CDI 5 Complete Notes II
CDI 5 Complete Notes II
CDI 5 Complete Notes II
is fire.
What is Fire?
• The heat and light that comes from burning substances, produced by
the combustion of substances.
• It is the manifestation of a rapid chemical reaction occurring between
a combustible matter and an oxidizer. Such rapid chemical reaction
releases energy in the form of heat and light. When a substance burns,
heat and light are produced. Burning is also called combustion.
• Fire is the product of a chemical reaction or a process called
combustion. When combustion takes place heat and light are
produced, and the heat and light is referred as fire.
• Fire is a product of combustion.
• Fire is the heat and light that is observed when combustion takes
place.
Combustion
Oxidation
Oxygen
Octet Rule
Examples of Oxidation
• The chemical reaction in which oxygen chemically combines with the organic
elements (fuel) of a combustible substance.
Slow oxidation sometimes becomes rapid. The rapid oxidation of material is chemically
termed as combustion. In some fuels, if the heat during oxidation is not easily
dissipated, the temperature gradually rises until the material automatically ignites.
When this situation occurs, the material has undergone spontaneous combustion. Rags
or papers saturated or soaked with animal fat (or vegetable oil), if stored in confined
space where the heat of oxidation is not dissipated fast enough, tend to undergo
spontaneous combustion.
Elements of Fire
Air is composed of: 21% oxygen, 78% nitrogen, 1% inert (inactive but are still
combustible) gases
Why heat is needed.
- Heat is needed so that the carbon and hydrogen molecules which are
the flammable vapors will be released from the fuel and to break the
bond between the carbon and hydrogen so that oxygen can attack and
chemically combine with the free carbon and hydrogen atoms.
- Heat is the activation energy that we need in order to reach the energy
level that is needed for our fuel and oxygen to undergo combustion and
turn into carbon dioxide and water.
Fire Triangle
If any of the elements are not available, the combustion does not take
place. Normally, oxygen is supplied by air, ignition temperature can be
provided by the ignition device (like a flame), and any combustible material
(usually organic matter) burns when heated by the ignition device. Most
combustible materials burn in the gaseous state only.
If there is a sufficient supply of oxygen, there is rapid oxidation resulting to
complete combustion. If the supply of oxygen and vaporization of a matter is
sufficient combustion is accompanied by heat and light. If there is an
insufficient supply of oxygen, there is smoldering fire. In a smoldering fire, no
flames are manifested.
To burn a fuel, its temperature must be raised (increased) until the ignition point
is reached. Thus, before a combustible material starts to burn or before it can
be ignited, it has to be exposed to a certain degree of temperature. When the
temperature of a substance is very high, it releases highly combustible vapors
known as free radicals.
FUEL
Fire Tetrahedron
Chemical
Chain
Reaction
FUEL
• The lowest / minimum temperature at which a substance gives off vapors that
burn momentarily (when a flame or spark is applied).
If a fuel’s temperature has reached its flash point, then it can be instantly ignited thus
producing a momentary fire. If its temperature still increases, such that it continuously
releases combustible vapors, the condition results in sustained burning
(combustion). Hence, the fuel is deemed to have reached its fire point.
Fire Point
• The temperature at which the fuel continues to burn after it has been ignited –
that even if the source of ignition has been removed, the fuel continues to
burn.
Fire Properties
Physical properties
1. Specific Gravity
2. Vapor Density
3. Vapor Pressure
4. Temperature
5. Boiling Point
6. Fire Point
7. Flash Point
8. Auto-ignition point – kindling temperature
Chemical properties
1. Endothermic reaction
2. Exothermic reaction
3. Oxidation
4. Combustion
5. Flame
Flames
Flame
1. high temperature
2. reactants (fuel and oxidizer / gases / vapors)
3. the concentration of short-lived intermediate chemical reaction between
reactants
Types of Flames
1.) According to color and completeness of combustion
1. Luminous flame
• reddish-orange in color
• it deposits soot because it is a product of incomplete combustion
• It has a lower temperature
2. Non-luminous flame
• bluish in color
• it does not deposit soot because it is a product of complete combustion
• it has a higher temperature than luminous flame
2.) According to burning fuel and air mixture
1. Premixed flame
– e.g. flame of a Bunsen Burner or LPG
– Are flame that are produced when the fuel are flammable
vapors are already combined with the oxygen or oxidizer
before undergoing combustion
2. Diffused flame
– e.g. flame of the oxyacetylene torch (ethyl alcohol lamp)
– Is when the fuel is not yet combine with an oxidizer or
oxygen will have to rely therefor with an oxygen present in
the environment.
