Section- A to aMo 18

section
manken
Seton-D
setonE
4nekeas
Smank
 seT F-m-70
Sec-A
b Auto oNdain o chlonoomn in air and Sunlyke
frlucef a Poisnng 1s Ksn s
(a) Tea gas ymustand gas C) Phasgene
a) chloune gag
2 which of the pllwing ligans is an amide
ntate isand 2?
co (b) No
Amang the oloing, which hos he hghest
vaue of pko?

4 The slope in Yhe plot f log-Ao Vs tme

o a Arst order reeactin S

2302 2-202
G when -lucase neats with HI,0t foems
) Gluconie aid b) n-hexane
) Saccharie acid d) Tado hexane.
GInversion of Canfiguration in
Co) SNl reacton
Nei ther S nrSN eaction
a Sn agwelag SN reacton.
 in liquid deereageg wh
InceeaRe in
a) reessure b) Temperatuna
() volme d) Numler solute aleculeg
which of he flowjg reeatims is incorereect?

q The rreagent that can he weed to disttn

guish acetopheone cnd ben zo phenone (s
2,4-dinitro pheryl hydrazine )aqueoug
NaHsog
fehling solution a) ITand naH
Jo which ¢the Followirg reacns curee fancy
feasibe ?
( CHycHy 3rt Na
o-ccH)>CtcHo
bY)c-lt Nato-CtzCts ’ c3CH-ocer)a
d) Neither Ca) nmb)
which f the pllnvirg mfas will eergo
self- Candensation in the prQgence fdilute
Naot solution
CoHscHo b) CH3c2_cHO
CHs)qC-CtHo G) H-CHo
)
12 for the reeaction 3A-> L0 rate f recct
iS equal to
dt
dt tdt
dt dt
|3 whict of e following traansittom metals
Shs tI and t2 oxidation sttes ?
(a mn 6) (b) 2n Se
4 The formua the Canplex Irron(0)
hexacyanido ferereate Q) is Fegfe

Given below are tuo statenents labelleal as

Assertin and Reogn(e)
select the ost appropri ate answer fnam he
optims ien belw
(a) Botth A) end(e) are true and R is Hhe Conort

Buha) and e) ane truul an RiS Ho

ot tha
(5)
Cornet explantion of A)
C) Ca) is true, but (R) is fale
a)aJ Ts false, bud () true
15 Assertin (A): The enthalP'y t mi xirg AmixH is
eqial to 2eo f an idool eog Solution .
Reacn o an idool Solutiam he in teractn
lbetween solute and Solvent mmleog îs striong
ert an h interaion between Solte- Solte
Solent solvent oleculeg.
l6 Assentin (A) : molon Concueti vity oleeneaseg
with jncreae in caneentretin
Reasn (e): when Centratin epprioaheg zen
the mohn Cndtivity is knun a limjtingmala
Cductvity Transitin metals show thein i
7 Assertin t) :
ghegt oxi datin stte with oygen
Peason(): The abiity of oaygen to forn md
ti Ple lbonds to etals -
15 As ertion A): Chlorabenzene is rresistant to
neleophilie substi twtan roactom at noom temle
ratue
Poagon (
Reason e-cL bnd gets weaker due to
rresonance
Setirn-B

PP what are nucleje aids why tu0 Strrands

in NA are ot dentcal but dre Canplemen

902 Do he ollwing Comergins ln not more h

tuo steps
() cttacooH to tco cH3
(b) Hes to -cooH

l write the chemiea eguation involveo in the

follavig roacttns:
(a) PeimerTiemem reaction
Acetylatin o salicyeie Acid
O The Cmvension f aleeule Ato D followeal Secn
rrcer kinetics |f Corcentrati mof Ainereae
to three tmes haw will it efect the rate f
frmatin of B ?
(9) Define Pseco first order reaction withan
exame
23 The vapu pressure of a Pene iquex and
Pure liquid Y t 25c ae 20 mm Hg and l69mm
H9 ragpectely IF equal moleg of°xandyane
ha
miyed to form an ideal Solution,calclate the
Vaprur fressure o the Stion:
Sa re reasns
Ci) mercury cel delives alenstent potential
during its ife tirne.
) Ln the expermental determinatn of eactrtayt
Condutrce , Direct Crrcent (D) is not used.
b) Define fuel cell with an example. what acvant
agee do the fuel cels hare aner primarg
 SeOndy batteriey
256) wrçte the
?
TUPAL names f
0fco (s),ON)7* thefollowtng.

