ww ww
a) Monel metal b) Bronze t t c) bell metal d) brass
i . N . etet
N i . N . ee
N i . N . etet
N i . N . etet
N
10. Which iof the following does not i give oxygen on heating? i i
d adsaasKlaaCr
a)
la
O d a
d saa(NH
b)
a
slala4)2Cr2O7 d ad saasc)laaKClO
la
d a
d
d)
aslaala
saZn(ClO ) d a
d saaslaa
aa
.P.P 2 2 7
.P.Paa .P.Paa 3
.P.P aa 3 2 aa
.P.P
w ww
w 11. In acid medium, w ww
w potassium permanganate w ww
w oxidizes oxalic acid w ww
to
w w ww
w
ww ww ww ww ww
a) oxalate b) Carbon dioxide c) acetate d) acetic acid
N tet
ethe N eteist not true? N etet N etet
12. Which a i . iof
. N following statements a i . i . N a i . i . N a i . i . N
a s
a)a
lala
ason passing H S, a
throughsa
la
aslaacidified K Cr O a s
solution,
a aslalaa milky colour isaobserved. saaslala a saaslaa
adad
.P.P
2
.P.Padad 2 2
.P.Padad
7
.P.P adad adad
.P.P
www w b) Na 2 Cr 2 O 7 isww w
preferred
w over K 2 Cr 2 O 7 in
ww wvolumetric
w analysis ww w w www w
ww ww
c) K2Cr2O7 solution in acidic medium is orange in colour
ww ww ww
d) K2Cr i . N2O
. e7tesolution
N t becomes yellow i . N . eteton increasing thei.PH
N N . N
tet
ebeyond 7 i . N . etet
N
l
asal a a i l a a i
asatol ________ in acidicasamedium l
asal a a i l
asala a i aslaa
s
13.aPermanganate
a ion changes
a sa a sa a sa
d
a ada) MnO42− d
a adb) Mn2+ d
a ad c) Mn3+ d
a add) MnO2 d
a ad
w .P.P
w w .P.P
w w .P.P
w w w.P.P w .P.P
w
w
www 14. A white crystalline w
www salt (A) react with w w
wwdilute HCl to liberateww
w w
a suffocating gas (B) and
w
wwwalso
forms a eyellow t etegas etet dichromate acidified etetwith dil
a i . Ni . Net precipitate la.lia.The N
i . N t (B) turns potassium
a i . N
i . N a i . N
i . N
d aH
d
l
sa2asSO l a
a 4 to a green coloured
d a
d saassolution(C).
a A,B and Csa
d ad a
l
are l a
sa respectively dadsaasa l l a
d a
d saaslaa
a a a) Na2SO3,SO2,Cr2.(SO aa a aNa2S2O3,SO2,Cr2(SO.P aa aa
w ww
w
.P.P
w wwP.P4)3
w w ww
w
.P.b)
P
w ww4.)3P
w w ww
w
.P.P
ww c) Na2S,SO2,Cr ww2(SO4)3 ww d) Na2SO4,SO2,Cr w2w(SO4)3 ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N Matric.Hr.Sec.School,
i . N. Netet T.Kallupatti
i . N . etet Page 5
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
aad ad a aa d a
d a Padasalai
aa d ad a aa d ad a d
aa a
d
ww .P.P ww.P.P ww .P.P ww .P.P ww.P.P
w
ww w ww w w ww w w www w ww w w

i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
saaslaal4a -react with Br dinadsaalkaline
15. MnO aslaala PH to give asaaslaala saaslaala- saaslaa
- -
d ad
a a a) BrO3 MnO2 , .P.P a a b) Br2,MnO4 d d
a aBr2,MnO2 d ad
a a d) BrO ,MnO4 d
aa a
d
ww .P.P wwof I2 are liberated
-
ww .P.c)P ww .P.P 2-
ww.P.P
w
ww w 16. How many w
moles
ww w w
when
ww w 1 mole of potassium www w
dichromate react withww w w
potassiumt iodide?
.N . e et
N .N . etet
N . N . etet
N . N . etet
N
a) 1lalia i b) 2lalia i c) 3 a i i d) 4 a i i
a saasa a sa asa a saaslala a saaslala a saaslaa
dadThe number of moles
a17. adaofdacidified KMnO4 .required adad to oxidize 1 mole aofdaferrous
d oxalate adad
w w.P.P (FeC O ) is w .P.P
w w w P.P w .P.P
w w .P.P
w
ww
ww 2 4
ww ww ww ww wwww ww ww
a) 5 b) 3 c) 0.6 d) 1.5
18. Wheni.N ai.N
tet compound of Mn
ebrown N tet ids treated with HCl,it
e(A) N etegives
t a gas (B).Thei.N gas ete(B)
t taken
a a i . i . N a i . i . N i . N
a s
ina
l a
al reacts with NH
asexcess a sa sl
ato a
l an explosive compound
agive a sa
l a
asal (C). The compound a sa
l a
asalA, B and C are asaaslaa
a
d
a ad d
a ad 3 d
a ad d
a ad adad
w .wP.P a) MnO 2,Cl2,NClw
.PP
3 w. b) MnO 2,Cl2,NHw
.wP.P
4Cl c) Mn 3O4,Cl2,NCl3 ww.
.PP d) Mn 3O4,Cl2,NClw
.PP
2 w.
ww
ww ww w ww ww ww
wis ww ww
19. Which one of w the following statements related to lanthanons w incorrect?
a) Europium
i .N . etet shows +2 oxidation
N i .N . N
tet
estate. i .N . etet
N i .N . etet
N
a i a i a i a i
d ab)
d
l
saasThe l a
a basicity decreases
d a
d saas l l a
asathe ionic radius decreases
d ad
l l a
saasa from Pr to Lu.dadsaasa l l a
d a
d saaslaa
a a c) All the lanthanons
.P.P aare
.P.P a much more reactive a athan aluminium. .P.P
.P.P aa aa
.P.P
w ww
w w www w ww
w w ww
w w ww
w
ww d) Ce4+ solutions ww are widely used as w w
oxidising agents in volumetric ww analysis. ww
20. Which ofethe
N tet following lanthanoid N eteions
t is diamagnetic? N etet N etet
laalai . i . N a i . i . N a i . i . N a i . i . N
d a
a)
dsaasEu 2+
d
b)sa
a
d a slala
Yb 2+ c) Cesala
d ad
2+
a s la d) Sm sala
d
2+
ad a s la d a
d saaslaa
a21.