3.)Based on smoothness
What are the factors which affects the color of the flame?
1. Completeness of Combustion
2. Additives that are present
Flame Test
- Is an analytical procedure used by the chemist to detect the presence of
particular metal ions, based on the color of the flame produced.
Hydrocarbon
• It refers to the chemical process whereby fire consumes the most solid part of
the fuel.
• It is the thermal decomposition of combustible matter.
• It is the chemical decomposition of a solid fuel through the action of heat.
1. hydrogen gas
2. carbon dioxide
3. carbon monoxide (most hazardous) – can cause asphyxia
4. nitrogen
• It is represented by the fire triangle with the three sides representing fuel,
temperature, and oxygen.
• The three elements of fire are present (Heat, Fuel, and Oxygen).
Evolution of fire
The world that we know today will be entirely different if man didn't master the science
of fire. So how did we learn how to tame fire? What were the prehistoric uses of fire?
What role did fire play in the development of early civilizations? And what are the
modern uses of fire? All of these questions will be answered by the end of this module.
EVOLUTION OF FIRE
Early humans used fire to warm themselves, cook food, and frighten away
predators. Sitting around a fire may have helped unite and strengthen family groups
and speed the evolution of early society. Fire enabled our human ancestors to travel out
of warm, equatorial regions and, eventually spread throughout the world. But fire also
posed great risks and challenges to early people, including the threat of burns, the
challenge of controlling fire, the greater challenge of starting a fire, and the threat of
wildfires.
As early civilizations developed, people discovered more uses of fire. They
used fire to provide light, to make better tools, and as a weapon in times of war. Early
religions often included fire as a part of their rituals, reflecting its importance to
society. Early myths focused on fire’s power.
Prometheus
• Fire bearer
• He stole fire from the gods, gave it to man, and taught him many useful arts
and sciences.
People learned to control fire by blowing at it through reed pipes. Then they
used this technique to burn hollows in logs to create cradles, bowls, and canoes.
Early 1980’s
- Koobi Forra
- Jawbone of fossils
- Homo Heidelbergensis – first who used fire
Introduction to fuels
FUELS (COMBUSTIBLE MATERIALS)
- Anything that burns and releases energy.
Most fuels release energy by burning with oxygen in the air. But some,
especially chemical fuels used in rockets, need special oxidizers in order to
burn. Oxidizers are compounds that contain oxygen. Nuclear fuels do not burn but
release energy through the fission (splitting) or fusion (joining together) of atoms.
In the fire triangle, fuel is one of the vital elements needed to produce fire. To
burn fuel, it must be heated to its ignition point.
Nuclear Fuel or Nuclear energy is called Green energy
➢ Materials that are in the form of flammable liquids such as alcohol, acidic
substances, oil, and other chemicals such as those liquid petroleum products.
Thermal Imbalance
Ceiling Jet
- Consist of a thin layer of voyant gases that moves rapidly just under the ceiling in
all direction away from the Plume.
- Responsible for the activation of smoke detectors sprinkler heads and so forth,
and as these gases formed in the upper levels in the compartment this start to
form thermal layers of varying temperature
- The hottest layer is one of the topmost and may be visible in your naked eye if
left on disturbed.
- Each layer will have its own color
1. Backdraft
Characteristics of Backdraft
3. Bite back
• A fatal condition that takes place when the fire resists extinguishments operation
and becomes stronger and bigger instead
4. Flashfire
- The three principle environmental elements affecting while in fire behavior which
are found in the environment tringle are fuel, weather, and topography
4 basic Concepts
1. Rate of spread
- 1 CHAIN = 66 ft
- 80 CHAINS = 1 mile
- 10 sq CHAINS = 1 acre
2. Fireline Intensity
- Measurement of heat released over a period of time
- Low relative humidity + heavy Fuels can lead to high fire intensity
3. Flame length
- Is the distance between the flame tip and the base of the midpoint of the flame at
ground level
4. Flame height
- Average maximum vertical extension of the flame
Parts of a Fire
1. Origin
2. head
3. Back
4. Flanking fire
- Spreads at right angles to the wind
5. Fingers
- Project from main body
6. Pockets
- Unburned areas between fingers
7. Island
- Unburned areas inside fire perimete
8. Spot
- New ignition outside fire perimeter
Types of Fire
1. Ground
- Spread primarily by smoldering combustion through subsurface fields including
deep dup, pit roots, rattan berry logs and other organic materials.