(bla) what is a
(19 what are chelate Cmplex)G) me exmple
examle hetenoleptie Conplexes Give
26 Ans Wer any |sectn-c
3 of the
follig:
Comtond Cs Hcl in bright Sirgle mmochlons
( Arerange Sunlight
the following on paznds
order of raactviy towanls SN² in ncreesing, )
reactin
2- Bronopentene, I-Brama pentene ,2-
Brmo-2- nesty
why Jbutene
oint
p-dihloro berzene his
han those of oLha and highermelting
) meta-isonerc ?
Ldentifg BrAand Bin the folwng.
B
Dny thea
at) wite the mechansm of the
follvwing folowig
413K CH3-H1-0-CH2-cH t H2o reacin
(i) twhg ortho-nitro phenol is steam olatile
while
paranitzophenal is not
 o
(b) what hrpenS when H3ce/onhyhag Ale
C) Anisole is trreated wih
) phenl is oxidisel with NazCa0+/Ht2
is heated with aufG3ko
() CH)ac-0H Spont d yrr
lwnite chemical equation in
anser
93a)Draw the geometrical isomers of
whicA geometri ced /somer f c (enhl"is not
optt cally active anel uhy
(b) Write the hy bricliseti on and magneti be
3
haisure of CoFe.
|Giren: Atamjc nem ber f co=27
24 A frst onder reactn is Go/, Comete in 30 minty
30 k an in Jo minuteg at 320 ko Calculate
at
activation energy (Ea) fore the reactin
(R=.314Tm7 44=0-602)|
lo93=o-4971,log
Giren log2Boj,
30 when 1959 hf F-Ct- CoolH(molarr mag =189 ma
Is dissulyedin Goo9 d waten, the depreessian in
freezing pint is observed to be |t. calulodte
the degree of dissa ciation f F-CH-caoH.
Given: ke Fore water= |·86k bg mo)
 SECTI9N-D
The following questins are cose
poad he passoge canefully and hagee questtons
ansue the
questns h t follaw
3l The carban-
oygen dable bon iS olariseal
in aldehyeg and ketones due to highen electe
egativity of gen nelatie ti carkon.
Thenefore they urlengo nudeophilie additian
rOActions witha nmber of ucleo philes such
HCN, Na tsug, alcohols, amnaniA derivatives
and Grig and reagets Aldehydeg are eosily o
dised by mild oxidising agert s ag Comfarcefto
hetnee The carbong gruaf f Canbghe aci
doeg ot ve reactmc f aldehydeg ad ketmeg
Carboyli ads arre considereably one acidic
han als hols and mst f Simple pheals
Arswer the blowing ?
a)Wrte the mne f the Araduet When an
aldehyde neacts with excess alshol in Arase
nCe of
cy
G) why carbo glie acid s a strger aid than
(C) Arange the ollawing ompanls in ineneasig
reler f their reactivity towanas cHs g Br:
H
CHscHO, (Ctt)eD CH3
0) Write a ehemical tegt to aistingsh betu
een pr faral an propane
 OR
C) Nite he main Piabet in the follwing.
(i)