.P.P a Which of the following a aoxidation states is.most
.P.P a a common among the
P.P .P.Palanthanoids?
a aa
.P.P
w ww
w a) 4 w ww w b) 2 w w
w w c) 5 w w
w w w w
w w
ww ww ww ww d) 3 ww
22. Assertion t: tCe4+ is used as an oxidizing agent in volumetric analysis.
i . N . e e4+
N i . N . etet
N i . N . etet
N i . N . etet
N
Reason:
aslalaa i Ce has the tendency a
aslala iof attaining +3 oxidation a
aslala i state. a
aslala i aslaa
a sa a sa a sa a sa a sa
adada) Both assertion .and
.P.P adareason
P.P d are true and reason adad is the correct explanation
.P.P .P.Padad of assertion. .P.P adad
www w b) Both assertion ww w w
and reason are true but www w
reason is not the correct ww w w
explanation of assertion . www w
ww ww ww ww ww
c) Assertion is true but reason is false. d) Both assertion and reason are false.
23. Theamost i . N . etecommon
N t oxidation i . N
state. eteoft actinoids is i.N.N
N etet i . N . etet
N
l
as+2al a i l a
al
as+3 a i l
asal a a i l
asala a i aslaa
d a s
a)a d a s
b)a c) d a
+4 sa d) +6 d a sa d a sa
a ad
.P.P a ad
.P.P a ad
.P.P .P.Pa ad a ad
.P.P
w w w 24. The actinoid w w
elements
w which show thew w
highest
w oxidation statew w
of +7
w are w w w
www a) Np,Pu,Am
www b) U, Fm, Th
www c) U, Th, Md www d) Es, No, Lr
www
25. Which.N
i one
. etetof the following isi.not
N N . N
tet
ecorrect? i .N . etet
N i .N . etet
N
a i a i a i a i
d aa)
d
l
saasLa(OH)
a l a 2 is less basic a
d than
d
l l a
saasaLu(OH)3 d adsaasal l a
d ad
l
saasa l a
d a
d saaslaa
a a b) In lanthanoid series
.P.P a aionic radius of Ln3+
.P.P a a decreases
.P.P
ions .P.Paa aa
.P.P
w ww
w w www w ww
w w ww
w w ww
w
ww c) La is actually ww an element of transition ww metal series ratherwthan w lanthanide series ww
d) Atomicetradii et of Zr and Hf are etet because of lanthanide
same etet contraction etet
i . Ni . N i . N
i . N i . N
i . N i . N
i . N
d adsaaslaala d a
d saaslaala d adsaaslaala d adsaaslaala d a
d saaslaa
aa
.P.P a a 5. Coordination
.P.P a a chemistry .P.P
.P.P aa aa
.P.P
w ww
w w www w ww
w w ww
w w ww
w
ww ww ww ww ww
1. The sum e ofteprimary
t valance and secondary etet valance of theemetal tet M in the complex etet
a i . Ni . N a i . N
i . N a i . N
i . N a i . N
i . N
a aaslala2(Ox)] Cl is L
[M(en)
s a sa aslala a saaslala a saaslala a saaslaa
adada) 3
.P.P adadb) 6
.P.P ada-3d
.P.c)P d).P adad
9.P adad
.P.P
w w
ww 2. An excess of w w w
ww nitrate is added tow100ml w w
ww of a 0.01M solution w w
wwof pentaaquachlorido www w
ww silver
w w ww ww
chromium(III)chloride. The number
i . N . etet
N i . N . etetof moles of AgCl precipitated
N i . N . etet
N
would be
i . N . etet
N
a)0.02
asall a a i b) l
asala
0.002 a i c) 0.01 l
asal a a i d) 0.2 l
asala a i aslaa
d a sa d a sa d a sa d a sa d a sa
a3.adA complex has a molecular
.P.P a ad formula MSO.4PCl.
.P.P a a6H
.P
d 2O.The aqueous.Psolution a ad of it gives white
.P a ad
.P.P
w w w w w w w w w w w w w w w
www precipitate www
with Barium chloride www
solution and no precipitate wwwis obtained when it iswww
treated
with silver nitrate solution. If the secondary valence of the metal is six, which one of the
tet
ecorrectly tet
ecomplex? etet etet
followinga i .N i . N represents a i N
.the
i . N a i .Ni . N a i .Ni . N
d aa)
d
l l a
saas[Ma (H2O)4Cl]SO4.2Hd2Oadsaasa l l a
b)d a
[M
dsaa(Hl l a
sa2O)6]SO4 d ad
l
saasa l a
d a
d saaslaa
aa
.P.P aa
P.P aa
.P.d)
P .2P aa aa
.P.P
w ww
w c) [M (H2O)5Cl]SO w w
..H
w4w 2O w ww
w [M (H2O)3Cl]SO4w ww
.3H
w O.P w ww
w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N i . . Netet
Matric.Hr.Sec.School,
N T.Kallupatti
i . N . etet Page 6
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
aad ad a aad a
d a Padasalaiaa d a
d a aa d a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww .P.P ww.P.P
w
ww w ww w w ww w w ww w w ww ww
4. Oxidationestate tet of Iron and the N charge
etet on the ligand NO inete[Fe(H
t 2O)5NO]SO4are.NN etet
i
laaland. N
i . N
a 0 respectively saslaala i . i . N a i . N
i . N a i i .
d a
a)
dsaas+2 d a
d a
b) +3sa
d a
d a slala0 respectively dadsaaslala
and
d a
d saaslaa
a a c) +3 and -1 respectively
.P.P .P.Paa .P.P ad)a+1 and +1 respectively .P.P aa aa
.P.P
w ww
w 5. As per IUPAC w ww
w
guidelines, the name of w
thewwcomplex
w [Co (en) w
(ONO)Cl]
w
w w Cl is wwww
ww ww ww 2 ww ww
a) chlorobisethylenediaminenitritocobalt(III) chloride
i . N . etet
N i . N . etet ⱪ- Ocobaltate(III)
N i . N . N
tet
echloride i . N . etet
N
aslala i
b) chloridobis(ethane-1,2-diamine)nitro
a a
aslala i a
aslala i a
aslala i aslaa
a sa a sa a sa a sa a sa
adadc) chloridobis(ethane-1,2-diammine)nitrito
.P.P .P.Padad .P
ⱪ-ad
.Pad
Ocobalt(II) chloride
.P.P adad adad
.P.P
www w d) w w
chloridobis(ethane-1,2-diamine)nitro
ww ww w
ⱪ-w Ocobalt(III) chloride ww w w wwww
ww ww ww ww ww
6. IUPAC name of the complex K3[Al(C2O4)3] is
i . N . etet
a) potassiumtrioxalatoaluminium(III)
N i . N . etet
N i . N . etet
N i . N . etet
N
lala a i
aspotassiumtrioxalatoaluminate(II) l
asal a a i l
asal a a i l
asal a a i aslaa
d a s
b)a d a sa d a sa d a sa d a sa
a ad
.P.P .P.Pa ad .P.P a ad .P.P a ad a ad
.P.P
w w w c) potassiumtrisoxalatoaluminate(III)
w w w w w w w w w w ww
www www
d) potassiumtrioxalatoaluminate(III)
www www www
7. A magnetic
i .N . etemoment
N t of 1.73BM.N
i will
. etebe
N t shown by one among
i . N . etetthe following (NEET)
N i . N . etet
N
a i a i a i a i
d aa)
d
l
saasTiCl
a 4l a
d b)s
a
d a
l
a[CoCll a
sa 6]− 4 c) [Cu(NH
d a
d
l l a
saasa 3)4]+ 2 d) [Ni(CN)
d a
d
l
sa4as]−a2 l a
d a
d saaslaa
a8.aCrystal field stabilization
.P.P .P.Pa a energy for high spin .P.P ada5 octahedral complex .P.P aisa aa
.P.P
w ww
w w ww
w w www w ww
w wwww
ww a) – 0.60 Δ0 ww b) 0 ww c) 2 (P − Δ0) ww d) 2 (P+ Δ0) ww
9. In which of
i . N . etethe
N t following coordination
i . N . etet entities the magnitude
N i . N . etet of Δ0 will be maximum?