2. Surface
- Spread by flaming combustions through fuels at or near the surface including
needles or leaves, grass, woody debris, small plants and shrubs
3. Crown
- Burns through shrubs and tree crowns in canapés
1. Spontaneous heating
o The automatic chemical reaction that results in spontaneous
combustion due to the auto-ignition of organic materials.
o The gradual rising of heat in a confined space until the
ignition temperature is reached.
o A slow process causing the burning of a plant combustible
material even without an external source of heat.
2. Lightning
o A form of electricity.
o A natural electric current with great magnitude, producing
tremendous amperage and voltage.
o It usually strikes objects that are better electrical conductors
than air.
o It can cause fire directly or indirectly.
o Indirectly when it strikes telephone and other transmission
lines causing an induced line surge.
o It can cause flash fire or dust explosion. When lightning strikes
steel or metal rod covered with dust, the dust would suddenly
burn thus resulting to an explosion.
o A lightning may be in the form of:
B. Accidental causes
1. Electrical Mishaps
1. short-circuit – unusual or accidental connection between 2
points at different potentials (charge) in an electrical circuit
of relatively low resistance.
2. arcing – production of sustained luminous electrical
discharge between separated electrodes; an electric hazard
that results when the electrical current crosses the gap
between 2 electrical conductors.
3. sparking – production of incandescent particles when 2
different potentials (charged conductors) come in contact;
occurs during short-circuits or welding operations.
4. Induced current-induced line surge – an increase of
electrical energy flow or power voltage; induced current; a
sudden increase of electrical current resulting in the burning
of insulating materials, exploding of the fuse-box, or burning
of active electrical appliances.
5. Overheating of electrical appliances – increase or rising of
amperage while electric current is flowing in a transmission
line resulting to the damage or destruction of insulating
materials; maybe gradual or rapid; internal or external.
1. smoking
2. misuse of fuels and explosives
3. misfiling of fuel tanks
4. motor vehicle traffic accidents
C. Intentional Causes – incendiary - arson
* Preparations or traces of accelerants and plants and trailers in the
burned area may indicate the intentional cause of the fire.
Steps
1. Pre-Fire Planning
- This activity involves developing and defining systematic course of action that
may be performed in order to realize the objectives of fire protection.
- It involves the process of establishing the SOP incase fire breaks out.
3. Evacuation
- The activity of transferring people, livestock, and property away from the burning
area to minimize damage or destruction that the fire might incur in case it
propagates to other adjacent buildings.
4. Entry
- This is the process of accessing the burning structure.
- Entry maybe done in a forcible manner.
- The following are the purpose of conducting forcible entry:
- To provide access of fighters with equipment for fire extinguishments.
- To provide rescue
- To aid in ventilation
5. Rescue
- This is the operation of removing (extricating)
- Thus, saving people and other livestock’s from the burning building and others
involved properties, conveying them to a secured.
7. Confinement
- This is the activity of restricting the fire of the place (room) where it started.
- The process of preventing fire from extending from another section or from one
section to another section of the involved building.
8. Ventilation
- This is the operation purposely conducted to displace toxic gases.
- It includes the process of displacing the heated atmosphere within the involved
building with normal air from outside atmosphere.
9. Salvage
- The activity of protecting properties from preventable damage other than the fire.
Steps:
a. Remove the material outside the burning area
b. Protect or cover materials by using tarpaulins (cotton canvass treated by water
proofing)
10. Extinguishment
- This is the process of putting out the main body of fire by using the 4 general
methods of fire extinguishments like cooling.
11. Overhaul
- This is the complete and detailed check of the structure and all materials therein
to eliminate conditions that may cause reflash.
