Unit 4 KTT 2 Organic Pathways - Solutions Book
Unit 4 KTT 2 Organic Pathways - Solutions Book
Unit 4 KTT 2 Organic Pathways - Solutions Book
Unit 4
Key Topic Test 2 – Organic pathways
SOLUTIONS
Question Response
1 D
2 B
3 D
4 A
5 C
6 A
7 B
8 A
9 A
10 B
Question 1
Answer: D
Explanation:
The bromine atoms were added across a double bond. The molecule used was pent-2-ene.
Question 2
Answer: B
Explanation:
They react to form an ester. The alcohol forms the first part of the name, propyl and the
carboxylic acid is the second part of the name, ethanoate.
Question 3
Answer: D
Explanation:
This is a substitution reaction. If excess chlorine is used, multiple substitutions of Cl atoms can
occur forming a whole range of products.
Question 4
Answer: A
Explanation:
The reaction is an addition reaction if both bromine atoms are placed on the molecule.
Question 5
Answer: C
Explanation:
A carboxylic acid will form when a primary alcohol is used. Molecules B and C are primary
alcohols. Molecule B might have a branch in the hydrocarbon chain but it is still a primary
alcohol.
Question 6
Answer: A
Explanation:
The amide bond is formed from the reaction between an amine and a carboxylic acid. The amine
will be ethanamine and the acid pentanoic acid.
Question 7
Answer: B
Explanation:
The first test indicates the presence of a C=C double bond as addition reaction occurred between
the hydrocarbon and the Br2.
The seconds test indicates an acid as the CO2 (g) was produced.
Question 8
Answer: A
Explanation:
The NaOH would convert the amine to an alcohol and the Cr2O72- would convert this to a
carboxylic acid.
Question 9
Answer: A
Explanation:
Question 10
Answer: B
Explanation:
The reaction of 0.5 mole of propene will form 0.5 mole of propane. The mass of 0.5 mole of
propane is 22 g.
Question 1
a.
i. 1-chloro propane
ii. propan-1-ol
iv. Ethanol
2 + 2 + 2 + 2 = 8 marks
b.
i. Substitution
ii. Substitution
iii. Oxidation
iv. Condensation
1 + 1 + 1 + 1 = 4 marks
Total 12 marks
Question 2
a. i. CH3CH2OCOH or HCOOCH2CH3
H H
H C
H C C O H
H H O
ii. H H H H
H C C C N
H H H
C O
2 + 1 = 3 marks
Total 5 marks
Question 3
a. amide group *
2 marks
b. i.
H H H H
C C C N
H H H H
ii. water
1 + 1 = 2 marks
c. i. Hexagon stands for benzene, an aromatic molecule with alternating double bonds*
H H
C C
H C C H
C C
H H
ii. CH
2 + 1 = 3 marks
Total 7 marks
Question 4
a. i. propanal H H H
H C C C
H H
O
ii. A catalyst is not changed in the reaction. The Cr2O72- ions are reduced in this process.
2 + 1 = 3 marks
b. propanoic acid O
H H
H C C C
H H 2 marks
O
c. propanone O
H
H C C
H H
C
H
H
2 marks
Question 5
a.
i. C2H4 + Br2 → C2H4Br2
ii. C2H4 + H2O → C2H5OH
iii. C2H4 + HCl → C2H5Cl
1 + 1 + 1 = 3 marks
b.
i. Addition reactions
ii. Only one product formed no undesired by-products are formed.
1 + 1 = 2 marks
c.
i. C2H6 + Cl2 → C2H5Cl + HCl
ii. Substitution reaction
iii. Two products have formed, although further substitution of chlorine is possible
1 + 1 + 1 = 3 marks
Total 8 marks