N i . N . etet
N
laala )6]i a i i i
d a
a)
dsaas[Co(CN 3-
d
b)sa
a
d a slala(C2O4)3]
[Co 3- c) [Co(H
d a
d saasla2aO)
la6] 3+ d) [Co (NH
d a
d saas3la)a6l]a
3+
d a
d saaslaa
a10.
.P.P a Which one of the .following aa
P.P will give a pair.P of
.Paenantiomorphs?
a .P.P aa aa
.P.P
w ww
w a) [Cr(NH3)6]w w w
w
[Co(CN)
w w ww w w w
w w wwww
ww w 6] b) [Co(en)2Clw 2]wCl c) [Pt(NH3)4][PtClw 4]w d) [Co(NH3)4Cl ]NO2 ww

11. Which type of isomerism is exhibited by [Pt(NH ) Cl ] ?

i . N . etet
N i . N . etet
N
3 2 2
i . N . etet
N i . N . etet
N
a) Coordination
aslalaa i isomerism a
aslala i b) Linkage isomerism
a
aslala i a
aslala i aslaa
a sa a sa a sa a sa a sa
adadc) Optical isomerism
.P.P .P.Padad adad isomerism .P.P
d) Geometrical
.P.P adad adad
.P.P
www w 12. How many w w
geometrical
ww isomers are w
possible
ww w for<<EVA035.eps>>? ww w w wwww
ww ww ww ww ww
a) 3 b) 4 c) 0 d) 15
13. Which i . None
. etetof the following pairs
N i . N . N
tet
erepresents linkageaisomers? i . N . etet
N i . N . etet
N
l a a i
al (NH3)4][PtCl4] andas[Pt(NH
as[Cu l a a i
asal 3)4][CuCl4] l l
asa[Co(NHa i l a l
asa[Co(NHa i aslaa
d a s
a)a d a d a sb)
a ) (NO )]SO d a s
anda ) (ONO)] d a sa
a ad
.P.P a ad
P.P
.]Cl .2P.Pa ad 3 5 3
P.P
.(c) a ad
4 3 5
a ad
.P.P
w w w c) [Co(NH 3)4(NCS)
w w 2w and [Co(NH 3)4 (SCN)w w w ]Cl d) both (b) and
w w w w ww
www 14. Which kindwofwisomerism w www
is possible for a complex<<EVA039.eps>>?
www www
a) geometrical
i .N . etet and ionization i.N.N
N etet b) geometrical
i .N . eteand
N t optical
i .N . etet
N
a i a i a i a i
d ac)
d
l l
saasoptical
a a and ionizationas
d d aasal l a saasa
d) geometrical
d a
d
l l a only
d a
d saasa l l a
d a
d saaslaa
a15.
.P.P a Which one of the .following aa aexpected
a aa aa
w ww
w w wwP.P
w
complexes iswnot
w w
.P.P
w to exhibitw
w w w.P.P
isomerism?
wwww.P.P
ww a) [Ni(NH3)4(H w2wO)2]+2 b) <<EVA041.eps>> ww c)[Co(NHw 3)4w SO4]Cl d) [Fe(en)3]3+ ww
16. A complex
i . N . etein
N t which the oxidation
i . N . etenumber
N t of the metal isetzero
i . N . N et is i . N . etet
N
i i i i
d adsaasKla4aFe(CN)
a) la 6
d
b)sa
a
d a
a
slala 3(NH3)]
[Fe(CN)
d a
d
laala
saasc)[Fe(CO) 5]
d a
d
d)sa
a
both a
slala (b) and (c) d a
d saaslaa
a17.
.P.P aa
a Formula of tris(ethane-1,2-diamine)iron(II)phosphate
.P.P .P.P aa .P.P aa aa
.P.P
w ww
w w w
w w w ww w w w
w w wwww
ww a) [Fe(CH3-CH(NH) ww 2)2)3] (PO4)3 wb)[Fe(H
w 2N-CH2-CH2 –NH w2w )3](PO4) ww
c)[Fe(H2N-CH -CH -NH ) ](PO ) d) [Fe(H N-CH -CH -NH ) ] (PO )
i . N . etet 2 2 2 3 4i.N
N
2
. etet
N
2 2
i . N . e2 tet 2 3 3 4 2
N i . N . etet
N
18. Which
aslalaa iof the following is a
aslala i
paramagnetic in nature? a
aslala i a
aslala 2- i aslaa
a sa a sa a sa a sa a sa
adada) [Zn(NH3)4]
.P.P
2+
.P.Padadb)[Co(NH3)6] 3+
.P.P adad c)[Ni(H2O)6] .P.P 2+
adadd)[Ni(CN)4] adad
.P.P
w w
ww 19. Fac-mer isomerism w w
ww is shown by ww ww w w ww w w wwww
ww ww ww ww
a) [Co(en)3]3+ b)[Co(NH3)4(Cl)2]+ c)[Co(NH3)3(Cl)3] d)[Co(NH3)5Cl ] SO4
20. Choose i . N . etetcorrect statement.i.N.N
N
the etet i . N . etet
N i . N . etet
N
lala
asSquare a i l a
asaarel a i l a
al a
aoctahedral i l
asal a a i aslaa
d a s
a)a planar d a
complexes sa more stable than
d a sa s complexes d a sa d a sa
a ad
.P.P .P.Pa ad .P.P a a2-d a ad
.itP.P a ad
.P.P
w w w b) The spin only
w w magnetic
w moment of w w
[Cu(Cl
w ) 4] is 1.732 BM and
w w w has square planar w ww
www structure.