cHO
HaNeoNHNH

32 canbo hydrates are optically atve polyyceo

82
xyaldehydeo and ketonee.
C Thay
re aso caloe)
Sacchaicle. AU tha
Saccharicley Al those Carbohyolratee which
roduco pehling's solution and Tollen's reogent
rnecicing sugors Glucise,
are profered to ossource man
impotat energy for
4he mst
mals , is obtained by the hycdralysis &stareh
Vitamins are accessory foo o fact reire)
0n the iet. roteins are the aymerg of
d-amino acids and perfom Variny truct
nal and dlnamie functims in the ongnsm
Defiiency f Vitmins leads to myy diseaseg
Arswer the ollaing :
a) The ertoacetate t gucese ebes ngt react
With H r vylamine - what coeg it idiate )
b) why Con not vitamin c be storciod in our bacdy 1
( Depne the follawig og rrelate to rzoteins :
) pertide linkage
() Deatuatin.
OR
 () Defne the following as
6) Armens i) Glycosjdie relateed to cansihyelrates:
linkage
23) (1 Give ncosms
SECTION-E
() Ani line on nitnatim gives gad
amnt f m
nitzaaniline
in /though -NH greup is o/P dirrectng
eletha phi lic
Sibslitutin rlactins.
() CH3 NH sS mae basic hen(CH3) Nin
eas slution
an aqu
0) ) Ammnolysis df albyl hadiees is nt a gad
mehad to prepare pene preimary amineg.
(1I) wlte the reeaction Involred in th follnwing:
) Carbyl amine teet
)) brjel phthalimide synthesis.
((T) wite thestrutunes of A,Barl c sn the
bllawing reactns:
(i)
(1) Fe/HetA NanoztH
NH3c
(1) why aniine does not undeng o friedel-crafts rea
() Arrange the follooing in increeosing ornderof thei
boiling Point i CatHsoH, CaltsNH,ats),N
 34- Conducivity & 2XI6 M
xlS scm. Calclotemethanie
)
aud is
its malare Creuct
vity ad degree f dis50iation if A3 for
methaie acid is yoy sCm mo.
(b) calcdate he Ana'anad log kefor the given
reortion at 278K
2+
Nisot2 Agtoa Níat2 AgG)
Niey
Given: ENt: -0-25 V, EAstlh+0"D
1F= 6500 Cmol7

3() Account or the following i

) E Value for mim2t Capla is much mare
positve then that for Crstc2t.
Gi) sa is colaurless wheneo T;34 s Calored
in an aaey sutn.
(T) Acti nioiels shaw wide
wlcle rrange t oxidatin
stateg .
(T) Write the chemicad equatins for the
proparcation of kmnoy fran mnog
OR
(b) Accaunt or the follawirgs
() Trnci tion etas fonn allays
4)
di) ceT is a strng oxidrsing agent
(T) Write one
Similarity and one
Actinoids.
diferenee,
betueen ehemfstry of lanthanoids anel
(0) Compete the follawirg Tonic eqMatian:
Cryo? t 20H
 3o),0
HAcetic +
OH
Cot Acetylatin (6)
Salieylic
Aid af
hycle)
aliylalde phenal
to
NaoH G)cHdst
aq-
OH
Tntermeliete
Phen)
NaoH
weHcl2
Acd
Benzo ete ben20 pot benzene Alky
cacmiwn (b)
CoaCH3),cddiodky Thonyt3 hlaride H3CoH 20
(a)
Thymine A’Guanine; ’ T Sol
s)ne C>y toAdenine, >A
bey bosespaiting
and AgTbetueen ains
between fomed re bonels the
H- Because
polymerg
f are aids Cleic N
g. cleo
18) ) (b) () 19)
c) 3)
(a) ) () ) 6)
(Answer) SET-|
92{) qttes
(b) A eactim that arpeang to be higher
follws Argt orer kinetics . orlerbut

Ptotal =(120 yons) t(lkaxo5) Snce it is eimo

Ptotal = \40 mm Hg
) Becauye the aeral reatton does not \nvolne
any im in the Solution whose Cncentration Can
Chare It (s also a nm- rrectangeable cell.
(:35V hrah
( ) Beeaue De changeg the Con posin ont its shel
& electnoly tie solution. Lifey