- It involves complete extinguishments of sparks or smoldering (glowing0
substances (embers) to prevent or eliminate possibilities of re-ignition or
rekindling.
➢ Assuming the above conditions, here are specific tips and firefighting techniques:
➢ Timing
Fire Response
1. Life safety and Personal protection
2. Incident stabilization
3. Property conservation
Triangle of
safety
Effective training
Extinguishment Agent
- A substance that will put out a fire
The specific actions involved in fire extinguishment
1. Cooling
- To reduce the temperature
- This is a direct attack on the heat side of the fire tetrahedron
2. Smothering
- To separate the fuel from oxygen
3. Oxygen dilution
- To reduce amount of available oxygen needed to sustain combustion.
4. Chain breaking
- To disrupt the chemical process that sustains the fire.
Classes of Fires
Class A fires
Class B fires
Class C fires
Class D fires
Class K fires
Note: Always follow the specific instructions on a fire extinguisher and familiarize
yourself with these instructions prior to an emergency situation. Persons should
be trained in the use of extinguishers to optimize their effectiveness.
REMEMBER:
Saving lives through a quick escape is far more important than saving property.
An emergency is not the time to read extinguisher instructions, if you do not know how
to use the extinguisher or the type of materials involved in the fire:
• Close the door to contain the fire
• Ensure everyone is out of the building
• Ring the fire service.
• Never go back into the building once out
• Wait to meet the fire service
Types of fire extinguishers
Water(solid Red): wood and paper fires - not electrical
Foam (Blue band): flammable liquid fires - not electrical
Carbon Dioxide (Black band) electrical fires
Dry Chemical (White band) flammable liquids and electrical fires
Wet chemical (Oatmeal band) fat / oil fires - not electrical
Special Purpose (Yellow band) various (eg. metal fires)
Fire extinguisher locations must be clearly identified. Extinguishers are color-
coded according to the extinguishing agent. The important thing to remember is that fire
fighting must always be secondary to the safety of people.
Extinguishing Agent - a substance that will put out a fire. Every extinguishing agent
operates by attacking one or more side of the fire tetrahedron. The specific actions
involved are the following:
1. Cooling To reduce the temperature. This is a direct attack on the heat side of the fire
tetrahedron.
2. Smothering To separate the fuel from oxygen.
3. Oxygen dilution To reduce amount of available oxygen needed to sustain
combustion.
4. Chain breaking To disrupt the chemical process that sustains the fire
- Halogenated Agents
- halogenated agents have been used for fire fighting since the early 1900’s
- of the ten halogenated agents that have been used two have been the most
common since the early 1970’s halon 1211 and halon 1301.
- to have better understanding of the chemical properties of these agents, the US
Army Corps of Engineers developed a numerical system for halogenated agents.
- halogenated agents suppress fire by interrupting the chemical chain reaction in
the combustion process, working in the fire chemically instead of physically.
Extracted how this Chain breaking process works is not completely understood.
4. AFFF – Aqueous Film Forming Foam Light water. A synthetic foam-forming liquid
designed for use with fresh water. When proportionally mixed with water, it generates
white foam with a remarkable ability to make a water float on flammable liquid which are
lighter than water. This double action foam and aqueous film enhances extinguishments
of flammable liquid fires and prevent reflash. This action also takes place on spilled or
leaking liquid fuels, which have not been ignited so they are secured and are not readily
ignited.
5. BCF-HALON 1211
- Stands for Bromochlorodifluoromethane
- One of the modern and effective fire-extinguishing agents available for general
risk.
- Vaporizing liquid which will chemically interrupt the chain reaction taking place in
the flames.
- Has the ability to minimize the possibility to reflash after the fire has been
extinguished.
- A colorless, non-corrosive liquefied gas that leaves no messy residue.
- Highly recommended for use in industrial factory, home computers and electronic
companies, motor vehicles, etc.
Flame Flare-Up
- Phenomenon, a unique property of dry chemicals that occurs when dry chemical
is applied to a flammable liquid fire.
Sodium Bicarbonate
- Also called as regular dry chemical
- In addition to effectiveness of class B and C fires, it will have some effect on the
flaming stages of a class A fire but no effect on the ember or deep seated stages
of a class A fire.