www www www www
c) Crystal i .N . etfield
N et splitting energyi.N (Δ
. e0)teoft [FeF6]4-is higheri.N
N than
. etetthe (Δ0) of [Fe(CN)i6.]N.4−N
N etet
l a a i l a a i l a a i a a i a
d ad)
d
l
saascrystal
a field stabilization
d a
d
l
saasaenergy of [V(H2O)6d]2+adissaashigher a l than the crystal
d a
d
l
sa stabilization dadsaasla
saafield l
a a of [Ti(H2O)6]2+ .P.P
.P.P aa .P.P aa .P.P aa .P.Paa
w ww
w w ww
w w www w ww
w www
w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N Matric.Hr.Sec.School,
i . N. Netet T.Kallupatti
i . N . etet Page 7
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s aslaalia. i.N s a slaalia. i.N s aslaalia. i.N saaslaa
aad ad a aa d a
d a Padasalai
aad a
d a aad a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww.P.P ww.P.P
w
ww w ww w w ww w w ww w w wwww

i . N . etet
N i . N . ete6.
N t Solid State.NN
i . etet i . N . etet
N
i i i i
1.da
dsaaslaala and diamonddare
Graphite a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
a a a) Covalent and molecular
.P.P .P.P a a crystals a aionic and covalent crystals
.P.b)
P aa
.P.P .P.Paa
w ww
w w ww
w w www w ww
w wwww
ww c) both covalent ww crystals ww d) both molecular wwcrystals ww
2. An ionicNcompound
i . . etet
N Ax By crystallizes
i . N . etet in fcc type crystal
N i . N . etet
structure
N with B ions N
i . atethe
. N
tet centre
of a i
lala face and A ion occupying
aseach a i
aslala entre of the cube. a i
la correct formula ofsasAlaxBlay is
aslathe a i aslaa
a sa a sa a sa a a a sa
adada) AB
.P.P .P.AB
b) Pada3d c) A .P.P
3B
adad d) A8B6w.P.P adad .P.Padad
w w
ww 3. The ratio of close w w
wwpacked atoms to tetrahedral ww w w w
ww is www w
ww ww ww hole in cubic packing ww ww
a) 1:1 etet b) 1:2 etet c) 2:1 ed)tet1:4 etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
4. Solid
a sa
l
asal 2COa is an example
a
of
sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
a ada) Covalent solid .P.P d
a adb) metallic solid .P.c)P d d
a amolecular solid d).P d
a adsolid
ionic d
a ad
w .P.P
w w w w w w w .P w .P.P
w
w
www 5. Assertion : monoclinic wwww sulphur is an w w
ww of monoclinic crystal
example w
www system w
www
Reason: for a monoclinic system, a≠b≠c and α=γ=90 0,β≠900 ,

a) Both i .N . etet
N
assertion and reason i .N
are . N
tet
etrue and reason islathe i .N . etet
N
correct explanationlaof i .N . etet
N
assertion.
a i a i i i
d ab)Both
d
l l a
saasa assertion and dreason a
d
l l a
saasa are true but reason d a
d
l a
saisasanot the correct explanation d a
d saasa of assertion. dadsaaslaa
l a
aa
.P.P aa
.P.but
P aa
.P.d)
P aa
P.P
.reason .P.Paa
w ww
w c) Assertion is w ww
true
w reason is false. w www Both assertion and
w ww
w are false. wwww
ww ww ww ww ww
6. In calcium fluoride, having the flurite structure the coordination number of Ca2+ ion and F-
Ion are i . N . etet
(NEET)
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d adsaas4laaand
a)
la 2 b) 6 and d a
d sa6aslaala c) 8 and d 4a
d saaslaala d) 4 and 8 dadsaaslaala d a
d saaslaa
aa
.P.P .P.P aa .P.Paa aa
.P40)
.P P.P
.in aa
w ww 7. The number ofwunit ww cells in 8 gm of an w welement
w X ( atomic mass w ww which crystallizes w ww
ww w w
w (NA is the Avogadro number) ww w ww w ww w
bcc pattern isw
a) 6.023
i . N . eXte10
N t 23 b) 6.023
i . N . eXte10
N t 22 c) 60.23 X N
i . 10N
. e23tet d) (6.023 X 10i.23N.N e/8tetX 40)
8. a
The a
ala
aslnumber i of carbon atoms a i
a unit cell of diamond
aslalper a
aslalais i a
aslala i aslaa
sa a sa a sa a sa a sa
adada) 8
.P.P b).P6
. adad
P c) 1w.P.P adad d) 4 w.P.P adad .P.Padad
w w
ww 9. In a solid atom www w wand w
w (1/3) of tetrahedral w
wwvoids are occupied by w w
watom
w
ww ww M occupies ccp lattice ww ww ww
N. find the eteformula
t of solid formed eteby
t M and N. etet etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
a
a)
sa
l
MN
asal a b) M 3 N
a sa
l
asal a c) MN 3
a sa
l
asal a d) M N
3 2
a sa
l
asal a
a saaslaa
dadThe composition .of
a10. d d
aaasample of wurtzite .is d
aFead0.93 O1.00 what % of.P.Iron d
a adpresent in the form d
a ad
w .P.P
w w w P.P w wP.P w w P w .P.P
w
w
www of Fe ? 3+
wwww wwww wwww w
www
a) 16.05%t t
i . N . e eradii ofb)A15.05%
N i . N . etet c) 18.05%
N i . N . eXd)te10
N t17.05%
i .N . etetnumber
N
11. Thelaionic i + and B− are
a i 0.98X10 -10m and 1.81
a i -10m. the coordination
a i
d a saaseach
of
d
a l a
ion in AB is d a
d saasal l a
d a
d saasa l l a
d a
d
l
saasa l a
d a
d saaslaa
aa
.P.P .P2.Paa .P.Paa aa
.P.P .P.Paa
w ww
w a) 8 w wb)w
w c)
w 6
www d) 4 w ww
w wwww
ww ww ww ww ww
12. CsCl has bcc arrangement, its unit cell edge length is 400pm, its inter atomic distance is
a) 400pm i . N . etet
N b) 800pm i.N . etet c)√ 3 100×pm i.N.N
N ed)tet(√3/2) X400 pm i.N.N etet
laala i i
aala structure. if the i
aslaala of the cation isas100pm i
aslaala , the radius asaaslaa
13.
d a saassolid
A compound XYdhas a saaslNaCl d a saradius d a
aa
.P.P d .P.P aa d .P.Paa d aa
.P.P d .P.Padad
www w of the anion will
www be
w ww w w www w www w
ww ww ww ww ww
a) (100/ 0.414) b) (0.732/100) c) 100 X 0414 d) (0.414/100)
14. The vacant i . N . etetspace in bcc lattice
N i . N . etet cell is
unit
N i . N . etet
N i . N . etet
N
a
lala
as48% i a
aslala i a i
aslala d) 26% a
aslala i aslaa
a
dad s
a)a b) 23% a sa c) 32% a sa a sa a sa
a15.