(b) AGalvanic cel/Fuel cell) uged to Convent the

Conbutin f Fuel direecty into
energy & fuel
electrica enegy for eyampe He-oz
cel
Acentag free.
and pollutiom
Hgh effiieng
jon.
5i) Perntaammineni trito -o-Cabalt(n)
(Ö) Potassim tetrachlorido nicke late(0)
b)) A anplex fonmed by en identate
3
o apoly.
dentate igad. 6 o(ox)3
(i) Complex in whieh a metal is bterd to mae then
eind of donogrnfS o ligards
26() cydo pentane
romo
(b) 2-brsmo -2-mehyl bdane < 2-Brmo etere <I-Penten
Becae pna ismene its wel jnto the
(c)
cystal lattice due to symmetny
Br
(a) A
H
Hö-H
() cHa-cH,--H +H
H

ph ensl
b) Due to interams lecakan ybding jn o-nitreaphen
while p- nntro fhas pheml has intere moleutcre
H-bonding
t C#3u inbyMclb
CS +

(9)
H*

(1) Cu/es
CH3
 co
en Co
en

Truns
The trens /some is not
mirto jmge is ofticaly adive becanse its
( spd', paramagneti supErimosabe

min-l
30

303R
ta
2:303e 300
Ea o477/ x/9197 x 300 X320
20
Ea = 43848 J m
30 ATE = ilç m

WA
=ix·86 Xl9-sx000
Goo
ilo5
=005
3-a) Acetal
(6) Becaye the Canboylate jn is mmee resmana
strbili ed than tha phénoxde in
(C) cHs
CHt
() Aed iondine (I), Nco H, ardl haat bth the
test tubes Cantining he given orgnie Comfo4
rds - Prsfarone gives yelaw PPtCcHT3) While
ro panal will not gie yelw Ppt
Ci) JtNN HCON H
H
Coo

a) Absence ff frree
(b) Becaye beirg water Sojwble It is excretee
thagh urine
(0) -co NH - linkage between tuo aming acjds
(1) Loss & biologica actirity When Paoteàn s
Subjecte to chare in temp:,pt ete

The somers CCansshydnte having a chenge i

Cntguretin at c-l Cpm aldosse S) ar -2Cfr ieto
0)A inkage joining tuo mnosachanieles hrnyh
09gen aton
33 (a)(T)
Þ) Aniline gets pratonated and ÎS deactivate,
Aniline on proto atin foms ani liniem ion
Which s meta directing'
(W) Aecauye f high slatin efect/hiqh hychatn
ereagg
0) difficet
()1) ecause it fos a mixtune
to separate
mineg hat is

(T) G) Carbyamine test

Gabriel phthalimicle syntosrs
Ci)
CN-R

N
amine

(6XE) CONH

NH2
G)A=
( ) ecauge the onmti o satt with lewis acd
anhydrag ALd3
()CaHs)a N<CtGNH<Cets OH
34a) Am= kx00 cmo
S
X)o00 S cm mo
23
= yosCm
Am
(b) AnG-nFEu
=-2Xq6500C mox(o804 0-25)v
=-2X 46G00 X/*05 Jmol
-202,650 J m
-
nEcel -35"
log ke =
350))
C) cnt charges fron d'to stobe hauf-Alledt
Cmfiguratin while mn Changes-to stusse half

) Becaye of ng wnpaireel electran jn thedar ,

unre ele!
of Se3+ whereag thene s one
ctron in T / T:*sos d-d trunsitin.
Ö) Because a Comperuble eeriee f sf,6
7S orbital
 Hao >2cro
t t20H cr0 (W)
e. racio are jdActËng
S whereae active
remanly
nn Lanthanoids Differencei
stable Shaw
a) jn
t Cantractin
lananoicls
and BothSimilarity:
state datin
ommm
t3 b
hechonges Becalye
Ce () )
adii identical dmost case Be ()
(b)
’2mnoy
O-2mnoy
tH20 mnot
Hko (1)