- When used with common cooking grease it will react with the hot grease form a
thick foam through a process known as “Saponification”
Potassium Bicarbonate
- “Purple-K” potassium bicarbonate or purple-K dry chemical was developed by the
U.S. Naval Research Lab.
- Claims of the effectiveness of the potassium bicarbonate agents range from
50% o 100% more effective on flammable liquid fires when compared to sodium
bicarbonate.
- Potassium bicarbonate is also called Alkaline in nature, has similar abilities to
saponify when used on hot cooking grease, but like sodium bicarbonate, it lacks
the cooling capability of wet chemical and is no longer agent of choice of class K
fires.
7. Wet Chemical
- Wet chemical agents are solutions of water mixed with potassium acetate,
potassium carbonate, potassium citrate or combinations thereof
- They are specifically designed for class K fires but they have demonstrated
superior effectiveness (gallon for gallon) on Class A fires when compared with
plain water.
- These agents are used in both hand portable extinguishers are pre-engineered
fixed systems.
Fire Extinguishing
Burning Material Extinguishing Method
Category Agent
Ordinary combustible
Class A Cool below flash point Water
materials
Flammable or
Class B Cut oxygen supply Foam
combustible liquids
Dry chemical
Class C Electrical Equipment Cut oxygen supply
powder
Accelerants
- Things that increase the burning or combustion
❖ It is important to know what cause the fire to know the traces for evidence
Systematic Approach
- The systematic approach recommended is that of the scientific method which is
used in the physical sciences. This method provides for the organizational and
analytical process so desirable and necessary in a successful fire investigation.
3. Collect
- Collect Data: Facts about the fire incident are now collected. This is done by
observation, experiment, or other direct data gathering means.
4. Analyze
- Analyze the Data (Inductive reasoning): All of the collected and observed
information is analyzed by inductive reasoning
5. Develop
- Develop Hypothesis: based upon the data analysis, the investigator must now
produce a hypothesis or group of hypotheses to explain the origin and cause of
the fire explosion incident.
6. Test
- Test the Hypothesis (Deductive Reasoning): All other reasonable origins and
causes must be eliminated.
2. Technical Investigation
- There is suspicion of arson in connection with the fire
- There is a suspicion of negligence or violation of regulations
- The cause of any fire is undetermined (to establish the most probable cause)
- There is evidence of negligence or mismanagement in the fire suppression or
rescue operation.
- Loss of fire or disabling as a result of fire.
3. Arson Investigation
- The direct result of the basic or technical investigation or it may be brought about
from outside knowledge.
Method of Entry
1. Consent
2. Exigent Circumstance
3. Administrative Search Warrant
4. Criminal Search Warrant
Sources of Information
❖ Purpose of Obtaining Information
- The thorough fire investigation always involves the examination of the fire scene,
or by evaluating the prior documentation of that scene. The fire Investigator
should not however, end with the mere examination of the fire scene.
Forms of information
❖ Verbal: Sources which, may be encountered by the fire investigator, may include
but are not limited to, verbal statements during interviews, telephone
conversations, tape recording and the like.
❖ Written: Sources may include, but are not limited to, written reports, written
documents, reference materials, newspapers and the like.
❖ Visual: Visual sources of information, by definition, are limited to those that are
gathered utilizing the sense of sight. Sources may include but are not limited to,
photographs, videotapes, motion pictures, and computer generated animations.
❖ There is no single item sufficient to establish the origin of fire, thus the
investigator must use all the available resources in developing potential
scenarios and determining which scenarios plausibly fit all of the evidence
available. It is important that the determination of the single point of origin not be
made unless the evidence is conclusive.
❖ There purpose of determining the origin of the fire is to identify the geographical
location where the fire begin. If the specific location where the heat source
ignited the first fuel can be identified, then the point of origin can be determined.
Cause of Determination
- The determination of the cause of fire requires the identification of those
circumstances and factors that were necessary for the fire to have occurred.
- The circumstances and factors include but are not limited to: device or equipment
involved in the ignition, the presence of competent ignition source, the type and
form of the material first ignited, and the human actions that allowed the factors
to come together so as to allow the fire to occur.