.P.P The radius of an .P.P
atom
adadis 300pm, if it crystallizes .P.Padad in a face centered .P.P
dad
acubic lattice, the length .P.Padad
www w www w ww w w www w www w
ww oif the edge w ofwthe unit cell is ww ww ww
a) 488.5pm
i . N . etet
N b) 848.5pm Netet c) 884.5pm
i . . N i . N . ed)tet484.5pm
N i . N . etet
N
16. The l a l a
asafraction i of total volume l al a i
asaoccupied by the atoms l a a i
asainl a simple cubic isasaasal l a a i aslaa
d a sa d a sa d a sa d d a sa
a ada) (/4√2)
.P.P .P.P a adb) (/6 ) .P.c)(
P d
a a/4) d) (/3√2) a ad
.P.P .P.Pa ad
w w w w w w w w w w w w w w w
www 17. The yellow colour www in NaCl crystal is wdue wwto www www
a) excitation etet of electrons in F icenters etet etet etet
a i . N
i . N a .Ni . N a i .Ni . N a i .Ni . N
d adsasa l l a
b)areflection of light from
d a
d
Cl-
saasal a
ion
l on the surface
d a
d saasa l l a
d a
d
l
saasa l a
d a
d saaslaa
a a c) refraction of light
.P.P .P.P afrom
a Na+ ion .P.Paa aa
.P.P .P.Paa
w ww
w d) all of the above w w
w w w ww w w w
w w www w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t Chemistry., Lord Venkateshwara
i . N . etet
N i . . Netet
Matric.Hr.Sec.School,
N T.Kallupatti
i . N . etet Page 8
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
aad ad a d
aa a
d a Padasalai d
aa a
d a aad a
d a d
aa a
d
ww.P.P ww.P.P ww.P.P ww .P.P ww .P.P
w
ww w ww w w ww w w ww w w ww w w
18. if ‘a’ stands etet for the edge length eof
tetthe cubic system N ; scete,t bcc, and fcc. Then ethe
tet ratio of
i . N
i . N i. Ni . N i . i . N i . N
i . N
d adsaaslaalof
radii a spheres in these ssystems
d a
d aaslaala will be respectively.
d a
d saaslaala d a
d saaslaala d a
d saaslaa
a a a) ( 𝑎 ∶ 𝑎 ∶ 𝑎 ).P.P
.P.P 1  3 2 aa a a( 𝑎 ∶ 𝑎 ∶ 𝑎 ) .P
.)P.c)P 1 3 1 aa 1 1
.P.Paa
w ww
w 2 2 2wwww b) (1a : 3a : 2a w www 2 4 22 ww wwd).P( 2 𝑎 ∶ 3a ∶ 2 𝑎 ) ww ww
ww ww ww
19. if ‘a’ is the length of the side of the cube, the distance between the body centered atom and
ww ww
one corneri . N . eteatom
N t in the cube will i . N . N
tet
ebe i . N . etet
N i . N . etet
N
a
lala
as(2/√3)a i a
asalala i a i
aslala d) (√3 /2) a asaaslala a i aslaa
aa)
sa b) (4/√3)a sa c) (√3 /4)aas a a sa
dad
a20. adastructure
d dad
aneighbor aAda0d. its atomic weight.P adad
w .P.P
w Potassium has w aw P.P
.bcc with nearestww.P.P distance w .P.P
4.52
w w wis.P
ww
ww 39. its density ww wwill
w be ww ww ww ww ww ww
a) 915 kgem
N tet-3 b) 2142 kg
N etem t -3 c) 452etkg
N e t m-3 d) 390 kgem
N te-3t
i . . N i . . N i . . N i . . N
a aaslaalai defect in a crystal
21. Schottky
s a sa
i
aslaaislaobserved when sa
a a s laalai
a saaslaalai a saaslaa
d
a ada) unequal number d d
a aanions dad
amissing d
a ad d
a ad
w .P.P
w w .P.of
w P and anions .are
ww P.P from the lattice
w .P.P
w w .P.P
w
w
www b) equal number w
wwwof anions and anions w
wwarew missing from the wlattice w
ww wwww
c) an ion leaves
i . N . etet its normal sitei.Nand
N . eteoccupies
N t an interstitialt site
i .N . e et
N i .N . etet
N
d)ano a i
ion is missing from its a i
lattice. a i a i
d
22.adThe
l l a
sasacation leaves its d a
d
normal
l l a
saasa position in the crystal d a
d
l l a
saasaand moves to some d a
d
l
saasa l a
interstitial position, d a
d saaslaa
aa
.P.P .P.P aa .P.P aa aa
.P.P .P.Paa
w ww
w the defect in w
the wcrystal
w w is known as w www w ww
w w ww
w
ww ww ww ww ww
a) Schottky defect b) F center c) Frenkel defect d) non-stoichiometric defect
23. Assertion:i . N . etedue
N t to Frenkel defect,
i . N . N
tet
edensity of the crystalline
i . N . etesolid
N t decreases. .NN
i . etet
i i i i
d a saaslaala in Frenkel defect
Reason:
d d a
d
a
slala and anion leaves
saacation d a
d
laala
saasthe crystal. d a
d saaslaala d a
d saaslaa
aa
.P.P P.P
.and aa aa
.Preason
.P aa
.P.P .P.Paa
w ww
w a) Both assertion w ww
w reason are true w and
www is the correct w w
wexplanation
w of assertion. w ww
w
ww ww ww ww ww
b)Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion
i . N . etetis true but reasoni.N
N is. N
tet
efalse. i . N . etet
N i . N . etet
N
a i
lala assertion and reason
asBoth a i
aslalaare false a
aslala i a
aslala i aslaa
a
dad s
d)a a sa a sa a sa a sa
a24.
.P.P The crystal withwaw
adad deficiency defect.P
.Pmetal
. P ad d
is.Pa
adad
.P.P .P.Padad
www w ww ww ww www w www w
ww a) NaCl ww b) FeO ww c) ZnO ww d) KCl ww
25. A two dimensional
i . N . etet
N solid patternete
i . N . N t
formed by two different
i . N . eteatoms
N t X and Y is shown
i . N . etet below.
