DOW CORNING CORPORATION

Material Safety Data Sheet

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DOW CORNING(R) 3145 RTV MIL-A-46146 ADHESIVE/SEALANT-CLEAR

1. PRODUCT AND COMPANY IDENTIFICATION

Dow Corning Corporation 24 Hour Emergency Telephone: (989) 496-5900

South Saginaw Road Customer Service: (989) 496-6000
Midland, Michigan 48686 Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300

MSDS No.: 01190300 Revision Date: 2013/02/19

Generic Description: Silicone elastomer

Physical Form: Paste
Color: Translucent white
Odor: Slight odor

NFPA Profile: Health 2 Flammability 1 Instability/Reactivity 0

Note: NFPA = National Fire Protection Association

2. HAZARDS IDENTIFICATION

POTENTIAL HEALTH EFFECTS

Acute Effects

Eye: Direct contact may cause temporary redness and discomfort.

Skin: No significant irritation expected from a single short-term exposure.

Inhalation: Irritates respiratory passages very slightly.

Oral: Low ingestion hazard in normal use.

Prolonged/Repeated Exposure Effects

Skin: Repeated skin contact may cause allergic skin reaction. Repeated or prolonged exposure
may cause irritation.

Inhalation: Overexposure by inhalation may injure the following organ(s): Kidneys. Bladder.

Oral: Repeated ingestion or swallowing large amounts may injure internally.

Signs and Symptoms of Overexposure

No known applicable information.

Medical Conditions Aggravated by Exposure

No known applicable information.

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The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.

3. COMPOSITION/INFORMATION ON INGREDIENTS

CAS Number Wt % Component Name

1185-55-3 5.0 - 10.0 Methyltrimethoxysilane

The above components are hazardous as defined in 29 CFR 1910.1200.

4. FIRST AID MEASURES

Eye: If irritation occurs, flush eye(s) with lukewarm gently flowing water for 5 minutes. Obtain
medical attention.

Skin: As quickly as possible remove contaminated clothing, shoes and leather goods (e.g.
watchbands, belts). Quickly and gently blot or brush away excess chemical. Immediately
flush with lukewarm gently flowing water for 15 minutes. Completely decontaminate clothing,
shoes and leather goods before reuse or discard. If irritation persists, obtain medical advice.

Inhalation: Remove from the source of contamination or move to fresh air. If irritation persists, obtain
medical advice.

Oral: If irritation or discomfort occur, obtain medical advice.

Notes to Physician: Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES

Flash Point: Not applicable.

Autoignition Temperature: Not determined.

Flammability Limits in Air: Not determined.

Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.
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Unusual Fire Hazards: None.

6. ACCIDENTAL RELEASE MEASURES

Containment/Clean up: Observe all personal protection equipment recommendations described in Sections 5 and 8.
Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since
spilled materials, even in small quantities, may present a slip hazard. Final cleaning may
require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning
materials appropriately, since spontaneous heating may occur. Local, state and federal laws
and regulations may apply to releases and disposal of this material, as well as those materials
and items employed in the cleanup of releases. You will need to determine which federal,
state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide
information regarding certain federal and state requirements.

Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is
required.

7. HANDLING AND STORAGE

Use with adequate ventilation. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air-supplied or self-contained breathing
apparatus. Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed.
Do not take internally.

Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or
moisture. This material in its finely divided form presents an explosion hazard. Follow NFPA 654 (for chemical dusts) or
484 (for metal dusts) as appropriate for managing dust hazards to minimize secondary explosion potential.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits

CAS Number Component Name Exposure Limits

1185-55-3 Methyltrimethoxysilane Dow Corning guide: TWA 50 ppm.

See methyl alcohol comments.

Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV-skin: TWA 200 ppm, STEL 250 ppm.

Engineering Controls

Local Ventilation: Recommended.

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General Ventilation: Recommended.

Personal Protective Equipment for Routine Handling

Eyes: Use proper protection - safety glasses as a minimum.

Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as
soon as possible and thoroughly flush affected areas with cool water. Chemical protective
gloves are recommended.

Suitable Gloves: Avoid skin contact by implementing good industrial hygiene practices and procedures. Select
and use gloves and/or protective clothing to further minimize the potential for skin contact.
Consult with your glove and/or personnel protective equipment manufacturer for selection of
appropriate compatible materials.

Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.

Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below
recommended limits. Where concentrations are above recommended limits or are unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29
CFR 1910.134) and use NIOSH/MSHA approved respirators.

Personal Protective Equipment for Spills

Eyes: Use full face respirator.

Skin: Wash at mealtime and end of shift. If skin contact occurs, change contaminated clothing as
soon as possible and thoroughly flush affected areas with cool water. Chemical protective
gloves are recommended.

Inhalation/Suitable Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
Respirator: 1910.134) and use NIOSH/MHSA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide adequate
protection.

Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep
container closed. Do not take internally. Use reasonable care.
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Comments: Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air-supplied or
self-contained breathing apparatus.

When heated to temperatures above 180 degrees C in the presence of air, product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard, a known skin and
respiratory sensitizer, and an irritant to the eyes, nose, throat, skin, and digestive system.
Safe handling conditions may be maintained by keeping vapor concentrations within the
OSHA Permissible Exposure Limit for formaldehyde.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require
added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Paste

Color: Translucent white
Odor: Slight odor
Specific Gravity @ 25°C: 1.12
Viscosity: Not determined.
Freezing/Melting Point: Not determined.
Boiling Point: Not determined.
Vapor Pressure @ 25°C: Not determined.
Vapor Density: Not determined.
Solubility in Water: Not determined.
pH: Not determined.
Volatile Content: Not determined.
Flash Point: Not applicable.
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.

