Thermodynamics 101 EE

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THERMODYNAMICS 101

Thermodynamics is a branch of physics that studies the relationships between heat,


energy, and work. It encompasses several key principles:

First Law of Thermodynamics:

Also known as the law of conservation of energy.


Energy cannot be created or destroyed, only transferred or converted between different
forms.
The equation for the first law is ΔU = Q - W, where ΔU is the change in internal energy,
Q is heat added to the system, and W is work done by the system.
Second Law of Thermodynamics:

Entropy tends to increase over time.


Heat naturally flows from hot to cold objects.
No process is 100% efficient; some energy is always lost as heat.
The second law is often stated in terms of the impossibility of a perpetual motion
machine of the second kind.
Zeroth Law of Thermodynamics:

If two systems are each in thermal equilibrium with a third system, they are in thermal
equilibrium with each other.
This law allows the definition of temperature.
Thermodynamic Processes:

Isothermal: Constant temperature.


Adiabatic: No heat exchange with the surroundings.
Isobaric: Constant pressure.
Isochoric: Constant volume.
Carnot Cycle:

The most efficient theoretical heat engine.


Composed of reversible isothermal and adiabatic processes.
Entropy:

A measure of the disorder or randomness in a system.


Entropy tends to increase in isolated systems, leading to the arrow of time.
Gibbs Free Energy:

Indicates whether a process will be spontaneous at constant temperature and pressure.


ΔG < 0 for a spontaneous process.
Phase Transitions:

Changes between solid, liquid, and gas phases.


Specific heat and latent heat play crucial roles.
Maxwell's Relations:

Mathematical relationships between thermodynamic properties.


Enthalpy:

A measure of a system's total energy content, including internal energy and the effects
of pressure and volume.
Heat Engines, Refrigerators, and Heat Pumps:

Different applications of thermodynamic principles in various devices.


Understanding thermodynamics is crucial for fields like engineering, chemistry, and
physics, providing a foundation for analyzing and predicting the behavior of physical
systems.

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