N
The l al
asablacka i and white squares l a a i
asal represent atomsaXsaasand l a a i
al Y respectively. the l a
al a
assimplesti formula aslaa
d a sa d a sa d d a sa d a sa
a adfor the compound.P
.P.P a ad on the unit cell from
based
.P .P.P d pattern is
a athe a ad
.P.P .P.Pa ad
w w w w w w w ww w w w w w w
www a) XY8 www b) X4Y9 www c) XY2 wwwd) XY4 www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d adsaasal l a
d a
d saasal l a
d a
d saasal l a
d a
d
l
saasa l a
d a
d saaslaa
ww
aa
.P.P ww.P.P aa 7. Chemical ww.P.P a a Kinetics
ww
aa
.P.P ww .P.Paa
w
ww w ww w w ww w w ww w w ww w w
1. For a firstetorder et reaction AB ___ tet rate constant is xNmin
ethe ete−1t . If the initial concentration etet of
a i . N
i . N a i . N
i . N a i . i . N a i . N
i . N
d aAsa
d a
is
sal l a
0.01M , the concentration
d a
d saasal l a of A after one hour
d a
d
l
is
saasa l a
given by the expression.
d a
d
l
saasa l a
d a
d saaslaa
a a a) 0.01 .e−x
.P.P a a -2(1-e-60×) c) (1X10
.P.1X10
P .P.P a a-2)e-60× aa
.P.these
P .P.Paa
w ww
w w wb)
w w w www d) nonewof
w w w w ww
w
ww ww ww ww ww
2. A zero order reaction XProduct ___ , with an initial concentration 0.02M has a half life of 10
min. if i . N
one
. etestarts
N t with concentration i . N . etet 0.04M, then thei.half
N N . etelife
N t is
i . N . etet
N
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
a sa a sa a sa a sa a sa
adada) 10 s
.P.P . .Pad
d
b)P5amin c) 20 P
. min
. adad
P adad
.P.P .P.Padad
www w www w ww
winformation
w www w www w
ww d) cannot bewpredicted w using the given ww ww ww
3. Among.N
i the
. etefollowing
N t graphs showing
i . N . etet variation of rate iconstant
N . N . etet with temperature
N i . N . N
tetfor a
e(T)
l a a i
asal the one that exhibits l a a i
asal Arrhenius behavior l a a i
al the entire temperature
asover l a a i
asal range is aslaa
areaction,
sa a sa a sa a sa a sa
d
a ad a) d
a ad b) d
a ad d
a ad d
a ad
w .P.P
w w .P.P
w ww.P.c)P d)w
w .P.P w .P.P
w
w
www www w wwww wwww wwww

i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d adsaasal l a
d a
d saasal l a
d a
d saasal l a
d a
d
l
saasa l a
d a
d saaslaa
aa
.P.P .P.P aa .P.P aa aa
.P.P .P.Paa
w ww
w w ww
w w www w ww
w both (b) and w (c)w
ww
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t
i . N . etet
Chemistry., Lord Venkateshwara
N i . . Netet
Matric.Hr.Sec.School,
N T.Kallupatti
i . N . etet Page 9
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
aad ad a aa d ad a Padasalai aa d a
d a aad a
d a d
aa a
d
ww.P.P ww .P.P ww .P.P ww .P.P ww.P.P
w
ww w ww w w www w www w www w
4. For a firsteorder tet reaction A eproduct
tet with initial concentration etet x mol L−1,has eteathalf life
i . N
i . N i . N
i . N i . N
i . N i . Ni . N
a sa aslaalaof 2.5 hours . Forasathe
period aslaasame
la reaction with sinitial
a a aslaala concentration (x/2) a sa aala L-1 the half
aslmol a saaslaa
d d
a a life is aa d d aa d d aad d d
aa d
ww.P.P ww .P.P ww .P.P ww .P.P ww.P.P
w
ww w a) (2.5 x 2) w
hours
ww w b) (2.5/2) hours
www w c) 2.5 hours www w www w
d) Withoutt knowing the rate constant, t cannot be determined from the given data
i . N . e et
N i . N . etet
N
1/2
i . N . etet
N i . N . etet
N
5. For the a
aslala i
reaction, 2NH 3 a
aslala N i 2 + 3H 2 , if –d[NH 3 ] /
aslaladt
a i
= k[NH 3 ] d[N 2 ] /dt =
aslala 3],
ka2 [NHi aslaa
a sa a sa a sa a sa a sa
adadd[H2]/dt = k[NH3] .then
.P.P P.Padathed relation between akd
.P.c)P1a,k
d2 and k3 is .P.Padad adad
.P.P
www w a) k = k = k ww w w b) k =3 k = 2k w
3 w
w w 1.5 k = 3 k = kw3 ww w d) 2k = k = 3k w
w3 w w
ww 1 2
w3```
w 1 2
ww 1 2
ww 1 2
ww
6. The decomposition of phosphine (PH3) on tungsten at low pressure is a first order reaction.
It is because
i . N . etet the (NEET)
N i . N . etet
N i . N . etet
N i . N . etet
N
l a a i
al is proportional toasathe
asrate l al a
asasurface i asall a a i l
asal a a i aslaa
d a s
a)a d coverage d a sa d a sa d a sa
a ad
.P.P a ad
.Pproportional
.P a ad
.P.P .P.Pa ad a ad
.P.P
w w w b) rate is inversely w w w to thew surface
w w coverage w w w w w w
www c) rate is independent
www of the surface coverage
www wwwof decomposition is wslow
d) rate ww
7. For a .N
i . etet Rate = k [acetone]
reaction
N i .N . etet 3/2 then unit ofi.N
N rate
. etetconstant and rate
N i .N . eoftetreaction
N
a i a i a i a i
d a saasa l l
respectively
d
a is
d adsaasa l l a
d a
d saasa l l a
d a
d saasal l a
d a
d saaslaa
a a a)( mol L-1s-1), (mol.P
.P.P aLa1/2 s-1 ) ,
.P
-1/2 a a(mol-1/2L1/2 s-1 ) , mol
.P.b)
P a-4as-4 )
.P.LP aa
.P.P
w ww
w w w
w w w ww w w w
w w w w
w w
ww c) (mol1/2 L1/2 wws -1), ( mol L-1 s-1 ) ww d) (mol L s -1 ) , (mol ww 1/2 L1/2 s) ww
8. The addition
i . N . etetof a catalyst during
N i . N . ea techemical
N t reaction alters
i . N . etewhich
N t of the following
i . N . etet
N
i i i i
d adsaaslaala
quantities? (NEET)
d adsaaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
a a a) Enthalpy
.P.P aa
.PActivation a aEntropy
.P.c)P d).P a a energy aa
.P.P
w ww
w w wb)w
w
.P energy
w www w w
w w Internal
.P w ww
w
ww 9. Consider thew w
following statements : ww ww ww
(i) increase
etet in concentration eoftethe
t reactant increases etethe
t rate of a zero order etreaction.
et
a i . N
i . N a i . N
i . N a i . N
i . N a i . Ni . N
a sa
la rate constant k issa
asla(ii) a a s lala to collision frequency
equal
a sa aslalaA if Ea = 0 a saaslala a saaslaa
adad (iii) rate constant
.P.P .P.Padakdis equal to collision a dad
frequency
.P.P A if Ea = ° .PP
. adad adad
.P.P
www w (iv) a plot w w w
ofwln (k) vs T is a straight
w
wwline.w ww w w ww w w
ww ww ww ww ww
(v) a plot of ln (k) vs (1/T ) is at straight line with a positive slope.