10. STABILITY AND REACTIVITY

Chemical Stability: Stable.

Hazardous Hazardous polymerization will not occur.

Polymerization:
Conditions to Avoid: None.

Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.

Hazardous Decomposition Products

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Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde. Metal
oxides. Nitrogen oxides.

11. TOXICOLOGICAL INFORMATION

Acute Toxicology Data for Product

Species Test Results

Dermal LD50: Rabbit > 2,000 mg/kg

Component Toxicology Information

Octamethylcyclotetrasiloxane administered to rats by inhalation at concentrations of 500 and 700 ppm resulted in
statistically significant decreases in the number of pups born and the live litter size in both the first and second
generations. Prolonged estrous cycles, and decreased mating and fertility indices were observed following 700 ppm
exposure in the second generation only. There were also increases in the incidence of deliveries of offspring extending
over an unusually long time period (dystocia).

Results from a 2 year repeated vapour inhalation exposure study to rats of octamethylcyclotetrasiloxane (D4) indicate
effects (benign uterine adenomas) in the uterus of female animals. This finding occurred at the highest exposure dose
(700 ppm) only.

Studies to date have not demonstrated if these effects occur through pathways that are relevant to humans.

Based on the available information on its potential to cause harm to human health, Health Canada, in a 2008 screening
assessment, has concluded that octamethylcyclotetrasiloxane is not entering the environment in a quantity or
concentration or under conditions that constitute or may constitute a danger in Canada to human life or health
(http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_556-67-2.cfm).

Repeated exposure in rats to D4 resulted in what appears to be protoporphyrin accumulation in the liver. Without
knowledge of the specific mechanism leading to the protoporphyrin accumulation the relevance of this finding to humans
is unknown.

This material contains methyltrimethoxysilane (MTMS). MTMS was evaluated in a combined repeated-dose toxicity study
with the reproduction/developmental toxicity screening test (OECD 422). Sprague-Dawley rats were gavaged daily at
dose levels of 0, 50, 250, and 1000 mg MTMS (in corn oil)/kg body weight. Test article-related effects were seen in one or
both sexes at the two top dose levels (unless otherwise noted) and included (but not limited to): increased liver weights;
increased incidence of hyperplasia and/or hypertrophy in the liver, thyroid and adrenals (high dose only); acanthocytosis
(high dose only); increased prothrombin time; elevations in blood platelet count (high dose only), serum total protein and
cholesterol. The no observed adverse effect level (NOAEL) was determined to be 50 mg/kg/day for parental toxicity and
1000 mg/kg/day for effects on reproductive performance and on developmental toxicity.

In a 90-day study, five (5) groups of 10 male and 10 female Sprague-Dawley rats were exposed to target
methyltrimethoxysilane concentrations of 0 (control), 25, 100, 400 and 1600 ppm for groups 1 through 5, respectively, for
six hours per day, five days per week. Additional satellite groups of 10 males and 10 females were included in the 0 and
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1600 ppm exposure groups for evaluation of a 28-day post-exposure recovery period. Based on the grossly observed
urinary bladder calculi and kidney dilation at the 400 and 1600 ppm exposure levels, the No Observable Effect Level
(NOEL) for methyltrimethoxysilane was 100 ppm.

This material may liberate methanol upon exposure to moisture or humid air. Overexposure to methanol can result in
blindness and nervous system effects.

Special Hazard Information on Components

Sensitizers

CAS Number Wt % Component Name

1185-55-3 5.0 - 10.0 Methyltrimethoxysilane Possible skin sensitizer.

12. ECOLOGICAL INFORMATION

Environmental Fate and Distribution

Complete information is not yet available.

Environmental Effects

Complete information is not yet available.

Fate and Effects in Waste Water Treatment Plants

Complete information is not yet available.

Ecotoxicity Classification Criteria

Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.

This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.

13. DISPOSAL CONSIDERATIONS

RCRA Hazard Class (40 CFR 261)

When a decision is made to discard this material, as received, is it classified as a hazardous waste? No

State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional
information is required.
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14. TRANSPORT INFORMATION

DOT Road Shipment Information (49 CFR 172.101)

Not subject to DOT.

Ocean Shipment (IMDG)

Not subject to IMDG code.

Air Shipment (IATA)

Not subject to IATA regulations.

Call Dow Corning Transportation, (989) 496-8577, if additional information is required.

15. REGULATORY INFORMATION

Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.

TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings

Section 302 Extremely Hazardous Substances (40 CFR 355):

None.

Section 304 CERCLA Hazardous Substances (40 CFR 302):

None.

Section 311/312 Hazard Class (40 CFR 370):

Acute: Yes
Chronic: Yes
Fire: No
Pressure: No
Reactive: No

Section 313 Toxic Chemicals (40 CFR 372):

None present or none present in regulated quantities.

Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.

Supplemental State Compliance Information

California
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Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.

CAS Number Wt % Component Name

67-56-1 <0.1000 Methyl alcohol Developmental toxin.

New Jersey

CAS Number Wt % Component Name

70131-67-8 55.0 - 75.0 Dimethyl siloxane, hydroxy-terminated

68909-20-6 15.0 - 35.0 Trimethylated silica

1185-55-3 5.0 - 10.0 Methyltrimethoxysilane

67-56-1 <0.1 Methyl alcohol

Pennsylvania

CAS Number Wt % Component Name

70131-67-8 55.0 - 75.0 Dimethyl siloxane, hydroxy-terminated

68909-20-6 15.0 - 35.0 Trimethylated silica

1185-55-3 5.0 - 10.0 Methyltrimethoxysilane

16. OTHER INFORMATION

Prepared by: Dow Corning Corporation

These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.

(R) indicates Registered Trademark