Classification of the Cause:
1. Accident Fire Cause
2. Incendiary Fire Cause
3. Natural Fire Cause
4. Undetermined Fire Cause
Safety
- Investigating the scene alone
- Safe clothing and equipment
- Fire scene hazard
- Personal health and safety
Arson Investigation
❖ Point of Origin
- It is established by examining the witness, by inspection of the debris at the fire
scene and by studying the fingerprints of the fire
- Also known as Area of Origin
Types of Pyromaniac
1. Abnormal youth
2. Hero type – a person set a building on fire and pretends to discover it, turn
on the alarm or make some rescue works to appear as hero
3. Drug addicts and alcoholics
4. Sexual deviates and perverts
Prime Suspects
The following technique may serve the investigation:
1. Search of the fire scene for physical evidence
2. Background study for policyholders, occupants of premises, owner of other
person having major interest in the fire.
3. Interviews and interrogation of persons who discovered the fire, and the one who
turned the alarm, firemen, and eyewitnesses
4. Surveillance
The Tell-tale signs of Arson
❖ Burning Building
- The type of building that may indicate a set of fire under certain circumstance.
❖ Separate fires
- When two or more separate fires break out within a building, the fire certainly is
suspicious
❖ Color of smoke - Some fire with little or no smoke must be made at the start of
the fire scene once the fire has assumed a major portion; the value of the smoke
is lost, because the smoke will not indicate the material used by the arsonist.
- when the white smoke appears before the water from the fire hose comes in
contact with the fire, it indicates humid material burning as burning hay,
vegetable fibers, phosphorous (with garlic)
- Biting smoke, irritating the nose and throat and causing lacrymation and
coughing- indicates plastic products and rubber.
❖ Color of flame
- The color of flame is a good indication of the intensity of the fire, an important
factor in determining incendiarism.
❖ Amount of Heat
- A reddish glow indicates heat of 500 degrees centigrade; a real bright red about
100 degrees centigrade, Red flames indicate petroleum. Blue flame indicates the
use of alcohol as accelerant.
❖ Smoke marks
- Investigator shall determine the volume of smoke involved at a fire and the
characters as residue deposited on walls or elsewhere.
❖ Size of fire
- Fire makes what is termed as normal progress. Such progress can be estimated
after examination of the material burned in the building and the normal ventilation
offered by the fire. The time element and the degree of headway by the flames to
determine the factors of possible incendiarism.
❖ Direction of travel
- While it is admitted that no two fires burn in identical fashion, yet it can be shown
that fire makes normal progress through various types of building materials,
combustibility of contents, channel of ventilation and circumstances surrounding
the sending of alarm, an experienced investigator can determine whether a fire
spread abnormally fast. (upward or lateral)
❖ Intensity
- The degree of heat given off by a fire and the color of its flame. This oftentimes
indicate that some accelerant ahs been added to the material normally present in
a building and the investigator must look for further evidence pointing to use such
accelerant. Difficulty in extinguishing a fire often led to suspect presence of such
fluid as gasoline and kerosine.
❖ Odor
- The odor of gasoline, alcohol, kerosene and other inflammable liquids which are
often used as accelerant and oftentimes arsonist are tapped because of this
telltale sign. Most of the fire-setters are inclined to use substance which will make
the blaze certain and at the same time burn up any evidence of their crime.
❖ Condition of Content
- Persons tending to set there house on fire frequently remove objects of value
either materially or sentimentally.
4. Purple or Violet
- Potassium Products
5. Greenish-yellow flame
- Chloride or manganese products
6. Bright reddish yellow flame
- Calcium products
Fire Response
1. Life safety and Personal Protection
2. Indent Stabilization
3. Property conservation
Arson
• It is the malicious or intentional destruction of property by fire.
1. Burning – that there was a fire that may be shown by direct testimony of the
complainant, firemen responding to the crime, other eyewitnesses. Burned
parts of the building may also indicate location.
2. Criminal design – must show that it was willfully and intentionally done. The
presence of incendiary devices, flammable substances/materials such as
gasoline and kerosene may indicate that the fire is not accidental.
3. Evidence of intent – when valuables were removed from the building before
the fire, ill-feeling between the accused and the occupants of the building
burned, absence of effort to put off the fire and such other indications.