Correct i . N . etet
N
statements are i . N . e et
N i . N . etet
N i . N . etet
N
l
asal a a i l
asal a a i asall a a i l
asal a a i aslaa
d a s
a)a (ii) only b) (ii)d a
andsa (iv) c) (ii) and d a s
(v)a d) (i), (ii) and d a
(v)sa d a sa
a ad
.P.P .P.Pa ad a ad
.P.P .P.Pa ad a ad
.P.P
w w w 10. In a reversible w w w
reaction, the enthalpy w
change
w w and the activation w w w
energy in the forward w w w
www www www www www
direction are respectively - x kJ mol -1 and y kJ mol-1. Therefore , the energy of activation in
the backwardi .N . etet direction is i.N.N
N etet i .N . etet
N i .N . etet
N
a i a i a i a i
d aa)
d
l l a
saas(ya– x ) kJ mol-1 dadb)saa(x l l a
sa+ y ) J mol-1 c)(x d a
d–sa ya
l l a
s)akJ mol-1 d) (x +dyads)aa×sa10 3 J mol-1. l l a
d a
d saaslaa
a11.
.P.P a What is the activation .P.Pa a energy for a reaction a aif its rate doubles.P
.P.P .Pa a the temperature .P aa
w ww
w w ww
w w www w wwwhen
w w wwis.P
w
ww raised from 200
ww K to 400 K? (R = 8.314 ww JK-1mol-1) ww ww
a) 234.65
i . N . etkJ
N et mol-1 b) 434.65
i . N . ete
N t mol-1 c) 434.65.NkJ
kJ
i . etemol
N t -1 d) 334.65
i . N . N
tet mol-1
ekJ
i i i i
d adsaaslaala d adsaaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
aa ; This
aa reaction follows firstaa order kinetics. The rate aa constant at particular aa
ww.P.P w .P.P
w .P.P
winitial
w .P.P
wcyclopropane
w ww.P.P
w
ww w temperature ww w
is w2.303 x 10 -2 hour -1. The
www w concentration www ofw is 0.25 wwwM.w
What will be the concentration of cyclopropane after 1806 minutes? (log 2 = 0.3010)
a) 0.125M i . N . etet
N b) 0.215Mi . N . etet
N c) 0.25 2.303M
i . N . ete×t
N d) 0.05M i . N . etet
N
a i
aslalaa first order reaction, a i
aslalathe rate constant a a
asislal6.909i a la
aslataken i aslaa
12.a saFor a sa a sa min -1.the time a sa for 75% a sa
adad
.P.P .P.Padad adad
.P.P .P.Padad adad
.P.P
www w conversion in w w
minutes
ww is ww w w ww w w ww w w
ww ww ww ww ww
a) (3/2) log 2 b) (2/3) log 2 c) (3/2) log (3/4) d) (2/3) log (4/3)
13. In a first N tet reaction xy ___N; e
eorder if tektis the rate constant N tet the initial concentration
eand N etet of the
a i . i . N a i . i . N a i . i . N a i . i . N
a s l
reactant
a
a
asal x is 0.1M, then, a sathe
l a
asalhalf life is a sa asall a
a sa
l
asal a
a saaslaa
d
a ada) log 2/k d
a adb) 0.693/ 0.1(k) .P.c)P d d
a a(ln2/ d
a add) none of these .P.P d
a ad
w .P.P
w w .P.P
w w w k) w w.P.P w w
w
www 14. Predict thewrate w
ww law of the following w
wwwreaction based on wthe w
wwdata given below www w
2A + B
i .N . etet
N C + 3D etet
i .N . N i .N . etet
N i .N . etet
N
a i a i a i a i
d adsaasa l l a
d adsaasa l l a
d a
d saasa l l a
d a
d saasal l a
d a
d saaslaa
aa
.P.P .P.Paa aa
.P.P .P.Paa aa
.P.P
w ww
w w ww
w w www w ww
w w ww
w
ww ww ww ww ww
P.Irulappan., PG
i . N . eteAsst.in
N t Chemistry., Lord Venkateshwara
i . N . etet
N Matric.Hr.Sec.School,
i . N. Netet T.Kallupatti
i . N . etet Page 10
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
 s as laalia. i.N s as laalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
aad ad a aa d ad a Padasalai aa d ad a d
aa a
d a d
aa a
d
ww .P.P ww .P.P ww .P.P ww.P.P ww .P.P
w
ww w ww w w ww w w www w ww w w

i . N . eteReaction
N t [A] i.N.N ete[B]
t Initial ratei.N.N etet i . N . etet
N
i i i i
d adsaaslaala number
d ad saaslaala (min)
(min) (Mas-1)
d d saaslaala d a
d saaslaala d a
d saaslaa
aa
.P.P aa
.P.P .P.P aa .P.P aa .P.P aa
w ww
w w 1w
ww 0.1 0.1ww ww x w ww
w w ww
w
ww ww ww ww ww
2 0.2 0.1 2x
i . N . etet 3
N 0.1ai.N . ete0.2
N t 4x ai.N . etet
N i . N . etet
N
a
aslala i aslala i aslala i a
aslala i aslaa
a sa 4 a sa
0.2 0.2 a
8x sa a sa a sa
adad
.P.P adad
.P.P .P.P adad .P.P adad .P.P adad
www w w w w w w w w w
ww a) rate = k [A]2w[B]
www b) rate = k [A]w
ww[B]w2
c) rate = k [A][B]w
www d) rate = k [A]1/2 w w
[B]
w3/2
w
15. Assertion:
i . N . eterate
N t of reaction doubles
i .N . etewhen
N t the concentration
i . N . etetof the reactant is idoubles
N . N . etet if it is
N
a l a a i
al order reaction. asaasal
asfirst l a a i l
asal a a i l
asal a a i aslaa
d a sa d d a sa d a sa d a sa
a adReason: rate constant
.P.P d doubles
a aalso
.P.P .P.P a ad .P.P a ad .P.P a ad
w w w w w w w w w w w w w w w
www a) Both assertion wwand w reason are true and w
wwreason is the correctw ww
explanation of assertion. www
b) Both assertion etet and reason arei.true etebut
t reason is not the ecorrect
tet explanation ofNassertion. etet
a i . Ni . N a N
i . N a i . N
i . N a i . i.N
d adsaasa l
c) Assertion l a is true but reason
d ad saasa l isl afalse.
d ad saasa l l a
d a
d saasal l a
d a
d saaslaa
ad)aBoth assertion and.Preason
.P.P a a are false.
.P .P.P aa .P.P aa .P.P aa
w ww
w 16. The rate constant w w
w w w w
w w w w
w w w w
w w
ww ww of a reaction is 5.8 wwx 10 s The order ofwthe
-2 -1.
w reaction is ww
a) First order b) zero order c) Second order d) Third order
i . N . etet
N i . N . etet2NO + 1/2O ,i.the
N N . ete
N t
i . N . etet
N
17. Forlathe i reaction N O i
aslaala -1 -1 aslaala i value of rate of i
disappearance
aslaala of
asala saaslaa
2 5(g) 2(g) 2(g)

d ads
Na O is given as 6.5 x d a
10
d sa-2 mol L s . The rate d ad s
ofa formation of NO d
and a
d s
Oa is given d a
d
aa
.P.P 2 5 aa
.P.P .P.P aa 2
.P.P aa 2
.P.P aa
w ww
w respectively as
w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
a) (3.25 x 10-2 mol L-1 s-1) and (1.3 x 10-2 mol L-1 s-1)
b) (1.3i.N x10
. ete-2t mol L-1 s-1) and (3.25
N i . N . ete
N t
x 10-2 mol L-1 s-1) i.N . etet
N i . N . etet
N
a
lala -1
as(1.3 i a i
la x 10-2 mol L-1 s-1as)lala
asla(3.25 a i a
lala
asthese i aslaa
a s
c)a x 10 mol L -1 s-1a) s
and
a a a d) None a s
of
a a sa
adad
.P.P adad
.P.P .P . adad
P .P.P adad .P.P adad
www w 18. During the decomposition
w w of H 2O2 to give w w dioxygen, 48 g O 2 is formed
w w per minute at certain
w w
ww point of time. w
ww w
The rate of formation ofw
ww w
water at this point is w
www ww ww
a) 0.75.Nmol
i . etetmin−1
N b) 1.5 .mol
i N . etemin
N t −1 c) 2.25
i . N . etmol
N et min−1 d) 3.0 mol i . N . N
tet −1
emin
19.as Ifa l a a i
al initial concentration
the l a a i
asalof the reactant isadoubled, l
asal a a i the time for a half l al a
asareactioni is also as aslaa
d a s d a sa d sa d sa d a
a addoubled. Then the.Porder
.P.P a ad of the reaction is.P.P
.P a ad .P.P a ad .P.P a ad
w w w w w w w w w w w w w w w
www a) Zero wwwb) one www c) Fraction www d) none www
20. In a homogeneous etet reaction A etet B + C + D, the eteinitial
t pressure was Pe0teand after
a i .itN
i . N a i N
.rate
i . N constant in terms a i .Ni . N a i . N
i . N t
d a
time
dsaasa l l
t a was P. expression
d ad saasa l
for l a
d ad saasa l l a
of P 0 , P and t will
d a
d
be
saasal l a
d a
d saaslaa
a a a) k = (2.303/t) log.P.(2P
.P.P a a / 3P0 – P) b) k =.P.(2.303/t) aa log (2P0 / P0 .–P.P) aa .P.P aa
w ww
w w ww P 0
w w ww P
w w ww P
w w ww
w
ww c) k = (2.303w /wt) log (3P0 - P/ 2P0) wd) wk = (2.303/t) log (2Pw 0w/ 3P0 – 2P) ww
21. If 75% of a first order reaction was completed in 60 minutes , 50% of the same reaction
under i . N
the . etesame
N t conditions would
i . N . ete
N be
t completed in .NN
i . etet i . N . etet
N
laala i i
laalaminutes aslaala i i
d adsaas20
a) minutes d ad saas30
b) c) d35ad saminutes d) 75 d a
d saaslaala
minutes d a
d saaslaa
a22.
.P.P a The half life period a aa radioactive element
.P.of
P .P.P aisa140 days. After 560.Pdays aa .P.P aa
w ww
w w ww
w w ww
w w ww.P , 1 g of element
w w wwill
w w
ww be reduced tow
w ww ww ww
a) (1/2)NgN
i . . etet b) (1/4) g
i . N . etet c) (1/8) g
N d) (1/16)
i . N . etet g
N i . N . etet
N
23.aThe a la
aslacorrect i difference between a i
aslala first and secondasorder a i
aslalareactions is that a(NEET) a
aslala i aslaa
sa a sa a sa a sa
adada) A first order reaction
.P.P adadcan be catalysed; .aP.second
.P.P adad order reaction.cannot
P P.Padad be catalysed. .P.P adad
www w ww w w w w
wwdoes not depend onww w w w
w the half life of awsecond www w
ww b) The half w lifew of a first order reaction ww [A0]; w
order etereaction
t does depend on ete[A0].
t etet etet
c) aThel a ila.N i .N
rate of a first order l a ia
reaction
asal
. N
i . N does not depend l
asal a i
ona. N
i . N
reactant concentrations; l a i . N
i . N
asal the rate of asaaslaa
a
a sa s a a sa a sa a sa
d
a ad a second order d
a ad does depend .on d
ad
areactant d
a ad adad
w .wP.P w .wP.reaction
P w P . P concentrations.
w . P. P w . P. P
ww
ww d) The rate w ofw wawfirst order reactionwdoes wwwdepend on reactant
w ww ww
wconcentrations; the rate
ww wwofwa
second order reaction does not depend on reactant concentrations.
i . N . etet
N i . N . etet
N i .N . etet
N i .N . etet
N
24. After a 2 i hours, a radioactive a i
substance becomes ( 1 / 16
a i
) of original amount. a Theni the half
saaslaa
th
saasa l l a saasa l l a saasa l l a saasal l a
aad alife
d ( in min) is aa d ad aa d ad d
aa a
d d
aa a
d
ww .P.P a) 60 minutesww ww .P.P b) 120 minutesww ww .P.P c) 30 minutes ww.P.P d) 15 minutes ww ww .P.P
w
ww w ww ww www w ww
P.Irulappan., PG
i . N . eteAsst.in
N t Chemistry., Lord Venkateshwara
i . N . etet
N Matric.Hr.Sec.School,
i . N . etet
N T.Kallupatti
i . N . etet Page 11
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas